CN104532595A - Mosquito-preventing and fly-repelling capsule finishing agent as well as preparation method and application thereof - Google Patents
Mosquito-preventing and fly-repelling capsule finishing agent as well as preparation method and application thereof Download PDFInfo
- Publication number
- CN104532595A CN104532595A CN201410773244.3A CN201410773244A CN104532595A CN 104532595 A CN104532595 A CN 104532595A CN 201410773244 A CN201410773244 A CN 201410773244A CN 104532595 A CN104532595 A CN 104532595A
- Authority
- CN
- China
- Prior art keywords
- mosquito
- fly
- proof
- proofly
- drives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a mosquito-preventing and fly-repelling capsule finishing agent. The mosquito-preventing and fly-repelling capsule finishing agent is prepared from the following components in percentage by mass: 15%-40% of a plant source mosquito-preventing and fly-repelling microcapsule, 5%-15% of aqueous polyurethane and the balance of deionized water, wherein the sum of all the components is 100%. The invention further discloses a preparation method of the mosquito-preventing and fly-repelling capsule finishing agent. The preparation method comprises the following implementation steps: step 1, preparing plant source mosquito-preventing and fly-repelling extracting liquid; step 2, preparing the plant source mosquito-preventing and fly-repelling micro-capsule from the plant source mosquito-preventing and fly-repelling extracting liquid in the step 1; and step 3, preparing the mosquito-preventing and fly-repelling capsule finishing agent by using the plant source mosquito-preventing and fly-repelling micro-capsule in the step 2. The invention further discloses a method for finishing a textile by using the finishing agent, and the problems that an existing mosquito-preventing and fly-repelling finishing technology has toxin and low mosquito-preventing rate are solved.
Description
Technical field
The invention belongs to textile technology field, relate to and a kind of mosquito-proofly drive fly finishing agent, be specifically related to a kind ofly mosquito-proofly drive fly microcapsule dressing agent.The invention still further relates to this mosquito-proof preparation method driving fly microcapsule dressing agent.Namely the application process that the invention still further relates to this finishing agent utilizes this mosquito-proof method of driving fly microcapsule dressing agent and arranging fabric.
Background technology
These years, along with the raising of expanding economy and people's living standard, people have higher requirement to the comfortableness of clothes and functional health.In summer, mosquitos and flies bothers work and the life of people, even threatens the health of the mankind, and mosquito-proof exploitation of driving fly functional textile has very high more practical value and open market prospects.Develop the mosquito-proof fly textiles that drives and mainly contain two kinds of methods, one is by preparing functional fiber material to obtain, and another kind obtains anti-mosquito function by Final finishing.Final finishing exploitation is taked mosquito-proofly to drive fly fabric at present, finishing agent is mostly chemical mosquito-proof fly-killing agent, it causes direct or potential harm to human body, certain pollution is caused to environment simultaneously, therefore, the exploitation of the mosquito-proof fly-killing agent of novel green is imperative, simultaneously, adopt prior art to textiles carry out mosquito-proof drive fly arrange, its poor effect, mosquito-proof fly functional layer of driving are not washable.
Summary of the invention
The object of this invention is to provide and a kind of mosquito-proofly drive fly microcapsule dressing agent, solve and existingly mosquito-proofly drive the low problem of toxic, the mosquito-proof rate of fly finishing technique.
The technical solution adopted in the present invention is, one is mosquito-proof drives fly microcapsule dressing agent, by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, all the other are deionized water, and the content sum of above each component is 100%.
Feature of the present invention is also,
Wherein, the mosquito-proof fly microcapsules that drive of plant source are prepared in accordance with the following methods:
Step 1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 ~ 400 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:2 ~ 4;
Step 2, the mosquito-proof fly plant mixture of driving taken in step 1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 ~ 5 hours, obtains raw material to be distilled;
Step 3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 ~ 90 DEG C of conditions, distillation extraction 2 ~ 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 4, fly extract is driven by mosquito-proof for the plant source obtained in step 3, be added drop-wise in gum arabic solution, wherein, the mass fraction of gum arabic solution is 2% ~ 6%, the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4 ~ 8, again mixed liquor is placed in emulsion reactor, under 2000r/min ~ 4000r/min rotating speed, emulsion is treated to through emulsification shear mixer, then gelatin solution is joined in above-mentioned emulsion and process 20 ~ 50min, wherein, the mass fraction of gelatin solution is 2% ~ 6%, the addition of gelatin solution is identical with the addition of gumwater, control temperature 30 ~ 60 DEG C, pH is 4.0 ~ 6.0, through time 10 ~ 30min, gelatin and gum Arabic are condensed, under the condition stirred, add deionized water, the quality of deionized water is 1:2 ~ 6 with the ratio of gelatin and Arabic gum mixed solution gross mass, regulation system temperature, to 10 ~ 25 DEG C, adds glutaraldehyde curing agent, wherein, the addition of glutaraldehyde curing agent accounts for 3% ~ 8% of whole mixed liquor quality, control pH is 8.0 ~ 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, drying, obtains and mosquito-proofly drives fly microcapsules.
Wherein, mosquito-proof fly plant mixture of driving consists of the following composition according to mass percent: cloves 10% ~ 20%, folium eucalypti 10% ~ 30%, peppermint 20% ~ 40%, wormwood 10% ~ 30% and tomato stem-leaf 20% ~ 50%, and each component content sum is 100%.
Another object of the present invention is to provide this mosquito-proof preparation method driving fly microcapsule dressing agent.
Another technical scheme of the present invention is, a kind of mosquito-proof preparation method driving fly microcapsule dressing agent, the mosquito-proof fly microcapsule dressing agent that drives consists of the following composition, plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, all the other are deionized water, and the content sum of above each component is 100%, and its preparation method is specifically implemented according to following steps:
Step 1, prepares that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules;
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent;
Feature of the present invention is also,
Wherein, step 1 is specifically implemented according to following steps:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 ~ 400 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:2 ~ 4;
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 ~ 5 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 ~ 90 DEG C of conditions, distillation extraction 2 ~ 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract.
Wherein, mosquito-proofly drive fly plant mixture, according to mass percent, cloves 10% ~ 20%, folium eucalypti 10% ~ 30%, peppermint 20% ~ 40%, wormwood 10% ~ 30% and tomato stem-leaf 20% ~ 50% form, each component total amount 100%.
Wherein, step 2 is specifically implemented according to following steps:
Step 2.1, drive fly extract by mosquito-proof for the plant source obtained in step 1, be added drop-wise in gum arabic solution, wherein, the mass fraction of gum arabic solution is 2% ~ 6%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4 ~ 8;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 2000r/min ~ 4000r/min rotating speed, emulsion is treated to through emulsification shear mixer, then gelatin solution is joined in above-mentioned emulsion and process 20 ~ 50min, wherein, the mass fraction of gelatin solution is 2% ~ 6%, the addition of gelatin solution is identical with the addition of gumwater, control temperature 30 ~ 60 DEG C, pH are 4.0 ~ 6.0, through time 10 ~ 30min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of deionized water is 1:2 ~ 6 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 10 ~ 25 DEG C;
Step 2.3, adds glutaraldehyde curing agent, wherein, the addition of glutaraldehyde curing agent accounts for 3% ~ 8% of whole mixed liquor quality, control pH is 8.0 ~ 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, drying, obtains and mosquito-proofly drives fly microcapsules.
Wherein, step 3, specifically implement according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 1 ~ 3 hour, then add deionized water and stirring 1 ~ 4 hour, obtained mosquito-proofly drive fly microcapsule dressing agent.
3rd object of the present invention is to provide this and mosquito-proofly drives the method that fly microcapsule dressing agent is applied to textile finishing.
3rd technical scheme of the present invention is, a kind of utilization mosquito-proofly drives the method that fly microcapsule dressing agent carries out textile finishing, specifically implements according to following steps:
Step a, the percentage accounting for the quality of fabric in finishing agent be 3 ~ 10% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:6 ~ 10;
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 50 ~ 80 DEG C, flood 40 ~ 80min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, completes the mosquito-proof of fabric and drives fly arrangement.
Feature of the present invention is also,
Wherein, the oven dry in step c be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 80 ~ 100 DEG C, and drying time is 20 ~ 30min; Cure be by dry after fabric be placed on the conveyer belt of heat setting machine, under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 150 ~ 180 DEG C, and the time of curing is 1 ~ 5min.
The invention has the beneficial effects as follows, the present invention adopts and naturally mosquito-proofly drives fly repellant, utilizes Micro-Encapsulation Technique, is obtained mosquito-proofly drive fly fabric by Final finishing, its low toxicity or nontoxic, can not produce burning heat sensation to skin, smell is pure and fresh, does not have residue of drug effect after using, easy degraded, non-environmental-pollutions etc., the use of microcapsules technology in the present invention simultaneously, improves the lasting of mosquito repellent fly effect and washing fastness etc.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is described in detail.
The present invention's one is mosquito-proof drives fly microcapsule dressing agent, and by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, and all the other are deionized water, the content sum of above each component is 100%.
Wherein, the mosquito-proof fly microcapsules that drive of plant source are prepared in accordance with the following methods:
Step 1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 ~ 400 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:2 ~ 4;
Wherein, mosquito-proof fly plant mixture of driving consists of the following composition according to mass percent: cloves 10% ~ 20%, folium eucalypti 10% ~ 30%, peppermint 20% ~ 40%, wormwood 10% ~ 30% and tomato stem-leaf 20% ~ 50%, and each component content sum is 100%.
Step 2, the mosquito-proof fly plant mixture of driving taken in step 1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 ~ 5 hours, obtains raw material to be distilled;
Step 3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 ~ 90 DEG C of conditions, distillation extraction 2 ~ 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 4, fly extract is driven by mosquito-proof for the plant source obtained in step 3, be added drop-wise in gum arabic solution, wherein, the mass fraction of gum arabic solution is 2% ~ 6%, the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4 ~ 8, again mixed liquor is placed in emulsion reactor, under 2000r/min ~ 4000r/min rotating speed, emulsion is treated to through emulsification shear mixer, then gelatin solution is joined in above-mentioned emulsion and process 20 ~ 50min, wherein, the mass fraction of gelatin solution is 2% ~ 6%, the addition of gelatin solution is identical with the addition of gumwater, control temperature 30 ~ 60 DEG C, pH is 4.0 ~ 6.0, through time 10 ~ 30min, gelatin and gum Arabic are condensed, under the condition stirred, add deionized water, the quality of deionized water is 1:2 ~ 6 with the ratio of gelatin and Arabic gum mixed solution gross mass, regulation system temperature, to 10 ~ 25 DEG C, adds glutaraldehyde curing agent, wherein, the addition of glutaraldehyde curing agent accounts for 3% ~ 8% of whole mixed liquor quality, control pH is 8.0 ~ 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, drying, obtains and mosquito-proofly drives fly microcapsules.
A kind of mosquito-proof preparation method driving fly microcapsule dressing agent of the present invention, wherein, the mosquito-proof fly microcapsule dressing agent that drives consists of the following composition, plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, all the other are deionized water, and the content sum of above each component is 100%, specifically implements according to following steps:
Step 1, prepares that plant source is mosquito-proof drives fly extract, specifically implements according to following steps:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 ~ 400 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:2 ~ 4; Wherein, mosquito-proofly drive fly plant mixture, according to mass percent, cloves 10% ~ 20%, folium eucalypti 10% ~ 30%, peppermint 20% ~ 40%, wormwood 10% ~ 30% and tomato stem-leaf 20% ~ 50% form, each component total amount 100%.
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 ~ 5 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 ~ 90 DEG C of conditions, distillation extraction 2 ~ 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules, specifically implements according to following steps:
Step 2.1, drive fly extract by mosquito-proof for the plant source obtained in step 1, be added drop-wise in gum arabic solution, wherein, the mass fraction of gum arabic solution is 2% ~ 6%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4 ~ 8;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 2000r/min ~ 4000r/min rotating speed, emulsion is treated to through emulsification shear mixer, then gelatin solution is joined in above-mentioned emulsion and process 20 ~ 50min, wherein, the mass fraction of gelatin solution is 2% ~ 6%, the addition of gelatin solution is identical with the addition of gumwater, control temperature 30 ~ 60 DEG C, pH are 4.0 ~ 6.0, through time 10 ~ 30min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of deionized water is 1:2 ~ 6 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 10 ~ 25 DEG C;
Step 2.3, adds glutaraldehyde curing agent, wherein, the addition of glutaraldehyde curing agent accounts for 3% ~ 8% of whole mixed liquor quality, control pH is 8.0 ~ 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, drying, obtains and mosquito-proofly drives fly microcapsules.
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent, specifically implements according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 1 ~ 3 hour, then add deionized water and stirring 1 ~ 4 hour, obtained mosquito-proofly drive fly microcapsule dressing agent.
Utilize and mosquito-proofly drive the method that fly microcapsule dressing agent carries out textile finishing, specifically implement according to following steps:
Step a, the percentage accounting for the quality of fabric in finishing agent be 3 ~ 10% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:6 ~ 10.
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 50 ~ 80 DEG C, flood 40 ~ 80min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, and what complete fabric mosquito-proofly drives fly and arrange, wherein, oven dry be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 80 ~ 100 DEG C, and drying time is 20 ~ 30min; Cure be by dry after fabric be placed on the conveyer belt of heat setting machine, under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 150 ~ 180 DEG C, and the time of curing is 1 ~ 5min.
Embodiment 1
The present invention's one is mosquito-proof drives fly microcapsule dressing agent, and by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 15%, aqueous polyurethane 15%, and all the other are deionized water, the content sum of above each component is 100%.Its preparation method is:
Step 1, prepares that plant source is mosquito-proof drives fly extract, and concrete steps are:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:2; Wherein, mosquito-proofly drive fly plant mixture, according to mass percent, cloves 20%, folium eucalypti 30%, peppermint 20%, wormwood 10% and tomato stem-leaf 30% form.
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 DEG C of conditions, distillation extraction 2 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules, specifically implements according to following steps:
Step 2.1, drives fly extract by mosquito-proof for the plant source obtained in step 1, is added drop-wise in gum arabic solution, and wherein, the mass fraction of gum arabic solution is 2%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 2000r/min rotating speed, be treated to emulsion through emulsification shear mixer, then gelatin solution joined in above-mentioned emulsion and process 20min, wherein, the mass fraction of gelatin solution is 2%, the addition of gelatin solution is identical with the addition of gumwater, and control temperature 30 DEG C, pH are 4.0, through time 10min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of deionized water is 1:2 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 10 DEG C;
Step 2.3, adds glutaraldehyde curing agent, and wherein, the addition of glutaraldehyde curing agent accounts for 3% of whole mixed liquor quality, and control pH is 8.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, dryings, obtained mosquito-proofly drives fly microcapsules.
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent, specifically implements according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 15%, aqueous polyurethane 5%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 1 hour, then add deionized water and stirring 1 hour, obtained mosquito-proofly drive fly microcapsule dressing agent.
Utilize the above-mentioned mosquito-proof fly microcapsule dressing agent that drives prepared to carry out textile finishing, concrete steps are:
Step a, the percentage accounting for the quality of fabric in finishing agent be 3% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:6;
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 50 C, flood 40min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, completes the mosquito-proof of fabric and drives fly arrangement.Wherein dry be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 80 DEG C, and drying time is 20min; Cure be by dry after fabric be placed on the conveyer belt of heat setting machine, under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 150 DEG C, and the time of curing is 1min.The prepared anti-mosquito fabric mosquito repellent rate of the fabric after arrangement is 72.48%.
Embodiment 2
The present invention's one is mosquito-proof drives fly microcapsule dressing agent, and by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 40%, aqueous polyurethane 10%, and all the other are deionized water, the content sum of above each component is 100%.Its preparation method is:
Step 1, prepares that plant source is mosquito-proof drives fly extract, and concrete steps are:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 400 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:4; Wherein, mosquito-proofly drive fly plant mixture, according to mass percent, cloves 10%, folium eucalypti 10%, peppermint 20%, wormwood 10% and tomato stem-leaf 50% form.
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 5 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 90 DEG C of conditions, distillation extraction 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules, specifically implements according to following steps:
Step 2.1, drives fly extract by mosquito-proof for the plant source obtained in step 1, is added drop-wise in gum arabic solution, and wherein, the mass fraction of gum arabic solution is 6%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:8;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 4000r/min rotating speed, be treated to emulsion through emulsification shear mixer, then gelatin solution joined in above-mentioned emulsion and process 50min, wherein, the mass fraction of gelatin solution is 6%, the addition of gelatin solution is identical with the addition of gumwater, and control temperature 60 DEG C, pH are 6.0, through time 30min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of deionized water is 1:6 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 25 DEG C;
Step 2.3, adds glutaraldehyde curing agent, and wherein, the addition of glutaraldehyde curing agent accounts for 8% of whole mixed liquor quality, and control pH is 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, dryings, obtained mosquito-proofly drives fly microcapsules.
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent, specifically implements according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 40%, aqueous polyurethane 10%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 3 hours, then add deionized water and stirring 4 hours, obtained mosquito-proofly drive fly microcapsule dressing agent.
Utilize the above-mentioned mosquito-proof fly microcapsule dressing agent that drives prepared to carry out textile finishing, concrete steps are:
Step a, the percentage accounting for the quality of fabric in finishing agent be 10% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:10;
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 80 DEG C, flood 80min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, completes the mosquito-proof of fabric and drives fly arrangement.Wherein dry be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 100 DEG C, and drying time is 30min; Cure be by dry after fabric be placed on the conveyer belt of heat setting machine, under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 180 DEG C, and the time of curing is 5min.The prepared anti-mosquito fabric mosquito repellent rate of the fabric after arrangement is 81.56%.
Embodiment 3
The present invention's one is mosquito-proof drives fly microcapsule dressing agent, and by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 30%, aqueous polyurethane 5%, and all the other are deionized water, the content sum of above each component is 100%.Its preparation method is:
Step 1, prepares that plant source is mosquito-proof drives fly extract, and concrete steps are:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 200 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:3; Wherein, mosquito-proofly drive fly plant mixture, according to mass percent, cloves 20%, folium eucalypti 10%, peppermint 40%, wormwood 10% and tomato stem-leaf 20% form.
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 4 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 75 DEG C of conditions, distillation extraction 4 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules, specifically implements according to following steps:
Step 2.1, drives fly extract by mosquito-proof for the plant source obtained in step 1, is added drop-wise in gum arabic solution, and wherein, the mass fraction of gum arabic solution is 4%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:6;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 3000r/min rotating speed, be treated to emulsion through emulsification shear mixer, then gelatin solution joined in above-mentioned emulsion and process 30min, wherein, the mass fraction of gelatin solution is 4%, the addition of gelatin solution is identical with the addition of gumwater, and control temperature 45 DEG C, pH are 5.0, through time 20min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of deionized water is 1:4 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 15 DEG C;
Step 2.3, adds glutaraldehyde curing agent, and wherein, the addition of glutaraldehyde curing agent accounts for 5% of whole mixed liquor quality, and control pH is 9.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, dryings, obtained mosquito-proofly drives fly microcapsules.
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent, specifically implements according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 30%, aqueous polyurethane 5%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 2 hours, then add deionized water and stirring 2.5 hours, obtained mosquito-proofly drive fly microcapsule dressing agent.
Utilize the above-mentioned mosquito-proof fly microcapsule dressing agent that drives prepared to carry out textile finishing, concrete steps are:
Step a, the percentage accounting for the quality of fabric in finishing agent be 6% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:8;
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 60 C, flood 60min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, completes the mosquito-proof of fabric and drives fly arrangement.Wherein dry be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 90 DEG C, and drying time is 25min; Cure be by dry after fabric be placed on the conveyer belt of heat setting machine, under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 160 DEG C, and the time of curing is 3min.The prepared anti-mosquito fabric mosquito repellent rate of the fabric after arrangement is 79.33%.
Embodiment 4
The present invention's one is mosquito-proof drives fly microcapsule dressing agent, and by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 20%, aqueous polyurethane 15%, and all the other are deionized water, the content sum of above each component is 100%.Its preparation method is:
Step 1, prepares that plant source is mosquito-proof drives fly extract, and concrete steps are:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:3; Wherein, mosquito-proofly drive fly plant mixture, according to mass percent, cloves 15%, folium eucalypti 15%, peppermint 20%, wormwood 30% and tomato stem-leaf 20% form.
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 5 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 DEG C of conditions, distillation extraction 5 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules, specifically implements according to following steps:
Step 2.1, drives fly extract by mosquito-proof for the plant source obtained in step 1, is added drop-wise in gum arabic solution, and wherein, the mass fraction of gum arabic solution is 6%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 2500r/min rotating speed, be treated to emulsion through emulsification shear mixer, then gelatin solution joined in above-mentioned emulsion and process 50min, wherein, the mass fraction of gelatin solution is 2%, the addition of gelatin solution is identical with the addition of gumwater, and control temperature 50 DEG C, pH are 6.0, through time 10min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of deionized water is 1:5 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 25 DEG C;
Step 2.3, adds glutaraldehyde curing agent, and wherein, the addition of glutaraldehyde curing agent accounts for 3% of whole mixed liquor quality, and control pH is 8.5 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, dryings, obtained mosquito-proofly drives fly microcapsules.
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent, specifically implements according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 20%, aqueous polyurethane 15%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 3 hours, then add deionized water and stirring 1 hour, obtained mosquito-proofly drive fly microcapsule dressing agent.
Utilize the above-mentioned mosquito-proof fly microcapsule dressing agent that drives prepared to carry out textile finishing, concrete steps are:
Step a, the percentage accounting for the quality of fabric in finishing agent be 7% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:10;
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 50 C, flood 50min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, completes the mosquito-proof of fabric and drives fly arrangement.Wherein dry be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 100 DEG C, and drying time is 20min; Cure be by dry after fabric be placed on the conveyer belt of heat setting machine, under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 170 DEG C, and the time of curing is 5min.The prepared anti-mosquito fabric mosquito repellent rate of the fabric after arrangement is 67.47%.
Embodiment 5
The present invention's one is mosquito-proof drives fly microcapsule dressing agent, and by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 35%, aqueous polyurethane 8%, and all the other are deionized water, the content sum of above each component is 100%.Its preparation method is:
Step 1, prepares that plant source is mosquito-proof drives fly extract, and concrete steps are:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 300 object powder, and takes distilled water, and the mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:4; Wherein, mosquito-proofly drive fly plant mixture, according to mass percent, cloves 10%, folium eucalypti 20%, peppermint 30%, wormwood 20% and tomato stem-leaf 20% form.
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 80 DEG C of conditions, distillation extraction 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules, specifically implements according to following steps:
Step 2.1, drives fly extract by mosquito-proof for the plant source obtained in step 1, is added drop-wise in gum arabic solution, and wherein, the mass fraction of gum arabic solution is 2%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:7;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 4000r/min rotating speed, be treated to emulsion through emulsification shear mixer, then gelatin solution joined in above-mentioned emulsion and process 20min, wherein, the mass fraction of gelatin solution is 3%, the addition of gelatin solution is identical with the addition of gumwater, and control temperature 60 DEG C, pH are 4.0, through time 15min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of deionized water is 1:6 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 10 DEG C;
Step 2.3, adds glutaraldehyde curing agent, and wherein, the addition of glutaraldehyde curing agent accounts for 4% of whole mixed liquor quality, and control pH is 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, dryings, obtained mosquito-proofly drives fly microcapsules.
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent, specifically implements according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 35%, aqueous polyurethane 8%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 1 hour, then add deionized water and stirring 2 hours, obtained mosquito-proofly drive fly microcapsule dressing agent.
Utilize the above-mentioned mosquito-proof fly microcapsule dressing agent that drives prepared to carry out textile finishing, concrete steps are:
Step a, the percentage accounting for the quality of fabric in finishing agent be 10% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:6;
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 55 DEG C, flood 80min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, completes the mosquito-proof of fabric and drives fly arrangement.Wherein dry be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 80 DEG C, and drying time is 28min; Cure be by dry after fabric be placed on the conveyer belt of heat setting machine, under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 180 DEG C, and the time of curing is 1min.The prepared anti-mosquito fabric mosquito repellent rate of the fabric after arrangement is 85.67%.
The invention has the beneficial effects as follows, the present invention adopts and naturally mosquito-proofly drives fly repellant, utilizes Micro-Encapsulation Technique, is obtained mosquito-proofly drive fly fabric by Final finishing.The main way of current control mosquitos and flies harm uses chemical insecticide and mosquito-fly repellent exactly.Chemical insecticide proves effective soon, and can prevent and treat multiple pathophorous biology, applicable scope is larger, but chemical insecticide can cause the resistance to the action of a drug of mosquito, works the mischief to environment simultaneously.The genotoxic potential problem existed along with synthesis repellant slowly displays, and the research and development demand of natural repellant is more urgent.Natural repellant has many advantages, low toxicity or nontoxic, can not produce burning heat sensation to skin, smell is pure and fresh, does not have residue of drug effect after using, and easily degrades, non-environmental-pollutions etc., the use of microcapsules technology in the present invention simultaneously, improves the lasting of mosquito repellent fly effect and washing fastness etc.Described anti-mosquito fabric mosquito repellent rate can reach more than 67.47%, forms all kinds of anti-mosquito textiles, to meet the demand of the clothing products of weaving such as family expenses, open air, occupation and army, has important society and economy meaning.
Claims (10)
1. mosquito-proofly drive a fly microcapsule dressing agent, it is characterized in that, by mass percentage, be made up of following component: plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, all the other are deionized water, and the content sum of above each component is 100%.
2. according to claim 1ly mosquito-proofly drive fly microcapsule dressing agent, it is characterized in that, the mosquito-proof fly microcapsules that drive of described plant source are prepared in accordance with the following methods:
Step 1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 ~ 400 object powder, and takes distilled water, and the described mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:2 ~ 4;
Step 2, the mosquito-proof fly plant mixture of driving taken in step 1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 ~ 5 hours, obtains raw material to be distilled;
Step 3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 ~ 90 DEG C of conditions, distillation extraction 2 ~ 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract;
Step 4, fly extract is driven by mosquito-proof for the plant source obtained in step 3, be added drop-wise in gum arabic solution, wherein, the mass fraction of gum arabic solution is 2% ~ 6%, the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4 ~ 8, again mixed liquor is placed in emulsion reactor, under 2000r/min ~ 4000r/min rotating speed, emulsion is treated to through emulsification shear mixer, then gelatin solution is joined in above-mentioned emulsion and process 20 ~ 50min, wherein, the mass fraction of gelatin solution is 2% ~ 6%, the addition of described gelatin solution is identical with the addition of gumwater, control temperature 30 ~ 60 DEG C, pH is 4.0 ~ 6.0, through time 10 ~ 30min, gelatin and gum Arabic are condensed, under the condition stirred, add deionized water, the quality of described deionized water is 1:2 ~ 6 with the ratio of gelatin and Arabic gum mixed solution gross mass, regulation system temperature, to 10 ~ 25 DEG C, adds glutaraldehyde curing agent, wherein, the addition of glutaraldehyde curing agent accounts for 3% ~ 8% of whole mixed liquor quality, control pH is 8.0 ~ 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, drying, obtains and mosquito-proofly drives fly microcapsules.
3. according to claim 2ly mosquito-proofly drive fly microcapsule dressing agent, it is characterized in that, described mosquito-proof fly plant mixture of driving consists of the following composition according to mass percent: cloves 10% ~ 20%, folium eucalypti 10% ~ 30%, peppermint 20% ~ 40%, wormwood 10% ~ 30% and tomato stem-leaf 20% ~ 50%, each component content sum is 100%.
4. the mosquito-proof preparation method driving fly microcapsule dressing agent, it is characterized in that, the described mosquito-proof fly microcapsule dressing agent that drives consists of the following composition, plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, all the other are deionized water, and the content sum of above each component is 100%, and its preparation method is specifically implemented according to following steps:
Step 1, prepares that plant source is mosquito-proof drives fly extract;
Step 2, to utilize in step 1 the mosquito-proof fly extract that drives of the plant source of preparation to prepare that plant source is mosquito-proof drives fly microcapsules;
Step 3, to utilize in step 2 the mosquito-proof fly microcapsules that drive of the plant source of preparation to prepare and mosquito-proofly drive fly microcapsule dressing agent.
5. the mosquito-proof preparation method driving fly microcapsule dressing agent according to claim 4, it is characterized in that, described step 1 is specifically implemented according to following steps:
Step 1.1, take and mosquito-proofly drive fly plant mixture, put into pulverizer and pulverize, obtaining granularity is 100 ~ 400 object powder, and takes distilled water, and the described mosquito-proof mass ratio driving fly plant mixture and distilled water is 1:2 ~ 4;
Step 1.2, the mosquito-proof fly plant mixture of driving taken in step 1.1 is put into the distilled water that step 1 takes and soaked, and soak time is 2 ~ 5 hours, obtains raw material to be distilled;
Step 1.3, in raw material defence area to be distilled distilling apparatus step 2 obtained, under temperature is 60 ~ 90 DEG C of conditions, distillation extraction 2 ~ 6 hours, collects cut, and by its active ingredient of n-hexane extraction, obtains that plant source is mosquito-proof drives fly extract.
6. the mosquito-proof preparation method driving fly microcapsule dressing agent according to claim 5, it is characterized in that, described mosquito-proofly drive fly plant mixture, according to mass percent, cloves 10% ~ 20%, folium eucalypti 10% ~ 30%, peppermint 20% ~ 40%, wormwood 10% ~ 30% and tomato stem-leaf 20% ~ 50% form, each component total amount 100%.
7. the mosquito-proof preparation method driving fly microcapsule dressing agent according to claim 4, it is characterized in that, described step 2 is specifically implemented according to following steps:
Step 2.1, drive fly extract by mosquito-proof for the plant source obtained in step 1, be added drop-wise in gum arabic solution, wherein, the mass fraction of gum arabic solution is 2% ~ 6%, and the mosquito-proof mass ratio of driving fly extract and gum arabic solution of plant source is 1:4 ~ 8;
Step 2.2, the mixed solution that step 2.1 is obtained is placed in emulsion reactor, under 2000r/min ~ 4000r/min rotating speed, emulsion is treated to through emulsification shear mixer, then gelatin solution is joined in above-mentioned emulsion and process 20 ~ 50min, wherein, the mass fraction of gelatin solution is 2% ~ 6%, the addition of described gelatin solution is identical with the addition of gumwater, control temperature 30 DEG C ~ 60, pH are 4.0 ~ 6.0, through time 10 ~ 30min, gelatin and gum Arabic are condensed; And under the condition stirred, add deionized water, the quality of described deionized water is 1:2 ~ 6 with the ratio of gelatin and Arabic gum mixed solution gross mass; Regulation system temperature is to 10 ~ 25 DEG C; Step 2.3, adds glutaraldehyde curing agent, wherein, the addition of glutaraldehyde curing agent accounts for 3% ~ 8% of whole mixed liquor quality, control pH is 8.0 ~ 10.0 solidifications, finally through operations such as vacuum pump using circulatory water suction filtration, washing, drying, obtains and mosquito-proofly drives fly microcapsules.
8. the mosquito-proof preparation method driving fly microcapsule dressing agent according to claim 4, is characterized in that, described step 3, specifically implements according to following steps:
Step 3.1, takes each component according to mass percent, and wherein, plant source is mosquito-proof drives fly microcapsules 15% ~ 40%, aqueous polyurethane 5% ~ 15%, and all the other are deionized water, and the content sum of above each component is 100%;
Step 3.2, the mosquito-proof fly microcapsules that drive step 3.1 taken mix with aqueous polyurethane, stir 1 ~ 3 hour, then add deionized water and stirring 1 ~ 4 hour, obtained mosquito-proofly drive fly microcapsule dressing agent.
9. to utilize described in claim 1 mosquito-proof drives the method that fly microcapsule dressing agent carries out textile finishing, it is characterized in that, specifically implements according to following steps:
Step a, the percentage accounting for the quality of fabric in finishing agent be 3 ~ 10% ratio take and mosquito-proofly drive fly microcapsule dressing agent, stir after being added water by finishing agent, formed and mosquito-proofly drive fly microcapsules dressing liquid, the mass ratio of this dressing liquid and required finish fabric is 1:6 ~ 10;
Step b, is placed in the above-mentioned mosquito-proof fly microcapsules dressing liquid that drives prepared in dressing container, then puts into fabric, under the condition of temperature 50 ~ 80 DEG C, flood 40 ~ 80min;
Step c, is undertaken drying and curing by the fabric after above-mentioned dressing, completes the mosquito-proof of fabric and drives fly arrangement.
10. mosquito-proofly drive the method that fly microcapsule dressing agent carries out textile finishing according to according to claim 9 utilization, it is characterized in that, oven dry in described step c be by dressing after fabric be placed in general drum-type dryer, its bake out temperature is 80 ~ 100 DEG C, and drying time is 20 ~ 30min; Described curing is that fabric by after drying is placed on the conveyer belt of heat setting machine, and under the transmission of conveyer belt, bring fabric into baking chamber, stoving temperature is 150 ~ 180 DEG C, and the time of curing is 1 ~ 5min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410773244.3A CN104532595A (en) | 2014-12-15 | 2014-12-15 | Mosquito-preventing and fly-repelling capsule finishing agent as well as preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410773244.3A CN104532595A (en) | 2014-12-15 | 2014-12-15 | Mosquito-preventing and fly-repelling capsule finishing agent as well as preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104532595A true CN104532595A (en) | 2015-04-22 |
Family
ID=52848205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410773244.3A Pending CN104532595A (en) | 2014-12-15 | 2014-12-15 | Mosquito-preventing and fly-repelling capsule finishing agent as well as preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104532595A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105603766A (en) * | 2016-02-25 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Preparation method of composite essential oil microcapsule finishing agent and application thereof |
| CN105821674A (en) * | 2016-05-24 | 2016-08-03 | 无锡市长安曙光手套厂 | Mosquito-and-fly-repellent microcapsule finishing agent and preparation method and application thereof |
| CN106012555A (en) * | 2016-06-23 | 2016-10-12 | 无锡市金五星针纺有限公司 | Mosquito preventing and fly repelling microcapsule finishing agent as well as preparation method and application thereof |
| CN106120354A (en) * | 2016-06-23 | 2016-11-16 | 无锡市金五星针纺有限公司 | It is a kind of that natural plant is mosquito-proof drives fly microcapsule dressing agent and its preparation method and application |
| CN106758267A (en) * | 2016-12-23 | 2017-05-31 | 句容市申兔工艺针织厂 | A kind of finishing technique of function of driving mosquitoes fabric |
| CN107012530A (en) * | 2017-05-12 | 2017-08-04 | 福建鑫森合纤科技有限公司 | A kind of mosquito repellent nylon-6 fiber and preparation method thereof |
| WO2017161613A1 (en) * | 2016-03-24 | 2017-09-28 | 江苏金太阳纺织科技股份有限公司 | Eucalyptus oil auxiliary agent, preparation method thereof, and fabric-finishing working solution |
| CN107354723A (en) * | 2017-08-10 | 2017-11-17 | 宁波广源纺织品有限公司 | A kind of mosquito-proof method for sorting of natural plants |
| CN107650469A (en) * | 2017-11-10 | 2018-02-02 | 安徽翰联纺织有限公司 | The preparation method of outdoor composite material, the application of the composite material |
| CN109023961A (en) * | 2018-05-29 | 2018-12-18 | 黄河科技学院 | A kind of preparation method of Chinese medicine microcapsules and Chinese medicine textile |
| CN109055633A (en) * | 2018-09-21 | 2018-12-21 | 佛山市森昂生物科技有限公司 | A kind of preparation method of genuine leather fabric finishing agent |
| CN113273571A (en) * | 2021-06-07 | 2021-08-20 | 山东安然纳米实业发展有限公司 | Mosquito-repelling cool-feeling dual-functional cross-linked microcapsule and preparation method thereof |
| CN115652459A (en) * | 2022-12-12 | 2023-01-31 | 潍坊欣龙生物材料有限公司 | Preparation method of anti-mosquito regenerated cellulose fiber |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101591859A (en) * | 2009-06-22 | 2009-12-02 | 华南农业大学 | A kind of Blumea oil microcapsule textile composite finishing agent and application thereof |
| CN102061625A (en) * | 2009-11-16 | 2011-05-18 | 香港理工大学 | Mugwort leaf oil microcapsule antibacterial crease-resistant fabric and preparation method thereof |
-
2014
- 2014-12-15 CN CN201410773244.3A patent/CN104532595A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101591859A (en) * | 2009-06-22 | 2009-12-02 | 华南农业大学 | A kind of Blumea oil microcapsule textile composite finishing agent and application thereof |
| CN102061625A (en) * | 2009-11-16 | 2011-05-18 | 香港理工大学 | Mugwort leaf oil microcapsule antibacterial crease-resistant fabric and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 吴倩: "防蝇纺织品的研究与开发", 《工程科技I辑》 * |
| 薛景庆 等: "一种复方天然驱蚊剂在驱蚊纺织品上的应用研究", 《纺织科技进展》 * |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105603766A (en) * | 2016-02-25 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Preparation method of composite essential oil microcapsule finishing agent and application thereof |
| WO2017161613A1 (en) * | 2016-03-24 | 2017-09-28 | 江苏金太阳纺织科技股份有限公司 | Eucalyptus oil auxiliary agent, preparation method thereof, and fabric-finishing working solution |
| CN105821674A (en) * | 2016-05-24 | 2016-08-03 | 无锡市长安曙光手套厂 | Mosquito-and-fly-repellent microcapsule finishing agent and preparation method and application thereof |
| CN106012555A (en) * | 2016-06-23 | 2016-10-12 | 无锡市金五星针纺有限公司 | Mosquito preventing and fly repelling microcapsule finishing agent as well as preparation method and application thereof |
| CN106120354A (en) * | 2016-06-23 | 2016-11-16 | 无锡市金五星针纺有限公司 | It is a kind of that natural plant is mosquito-proof drives fly microcapsule dressing agent and its preparation method and application |
| CN106758267A (en) * | 2016-12-23 | 2017-05-31 | 句容市申兔工艺针织厂 | A kind of finishing technique of function of driving mosquitoes fabric |
| CN107012530B (en) * | 2017-05-12 | 2018-06-12 | 福建鑫森合纤科技有限公司 | A kind of mosquito repellent nylon-6 fiber and preparation method thereof |
| CN107012530A (en) * | 2017-05-12 | 2017-08-04 | 福建鑫森合纤科技有限公司 | A kind of mosquito repellent nylon-6 fiber and preparation method thereof |
| CN107354723A (en) * | 2017-08-10 | 2017-11-17 | 宁波广源纺织品有限公司 | A kind of mosquito-proof method for sorting of natural plants |
| CN107650469A (en) * | 2017-11-10 | 2018-02-02 | 安徽翰联纺织有限公司 | The preparation method of outdoor composite material, the application of the composite material |
| CN109023961A (en) * | 2018-05-29 | 2018-12-18 | 黄河科技学院 | A kind of preparation method of Chinese medicine microcapsules and Chinese medicine textile |
| CN109055633A (en) * | 2018-09-21 | 2018-12-21 | 佛山市森昂生物科技有限公司 | A kind of preparation method of genuine leather fabric finishing agent |
| CN109055633B (en) * | 2018-09-21 | 2021-09-10 | 佛山市森昂生物科技有限公司 | Preparation method of leather fabric finishing agent |
| CN113273571A (en) * | 2021-06-07 | 2021-08-20 | 山东安然纳米实业发展有限公司 | Mosquito-repelling cool-feeling dual-functional cross-linked microcapsule and preparation method thereof |
| CN115652459A (en) * | 2022-12-12 | 2023-01-31 | 潍坊欣龙生物材料有限公司 | Preparation method of anti-mosquito regenerated cellulose fiber |
| CN115652459B (en) * | 2022-12-12 | 2024-02-02 | 潍坊欣龙生物材料有限公司 | Preparation method of mosquito-proof regenerated cellulose fiber |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104532595A (en) | Mosquito-preventing and fly-repelling capsule finishing agent as well as preparation method and application thereof | |
| CN105594755B (en) | A kind of plant mosquito-repellent and the preparation method with repelling effect fabric | |
| CN102154841B (en) | Anti-mosquito finishing process of textile fabric | |
| CN105734985B (en) | A kind of preparation method of microcapsules composite liner material | |
| CN107397386B (en) | A kind of moxa by and preparation method thereof | |
| CN105165911A (en) | Preparation method of herba schizonepetae essential oil nanometer mosquito-repellent microcapsules | |
| CN106135315A (en) | A kind of natural botanical insecticide | |
| CN107006543A (en) | It is a kind of for insect-proof agent of flower planting and preparation method thereof | |
| CN110368457A (en) | A kind of the enlarging and exercising breast product formula and preparation method of pure natural aromatic essential oil | |
| CN107136126A (en) | A kind of gardens high-efficiency environment friendly ecological pesticide and preparation method thereof | |
| KR20080028214A (en) | Functional fabric prepared by using persimmon juice and a preparation method thereof | |
| CN106400520A (en) | Mosquito repelling tent and production method thereof | |
| CN107056502A (en) | A kind of China rose dedicated fertilizer and preparation method thereof | |
| CN103103752A (en) | Production method of fragrant cotton fabric | |
| CN107114173A (en) | A kind of nectarine high-yield planting method | |
| CN106149386A (en) | A kind of microcapsule dressing agent for preventing mosquito and its preparation method and application | |
| CN105821674B (en) | Mosquito-proof drive fly microcapsule dressing agent and its preparation method and application | |
| CN107747217A (en) | Clothing finishing agent and preparation method thereof | |
| CN107260634A (en) | A kind of green Chinese nti-freckle suncream and preparation method thereof | |
| KR100907086B1 (en) | Method of producing cosmetic patch comprising the fermented ginseng extracts | |
| CN106416855A (en) | Reusable bird net | |
| CN104694676B (en) | Aromatic antibacterial tanning agent based on fragrant eupatorium herb extract, and preparation method thereof | |
| CN109173703A (en) | A kind of pig house special bio deodorant and its application method | |
| CN107549217A (en) | A kind of vegetable cultivation green composite bactericide and preparation method thereof | |
| CN106120354A (en) | It is a kind of that natural plant is mosquito-proof drives fly microcapsule dressing agent and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150422 |