CN103571599A - Application of lubricating oil composition in tire fitting - Google Patents
Application of lubricating oil composition in tire fitting Download PDFInfo
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- CN103571599A CN103571599A CN201210278175.XA CN201210278175A CN103571599A CN 103571599 A CN103571599 A CN 103571599A CN 201210278175 A CN201210278175 A CN 201210278175A CN 103571599 A CN103571599 A CN 103571599A
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Abstract
The invention relates to application of a lubricating oil composition in tire fitting, and is mainly used for solving the problem that polymer type fitting lubricating oil in the prior art has no anti-corrosive property to aluminum alloy rim. The problem is well solved by the technical scheme that the lubricating oil composition comprises the following components in parts by weight: a) 10-30 parts of base oil, b) 15-35 parts of corrosion inhibitor, c) 8-20 parts of emulsifier, d) 1-6 parts of oil agent, and e) 5-40 parts of water. The lubricating oil composition can be applied to industrial production of automobile radial tire fitting.
Description
Technical field
The present invention relates to the application of a kind of lubricating fluid composition in tire assembling.
Background technology
Tire is the vitals in automobile running system, can play the effect of supporting vehicle body, buffering foreign impacts, realizes the rideability that contacts and guarantee vehicle with road surface.The assembling process of tire, is exactly by the ground connection rolling circle cyclic spring rubber item on various vehicles, under certain pressure and lubricating condition, is arranged in alloy rim.Be no matter original equipped tyre or replace tire, although assembling is simple to operate,, assembly quality is very large on the life-span of tire and vehicle handling quality impact, has caused the attention of Automobile Enterprises.
At present, owing to having, quality is light, tire flexibility is large, damping property is good, exercise in the advantage such as the low and long service life of tire temperature, on car, nearly all adopt radial.But radial hardness is higher simultaneously, therefore when assembling, should smear at tire bead position one deck lubricant, to reduce dress tire resistance, just to fill inflation pressure and the damage to tire, do not affect transient equilibrium and the resistance to air loss of tire.In the past, the assembling lubricating fluid that people commonly use, comprises water, suds, liquid detergent etc., and cost is lower, originates simple and easy, but can easily make aluminium alloy wheel rim get rusty; Adopt machine oil, kerosene, butter etc. can have certain corrosion to the rubber of tire again, result of use is all undesirable.The assembling lubricating fluid of import can meet use needs, but procurement cycle is long, expensive, and application is at home restricted, and has no any disclosed technical literature report and patent simultaneously abroad.
Patent CN1546620A discloses a kind of aqueous solutions of polymers by fatty compounds and derivative thereof, acrylate copolymer, Oleum Cocois alkylolamide, the three red oily tire fitting lubricants that form, and for tubeless meridian tire, assembles.But polymer-type assembling liquid wherein is only mentioned the adaptability of this lubricating fluid to wheel rim lacquer painting; lubricant film is colourless, without cracked and come off; and the antirust and provide protection that aluminium alloy wheel rim is played of not mentioned product, and its preparation time is long, and only polymkeric substance uniform dissolution just needs approximately 5 ~ 7 days in water.
Summary of the invention
Technical problem to be solved by this invention is in prior art, to assemble lubricating fluid not possess the problem to the Corrosion Protection of aluminium alloy wheel rim, provides a kind of lubricating fluid composition to be applied to automobile radial tire assembling.When this lubricating fluid composition is used in tire assembling process, not only have good oilness and rubber compatibility, and can play antirust and provide protection to aluminium alloy wheel rim, preparation technology is simple, consuming time short simultaneously.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows: the application of a kind of lubricating fluid composition in tire assembling, and wherein said lubricating fluid compound, comprises following component in parts by weight:
A) base oil of 10 ~ 30 parts;
B) corrosion inhibitor of 15 ~ 35 parts;
C) emulsifying agent of 8 ~ 20 parts;
D) oiliness improver of 1 ~ 6 part;
E) water of 5 ~ 40 parts;
Wherein, described corrosion inhibitor is selected from least one in boric acid, borate, boric acid ester, carboxylic acid, acid amides, hydramine or sulfonate;
Described emulsifying agent is selected from least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene ester, polyol ester, sodium sulfonate, fatty acid soaps class or alkylol amide;
Described oiliness improver is selected from least one in palmitinic acid, stearic acid, oleic acid, linolic acid, linoleic acid dimer, ricinoleic acid, sylvic acid or linolenic acid.
In technique scheme, in parts by weight, the consumption preferable range of base oil is 10 ~ 20 parts, the consumption preferable range of corrosion inhibitor is 18 ~ 30 parts, the consumption preferable range of emulsifying agent is 10 ~ 18 parts, the consumption preferable range of oiliness improver is 1.5 ~ 4.5 parts, and the consumption preferable range of water is 8 ~ 35 parts.Described base oil preferred version is that the kinematic viscosity being selected from 40 ℃ is not more than 30mm
2s
-1mineral type base oil.In described corrosion inhibitor, carboxylic acid preferred version contains C for being selected from
2~ C
16straight or branched alkyl carboxylic acid at least one; Acid amides preferred version is at least one being selected from fatty monoethanol amide, fatty diglycollic amide, lipid acid diisopropanol acid amides or boron acid amides; Hydramine preferred version is at least one being selected from monoethanolamine, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA) or 2-amino-2-methyl-1-propanol; Sulfonate preferred version is at least one being selected from sodium sulfonate or barium sulfonate.In described emulsifying agent, fatty alcohol-polyoxyethylene ether preferred version is for being selected from C
12~ C
20fatty alcohol-polyoxyethylene ether; Alkylphenol polyoxyethylene preferred version is for being selected from C
8~ C
9alkylphenol polyoxyethylene; Polyoxyethylene ester preferred version is at least one being selected from stearic acid polyoxyethylene ester, lauric acid polyoxyethylene ester or castor oil polyoxyethylene ester; Polyol ester preferred version is for being selected from sorbitan fatty acid ester; Fatty acid soaps class preferred version is at least one being selected from triethanolamine oleate, linolic acid monoethanolamine soap or succinic acid trolamine soap; Alkylol amide preferred version is at least one being selected from coconut oleoyl diethanolamine or lauroyl diethanolamine.
In technique scheme, in parts by weight, preferred version is also to comprise f in described lubricating fluid composition) defoamer or g) at least one in sterilant; The consumption of defoamer is 0.001~1 part, and preferable range is 0.01~0.1 part; The consumption of sterilant is 0.01~5 part, and preferable range is 0.01~3 part.Described defoamer preferred version is at least one being selected from polyethers defoamer or silicone emulsion; Sterilant preferred version is at least one being selected from triazine, morpholine, pyridine sodium-mercaptan oxidation thing, Phenoxyethanol or isothiazolinone.
In technique scheme, described tire preferred version is radial.
The preparation method of lubricating fluid composition of the present invention is as follows: when base oil is heated to 30~40 ℃, the water, corrosion inhibitor, emulsifying agent, oiliness improver, defoamer and the sterilant that add successively aequum, continue insulated and stirred at 30~40 ℃ and within 2 ~ 10 hours, obtain described lubricating fluid composition.This liquid can be used after in 2 ~ 20 % by weight ratio thin ups, preferably 5 ~ 15 % by weight.
Lubricating fluid composition in the present invention; owing to taking full advantage of the synergy of base oil, corrosion inhibitor, emulsifying agent and oiliness improver; while being used for the assembling process of doughnut; can not only meet the requirement of the automobile radial tire assembling lubricity that hardness is larger; and can keep weakly alkaline and form certain adsorption film at contact surface; aluminium alloy wheel rim is played to antirust and provide protection, simultaneously good with rubber for tire consistency.Preparation technology is simple for this lubricating fluid composition, consuming time short, only needs can prepare about half a day.In addition, composition can dilute use, good economy performance, and in use, diluent is uniformly dispersed stablely, is difficult for layering, has obtained good technique effect.
Below by embodiment, the invention will be further elaborated.
Embodiment
[embodiment 1 ~ 5]
Base oil is pumped into blending kettle, starts agitator and heater switch, when oil product is heated to 40 ℃, add successively each component of aequum, at 40 ℃, continue insulated and stirred and within 3 hours, obtain faint yellow uniform liquid.This liquid is carried out to performance test after in 10 % by weight ratio thin ups.In lubricating fluid composition, each component and content are in Table 1, and its respective performances index is in Table 3.In table 1,
T-80, sorbitan oleate Soxylat A 25-7, auxiliary reagent factory, Tianjin 6501, dodecyl diglycollic amide, second auxiliary factory, Shanghai
S-80, sorbitan monooleate, auxiliary reagent factory, Tianjin Emulgen M, aliphatic acid polyethenoxy ether, Clariant company
S-60, sorbitan monooleate, auxiliary reagent factory, Tianjin OP-10, polyoxyethylene Zhong Xin phenolic ether-10, chemical plant, Lvshun
TX-10, polyoxyethylene octylphenol ether 10, the NP-10 of Shanghai Gao Huasan factory, polyoxyethylene nonylphenol ether 10, Xingtai City auxiliary reagent factory
TX-7, polyoxyethylene octylphenol ether 7, the L-AN5 of Shanghai Gao Huasan factory, oil for total loss system, high bridge refinery
AEO-3, polyoxyethylene aliphatic alcohol ether, the L-AN15 of Zhejiang Huang Ma chemical company, oil for total loss system, high bridge refinery
AEO-7, polyoxyethylene aliphatic alcohol ether, the L-AN32 of Zhejiang Huang Ma chemical company, oil for total loss system, high bridge refinery
MOA-3, polyoxyethylene aliphatic alcohol ether, the HVI75 of Zhejiang Huang Ma chemical company, lubricant base, high bridge refinery
MOA-5, polyoxyethylene aliphatic alcohol ether, the bubble enemy of Zhejiang Huang Ma chemical company, glycerol polyoxypropylene oxygen Vinyl Ether, chemical plant, Binzhou
MOA-7, polyoxyethylene aliphatic alcohol ether, Zhejiang Huang Ma chemical company silicone emulsion, Shanghai Resin Factory
AMP-95, the Antifoam HW of 2-amino-2-methyl-1-propanol ,DOW company, non-silicon kilfoam, polartech company
The corrosion test of lubricating fluid composition carries out in certain Limousine Assembly workshop.During test, the lubricating fluid composition of 2 ~ 20% weaker concns is brushed 2 times on edge, aluminium alloy wheel rim outer ring, be placed in indoor shady and cool place, observe respectively 7 days, 15 days, 30 days rear rim surface changing conditions and grade.Wherein, A level---rustless, gloss is as newly; B level---slightly dimmed; C level---moderate is dimmed; D level---seriously dimmed.
Changes in weight method in the test reference GB/T1690 of lubricating fluid rubber compatibility is carried out.
[comparative example 1 ~ 3]
Formulated according to each component in the disclosed tire fitting lubricant of patent CN1546620A, directly stoste is carried out to performance test.In the product of comparative example, each component and content are in Table 2, and product performance are in Table 3.
[embodiment 6]
By the lubricating fluid composition of [embodiment 1 ~ 5] in 10 % by weight ratio thin ups after, lubricated for automobile radial tire assembling.In use procedure, show good lubricity, time saving and energy saving.Tire assembled and places after the long period, and aluminium alloy wheel rim gloss is as newly, and lubricating fluid composition has played certain antirust and provide protection, and simultaneously good with rubber for tire consistency, tyre air tightness is good.
Table 1
Table 2
Table 3
Claims (9)
1. the application of lubricating fluid composition in tire assembling, wherein said lubricating fluid compound, comprises following component in parts by weight:
A) base oil of 10 ~ 30 parts;
B) corrosion inhibitor of 15 ~ 35 parts;
C) emulsifying agent of 8 ~ 20 parts;
D) oiliness improver of 1 ~ 6 part;
E) water of 5 ~ 40 parts;
Wherein, described corrosion inhibitor is selected from least one in boric acid, borate, boric acid ester, carboxylic acid, acid amides, hydramine or sulfonate;
Described emulsifying agent is selected from least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene ester, polyol ester, sodium sulfonate, fatty acid soaps class or alkylol amide;
Described oiliness improver is selected from least one in palmitinic acid, stearic acid, oleic acid, linolic acid, linoleic acid dimer, ricinoleic acid, sylvic acid or linolenic acid.
2. the application of lubricating fluid composition according to claim 1 in tire assembling, it is characterized in that in parts by weight, the consumption of base oil is 10 ~ 20 parts, the consumption of corrosion inhibitor is 18 ~ 30 parts, the consumption of emulsifying agent is 10 ~ 18 parts, the consumption of oiliness improver is 1.5 ~ 4.5 parts, and the consumption of water is 8 ~ 35 parts.
3. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that the kinematic viscosity that described base oil is selected from 40 ℃ is not more than 30mm
2s
-1mineral type base oil.
4. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that in described corrosion inhibitor, carboxylic acid is selected from and contains C
2~ C
16straight or branched alkyl carboxylic acid at least one; Acid amides is selected from least one in fatty monoethanol amide, fatty diglycollic amide, lipid acid diisopropanol acid amides or boron acid amides; Hydramine is selected from least one in monoethanolamine, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA) or 2-amino-2-methyl-1-propanol; Sulfonate is selected from least one in sodium sulfonate or barium sulfonate.
5. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that in described emulsifying agent, fatty alcohol-polyoxyethylene ether is selected from C
12~ C
20fatty alcohol-polyoxyethylene ether; Alkylphenol polyoxyethylene is selected from C
8~ C
9alkylphenol polyoxyethylene; Polyoxyethylene ester is selected from least one in stearic acid polyoxyethylene ester, lauric acid polyoxyethylene ester or castor oil polyoxyethylene ester; Polyol ester is selected from sorbitan fatty acid ester; Fatty acid soaps class is selected from least one in triethanolamine oleate, linolic acid monoethanolamine soap or succinic acid trolamine soap; Alkylol amide is selected from least one in coconut oleoyl diethanolamine or lauroyl diethanolamine.
6. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that in parts by weight, in described lubricating fluid composition, also comprises f) defoamer or g) at least one in sterilant; The consumption of defoamer is 0.001~1 part, and the consumption of sterilant is 0.01~5 part.
7. the application of lubricating fluid composition according to claim 6 in tire assembling, is characterized in that described defoamer is selected from least one in polyethers defoamer or silicone emulsion; Sterilant is selected from least one in triazine, morpholine, pyridine sodium-mercaptan oxidation thing, Phenoxyethanol or isothiazolinone.
8. the application of lubricating fluid composition according to claim 6 in tire assembling, the consumption that it is characterized in that described defoamer is 0.01~0.1 part; The consumption of sterilant is 0.01~3 part.
9. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that described tire is radial.
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