CN105733781B - A kind of motor tricycle special antiwear energy-saving lubricant oil and preparation method thereof - Google Patents

A kind of motor tricycle special antiwear energy-saving lubricant oil and preparation method thereof Download PDF

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CN105733781B
CN105733781B CN201610182006.4A CN201610182006A CN105733781B CN 105733781 B CN105733781 B CN 105733781B CN 201610182006 A CN201610182006 A CN 201610182006A CN 105733781 B CN105733781 B CN 105733781B
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parts
ester
motor tricycle
lubricant oil
saving lubricant
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CN105733781A (en
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黄毅
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Dongying Guoan Chemical Co ltd
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Dongying Guoan Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C10M2207/2825—Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/285—Esters of aromatic polycarboxylic acids
    • C10M2207/2855—Esters of aromatic polycarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06—Perfluoro polymers
    • C10M2213/062—Polytetrafluoroethylene [PTFE]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

Abstract

The invention discloses a kind of motor tricycle special antiwear energy-saving lubricant oils and preparation method thereof, the motor tricycle special antiwear energy-saving lubricant oil is made of the raw material of following weight parts: 2-4 parts of sulfurized alkylphenol calcium, 2-4 parts of boronation polyisobutene succinimide, 0.8-1.2 parts of zinc dibutyl dithiophosphate, 2-4 parts of polytetrafluoroethylene (PTFE), 3-7 parts of hydrogenated styrene isoprene copolymer, 0.2-0.8 parts of phenolic ester type ashless oxidation inhibitor, 4, 0.2-0.8 parts of 4'- dioctyl diphenylamine, 0.5-1 parts of polymethacrylates, 0.002-0.005 parts of dimethicone, 80-90 parts of base oil.Motor tricycle special antiwear energy-saving lubricant oil of the present invention, with suitable viscosity index (VI) and good viscosity temperature characteristic, good cryogenic property, excellent rubber compatibility, good corrosion resistance and antioxygenic property, the service life for extending engine, reduces the maintenance cost of equipment, and clean wear protection mode is provided for motorcycle engine；Preparation method, step are simple and environmentally-friendly, easy to implement.

Description

A kind of motor tricycle special antiwear energy-saving lubricant oil and preparation method thereof
Technical field
It is a kind of motor tricycle special antiwear energy-saving lubricant oil and its preparation side the present invention relates to technical field of lubricating oil Method.
Background technique
Lubricating oil is the oily liquids for being coated in machine bearing surface, divides animal oil, vegetable oil, petroleum oil by its source With four major class of synthetic lubricant fluid, has the effects that reduce friction, avoid generating heat, prevent wear and tear in machines.
However the engine lubricating oil of traditional motorcycle is easy blackening shortly after use, this is because engine moistens Lubricating oil covers the black carbon mud pellet attached bag for generating thick after the oxygen in air works with engine oil in lasting cleaning carbon particle On engine part, when the running speed and temperature of engine are higher, decomposition rate is faster, which is not only to hair Motivation damages, and can block oil pipe, and oil product is caused to be not transferred to engine, increases cost of equipment maintenance, reduces Service life of aeroengine.
Summary of the invention
For the deficiencies in the prior art, the first technical problem to be solved by the present invention is to provide a kind of three-wheel and rubs Motorcycle special antiwear energy-saving lubricant oil.
The second technical problem to be solved by the present invention is to provide a kind of motor tricycle special antiwear energy-saving lubricant oil Preparation method.
Object of the present invention is to what is be achieved through the following technical solutions:
A kind of motor tricycle special antiwear energy-saving lubricant oil, is made of: sulfurized alkylphenol calcium the raw material of following weight parts 2-4 parts, 2-4 parts of boronation polyisobutene succinimide, 0.8-1.2 parts of zinc dibutyl dithiophosphate, polytetrafluoroethylene (PTFE) 2-4 Part, 3-7 parts of hydrogenated styrene isoprene copolymer, 0.2-0.8 parts of phenolic ester type ashless oxidation inhibitor, 4,4'- dioctyl diphenylamine 0.2-0.8 parts, 0.5-1 parts of polymethacrylates, 0.002-0.005 parts of dimethicone, 80-90 parts of base oil.
The base oil is by tri trimellitate nonyl ester, 1,2,4 benzenetricarboxylic acid three (2- ethylhexyl) ester, adipic acid two N-octyl mixes；The tri trimellitate nonyl ester, 1,2,4 benzenetricarboxylic acid three (2- ethylhexyl) ester, adipic acid-di-n are pungent The mass ratio of ester is (1-3): (1-3): (1-3).
Preferably, the phenolic ester type ashless oxidation inhibitor is by bis- [3- (3, the 5- di-t-butyls-of the thio diethylene of 40-60wt% 4- hydroxy phenyl) propionic ester] and 40-60wt% triethylene glycol ether-two (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester Composition.
Preferably, the polytetrafluoroethylene (PTFE) is ptfe micropowder.
The present invention also provides the preparation methods of above-mentioned motor tricycle special antiwear energy-saving lubricant oil: by sulfenyl phenolate Calcium, boronation polyisobutene succinimide, zinc dibutyl dithiophosphate, polytetrafluoroethylene (PTFE), hydrogenated styrene isoprene are total Polymers, phenolic ester type ashless oxidation inhibitor, 4,4'- dioctyl diphenylamine, polymethacrylates, dimethicone, base oil are added It is uniformly mixed in reconciliation kettle to get the motor tricycle special antiwear energy-saving lubricant oil.
Motor tricycle special antiwear energy-saving lubricant oil of the present invention has suitable viscosity index (VI) and good viscous warm nature Energy, good cryogenic property, excellent rubber compatibility, good corrosion resistance and antioxygenic property, extend engine Service life reduces the maintenance cost of equipment, and clean wear protection mode is provided for motorcycle engine；Preparation method, step It is rapid simple and environmentally-friendly, it is easy to implement.
Specific embodiment
The present invention will be further explained with reference to the examples below, as described below, is only to preferable implementation of the invention Example, not limits the present invention, any person skilled in the art is possibly also with the disclosure above Technology contents be changed to the equivalent embodiment changed on an equal basis.Without departing from the concept of the present invention, according to the present invention Technical spirit any simple modification or equivalent variations that following embodiment is made, fall within the scope of protection of the present invention.
Each raw material introduction in embodiment:
Sulfurized alkylphenol calcium, using number of patent application: the method preparation of embodiment 1 in 201210389112.1.
Boronation polyisobutene succinimide, synthetic method is referring to ten thousand strong heros, Feng Jieyong, Luo Xinping " boronation ashless dispersion The development and application of agent ", lubricating oil, 2001, structural formula is as follows:
Wherein, R is the polyisobutene that molecular weight is 1000, R'=H.
Zinc dibutyl dithiophosphate, No. CAS: 6990-43-8.
Hydrogenated styrene isoprene copolymer is random using hydrogenated polystyrene-b- phenylethylene/butadiene/isoprene Copolymer, using number of patent application: the method preparation of embodiment 1 in 201410115135.2.
Polymethacrylates, using number of patent application: the method for embodiment 1 prepares poly- methyl in 201410753667.9 Acrylate.
Dimethicone, No. CAS: 63148-62-9, using DOW CORNING PMX-200 conventional viscosity defoaming agent dimethyl-silicon Oil, viscosity 350cs.
4,4'- dioctyl diphenylamines, No. CAS: 101-67-7.
Thio diethylene is bis- [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic ester], and No. CAS: 41484-35-9.
Triethylene glycol ether-two (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester, No. CAS: 36443-68-2.
Polytetrafluoroethylene (PTFE) is ptfe micropowder, No. CAS: 9002-84-0, using the auspicious micropowder material factory in the Shenyang City sky The ptfe micropowder of the model B01 of offer.
Tri trimellitate nonyl ester, No. CAS: 35415-27-1.
1,2,4- benzenetricarboxylic acid three (2- ethylhexyl) ester, No. CAS: 3319-31-1.
Di n octyl adipate, No. CAS: 123-79-5.
Embodiment 1
Motor tricycle special antiwear energy-saving lubricant oil raw material (parts by weight): 3 parts of sulfurized alkylphenol calcium, boronation polyisobutene 3 parts of succimide, 1 part of zinc dibutyl dithiophosphate, 2.5 parts of ptfe micropowder, hydrogenated styrene isoprene are total 5 parts of polymers, 0.5 part of phenolic ester type ashless oxidation inhibitor, 0.4 part of 4,4'- dioctyl diphenylamine, 0.7 part of polymethacrylates, diformazan 0.003 part of base silicone oil, 84 parts of base oil.
The base oil is by tri trimellitate nonyl ester, 1,2,4 benzenetricarboxylic acid three (2- ethylhexyl) ester, adipic acid two N-octyl is that 1:1:1 is uniformly mixed to obtain in mass ratio.
The phenolic ester type ashless oxidation inhibitor is by the bis- [3- (3,5- di-t-butyl -4- hydroxy benzenes of the thio diethylene of 50wt% Base) propionic ester] and 50wt% triethylene glycol ether-two (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester be uniformly mixed It obtains.
The preparation of motor tricycle special antiwear energy-saving lubricant oil:
Base oil is added in reconciliation kettle, is warming up to 50 DEG C, polymethacrylates, hydrogenated styrene isoprene is added Copolymer is warming up to 50 DEG C, and 300 revs/min are stirred 60 minutes；Sulfurized alkylphenol calcium, boronation polyisobutene succinimide is added, 65 DEG C are warming up to, 300 revs/min are stirred 60 minutes；Addition phenolic ester type ashless oxidation inhibitor, 4,4'- dioctyl diphenylamine, 300 revs/min Stirring 60 minutes；Above procedure carries out under 0.1MPa nitrogen protection, bleeds off nitrogen, deaerates 60 under conditions of -0.06MPa Minute；Temperature is down to 45 DEG C, bleeds off negative pressure, and zinc dibutyl dithiophosphate, ptfe micropowder, dimethicone is added, 300 revs/min are stirred 30 minutes；It is filtered by 5 μm of filters.Obtain the motor tricycle special antiwear energy conservation profit of embodiment 1 Lubricating oil.
Embodiment 2
Same as Example 1, difference is only in that: the base oil is by 1,2,4- benzenetricarboxylic acid three (2- ethylhexyl) Ester, di n octyl adipate are that 1:1 is uniformly mixed to obtain in mass ratio.The motor tricycle for obtaining embodiment 2 is dedicated anti- Grind energy-saving lubricant oil.
Embodiment 3
Same as Example 1, difference is only in that: the base oil is pungent by tri trimellitate nonyl ester, adipic acid-di-n Ester is that 1:1 is uniformly mixed to obtain in mass ratio.Obtain the motor tricycle special antiwear energy-saving lubricant oil of embodiment 3.
Embodiment 4
Same as Example 1, difference is only in that: the base oil is by tri trimellitate nonyl ester, 1,2,4- benzene front threes Sour three (2- ethylhexyl) esters are that 1:1 is uniformly mixed to obtain in mass ratio.The motor tricycle for obtaining embodiment 4 is dedicated anti- Grind energy-saving lubricant oil.
Embodiment 5
Same as Example 1, difference is only in that: the phenolic ester type ashless oxidation inhibitor is only the bis- [3- of thio diethylene (3,5- di-tert-butyl-hydroxy phenyl) propionic ester].Obtain the motor tricycle special antiwear energy-saving lubricant oil of embodiment 5.
Embodiment 6
Same as Example 1, difference is only in that: the phenolic ester type ashless oxidation inhibitor is only the (3- of triethylene glycol ether-two Tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester.Obtain the motor tricycle special antiwear energy-saving lubricant oil of embodiment 6.
Test case 1
The motor tricycle special antiwear energy-saving lubricant oil service performance of embodiment 4-6 is tested, it is straight that oil product grinds spot Diameter and average frictional force data are four ball frictional testing machine test datas, and test method is according to GB/T12583-90, four balls It is load 40kgf, runing time 1h that condition, which is arranged, in testing machine, and initial temperature and revolving speed are shown in Table 1.Specific test result is shown in Table 1.
Table 1: service performance test result table
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (tri trimellitate nonyl ester, 1,2,4- benzenetricarboxylic acid, three (2- ethyl Hexyl) ester, di n octyl adipate compounding) motor tricycle special antiwear energy-saving lubricant oil service performance is substantially better than embodiment 2-4 is (tri trimellitate nonyl ester, 1,2,4 benzenetricarboxylic acid three (2- ethylhexyl) ester, both any multiple in di n octyl adipate With).
Comparing embodiment 1 and embodiment 5-6, (thio bis- [3- (3, the 5- di-t-butyl -4- hydroxy benzenes of diethylene of embodiment 1 Base) propionic ester] and (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester of triethylene glycol ether-two compounding) motor tricycle is special Embodiment 5-6 (thio bis- [3- (3,5- di-t-butyl -4- the hydroxyls of diethylene are substantially better than with antiwear and energy-saving lubricant oil service performance Phenyl) propionic ester] and triethylene glycol ether-two (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester in single raw material).
Test case 2
The motor tricycle special antiwear energy-saving lubricant oil antioxygen property of embodiment 1-6 is tested, is tested according to SH/ The measurement of T 0193-2008 lubricating oil oxidation stability-rotary bomb oxidation test detection, the more long then antioxidant of oxidization time are better.Tool Body test result is shown in Table 2.
Table 2: antioxygen property test result table
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (tri trimellitate nonyl ester, 1,2,4- benzenetricarboxylic acid, three (2- ethyl Hexyl) ester, di n octyl adipate compounding) motor tricycle special antiwear energy-saving lubricant oil antioxygen property is substantially better than embodiment 2-4 is (tri trimellitate nonyl ester, 1,2,4 benzenetricarboxylic acid three (2- ethylhexyl) ester, both any multiple in di n octyl adipate With).
Comparing embodiment 1 and embodiment 5-6, (thio bis- [3- (3, the 5- di-t-butyl -4- hydroxy benzenes of diethylene of embodiment 1 Base) propionic ester] and (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester of triethylene glycol ether-two compounding) motor tricycle is special Embodiment 5-6 (thio bis- [3- (3,5- di-t-butyl -4- the hydroxyls of diethylene are substantially better than with antiwear and energy-saving lubricant oil antioxygen property Phenyl) propionic ester] and triethylene glycol ether-two (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionic ester in single raw material).

Claims (3)

1. a kind of motor tricycle special antiwear energy-saving lubricant oil, which is characterized in that be made of the raw material of following weight parts: vulcanization 2-4 parts of alkyl phenol calcium, 2-4 parts of boronation polyisobutene succinimide, 0.8-1.2 parts of zinc dibutyl dithiophosphate, polytetrafluoro 2-4 parts of ethylene, 3-7 parts of hydrogenated styrene isoprene copolymer, 0.2-0.8 parts of phenolic ester type ashless oxidation inhibitor, 4,4'- dioctyl 0.2-0.8 parts of diphenylamines, 0.5-1 parts of polymethacrylates, 0.002-0.005 parts of dimethicone, 80-90 parts of base oil；
The base oil is pungent by tri trimellitate nonyl ester, 1,2,4 benzenetricarboxylic acid three (2- ethylhexyl) ester, adipic acid-di-n Ester mixes；The tri trimellitate nonyl ester, 1,2,4 benzenetricarboxylic acid three (2- ethylhexyl) ester, di n octyl adipate Mass ratio is (1-3): (1-3): (1-3)；The phenolic ester type ashless oxidation inhibitor by the thio diethylene of 40-60wt% it is bis- [3- (3, 5- di-tert-butyl-hydroxy phenyl) propionic ester] and (3- tertiary butyl-4-hydroxy -5- methyl of 40-60wt% triethylene glycol ether-two Phenyl) propionic ester composition.
2. motor tricycle special antiwear energy-saving lubricant oil as described in claim 1, it is characterised in that: the polytetrafluoroethyl-ne Alkene is ptfe micropowder.
3. the preparation method of motor tricycle special antiwear energy-saving lubricant oil as claimed in claim 1 or 2, it is characterised in that: By sulfurized alkylphenol calcium, boronation polyisobutene succinimide, zinc dibutyl dithiophosphate, polytetrafluoroethylene (PTFE), hydrogenation of benzene second Alkene isoprene copolymer, phenolic ester type ashless oxidation inhibitor, 4,4'- dioctyl diphenylamine, polymethacrylates, dimethyl-silicon Oil, base oil are added in reconciliation kettle and are uniformly mixed to get the motor tricycle special antiwear energy-saving lubricant oil.
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CN106590880A (en) * 2016-12-13 2017-04-26 天津箭牌石油化工有限公司 Lubricating oil viscosity index improver and preparation method thereof
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CN103113967A (en) * 2013-03-06 2013-05-22 广西大学 Environment-friendly and energy-saving gasoline engine lubricating oil
CN103666661A (en) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 Petroleum-engine oil composition and application thereof

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CN101195786A (en) * 2006-12-07 2008-06-11 中国石油天然气股份有限公司 Gasoline and engine oil composition
CN103666661A (en) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 Petroleum-engine oil composition and application thereof
CN103113967A (en) * 2013-03-06 2013-05-22 广西大学 Environment-friendly and energy-saving gasoline engine lubricating oil

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