CN105442330A - Care agent containing cinnamon oil microcapsules and preparation method of care agent - Google Patents
Care agent containing cinnamon oil microcapsules and preparation method of care agent Download PDFInfo
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- CN105442330A CN105442330A CN201510992877.8A CN201510992877A CN105442330A CN 105442330 A CN105442330 A CN 105442330A CN 201510992877 A CN201510992877 A CN 201510992877A CN 105442330 A CN105442330 A CN 105442330A
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- cinnamon oil
- care agent
- oil microcapsules
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- agent containing
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
The invention provides a care agent containing cinnamon oil microcapsules and a preparation method of the care agent. The care agent comprises nonylphenol polyoxyethylene ether, cinnamon oilmicrocapsules, distearate, a softening agent, apreservativeand deionized water. The preparation method comprises the following steps: firstly, purifying the cinnamon oil, preparing the purified cinnamon oil into microcapsules, then adding the microcapsules into nonylphenol polyoxyethylene ether, adding deionized water accounting for 1/2 of the total weight, stirring, then adding the softening agent and the preservative, and adjusting the pH value to 6.5-7.5 to obtain a mixed solution; and finally, mixing a prepared distearateaqueoussolution with the mixed solution, and performing defoaming to obtain the care agent. The care agent provided by the invention not only has an effect of softening and caring fabricsbut also has a capsule core material being a pure natural material, can achieve an antibacterial and anti-mite effect after fabric caring, and has no burden on a human body.
Description
Technical field
The invention belongs to household chemicals technical field, be specifically related to a kind of care agent containing cinnamon oil microcapsules and preparation method thereof.
Background technology
Textiles is requisite articles for use in people's daily life, but environment, the factor such as artificial can be subject to without the fabric that any specific function is protected, the hotbed becoming bacterium and increase with the microorganism of human body symbiosis, breed, as: acarid etc., also be subject to the long-term infringement of the dermatophagoides pteronyssinus coming from occurring in nature etc., cause various allergic symptom and disease, the safety of textiles has become the focus of consumer's common concern, so the functional requirements such as the anti-mite of antibacterial textile are more and more urgent, therefore research and development have very important value.
The anti-mite field of current antibacterial textile, a lot of material is employed, such as: quaternary ammonium compound, silver ion series antiseptic, macromolecular organic compound antiseptic, nitro compound, formaldehyde derivatives etc., but most of antiseptic not only can cause certain injury to human body, and great majority exist non-degradable, to the problem that environment impacts.So emphasis is transferred in the material research of natural Chinese herbal medicine and pure plant origin by some enterprises, colleges and universities in recent years, therefore green, safe antibiosis anti-acarien auxiliary agent becomes the focus of exploitation.
Cinnamon oil, also known as oil of bay, its main component is cinnamic acid, is a kind of plants essential oil of pure natural.Known its when low concentration, for the effect that bacterium, fungi, microorganism, mosquito etc. have repellent, kill, the cinnamon oil of 0.2% to the scattering ratio of the insects such as mite, kill 24h and can reach more than 90%, belong to and there is good anti-mite effect.And it is less to human toxicity, can not secondary pollution be caused, therefore there is wide DEVELOPMENT PROSPECT.
But due to the smell that cinnamon oil is special, become one of factor limiting its extensive use, itself there is stronger special odor, there is stronger volatility, and fast light and thermally labile, produces certain impact to its pharmacological action, directly uses on textiles, do not reach durable effective effect, thus can not be identified as a kind of antibiosis anti-acarien auxiliary agent of high-efficient and lasting.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and a kind of care agent containing cinnamon oil microcapsules and preparation method thereof is provided, it is large, volatile that this care agent can effectively solve cinnamon oil smell, and fast light and thermally labile shortcoming, and possess good antibiosis anti-acarien effect, also clothing is had to the effect of soft nursing simultaneously.
Containing a care agent for cinnamon oil microcapsules, comprise with parts by weight: polyoxyethylene nonylphenol ether 2-5 part, cinnamon oil microcapsules 2-10 part, distearate 0.5-3 part, softener 0.5-3 part, preservative agent 0.1-0.3 part, deionized water 20-50 part.
Further, described softener is anionic softener or nonionic silicone oil softener.
Further, described care agent also comprises 0.2-1.0 part sodium chloride with parts by weight.
The preparation method of the described care agent containing cinnamon oil microcapsules, comprises the following steps:
Step 1, cinnamon oil is purified;
Step 2, prepares cinnamon oil microcapsules;
Gained cinnamon oil microcapsules are added in polyoxyethylene nonylphenol ether by step 3, add 1/2 weight deionized water, stir, obtain solution A;
Step 4, adds in gained solution A by softener, preservative agent, regulates pH to 6.5-7.5, obtains solution B;
Step 5, adds distearate in residue deionized water, obtains solution C;
Step 6, mixes gained solution B with gained solution C, stirs, after froth breaking and get final product.
Further, the concrete grammar preparing cinnamon oil microcapsules in step 2 is: be added to by cinnamon oil in the mixed aqueous solution of Arabic gum and modification of chitosan, and the mass ratio of cinnamon oil and mixed aqueous solution is 1:4-10, fully stirs, gained solution is spray-dried, obtains cinnamon oil microscapsule powder.
Further, in described mixed aqueous solution, the total concentration of Arabic gum and modification of chitosan is 3-5%.
Further, described modification of chitosan is one or more the mixture in chitosan hydrochloride, shitosan nitrate or Chitosan citrate.
Further, the concrete grammar of step 5 be distearate is added to 40-60 DEG C deionized water for stirring to dissolving, stop heating up, then cooling naturally under stirring.
Further, sodium chloride can also be added in step 4.
Cinnamon oil very easily produces migration by temperature or moisture effects, and be directly organized in durability on fabric very poor, after being made into microcapsule product, owing to there being the protection of wall material, can guarantee that main effectiveness composition does not lose, specific function is not lost.Cinnamon oil has certain fragrance, acrid odors simultaneously; directly be organized on fabric; smell is directly received by human body; after making microcapsules, microcapsules effect is equivalent to layer protecting film; a shielding container; effectively can control the smell of product own, when microcapsules do not break, taste can not shed, and has slow release effect.
Care agent of the present invention has the effect of submissive nursing fabric, and core materials is natural material, can have the effect of antibiosis anti-acarien after completing fabric nursing, free of a burden to human body.
Detailed description of the invention
Below by detailed description of the invention, the present invention is described in further detail.But it will be understood to those of skill in the art that the following example only for illustration of the present invention, and should not be considered as limiting scope of the present invention.Unreceipted concrete technology or condition person in embodiment, according to the technology described by the document in this area or condition (such as with reference to " dyeing and finishing technology and principle " that Zhao Tao writes, China Textiles Press, 2009) or carry out according to product description.Agents useful for same or the unreceipted production firm person of instrument, being can by the conventional products of commercial acquisition.
Cinnamon oil derives from a kind of pure plant, can be antimycotic, is a kind of pure natural plant oil with antibiosis anti-acarien performance.Polyoxyethylene nonylphenol ether has excellent emulsifying capacity, plays W/O effect in body series, has peptizaiton to cinnamon oil microcapsules.Distearate thickening, emulsification, control viscosity, and thickening effect is good, makes finishing agent have good finishing effect.Silicone oil softener makes face liber submissive, possesses nursing efficacy, can reduce fibre damage in arrangement process simultaneously, protection fiber strength.Sodium chloride thickening, improves the ability of aggregation of ionic surface active agent.
Cinnamon oil is water-fast essential oil, Arabic gum has certain emulsifying effectiveness, modification of chitosan molecular weight is little, Arabic gum can be assisted to strengthen coated essential oil, effectively the spilling that essential oil is stressed or temperature is unstable and cause is reduced in spraying drying course, microcapsules rate is improved, and obtained microcapsules not only can ensure antibiosis anti-acarien effect, and essential oil can be prevented to be oxidized guaranteed quality.
Embodiment 1
Containing a care agent for cinnamon oil microcapsules, comprise with parts by weight:
Its preparation method comprises the following steps:
Step 1, is positioned over cinnamon oil to revolve and steams in bottle, revolves steaming temperature 20 DEG C of Rotary Evaporators temperature and vacuumizes decompression, suction-0.1MPa, evaporation time 30min, collect the cinnamon oil revolved in steaming bottle for subsequent use;
Step 2, by purify after cinnamon oil join mass fraction be 3% Arabic gum and chitosan hydrochloride mixed aqueous solution in, the mass ratio of cinnamon oil and mixed aqueous solution is 1:4, in mixed aqueous solution, the mass ratio of Arabic gum and chitosan hydrochloride is 1:1, abundant stirring, obtains mixture, then uses spray-on process, dry for 140 DEG C, collect and obtain cinnamon oil microscapsule powder;
Gained cinnamon oil microcapsules are added polyoxyethylene nonylphenol ether and disperse, add 1/2 parts by weight of deionized water, obtain solution A by step 3;
Step 4, nonionic silicone oil softener, preservative agent, sodium chloride add in solution A, regulate pH value to 7.0 to obtain solution B;
Step 5, deionized water for stirring distearate being added to 40-60 DEG C, to dissolving, stops heating up, then naturally cools under stirring, obtain solution C;
Step 6, mixes gained solution B with gained solution C, stirs, after froth breaking and get final product.
Embodiment 2
Containing a care agent for cinnamon oil microcapsules, comprise with parts by weight:
Its preparation method comprises the following steps:
Step 1, is positioned over cinnamon oil to revolve and steams in bottle, revolves steaming temperature 20 DEG C of Rotary Evaporators temperature and vacuumizes decompression, suction-0.1MPa, evaporation time 40min, collect the cinnamon oil revolved in steaming bottle for subsequent use;
Step 2, cinnamon oil is joined mass fraction be 4% Arabic gum, chitosan hydrochloride, in shitosan mixed nitrate aqueous solution, the mass ratio of cinnamon oil and mixed aqueous solution is 1:5, in mixed aqueous solution, the mass ratio of Arabic gum, chitosan hydrochloride, shitosan nitrate is 1:0.5:0.5, abundant stirring, obtains mixture, then uses spray-on process, dry for 160 DEG C, collect and obtain cinnamon oil microscapsule powder;
Gained cinnamon oil microcapsules are added polyoxyethylene nonylphenol ether and disperse by step 3, add 1/2 weight deionized water, obtain solution A;
Step 4, nonionic silicone oil softener, preservative agent add in solution A, regulate pH value to 7.0 to obtain solution B;
Step 5, deionized water for stirring distearate being added to 40-60 DEG C, to dissolving, stops heating up, then naturally cools under stirring, obtain solution C;
Step 6, mixes gained solution B with gained solution C, stirs, after froth breaking and get final product.
Embodiment 3
Containing a care agent for cinnamon oil microcapsules, comprise with parts by weight:
Its preparation method comprises the following steps:
Step 1, is positioned over cinnamon oil to revolve and steams in bottle, revolves steaming temperature 20 DEG C of Rotary Evaporators temperature and vacuumizes decompression, suction-0.1MPa, evaporation time 60min, collect the cinnamon oil revolved in steaming bottle for subsequent use;
Step 2, cinnamon oil is joined mass fraction be 5% Arabic gum, chitosan hydrochloride, shitosan nitrate, in Chitosan citrate mixed aqueous solution, the mass ratio of cinnamon oil and mixed aqueous solution is 1:8, in mixed aqueous solution, the mass ratio of Arabic gum, chitosan hydrochloride, shitosan nitrate, Chitosan citrate is 1:0.4:0.4:0.4, abundant stirring, obtains mixture, then uses spray-on process, dry for 160 DEG C, collect and obtain cinnamon oil microscapsule powder;
Gained cinnamon oil microcapsules are added polyoxyethylene nonylphenol ether and disperse by step 3, add 1/2 weight deionized water, obtain solution A;
Step 4, anionic softener, preservative agent add in solution A, regulate pH value to 7.0 to obtain solution B;
Step 5, deionized water for stirring distearate being added to 40-60 DEG C, to dissolving, stops heating up, then naturally cools under stirring, obtain solution C;
Step 6, mixes gained solution B with gained solution C, stirs, after froth breaking and get final product.
Get the room temperature clear water of certain volume, join in clear water by embodiment 1 to 3 gained care agent, addition is 10g/L, after mixing, is soaked wherein by fabric, soak time 3-5min, wrings out or airing after dewatering;
Detect: the evaluation part 2 of (1) anti-microbial property: absorption process
(2) the evaluation repellent method of anti-mite performance
| Blank sample | Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Anti-microbial property-bacteriostasis rate | 0％ | 99％ | 97％ | 99％ |
| Anti-mite performance-scattering ratio | 0％ | 90％ | 86％ | 87％ |
Note: bacteriostasis rate >=90%, sample has antibacterial effect; Bacteriostasis rate >=99%, sample has good antibacterial effect. scattering ratio >=60%, and sample has anti-mite effect; Scattering ratio >=80%, sample has stronger anti-mite effect; Scattering ratio >=95%, sample has extremely strong anti-mite effect.
Claims (9)
1., containing a care agent for cinnamon oil microcapsules, it is characterized in that: comprise with parts by weight: polyoxyethylene nonylphenol ether 2-5 part, cinnamon oil microcapsules 2-10 part, distearate 0.5-3 part, softener 0.5-3 part, preservative agent 0.1-0.3 part, deionized water 20-50 part.
2. the care agent containing cinnamon oil microcapsules according to claim 1, is characterized in that: described softener is anionic softener or nonionic silicone oil softener.
3. the care agent containing cinnamon oil microcapsules according to claim 1, is characterized in that: described care agent also comprises 0.2-1.0 part sodium chloride with parts by weight.
4. the preparation method of the care agent containing cinnamon oil microcapsules according to claim 1, is characterized in that: comprise the following steps:
Step 1, cinnamon oil is purified;
Step 2, prepares cinnamon oil microcapsules;
Gained cinnamon oil microcapsules are added in polyoxyethylene nonylphenol ether by step 3, add 1/2 weight deionized water, stir, obtain solution A;
Step 4, adds in gained solution A by softener, preservative agent, regulates pH to 6.5-7.5, obtains solution B;
Step 5, adds distearate in residue deionized water, obtains solution C;
Step 6, mixes gained solution B with gained solution C, stirs, after froth breaking and get final product.
5. the preparation method of the care agent containing cinnamon oil microcapsules according to claim 4, it is characterized in that: the concrete grammar preparing cinnamon oil microcapsules in step 2 is: cinnamon oil is added in the mixed aqueous solution of Arabic gum and modification of chitosan, the mass ratio of cinnamon oil and mixed aqueous solution is 1:4-10, abundant stirring, gained solution is spray-dried, obtains cinnamon oil microscapsule powder.
6. the preparation method of the care agent containing cinnamon oil microcapsules according to claim 5, is characterized in that: in described mixed aqueous solution, the total concentration of Arabic gum and modification of chitosan is 3-5%.
7. the preparation method of the care agent containing cinnamon oil microcapsules according to claim 5, is characterized in that: described modification of chitosan is one or more the mixture in chitosan hydrochloride, shitosan nitrate or Chitosan citrate.
8. the preparation method of the care agent containing cinnamon oil microcapsules according to claim 4, it is characterized in that: the concrete grammar of step 5 be distearate is added to 40-60 DEG C deionized water for stirring to dissolving, stop heating up, then naturally cool under stirring.
9. the preparation method of the care agent containing cinnamon oil microcapsules according to claim 4, is characterized in that: can also add sodium chloride in step 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510992877.8A CN105442330A (en) | 2015-12-25 | 2015-12-25 | Care agent containing cinnamon oil microcapsules and preparation method of care agent |
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| CN201510992877.8A CN105442330A (en) | 2015-12-25 | 2015-12-25 | Care agent containing cinnamon oil microcapsules and preparation method of care agent |
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| CN105442330A true CN105442330A (en) | 2016-03-30 |
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| CN201510992877.8A Pending CN105442330A (en) | 2015-12-25 | 2015-12-25 | Care agent containing cinnamon oil microcapsules and preparation method of care agent |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106811329A (en) * | 2016-12-08 | 2017-06-09 | 江苏金太阳纺织科技股份有限公司 | A kind of laundry sheet of antibiosis anti-acarien and preparation method thereof |
| CN112941651A (en) * | 2019-12-10 | 2021-06-11 | 上海美纤智能科技有限公司 | Mite-repelling textile |
| CN113278476A (en) * | 2021-05-26 | 2021-08-20 | 广州大白生物科技有限公司 | Water-soluble film-wrapped beadlets comprising cinnamon oil microcapsule film |
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| CN1427047A (en) * | 2001-12-19 | 2003-07-02 | 明基电通股份有限公司 | Ink composition using microencapsulated compound to provide fragrance |
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| CN104532596A (en) * | 2014-12-30 | 2015-04-22 | 华南农业大学 | Cinnamon oil microcapsule fabric finishing liquid as well as preparation method and application thereof |
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2015
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| CN1427047A (en) * | 2001-12-19 | 2003-07-02 | 明基电通股份有限公司 | Ink composition using microencapsulated compound to provide fragrance |
| CN101321906A (en) * | 2005-11-30 | 2008-12-10 | 考格尼斯知识产权管理有限责任公司 | Textiles finishing |
| CN104532596A (en) * | 2014-12-30 | 2015-04-22 | 华南农业大学 | Cinnamon oil microcapsule fabric finishing liquid as well as preparation method and application thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106811329A (en) * | 2016-12-08 | 2017-06-09 | 江苏金太阳纺织科技股份有限公司 | A kind of laundry sheet of antibiosis anti-acarien and preparation method thereof |
| CN106811329B (en) * | 2016-12-08 | 2019-07-09 | 江苏金太阳纺织科技股份有限公司 | A kind of laundry sheet of antibiosis anti-acarien and preparation method thereof |
| CN112941651A (en) * | 2019-12-10 | 2021-06-11 | 上海美纤智能科技有限公司 | Mite-repelling textile |
| CN113278476A (en) * | 2021-05-26 | 2021-08-20 | 广州大白生物科技有限公司 | Water-soluble film-wrapped beadlets comprising cinnamon oil microcapsule film |
| CN113278476B (en) * | 2021-05-26 | 2023-08-11 | 广州大白生物科技有限公司 | Water-soluble film-coated gel bead containing cinnamon oil microcapsule film |
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