CN103571599B - Application of lubricating oil composition in tire fitting - Google Patents

Application of lubricating oil composition in tire fitting Download PDF

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CN103571599B
CN103571599B CN201210278175.XA CN201210278175A CN103571599B CN 103571599 B CN103571599 B CN 103571599B CN 201210278175 A CN201210278175 A CN 201210278175A CN 103571599 B CN103571599 B CN 103571599B
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acid
parts
lubricating fluid
fluid composition
consumption
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CN103571599A (en
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郑春燕
李谨
周勤祖
陈晨
张志东
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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Abstract

The invention relates to application of a lubricating oil composition in tire fitting, and is mainly used for solving the problem that polymer type fitting lubricating oil in the prior art has no anti-corrosive property to aluminum alloy rim. The problem is well solved by the technical scheme that the lubricating oil composition comprises the following components in parts by weight: a) 10-30 parts of base oil, b) 15-35 parts of corrosion inhibitor, c) 8-20 parts of emulsifier, d) 1-6 parts of oil agent, and e) 5-40 parts of water. The lubricating oil composition can be applied to industrial production of automobile radial tire fitting.

Description

The application of lubricating fluid composition in tire assembling
Technical field
The present invention relates to the application of a kind of lubricating fluid composition in tire assembling.
Background technology
Tire is the vitals in automobile running system, can play the effect of supporting vehicle body, buffering foreign impacts, realizes with the contact on road surface and ensures the rideability of vehicle.The assembling process of tire, is exactly by the ground connection rolling circle cyclic spring rubber item on various vehicle, under certain pressure and lubricating condition, is arranged in alloy rim.No matter be original equipped tyre or replacement tire, although assembling is simple to operate, assembly quality affects very large on the life-span of tire and vehicle handling quality, caused the attention of Automobile Enterprises.
At present, owing to having, quality is light, tire flexibility is large, damping property is good, exercise in the advantage such as the low and long service life of tire temperature, car nearly all adopts radial.But radial hardness is higher simultaneously, therefore one deck lubricant be should smear at tire bead position when assembling, to reduce dress tire resistance, just dress inflation pressure and the damage to tire, transient equilibrium and the resistance to air loss of tire do not affected.Past, the assembling lubricating fluid that people commonly use, comprise water, suds, liquid detergent etc., cost is lower, originates simple and easy, but can easily make aluminium alloy wheel rim get rusty; Adopt machine oil, kerosene, butter etc. can have certain corrosion to the rubber of tire again, result of use is all undesirable.The assembling lubricating fluid of import can meet use needs, but procurement cycle is long, expensive, and application is at home restricted, and has no any disclosed technical literature report and patent abroad simultaneously.
The tire fitting lubricants that patent CN1546620A discloses a kind of aqueous solutions of polymers by fatty compounds and derivative thereof, acrylate copolymer, Oleum Cocois alkylolamide, three red oil form, assemble for tubeless meridian tire.But polymer-type assembling liquid wherein only mentions the adaptability of this lubricating fluid to wheel rim lacquer painting; lubricant film is colourless, without cracked and come off; and the antirust and provide protection that not mentioned product plays aluminium alloy wheel rim, and its preparation time is long, only polymer uniform is dissolved in water and just needs about 5 ~ 7 days.
Summary of the invention
Technical problem to be solved by this invention assembles the problem that lubricating fluid does not possess the Corrosion Protection to aluminium alloy wheel rim in prior art, provides a kind of lubricating fluid composition to be applied to automobile radial tire assembling.When this lubricating fluid composition uses in tyre assembling process, not only have good oilness and rubber compatibility, and can play antirust and provide protection to aluminium alloy wheel rim, preparation technology is simple simultaneously, consuming time short.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows: the application of a kind of lubricating fluid composition in tire assembling, and wherein said lubricating fluid compound, comprises following component with weight parts:
A) base oil of 10 ~ 30 parts;
B) corrosion inhibitor of 15 ~ 35 parts;
C) emulsifying agent of 8 ~ 20 parts;
D) oiliness improver of 1 ~ 6 part;
E) water of 5 ~ 40 parts;
Wherein, described corrosion inhibitor is selected from least one in boric acid, borate, boric acid ester, carboxylic acid, acid amides, hydramine or sulfonate;
Described emulsifying agent is selected from least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene ester, polyol ester, sodium sulfonate, fatty acid soaps class or alkylol amide;
Described oiliness improver is selected from least one in palmitinic acid, stearic acid, oleic acid, linolic acid, linoleic acid dimer, ricinoleic acid, sylvic acid or linolenic acid.
In technique scheme, with weight parts, the consumption preferable range of base oil is 10 ~ 20 parts, the consumption preferable range of corrosion inhibitor is 18 ~ 30 parts, the consumption preferable range of emulsifying agent is 10 ~ 18 parts, the consumption preferable range of oiliness improver is 1.5 ~ 4.5 parts, and the consumption preferable range of water is 8 ~ 35 parts.Described base oil preferred version is that the kinematic viscosity be selected from 40 DEG C is not more than 30mm 2s -1mineral type base oil.In described corrosion inhibitor, carboxylic acid preferred version is for being selected from containing C 2~ C 16straight or branched alkyl carboxylic acid at least one; Acid amides preferred version is be selected from least one in fatty monoethanol amide, fatty diglycollic amide, lipid acid diisopropanol acid amides or boron acid amides; Hydramine preferred version is be selected from least one in monoethanolamine, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA) or 2-amino-2-methyl-1-propanol; Sulfonate preferred version is be selected from least one in sodium sulfonate or barium sulfonate.In described emulsifying agent, fatty alcohol-polyoxyethylene ether preferred version is for being selected from C 12~ C 20fatty alcohol-polyoxyethylene ether; Alkylphenol polyoxyethylene preferred version is for being selected from C 8~ C 9alkylphenol polyoxyethylene; Polyoxyethylene ester preferred version is be selected from least one in stearic acid polyoxyethylene ester, lauric acid polyoxyethylene ester or castor oil polyoxyethylene ester; Polyol ester preferred version is for being selected from sorbitan fatty acid ester; Fatty acid soaps class preferred version is be selected from least one in triethanolamine oleate, linolic acid monoethanolamine soap or succinic acid trolamine soap; Alkylol amide preferred version is be selected from least one in coconut oleoyl diethanolamine or lauroyl diethanolamine.
In technique scheme, with weight parts, preferred version is also comprise f) defoamer or at least one g) in sterilant in described lubricating fluid composition; The consumption of defoamer is 0.001 ~ 1 part, and preferable range is 0.01 ~ 0.1 part; The consumption of sterilant is 0.01 ~ 5 part, and preferable range is 0.01 ~ 3 part.Described defoamer preferred version is be selected from least one in polyethers defoamer or silicone emulsion; Sterilant preferred version is be selected from least one in triazine, morpholine, pyridine sodium-mercaptan oxidation thing, Phenoxyethanol or isothiazolinone.
In technique scheme, described tire preferred version is radial.
The preparation method of lubricating fluid composition of the present invention is as follows: when base oil being heated to 30 ~ 40 DEG C, add the water of aequum, corrosion inhibitor, emulsifying agent, oiliness improver, defoamer and sterilant successively, continue insulated and stirred at 30 ~ 40 DEG C and within 2 ~ 10 hours, namely obtain described lubricating fluid composition.This liquid can be used in after 2 ~ 20 % by weight ratio thin ups, preferably 5 ~ 15 % by weight.
Lubricating fluid composition in the present invention; owing to taking full advantage of the synergy of base oil, corrosion inhibitor, emulsifying agent and oiliness improver; during assembling process for doughnut; the requirement of the larger automobile radial tire assembling lubricity of hardness can not only be met; and weakly alkaline can be kept and form certain adsorption film at contact surface; antirust and provide protection is played to aluminium alloy wheel rim, simultaneously good with rubber for tire consistency.This lubricating fluid composition preparation technology is simple, consuming time short, can prepare about only needing half a day.In addition, composition can dilute use, good economy performance, uses middle diluent to be uniformly dispersed stable, not easily layering, achieves good technique effect.
Below by embodiment, the invention will be further elaborated.
Embodiment
[embodiment 1 ~ 5]
Base oil is pumped into blending kettle, starts agitator and heater switch, when oil product is heated to 40 DEG C, add each component of aequum successively, continue insulated and stirred at 40 DEG C and namely obtain faint yellow uniform liquid in 3 hours.This liquid is carried out performance test in after 10 % by weight ratio thin ups.In lubricating fluid composition, each component and content are in table 1, and its respective performances index is in table 3.In table 1,
T-80, sorbitan oleate Soxylat A 25-7, Tianjin auxiliary reagent factory 6501, lauryl diethanolamide, Shanghai second auxiliary factory
S-80, sorbitan monooleate, Tianjin auxiliary reagent factory Emulgen M, aliphatic acid polyethenoxy ether, Clariant company
S-60, sorbitan monooleate, Tianjin auxiliary reagent factory OP-10, polyoxyethylene Zhong Xin phenolic ether-10, chemical plant, Lvshun
TX-10, polyoxyethylene octylphenol ether 10, Shanghai Gao Huasan factory NP-10, polyoxyethylene nonylphenol ether 10, Xingtai City auxiliary reagent factory
TX-7, polyoxyethylene octylphenol ether 7, Shanghai Gao Huasan factory L-AN5, total loss system oil, high bridge refinery
AEO-3, polyoxyethylene aliphatic alcohol ether, Zhejiang Huang Ma chemical company L-AN15, total loss system oil, high bridge refinery
AEO-7, polyoxyethylene aliphatic alcohol ether, Zhejiang Huang Ma chemical company L-AN32, total loss system oil, high bridge refinery
MOA-3, polyoxyethylene aliphatic alcohol ether, Zhejiang Huang Ma chemical company HVI75, lubricant base, high bridge refinery
MOA-5, polyoxyethylene aliphatic alcohol ether, Zhejiang Huang Ma chemical company bubble enemy, glycerol polyoxypropylene oxygen Vinyl Ether, chemical plant, Binzhou
MOA-7, polyoxyethylene aliphatic alcohol ether, Zhejiang Huang Ma chemical company silicone emulsion, Shanghai Resin Factory
AMP-95,2-amino-2-methyl-1-propanol, DOW company Antifoam HW, non-silicon kilfoam, polartech company
The corrosion test of lubricating fluid composition carries out in certain Limousine Assembly workshop.During test, the lubricating fluid composition of 2 ~ 20% weaker concns is brushed 2 times on edge, aluminium alloy wheel rim outer ring, be placed in indoor shady and cool place, observe 7 days, 15 days, 30 days rear rim surface changing conditions respectively and grade.Wherein, A level---rustless, gloss is as newly; B level---slightly dimmed; C level---moderate is dimmed; D level---seriously dimmed.
Changes in weight method in the test reference GB/T1690 of lubricating fluid rubber compatibility is carried out.
[comparative example 1 ~ 3]
In tire fitting lubricant disclosed in patent CN1546620A, each component is formulated, directly carries out performance test to stoste.In the product of comparative example, each component and content are in table 2, and product performance are in table 3.
[embodiment 6]
By the lubricating fluid composition of [embodiment 1 ~ 5] in after 10 % by weight ratio thin ups, for automobile radial tire assembling lubrication.In use procedure, show good lubricity, time saving and energy saving.Tire assembles and after placing the long period, aluminium alloy wheel rim gloss is as newly, and lubricating fluid composition serves certain antirust and provide protection, and simultaneously good with rubber for tire consistency, tyre air tightness is good.
Table 1
Table 2
Table 3

Claims (8)

1. the application of lubricating fluid composition in tire assembling, wherein said lubricating fluid composition, comprises following component with weight parts:
A) base oil of 10 ~ 30 parts;
B) corrosion inhibitor of 15 ~ 35 parts;
C) emulsifying agent of 8 ~ 20 parts;
D) oiliness improver of 1 ~ 6 part;
E) water of 5 ~ 40 parts;
Wherein, described corrosion inhibitor is selected from least one in boric acid, borate, boric acid ester, carboxylic acid, acid amides, hydramine or sulfonate;
Described emulsifying agent is selected from least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene ester, polyol ester, sodium sulfonate, fatty acid soaps class or alkylol amide;
Described oiliness improver is selected from least one in palmitinic acid, stearic acid, oleic acid, linolic acid, linoleic acid dimer, ricinoleic acid, sylvic acid or linolenic acid;
The kinematic viscosity that described base oil is selected from 40 DEG C is not more than 30mm 2s -1mineral type base oil.
2. the application of lubricating fluid composition according to claim 1 in tire assembling, it is characterized in that with weight parts, the consumption of base oil is 10 ~ 20 parts, the consumption of corrosion inhibitor is 18 ~ 30 parts, the consumption of emulsifying agent is 10 ~ 18 parts, the consumption of oiliness improver is 1.5 ~ 4.5 parts, and the consumption of water is 8 ~ 35 parts.
3. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that in described corrosion inhibitor, carboxylic acid is selected from containing C 2~ C 16straight or branched alkyl carboxylic acid at least one; Acid amides is selected from least one in fatty monoethanol amide, fatty diglycollic amide, lipid acid diisopropanol acid amides or boron acid amides; Hydramine is selected from least one in monoethanolamine, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA) or 2-amino-2-methyl-1-propanol; Sulfonate is selected from least one in sodium sulfonate or barium sulfonate.
4. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that in described emulsifying agent, fatty alcohol-polyoxyethylene ether is selected from C 12~ C 20fatty alcohol-polyoxyethylene ether; Alkylphenol polyoxyethylene is selected from C 8~ C 9alkylphenol polyoxyethylene; Polyoxyethylene ester is selected from least one in stearic acid polyoxyethylene ester, lauric acid polyoxyethylene ester or castor oil polyoxyethylene ester; Polyol ester is selected from sorbitan fatty acid ester; Fatty acid soaps class is selected from least one in triethanolamine oleate, linolic acid monoethanolamine soap or succinic acid trolamine soap; Alkylol amide is selected from least one in coconut oleoyl diethanolamine or lauroyl diethanolamine.
5. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that with weight parts, also comprises f) defoamer or at least one g) in sterilant in described lubricating fluid composition; The consumption of defoamer is 0.001 ~ 1 part, and the consumption of sterilant is 0.01 ~ 5 part.
6. the application of lubricating fluid composition according to claim 5 in tire assembling, is characterized in that described defoamer is selected from least one in polyethers defoamer or silicone emulsion; Sterilant is selected from least one in triazine, morpholine, pyridine sodium-mercaptan oxidation thing, Phenoxyethanol or isothiazolinone.
7. the application of lubricating fluid composition according to claim 5 in tire assembling, is characterized in that the consumption of described defoamer is 0.01 ~ 0.1 part; The consumption of sterilant is 0.01 ~ 3 part.
8. the application of lubricating fluid composition according to claim 1 in tire assembling, is characterized in that described tire is radial.
CN201210278175.XA 2012-08-06 2012-08-06 Application of lubricating oil composition in tire fitting Active CN103571599B (en)

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CN105154199A (en) * 2015-08-24 2015-12-16 当涂县中澜橡塑制品有限公司 Pipeline installation lubricant
US10266745B2 (en) 2017-02-03 2019-04-23 Saudi Arabian Oil Company Anti-bit balling drilling fluids, and methods of making and use thereof
CN107118829A (en) * 2017-05-25 2017-09-01 明光速耐德实心轮胎有限公司 A kind of lubricant assembled for tire and preparation method thereof
CN107090345A (en) * 2017-06-03 2017-08-25 明光速耐德实心轮胎有限公司 A kind of lubricating fluid assembled for solid tyre and preparation method
CN107502438A (en) * 2017-09-06 2017-12-22 苏州纽东精密制造科技有限公司 A kind of preparation method of lubricating fluid
CN107603714A (en) * 2017-11-07 2018-01-19 刘兴满 Magnetic drive pump bearing lubricating fluid
CN107892977A (en) * 2017-11-07 2018-04-10 刘兴满 Diving pump rotor lubricating fluid
CN108865347A (en) * 2018-06-12 2018-11-23 界首市皖俊轴承有限公司 A kind of preparation method of lubricating fluid
CN111117756B (en) * 2020-01-07 2022-07-01 山东奥力新材料有限公司 Traceless water-based lubricating liquid for tire assembly and preparation method thereof
CN112126502A (en) * 2020-10-09 2020-12-25 江苏东科新能源材料有限公司 Preparation method of lubricating concentrated solution based on improvement of surface tension of base material
CN113462457A (en) * 2021-06-25 2021-10-01 赛轮(沈阳)轮胎有限公司 Lubricating liquid for dynamic homogeneity and preparation method thereof
CN115678654B (en) * 2022-10-21 2024-03-26 清华大学 Low-die-consumption low-abrasion-loss steel cord wiredrawing liquid and preparation method thereof

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CN1546620A (en) * 2003-12-16 2004-11-17 东风汽车有限公司 Tire assembling lubricating liquid

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US8658018B2 (en) * 2006-12-20 2014-02-25 Chevron U.S.A. Inc. Lubricant base oil blend having low wt% noack volatility

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