CN105696355A - Cinnamon oil containing adjuvant for textiles and preparation method and application thereof - Google Patents
Cinnamon oil containing adjuvant for textiles and preparation method and application thereof Download PDFInfo
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- CN105696355A CN105696355A CN201610166331.1A CN201610166331A CN105696355A CN 105696355 A CN105696355 A CN 105696355A CN 201610166331 A CN201610166331 A CN 201610166331A CN 105696355 A CN105696355 A CN 105696355A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/13—Unsaturated aldehydes, e.g. acrolein; Unsaturated ketones; Ketenes ; Diketenes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a cinnamon oil containing adjuvant for textiles and a preparation method and application thereof. The adjuvant contains cinnamon oil microcapsules, cinnamon oil, a nonionic emulsifier, an anionic thickener, a polyurethane binder and deionized water. The preparation method comprises the steps of firstly, preparing the cinnamon oil microcapsules, then, adding the prepared cinnamon oil microcapsules into an aqueous solution of the cinnamon oil and the nonionic emulsifier, and finally, mixing the cinnamon oil microcapsule added aqueous solution with an aqueous solution of the anionic thickener and the polyurethane binder, thereby obtaining the cinnamon oil containing adjuvant. According to the adjuvant provided by the invention, the cinnamon oil and the cinnamon oil microcapsules are simultaneously added, the retention time of effective ingredients of the cinnamon oil can be prolonged under the protection of capsule walls, and the functional effect is prolonged, so that the optimal use effect of shell fabrics is guaranteed.
Description
Technical field
The invention belongs to textile auxiliary agent technical field, be specifically related to a kind of textile auxiliary agent containing Oleum Cinnamomi and its preparation method and application。
Background technology
Mosquito is a kind of main vector, is listed in one of four pests, and it can propagate the infectious disease such as malaria, epidemic encephalitis type B, dengue fever, yellow fever, brings inconvenience to people's life。Repellant refers to certain abnormal smells from the patient that can naturally volatilize so that insecticide smell after produce repellent and dare not be close chemical substance。Repellant itself is without insecticidal action, but human or animal can be avoided from insect infestation, effectively prevents infectious disease from occurring。
Anophelifuge conventional in current weaving chemicals auxiliary agent is mainly to synthesize repellant, most popular is diethyltoluamide [DEET, N, N-diethyl-3-methyl benzamide], Yi Moning [3-(N-normal-butyl acetylamino)-ethyl propionate], Permethrin or pyrethrin etc., but in recent years more researcher prove synthesis chemosynthesis repellant its to environment, people, animal safety can produce serious threat。Therefore natural harmless raw material is widely studied。
Oleum Cinnamomi, also known as cassia oil, it is mainly composed of cinnamic aldehyde, is the plants essential oil of a kind of pure natural。Known its when low concentration, for the effect that antibacterial, fungus, microorganism etc. have repellent, kill, when its quintessence oil consumption is 5 μ L, to the scattering ratio of Aedes albopictus up to 87.5%, the quintessence oil of other similar functions certainly composite can effectively promote repelling effect。And it is less to human toxicity, do not result in secondary pollution, therefore there is wide DEVELOPMENT PROSPECT。But owing to Oleum Cinnamomi itself has a volatility, and light resistance and thermostability unstable, its pharmacological action can be produced certain negative effect, it is not possible to directly use to textile, not only not reach the effect of its script, and can also affect on product quality。
Therefore, how effective exploitation and utilize me also to have and use it on textile, become technical problem urgently to be resolved hurrily at present。
Summary of the invention
Solve the technical problem that: it is an object of the invention to overcome the deficiencies in the prior art to provide a kind of textile auxiliary agent containing Oleum Cinnamomi and its preparation method and application, this auxiliary agent can effectively solve the problem that Oleum Cinnamomi abnormal smells from the patient is big, volatile, and fast light and thermally labile shortcoming, and possess good anophelifuge, fungistatic effect。
Technical scheme:
A kind of textile auxiliary agent containing Oleum Cinnamomi, includes with parts by weight: Oleum Cinnamomi microcapsule 5-20 part, Oleum Cinnamomi 5-10 part, nonionic emulsifier 1-20 part, anion thickener 1-5 part, polyurethane binder 5-10 part, deionized water 30-50 part。
Further, described auxiliary agent also includes at least one in Indian oil of verbena 1-5 part, Herba Schizonepetae oil 1-5 part or Oleum menthae 1-5 part with parts by weight。
Further, the HLB value of described nonionic emulsifier is 8.5-14.5。
Further, described auxiliary agent also includes KF88 preservative 0.1-0.2 part and organosilicon emulsion-type defoamer 0.01-0.02 part with parts by weight。
The preparation method of the described textile auxiliary agent containing Oleum Cinnamomi, comprises the following steps:
Step 1, prepares Oleum Cinnamomi microcapsule；
Step 2, adds to Oleum Cinnamomi and carries out in nonionic emulsifier shearing dispersion, add the deionized water of 1/3-2/3 amount, obtain solution A；
Step 3, adds step 1 gained Oleum Cinnamomi microcapsule in step 2 gained solution A, stirring, obtains solution B；
Step 4, adds to anion thickener, polyurethane binder in remaining deionized water, obtains solution C；
Step 5, mixes step 3 gained solution B with step 4 gained solution C, stirring, standing, to obtain final product。
Further, in step 1, the preparation method of Oleum Cinnamomi microcapsule is: added by Oleum Cinnamomi in the mixed aqueous solution of arabic gum and modification of chitosan, and stirring, spray drying to obtain final product；Wherein, the mass ratio of Oleum Cinnamomi and mixed aqueous solution is 1:4-10, and in mixed aqueous solution, arabic gum is 3-5% with the mass fraction of modification of chitosan, and in mixed aqueous solution, arabic gum is 1:1 with the mass ratio of modification of chitosan。
Further, described modification of chitosan is at least one in chitosan hydrochlorate, chitosan nitrate or Chitosan citrate.。
Further, Oleum Cinnamomi first mix with at least one in Indian oil of verbena, Herba Schizonepetae oil or Oleum menthae by step 2, then add to nonionic emulsifier to carry out shear and disperse。
Further, step 4 also needs to add preservative and defoamer。
The application of the textile auxiliary agent containing Oleum Cinnamomi, is add in fabric Final finishing working solution by the textile auxiliary agent containing Oleum Cinnamomi described in claim 1, fabric in working solution through heat treatment。
Beneficial effect:
Compared with prior art, it has the great advantage that first to the present invention, adopts emulsifying process, is dissolved in emulsifying agent by Oleum Cinnamomi, and face liber is had good affinity and assimilation effect by the auxiliary agent obtained；Second, it is simultaneously introduced Oleum Cinnamomi and Oleum Cinnamomi microcapsule, makes the retention time of Oleum Cinnamomi effective ingredient increase under the protection of cyst wall, its functional effect extends, it is ensured that the best result of use of fabric；3rd, emulsifying agent can add one or more quintessence oils, the non-oxidizability of quintessence oil itself can be improved, also can improve the storage stability of auxiliary agent, it is to avoid the layering caused due to action of gravity for a long time；4th, manufacture method is simple, it is easy to realize。
Detailed description of the invention
Below by detailed description of the invention, the present invention is described in further detail。It will be apparent, however, to one skilled in the art, that the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention。Unreceipted concrete technology or condition person in embodiment, technology described by the document in this area or condition (such as with reference to Zhao Tao " dyeing and finishing technology and the principle " write, China Textiles Press, 2009) or carry out according to product description。Agents useful for same or the unreceipted production firm person of instrument, be can pass through city available from conventional products。
Textile auxiliary agent containing Oleum Cinnamomi provided by the invention, includes with parts by weight: Oleum Cinnamomi microcapsule 5-20 part, Oleum Cinnamomi 5-10 part, nonionic emulsifier 1-20 part, anion thickener 1-5 part, polyurethane binder 5-10 part, deionized water 30-50 part。
Wherein, Oleum Cinnamomi microcapsule is to be added by Oleum Cinnamomi in the aqueous solution of arabic gum and modification of chitosan, and stirring, spray drying to obtain final product。There is the protection of microcapsule wall material, the impact of temperature or moisture can be not easily susceptible to being diffused in air by the effective ingredient effectively maintained in Oleum Cinnamomi, thus ensureing the stability of its function。Wherein, modification of chitosan is at least one in chitosan hydrochlorate, chitosan nitrate, Chitosan citrate.。
In above-mentioned auxiliary agent, Oleum Cinnamomi, after the emulsifying of emulsifying agent, makes the emulsion being cellulose fibre or chemical fibre all have affinity and energy uniform pickup, it is ensured that after arrangement, fabric also can play repelling effect not by External Force Acting time。The present invention selects nonionic emulsifier, and HLB value is 8.5-14.5, RHLB is the requirements of oil emulsion phase time, as HLB=RHLB, effect is best, oil-in-water system (RHLB is 8.0-18.0), oil phase HLB in the present invention between 8.5-14.5, optimal stability。Nonionic emulsifier can select span 20 (purchased from Zibo Hai Jie Chemical Co., Ltd.), polysorbate85 (purchased from Zibo Hai Jie Chemical Co., Ltd.), alkylphenol polyoxyethylene-4 (purchased from Zibo Hai Jie Chemical Co., Ltd.)。
Thickening agent has increase system viscosity effect, selects anion thickener such as CMC, while thickening power, without affecting product water dissolubility。
Binding agent has the effect that raising auxiliary agent is combined with fiber, repeatedly remains to be combined with fiber effect preferably after washing, can be selected for polyurethane binder, and bonding strength is high, and good with the adjuvant system compatibility, and auxiliary agent storage is not produced counter productive。
The auxiliary agent of the present invention can also also include at least one in Indian oil of verbena, Herba Schizonepetae oil or Oleum menthae。These quintessence oils can play the effect of uniform dissolution Oleum Cinnamomi, finds by repeatedly implementing contrast, and the quintessence oil adopting multiple pharmacology similar is composite, can effectively promote beneficial effect, thus reaching optimum efficiency, and make up folk prescription quintessence oil defects more that may be present, such as volatility, abnormal smells from the patient, color etc.；Adopt pure natural plant source quintessence oil, the relatively quintessence oil of synthetic, there is advantages such as having no side effect, safety is relieved。
Auxiliary agent of the present invention can also include preservative and defoamer。Wherein, preservative can select KF88 preservative, and defoamer can be selected from organosilicon emulsion-type defoamer。KF88 broad-spectrum high efficacy, superpower sterilizing and bacteriostasis efficacy, organosilicon emulsion-type defoamer, consumption is few, effective, is suitable for textile auxiliary agent froth breaking。
Embodiment 1
(1) the textile auxiliary agent containing Oleum Cinnamomi, includes with parts by weight:
Oleum Cinnamomi microcapsule 20 parts, Oleum Cinnamomi 10 parts, span 20 5 parts, polysorbate85 5 parts, alkylphenol polyoxyethylene-410 parts, thickening agent CMC10 part, polyurethane binder 10 parts, deionized water 50 parts。
(2) preparation method of the textile auxiliary agent containing Oleum Cinnamomi, comprises the following steps:
Step 1, joins Oleum Cinnamomi in the arabic gum and chitosan mixed nitrate aqueous solution that mass fraction is 3%, and the mass ratio of Oleum Cinnamomi and mixed aqueous solution is 1:4, and in mixed aqueous solution, arabic gum is 1:1 with the mass ratio of chitosan nitrate。Abundant shear agitation, obtains mixture, then uses nebulization, dries for 140 DEG C, collects and obtains Oleum Cinnamomi microscapsule powder；
Step 2, by Oleum Cinnamomi 5 parts, add mix span 20, polysorbate85, in alkylphenol polyoxyethylene-4 mixture, use high-speed shearing machine to carry out emulsion dispersion, shear time 30min, be subsequently adding the deionized water of 1/3 amount, continue stirring 30min, obtain solution A；
Step 3, takes Oleum Cinnamomi microscapsule powder and joins in solution A, be uniformly mixing to obtain solution B；
Step 4, by thickening agent CMC, polyurethane binder, adds remaining deionized water for stirring 30min, obtains solution C；
Step 5, stirs solution B and solution C, after standing and get final product。
(3) the material treatment method of the textile auxiliary agent containing Oleum Cinnamomi
With fabric for cotton C40*C40/144*76
Step 1, prepare fabric Final finishing working solution, wherein add above-mentioned preparation containing Oleum Cinnamomi auxiliary agent, addition is 30g/L, joins in forming machine material cylinder, stirs；
Step 2, forming machine temperature 140 DEG C, shaping time 60s, material treatment completes。
Embodiment 2
(1) the textile auxiliary agent containing Oleum Cinnamomi, includes with parts by weight:
Oleum Cinnamomi microcapsule 5 parts, Oleum Cinnamomi 5 parts, span 20 3 parts, polysorbate85 3 parts, alkylphenol polyoxyethylene-44 parts, thickening agent CMC5 part, polyurethane binder 5 parts, deionized water 30 parts, preservative 0.1 part, defoamer 0.01 part。
(2) preparation method of the textile auxiliary agent containing Oleum Cinnamomi, comprises the following steps:
Step 1, joins Oleum Cinnamomi in the arabic gum and chitosan hydrochlorate mixed aqueous solution that mass fraction is 3%, and the mass ratio of Oleum Cinnamomi and mixed aqueous solution is 1:4, and in mixed aqueous solution, arabic gum is 1:1 with the mass ratio of chitosan hydrochlorate。Abundant shear agitation, obtains mixture, then uses nebulization, dries for 140 DEG C, collects and obtains Oleum Cinnamomi microscapsule powder；
Step 2, by Oleum Cinnamomi 5 parts, add mix span 20, polysorbate85, in alkylphenol polyoxyethylene-4 mixture, use high-speed shearing machine to carry out emulsion dispersion, shear time 30min, be subsequently adding the deionized water of 1/2 amount, continue stirring 30min, obtain solution A；
Step 3, takes Oleum Cinnamomi microscapsule powder and joins in solution A, be uniformly mixing to obtain solution B；
Step 4, by thickening agent CMC, polyurethane binder, preservative, defoamer, adds remaining deionized water for stirring 30min, obtains solution C；
Step 5, stirs solution B and solution C, after standing and get final product。
(3) the material treatment method of the textile auxiliary agent containing Oleum Cinnamomi
Fabric is for cotton C60*C60/200*100
Step 1, prepare fabric Final finishing working solution, wherein add above-mentioned preparation containing Oleum Cinnamomi auxiliary agent, addition is 10g/L, joins in forming machine material cylinder, stirs；
Step 2, forming machine temperature 150 DEG C, shaping time 60s, material treatment completes。
Embodiment 3
(1) the textile auxiliary agent containing Oleum Cinnamomi, includes with parts by weight:
Oleum Cinnamomi microcapsule 5 parts, Oleum Cinnamomi 10 parts, Indian oil of verbena 5 parts, Herba Schizonepetae oil 4 parts, Oleum menthae 1 part, span 20 5 parts, polysorbate85 5 parts, alkylphenol polyoxyethylene-410 parts, thickening agent CMC1 part, polyurethane binder 10 parts, preservative 0.2 part, defoamer 0.02 part, deionized water 50 parts。
(2) preparation method of the textile auxiliary agent containing Oleum Cinnamomi, comprises the following steps:
Step 1, Oleum Cinnamomi is joined in the arabic gum and Chitosan citrate. mixed aqueous solution that mass fraction is 5%, the mass ratio of Oleum Cinnamomi and mixed aqueous solution is 1:8, in mixed aqueous solution, arabic gum is 1:1 with the mass ratio of Chitosan citrate., abundant shear agitation, obtains mixture, then uses nebulization, dry for 140 DEG C, collect and obtain Oleum Cinnamomi microscapsule powder；
Step 2, by Oleum Cinnamomi 10 parts, Indian oil of verbena 5 parts, Herba Schizonepetae oil 4 parts, Oleum menthae 1 part compound oil be sufficiently mixed, add mix span 20, polysorbate85, in alkylphenol polyoxyethylene-4 mixture, high-speed shearing machine is used to carry out emulsion dispersion, shear time 30min, it is subsequently adding the deionized water of 2/3 amount, continues stirring 30min, obtain solution A；
Step 3, Oleum Cinnamomi microscapsule powder adds in solution A, is uniformly mixing to obtain solution B；
Step 4, adds thickening agent, binding agent, preservative and defoamer residue deionized water for stirring 30min, obtains solution C；
Step 5, stirs solution B and solution C, after standing and get final product。
(3) the material treatment method of the textile auxiliary agent containing Oleum Cinnamomi
Fabric is for tencel 80*80/200*120
Step 1, prepare fabric Final finishing working solution, wherein add above-mentioned preparation containing Oleum Cinnamomi auxiliary agent, addition is 5g/L, joins in forming machine material cylinder, stirs；
Step 2, forming machine temperature 140 DEG C, shaping time 60s, material treatment completes。
Reference examples 1
The present embodiment and embodiment 2 are distinctive in that: do not include Oleum Cinnamomi in auxiliary agent。
(1) the textile auxiliary agent containing Oleum Cinnamomi, includes with parts by weight:
Oleum Cinnamomi microcapsule 5 parts, span 20 3 parts, polysorbate85 3 parts, alkylphenol polyoxyethylene-44 parts, thickening agent CMC5 part, polyurethane binder 5 parts, deionized water 30 parts, preservative 0.1 part, defoamer 0.01 part。
(2) preparation method of the textile auxiliary agent containing Oleum Cinnamomi, comprises the following steps:
Step 1, Oleum Cinnamomi is joined in the arabic gum and chitosan hydrochlorate mixed aqueous solution that mass fraction is 3%, the mass ratio of Oleum Cinnamomi and mixed aqueous solution is 1:4, in mixed aqueous solution, arabic gum is 1:1 with the mass ratio of chitosan hydrochlorate, abundant shear agitation, obtains mixture, then uses nebulization, dry for 140 DEG C, collect and obtain Oleum Cinnamomi microscapsule powder；
Step 2, the Oleum Cinnamomi microcapsule 5 parts that step 1 is prepared, add mix span 20, polysorbate85, in alkylphenol polyoxyethylene-4 mixture, use high-speed shearing machine to carry out emulsion dispersion, shear time 30min, be subsequently adding the deionized water of 1/2 amount, continue stirring 30min, obtain solution A；
Step 3, takes Oleum Cinnamomi microscapsule powder and joins in solution A, be uniformly mixing to obtain solution B；
Step 4, by thickening agent CMC, polyurethane binder, preservative and defoamer, adds remaining deionized water for stirring 30min, obtains solution C；
Step 5, mixes solution B with solution C, adds preservative, defoamer, after standing and get final product。
(3) the material treatment method of the textile auxiliary agent containing Oleum Cinnamomi
Step 1, prepare fabric Final finishing working solution, wherein add above-mentioned preparation containing Oleum Cinnamomi auxiliary agent, addition is 10g/L, joins in forming machine material cylinder, stirs；
Step 2, forming machine temperature 150 DEG C, shaping time 60s, material treatment completes。
Reference examples 2
The present embodiment and embodiment 2 are distinctive in that: do not include Oleum Cinnamomi microcapsule in auxiliary agent。
(1) the textile auxiliary agent containing Oleum Cinnamomi, includes with parts by weight:
Oleum Cinnamomi 5 parts, span 20 3 parts, polysorbate85 3 parts, alkylphenol polyoxyethylene-44 parts, thickening agent CMC5 part, polyurethane binder 5 parts, deionized water 30 parts。
(2) preparation method of the textile auxiliary agent containing Oleum Cinnamomi, comprises the following steps:
Step 1, by Oleum Cinnamomi 5 parts, add mix span 20, polysorbate85, in alkylphenol polyoxyethylene-4 mixture, use high-speed shearing machine to carry out emulsion dispersion, shear time 30min, be subsequently adding the deionized water of 1/2 amount, continue stirring 30min, obtain solution A；
Step 2, adds thickening agent 5 parts, binding agent 5 parts, preservative and defoamer in the solution A that step 1 prepares, adds residue deionized water for stirring 30min, obtain solution B；
Step 3, in the solution B prepare step 3, adds preservative, defoamer, after standing and get final product。
(3) the material treatment method of the textile auxiliary agent containing Oleum Cinnamomi
Step 1, prepare fabric Final finishing working solution, wherein add above-mentioned preparation containing Oleum Cinnamomi auxiliary agent, addition is 10g/L, joins in forming machine material cylinder, stirs；
Step 2, forming machine temperature 150 DEG C, shaping time 60s, material treatment completes。
Above-described embodiment gained auxiliary agent and fabric are carried out performance test, and result is as follows:
As seen from the above table, the auxiliary agent of the present invention is simultaneously introduced Oleum Cinnamomi and Oleum Cinnamomi microcapsule, makes the retention time of Oleum Cinnamomi effective ingredient increase under the protection of cyst wall, and its functional effect extends, it is ensured that the best result of use of fabric。
Claims (10)
1. the textile auxiliary agent containing Oleum Cinnamomi, it is characterised in that: include with parts by weight: Oleum Cinnamomi microcapsule 5-20 part, Oleum Cinnamomi 5-10 part, nonionic emulsifier 1-20 part, anion thickener 1-5 part, polyurethane binder 5-10 part, deionized water 30-50 part。
2. the textile auxiliary agent containing Oleum Cinnamomi according to claim 1, it is characterised in that: with parts by weight, also include at least one in Indian oil of verbena 1-5 part, Herba Schizonepetae oil 1-5 part or Oleum menthae 1-5 part。
3. the textile auxiliary agent containing Oleum Cinnamomi according to claim 1, it is characterised in that: the HLB value of described nonionic emulsifier is 8.5-14.5。
4. the textile auxiliary agent containing Oleum Cinnamomi according to claim 1, it is characterised in that: with parts by weight, also include KF88 preservative 0.1-0.2 part and organosilicon emulsion-type defoamer 0.01-0.02 part。
5. the preparation method of the textile auxiliary agent containing Oleum Cinnamomi described in claim 1, it is characterised in that: comprise the following steps:
Step 1, prepares Oleum Cinnamomi microcapsule；
Step 2, adds to Oleum Cinnamomi and carries out in nonionic emulsifier shearing dispersion, add the deionized water of 1/3-2/3 amount, obtain solution A；
Step 3, adds step 1 gained Oleum Cinnamomi microcapsule in step 2 gained solution A, stirring, obtains solution B；
Step 4, adds to anion thickener, polyurethane binder in remaining deionized water, obtains solution C；
Step 5, mixes step 3 gained solution B with step 4 gained solution C, stirring, standing, to obtain final product。
6. the preparation method of the textile auxiliary agent containing Oleum Cinnamomi according to claim 5, it is characterized in that: in step 1, the preparation method of Oleum Cinnamomi microcapsule is: Oleum Cinnamomi is added in the mixed aqueous solution of arabic gum and modification of chitosan, stirring, spray drying, to obtain final product；Wherein, the mass ratio of Oleum Cinnamomi and mixed aqueous solution is 1:4-10, and in mixed aqueous solution, arabic gum is 3-5% with the mass fraction of modification of chitosan, and in mixed aqueous solution, arabic gum is 1:1 with the mass ratio of modification of chitosan。
7. the preparation method of the textile auxiliary agent containing Oleum Cinnamomi according to claim 6, it is characterised in that: described modification of chitosan is at least one in chitosan hydrochlorate, chitosan nitrate or Chitosan citrate.。
8. the preparation method of the textile auxiliary agent containing Oleum Cinnamomi according to claim 5, it is characterised in that: Oleum Cinnamomi first mix with at least one in Indian oil of verbena, Herba Schizonepetae oil or Oleum menthae by step 2, then adds to nonionic emulsifier to carry out shear and disperse。
9. the preparation method of the textile auxiliary agent containing Oleum Cinnamomi according to claim 5, it is characterised in that: step 4 also needs to add preservative and defoamer。
10. the application of the textile auxiliary agent containing Oleum Cinnamomi described in claim 1, it is characterised in that: first the textile auxiliary agent containing Oleum Cinnamomi described in claim 1 is added in fabric Final finishing working solution, then by fabric in working solution through heat treatment。
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Cited By (1)
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| CN110396861A (en) * | 2019-07-08 | 2019-11-01 | 天津科技大学 | A kind of preparation method of microencapsulation fire retardant |
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| CN103437192A (en) * | 2013-08-13 | 2013-12-11 | 江苏金太阳纺织科技有限公司 | Preparation method and application of pure-natural fragrant microcapsule textile finishing agent |
| CN103541227A (en) * | 2013-09-10 | 2014-01-29 | 上海应用技术学院 | Natural essential oil aromatic finishing agent for real silk fabrics and preparation method thereof |
| CN104250927A (en) * | 2014-06-09 | 2014-12-31 | 浙江纺织服装科技有限公司 | Wrinkle resistant and shrink proof mugwort microcapsule finishing agent for fabric and preparation method thereof |
| CN104532596A (en) * | 2014-12-30 | 2015-04-22 | 华南农业大学 | Cinnamon oil microcapsule fabric finishing liquid as well as preparation method and application thereof |
| CN104975513A (en) * | 2015-05-29 | 2015-10-14 | 天津城建大学 | Efficient antibacterial chitosan essential oil microcapsule preparation method |
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