CN105735042B - A kind of preparation technology of water-transfer printing paper - Google Patents
A kind of preparation technology of water-transfer printing paper Download PDFInfo
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- CN105735042B CN105735042B CN201610208271.5A CN201610208271A CN105735042B CN 105735042 B CN105735042 B CN 105735042B CN 201610208271 A CN201610208271 A CN 201610208271A CN 105735042 B CN105735042 B CN 105735042B
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- water
- parts
- printing paper
- transfer printing
- preparation technology
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Abstract
The present invention provides a kind of preparation technology of water-transfer printing paper, and its formula is as follows：20 30 parts of water, 12 20 parts of cornstarch, 8 12 parts of farina, 5 12 parts of polyvinyl alcohol, 10 15 parts of ethanol, 48 parts of polyvinylpyrrolidone, 25 parts of organic titanate, 0.1 0.2 parts of nano silicon.Provided by the invention environmental friendly, pollution-free, surface smoothness is high.
Description
Technical field
The invention belongs to transfer technique field, and in particular to a kind of preparation technology of water-transfer printing paper.
Background technology
Water transfer technique is the newest digital imaging technique for surmounting any printing technical approach, and it is to be with special paper
Ink, realize and print image on any solid dielectric.Its maximum technical advantage is not need special equipment, not by medium
Limitation, it is not necessary to special consumptive material, it is not necessary to be heated at high temperature, only need in image input tool, such as：Scanner or digital camera；
Drawing tool, such as：Computer, image output instrument；Such as：Ink-jet printer；, just can be in office plus water-transfer printing paper and ink
Any image is indiscriminately ad. as one wishes printed in what solid objects, any curved surface.In recent years, water transfer technique has obtained widely should
With.
Water-transfer printing paper is the transfer thing as intermediate carrier in water transfer skill, and typically by up of three layers, lower floor is primary coat
Layer, centre for can film forming adhesive layer, upper strata is water-soluble adhesive layer.The Chinese invention application of Publication No. 101412836 discloses one
Kind covering water transfer printing polyvinyl alcohol blank base film formula and processing technology.Its counterdie formula is formed by following proportioning Raw material processings
's:Polyvinyl alcohol 75%-85%, water 5%-15%, ethylene glycol 0.1%-1%, cornstarch 1.5%-3.5%, O-phthalic
Sour dibutyl ester 0.1%-1%, alkyl sulfate system surfactant 2%-5.5%, glycerine 1%-2%, tbp
0.1%-1.0%.The patent application additionally provides the production technology of production covering water transfer printing polyvinyl alcohol blank base film, and it is to adopt
It is as follows with salivation film-forming process, its processing step:Polyvinyl alcohol is placed in reactor and is heated to 50 DEG C -70 DEG C；Then successively
Add water, ethylene glycol, cornstarch, o-phthalic acid dibutyl ester, alkyl sulfate system surfactant, glycerine, tricresyl phosphate
Slurry is made in -180 minutes 150 minutes in fourth fat, stirring；By slurry on coating machine even spread, then pass through 90 DEG C -100 DEG C
Drying tunnel heating winding film-like.Calligraphy and painting pattern is printed onto in the present invention by printing, then transferred by water by calligraphy and painting pattern
It is transferred on complex-shaped changeable product surface so that product designer, which is able to give full play to, is conceivable to deisgn product structure shape
Shape and style, and then image appearance and the market sale of product can be improved.
But the counterdie of the patent application contains substantial amounts of inorganic chemical, not environmentally；Moreover, the coating that the counterdie is deposited
It is poor for polyvinyl alcohol, its levelability so that the smoothness and glossiness of product are low, and printing effect is undesirable.And the life of the counterdie
Production. art is complicated, and cost is high, it is impossible to is widely popularized in market.
The content of the invention
It is provided by the invention environmental friendly, pollution-free it is an object of the invention to provide a kind of preparation technology of water-transfer printing paper,
Surface smoothness is high.
A kind of preparation technology of water-transfer printing paper, its formula are as follows：Water 20-30 parts, cornstarch 12-20 parts, potato are formed sediment
Powder 8-12 parts, polyvinyl alcohol 5-12 parts, ethanol 10-15 parts, polyvinylpyrrolidone 4-8 parts, organic titanate 2-5 parts, nanometer
Silica 0.1-0.2 parts.
The nano silicon is not more than 500 nanometers of silica using particle diameter.
The granularity of the cornstarch and farina is 150-200 mesh.
A kind of preparation technology of water-transfer printing paper, its step are as follows：
(1) starch mixes：Cornstarch is stirred with farina using powder agitating device and mixed, until stirring
Mix uniformly；
(2) dissolving stirring：Add water in mixing starch, heated while stirring, and be incubated and obtain pastel；
(3) cool down：Add polyvinyl alcohol and be stirred, quickly cooled down by the way of freezing, obtain solubility
Splendid table masking liquid；
(4) antiseptic synthesizes：Nano silicon is put into ethanol, and carries out low temperature ultrasonic；Add polyvinyl pyrrole
Alkanone, carry out secondary low temperature ultrasonic；Organic titanate is added, low temperature is carried out and quickly stirs；
(5) mixing water transfer coating：Antiseptic is added to table masking liquid, and quick ultrasound 3 is carried out using cell disruptor
Minute.
Mixing speed is 1000-3000r/min in the step (2), and heating-up temperature is 90-95 DEG C.
Mixing speed in the step (3) is 500-1200r/min, and cryogenic temperature is 40-50 DEG C.
Supersonic frequency in the step (4) is 30MHz.
The low temperature stirring of the step (4) is 30-50 DEG C.
Compared with prior art, the invention has the advantages that：
1. printing effect is good, the transfer paper smoothness worked it out according to this technique further improves, and can reach 110Sec/
More than 10ml, paper is finer and smoother, and glossiness can reach 85%GE, and color reducibility is good, that is, has splendid printing effect to ensure；
2. the feature of environmental protection is good, the present invention uses natural organic matter, coating provide for oneself and follow-up consumer product in, do not remain nothing
Machine thing chemicals and heavy metal, the use to many commodity, there is provided environmental protection ensures；
3. stripping rate is fast, the transfer requirement to high-quality, the demoulding can be accomplished soon to 45 seconds；
4. pattern remains without glue-line when being transferred using the water-transfer printing paper of table film of the present invention, ensure the cleaning of transfer article pattern
It is beautiful；
5. being placed with antiseptic in the present invention, there is good antibacterial effect, and favorable dispersibility, be easy to overall antibacterial to make
With.
Embodiment
The present invention is described further with reference to embodiment：
Embodiment 1
A kind of preparation technology of water-transfer printing paper, its formula are as follows：20 parts of water, 12 parts of cornstarch, 8 parts of farina,
5 parts of polyvinyl alcohol, 10 parts of ethanol, 4 parts of polyvinylpyrrolidone, 2 parts of organic titanate, 0.1 part of nano silicon.
The nano silicon uses the silica of 500 nanometers of particle diameter.
The granularity of the cornstarch and farina is 150 mesh.
A kind of preparation technology of water-transfer printing paper, its step are as follows：
(1) starch mixes：Cornstarch is stirred with farina using powder agitating device and mixed, until stirring
Mix uniformly；
(2) dissolving stirring：Add water in mixing starch, heated while stirring, and be incubated and obtain pastel；
(3) cool down：Add polyvinyl alcohol and be stirred, quickly cooled down by the way of freezing, obtain solubility
Splendid table masking liquid；
(4) antiseptic synthesizes：Nano silicon is put into ethanol, and carries out low temperature ultrasonic；Add polyvinyl pyrrole
Alkanone, carry out secondary low temperature ultrasonic；Organic titanate is added, low temperature is carried out and quickly stirs；
(5) mixing water transfer coating：Antiseptic is added to table masking liquid, and quick ultrasound 3 is carried out using cell disruptor
Minute.
Mixing speed is 1000r/min in the step (2), and heating-up temperature is 90 DEG C.
Mixing speed in the step (3) is 500r/min, and cryogenic temperature is 40 DEG C.
Supersonic frequency in the step (4) is 30MHz.
The low temperature stirring of the step (4) is 30 DEG C.
Embodiment 2
A kind of preparation technology of water-transfer printing paper, its formula are as follows：30 parts of water, 20 parts of cornstarch, 12 parts of farina,
12 parts of polyvinyl alcohol, 15 parts of ethanol, 8 parts of polyvinylpyrrolidone, 5 parts of organic titanate, 0.2 part of nano silicon.
The nano silicon uses the silica of 400 nanometers of particle diameter.
The granularity of the cornstarch and farina is 200 mesh.
A kind of preparation technology of water-transfer printing paper, its step are as follows：
(1) starch mixes：Cornstarch is stirred with farina using powder agitating device and mixed, until stirring
Mix uniformly；
(2) dissolving stirring：Add water in mixing starch, heated while stirring, and be incubated and obtain pastel；
(3) cool down：Add polyvinyl alcohol and be stirred, quickly cooled down by the way of freezing, obtain solubility
Splendid table masking liquid；
(4) antiseptic synthesizes：Nano silicon is put into ethanol, and carries out low temperature ultrasonic；Add polyvinyl pyrrole
Alkanone, carry out secondary low temperature ultrasonic；Organic titanate is added, low temperature is carried out and quickly stirs；
(5) mixing water transfer coating：Antiseptic is added to table masking liquid, and quick ultrasound 3 is carried out using cell disruptor
Minute.
Mixing speed is 3000r/min in the step (2), and heating-up temperature is 95 DEG C.
Mixing speed in the step (3) is 1200r/min, and cryogenic temperature is 50 DEG C.
Supersonic frequency in the step (4) is 30MHz.
The low temperature stirring of the step (4) is 50 DEG C.
Embodiment 3
A kind of preparation technology of water-transfer printing paper, its formula are as follows：25 parts of water, 16 parts of cornstarch, 10 parts of farina,
9 parts of polyvinyl alcohol, 13 parts of ethanol, 6 parts of polyvinylpyrrolidone, 3 parts of organic titanate, 0.1 part of nano silicon.
The nano silicon uses the silica of 300 nanometers of particle diameter.
The granularity of the cornstarch and farina is 170 mesh.
A kind of preparation technology of water-transfer printing paper, its step are as follows：
(1) starch mixes：Cornstarch is stirred with farina using powder agitating device and mixed, until stirring
Mix uniformly；
(2) dissolving stirring：Add water in mixing starch, heated while stirring, and be incubated and obtain pastel；
(3) cool down：Add polyvinyl alcohol and be stirred, quickly cooled down by the way of freezing, obtain solubility
Splendid table masking liquid；
(4) antiseptic synthesizes：Nano silicon is put into ethanol, and carries out low temperature ultrasonic；Add polyvinyl pyrrole
Alkanone, carry out secondary low temperature ultrasonic；Organic titanate is added, low temperature is carried out and quickly stirs；
(5) mixing water transfer coating：Antiseptic is added to table masking liquid, and quick ultrasound 3 is carried out using cell disruptor
Minute.
Mixing speed is 2000r/min in the step (2), and heating-up temperature is 92 DEG C.
Mixing speed in the step (3) is 900r/min, and cryogenic temperature is 45 DEG C.
Supersonic frequency in the step (4) is 30MHz.
The low temperature stirring of the step (4) is 40 DEG C.
One embodiment of the invention is the foregoing is only, is not intended to limit the present invention, it is all to use equivalent substitution or equivalent transformation
The technical scheme that is obtained of mode, all fall within protection scope of the present invention.
Claims (7)
- A kind of 1. preparation technology of water-transfer printing paper, it is characterised in that：Its formula is as follows：Water 20-30 parts, cornstarch 12-20 parts, Farina 8-12 parts, polyvinyl alcohol 5-12 parts, ethanol 10-15 parts, polyvinylpyrrolidone 4-8 parts, organic titanate 2-5 Part, nano silicon 0.1-0.2 parts,Its step is as follows：(1) starch mixes：Cornstarch is stirred with farina using powder agitating device and mixed, until stirring is equal It is even；(2) dissolving stirring：Add water in mixing starch, heated while stirring, and be incubated and obtain pastel；(3) cool down：Add polyvinyl alcohol and be stirred, use cryogenic temperature quickly to be cooled down for 40-50 DEG C of mode, obtain To soluble splendid table masking liquid；(4) antiseptic synthesizes：Nano silicon is put into ethanol, and carries out low temperature ultrasonic；Add polyvinylpyrrolidone, Carry out secondary low temperature ultrasonic；Organic titanate is added, low temperature is carried out and quickly stirs；(5) mixing water transfer coating：Antiseptic is added to table masking liquid, and quick ultrasound is carried out 3 minutes using cell disruptor.
- A kind of 2. preparation technology of water-transfer printing paper according to claims 1, it is characterised in that the nano silicon It is not more than 500 nanometers of silica using particle diameter.
- 3. the preparation technology of a kind of water-transfer printing paper according to claims 1, it is characterised in that the cornstarch and horse The granularity of bell sweet potato starch is 150-200 mesh.
- 4. the preparation technology of a kind of water-transfer printing paper according to claims 1, it is characterised in that stirred in the step (2) It is 1000-3000r/min to mix speed, and heating-up temperature is 90-95 DEG C.
- 5. the preparation technology of a kind of water-transfer printing paper according to claims 1, it is characterised in that in the step (3) Mixing speed is 500-1200r/min.
- 6. the preparation technology of a kind of water-transfer printing paper according to claims 1, it is characterised in that in the step (4) Supersonic frequency is 30MHz.
- A kind of 7. preparation technology of water-transfer printing paper according to claims 1, it is characterised in that the step (4) it is low Temperature stirring is 30-50 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610208271.5A CN105735042B (en) | 2016-04-05 | 2016-04-05 | A kind of preparation technology of water-transfer printing paper |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610208271.5A CN105735042B (en) | 2016-04-05 | 2016-04-05 | A kind of preparation technology of water-transfer printing paper |
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| CN105735042A CN105735042A (en) | 2016-07-06 |
| CN105735042B true CN105735042B (en) | 2017-11-10 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106522023A (en) * | 2016-09-27 | 2017-03-22 | 苏州吉谷新材料有限公司 | Thermal-sublimation instant drying transfer paper and coating layer thereof |
| CN106433382A (en) * | 2016-09-29 | 2017-02-22 | 苏州吉谷新材料有限公司 | Surface coating solution for printing transfer paper |
| CN106638129A (en) * | 2016-09-29 | 2017-05-10 | 苏州吉谷新材料有限公司 | Instantly dry transfer paper |
| CN106702814A (en) * | 2016-12-20 | 2017-05-24 | 苏州吉谷新材料有限公司 | Thermal sublimation coating high in bonding firmness |
| CN106904015B (en) * | 2017-04-20 | 2020-04-03 | 东升新材料（山东）有限公司 | Environment-friendly degradable high-definition digital printing water transfer paper and preparation method thereof |
| CN110816102B (en) * | 2018-08-14 | 2021-12-14 | 亿豪纳米科技股份有限公司 | Water transfer film with environmental protection and without using activator and transfer printing method thereof |
| CN111910463B (en) * | 2020-08-17 | 2022-09-09 | 明德新材料科技(浙江)股份有限公司 | Preparation process of water transfer printing paper |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4464585B2 (en) * | 2001-07-04 | 2010-05-19 | 日本合成化学工業株式会社 | Base film for transfer printing |
| CN1209411C (en) * | 2002-01-16 | 2005-07-06 | 郝喜海 | Method for regulating dissolving speed of water-soluble film |
| CN101412836A (en) * | 2008-09-19 | 2009-04-22 | 丁元波 | Covering water transfer printing polyvinyl alcohol blank base film prescription and production technique |
| CN102409575B (en) * | 2011-11-08 | 2014-03-19 | 深圳市域成华升转印材料有限公司 | Full degradable prime coat film of water transfer paper and production technology of prime coat film |
| CN103289131A (en) * | 2013-05-22 | 2013-09-11 | 南京财经大学 | Preparation method for starch-polyvinyl alcohol biologically-cross-linked nano-composite plastic film |
| CN105038054B (en) * | 2015-07-02 | 2017-11-24 | 嘉善宏瑞包装材料有限公司 | Water transfer printing film |
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