CN105741915A - Multilayer metal electrode capable of being firmly combined with glass - Google Patents
Multilayer metal electrode capable of being firmly combined with glass Download PDFInfo
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- CN105741915A CN105741915A CN201410746185.0A CN201410746185A CN105741915A CN 105741915 A CN105741915 A CN 105741915A CN 201410746185 A CN201410746185 A CN 201410746185A CN 105741915 A CN105741915 A CN 105741915A
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Abstract
The invention relates to a multilayer metal electrode capable of being firmly combined with glass, belonging to the physical power supply technical field. The multilayer metal electrode is characterized by employing a multilayer metallization electrode structure; an electrode system is an aluminum-titanium-palladium-silver structure; aluminum, titanium, palladium and silver structure metal layers are successively arranged on a glass substrate. The multilayer metal electrode can be firmly combined with the glass substrate, has the advantages of high reliability and great firmness, and can be widely applied in civil, military industry and spaceflight fields in future.
Description
Technical field
The invention belongs to physical power source technical field, particularly relate to a kind of can with the multilayer metallic electrode of glass strong bonded.
Background technology
At present, along with the development of electronics and information industry, various be substrate with glass product be used to the production of a lot of product such as display screen and liquid crystal device.A lot it is required in substrate of glass preparing metal electrode or lead-in wire is drawn at the variable color of display device, solaode, energy conversion window or architectural employing or alternating temperature glass etc..Existing electrode mainly includes conductive rubber, containing silver conductive adhesive and metal fixture three kinds.Conductive rubber is easily aging easily aging when especially working at higher or lower temperatures even to ftracture；Containing silver conductive adhesive prepare metal electrode generally require carry out repeatedly, the etching of different etching liquids or etching paste obtains required figure, again through the coating of silver paste, molding, obtain.But, surface is had to the product of membrane structure, it is necessary to select suitable etching liquid, and production process needs step more；It is bigger that metal fixture electrode compares volume.For some to the exigent industry of firmness, electrode as above in the field such as military project, space flight can not meet its requirement to reliability.
Patent of invention CN101442174B discloses the preparation method of electrode welding lead on a kind of electro-conductive glass, it is characterized in that adopting glass dust to mix containing silver paste, prepares contact conductor by coating and reduction process in Conducting Glass.But there is also the technical problem such as reliability, firmness.
Summary of the invention
The present invention solves in known technology exist technical problem and provide a kind of can with the multilayer metallic electrode of glass strong bonded.
An object of the present invention is to provide a kind of to be had between electrode and glass substrate and has significantly high adhesion, and reliability is high, the features such as firmness is good can with the multilayer metallic electrode of glass strong bonded.
The present invention provides without glass etching, so that it may preparation on glass, will not ftracture under the temperature shock of temperature-180 DEG C～100 DEG C, and tensile strength reaches 0.83N/mm2The electrode with good reliability and firmness or the structure of contact conductor.
The present invention can be adopted the technical scheme that with the multilayer metallic electrode of glass strong bonded:
A kind of can with the multilayer metallic electrode of glass strong bonded, it is characterized in that: with the multilayer metallic electrode of glass strong bonded for adopting multiple-layer metallization electrode structure, electrode system is aluminum-titanium-palladium-Yin structure, and substrate of glass is followed successively by aluminum-titanium-palladium-Yin structural metal layer.
The present invention can also be able to adopt the following technical scheme that with the multilayer metallic electrode of glass strong bonded
Described with the multilayer metallic electrode of glass strong bonded, can be characterized in: aluminum-titanium-palladium-Yin structural metal layer thickness respectively 100 ± 30nm, 300 ± 80nm, 100 ± 30nm, 5000 ± 100nm.
The present invention has the advantage that and has the benefit effect that
Technical scheme that can be brand-new owing to have employed the present invention with the multilayer metallic electrode of glass strong bonded, compared with prior art, the invention have the characteristics that:
1, the present invention adopts multiple-layer metallization electrode structure, improves the adhesive ability between metal and cover plate, it is possible to withstand the test of solder joint tension intensity, and reliability is high, and firmness is good.It is no matter civilian or can apply in the field such as military project, space flight.
2, the present invention is in process of production without performing etching glass substrate, decreases the loss that etching error causes.Metal electrode can be removed by acid solution, it is possible to does over again.
Accompanying drawing explanation
Fig. 1 is that the present invention can with the metal electrode structure schematic diagram with four-layer structure of glass strong bonded；
In figure, substrate of glass is followed successively by aluminum-titanium-palladium-Yin structural metal layer.1, silver, 2, palladium, 3, titanium, 4, aluminum, 5, glass.
Detailed description of the invention
For the summary of the invention of the present invention, feature and effect can be further appreciated that, hereby enumerate following example, and it be as follows to coordinate accompanying drawing to describe in detail:
Embodiment 1
Accompanying drawings 1.
A kind of can with the multilayer metallic electrode of glass strong bonded, adopt multiple-layer metallization electrode structure, electrode system is aluminum-titanium-palladium-Yin structure, and substrate of glass is followed successively by aluminum-titanium-palladium-Yin structural metal layer.Aluminum-titanium-palladium-Yin structural metal layer thickness respectively 100 ± 30nm, 300 ± 80nm, 100 ± 30nm, 5000 ± 100nm.Four layers of metal structure electrode of Al-Ti-Pd-Ag structure, metallic aluminium is positioned at orlop and contacts with substrate of glass, and argent is positioned at the superiors.
The manufacturing process of four layers of metal structure electrode of the present embodiment Al-Ti-Pd-Ag structure:
1. the making of four-layer structure metal electrode
Multilayer metallic electrode adopts the mode of electron beam vacuum evaporation, is placed on fixture by substrate of glass and puts in vacuum chamber.Metal is put in the crucible of vacuum equipment, it is not necessary to heating, set the thickness respectively 100nm of aluminum titanium palladium-silver, 300nm, 100nm and 5000nm.1 × 10 is reached at air pressure-3Starting evaporation during below Pa, the figure of evaporation is determined by template.Electrode pattern as required makes and is deposited with mould accordingly.
2. pair product is sintered
The product of complete for above-mentioned evaporation metal electrode in annealing device, it is sintered.Sintering temperature is set as 270 DEG C, and the time is 30 minutes.
Prepared electrode is carried out the test of tensile strength, hangs below the native silver of Impact direction 45 ° and be not less than 0.83N/mm2Counterweight, electrode does not come off.
Product not only has good firmness at room temperature, still has good firmness after higher and relatively low temperature shock.In temperature from the temperature shock of the moment of-80 DEG C～100 DEG C, electrode still has good firmness, will not fall off when temperature shock.
Result from above: the present invention prepares four layers of metal electrode of aluminum-titanium-palladium-Yin structure and firmly can be combined with glass substrate formation, and its tensile strength can reach 0.83N/mm2Above.And still there is good firmness under the impact of temperature-80 DEG C～100 DEG C.
The present embodiment has between described electrode and glass substrate and has significantly high adhesion, and reliability is high, and firmness waits well good effect.It is civilian or all have wide practical use in the field such as military project, space flight.
Claims (2)
1. one kind can with the multilayer metallic electrode of glass strong bonded, it is characterized in that: with the multilayer metallic electrode of glass strong bonded for adopting multiple-layer metallization electrode structure, electrode system is aluminum-titanium-palladium-Yin structure, and substrate of glass is followed successively by aluminum-titanium-palladium-Yin structural metal layer.
2. according to claim 1 with the multilayer metallic electrode of glass strong bonded, can it is characterized in that: aluminum-titanium-palladium-Yin structural metal layer thickness respectively 100 ± 30nm, 300 ± 80nm, 100 ± 30nm, 5000 ± 100nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410746185.0A CN105741915A (en) | 2014-12-08 | 2014-12-08 | Multilayer metal electrode capable of being firmly combined with glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410746185.0A CN105741915A (en) | 2014-12-08 | 2014-12-08 | Multilayer metal electrode capable of being firmly combined with glass |
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| Publication Number | Publication Date |
|---|---|
| CN105741915A true CN105741915A (en) | 2016-07-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410746185.0A Pending CN105741915A (en) | 2014-12-08 | 2014-12-08 | Multilayer metal electrode capable of being firmly combined with glass |
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| CN (1) | CN105741915A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN203434160U (en) * | 2013-07-22 | 2014-02-12 | 天津恒电空间电源有限公司 | Large-area silicon bypass diode for solar cell array |
| CN203503665U (en) * | 2013-08-05 | 2014-03-26 | 天津恒电空间电源有限公司 | Solar cell glass cover plate |
| CN103779448A (en) * | 2014-02-26 | 2014-05-07 | 中国科学院大学 | Silicon nanowire radial heterojunction solar battery manufacture method |
| CN103824969A (en) * | 2014-03-10 | 2014-05-28 | 太原理工大学 | Organic electroluminescence device with multi-layer metal composite electrode |
-
2014
- 2014-12-08 CN CN201410746185.0A patent/CN105741915A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN203434160U (en) * | 2013-07-22 | 2014-02-12 | 天津恒电空间电源有限公司 | Large-area silicon bypass diode for solar cell array |
| CN203503665U (en) * | 2013-08-05 | 2014-03-26 | 天津恒电空间电源有限公司 | Solar cell glass cover plate |
| CN103779448A (en) * | 2014-02-26 | 2014-05-07 | 中国科学院大学 | Silicon nanowire radial heterojunction solar battery manufacture method |
| CN103824969A (en) * | 2014-03-10 | 2014-05-28 | 太原理工大学 | Organic electroluminescence device with multi-layer metal composite electrode |
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Application publication date: 20160706 |