CN105713454B - A kind of archives ballpoint pen writing protective agent and guard method - Google Patents
A kind of archives ballpoint pen writing protective agent and guard method Download PDFInfo
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- CN105713454B CN105713454B CN201610066150.1A CN201610066150A CN105713454B CN 105713454 B CN105713454 B CN 105713454B CN 201610066150 A CN201610066150 A CN 201610066150A CN 105713454 B CN105713454 B CN 105713454B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/04—Alginic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Pens And Brushes (AREA)
Abstract
The invention discloses a kind of archives ballpoint pen writing protective agent and guard methods; belong to archives conservation and repair field; the protective agent is made of component A and B component; wherein component A is mixed by the water of the sodium alginate of 28 parts by weight, the glycerine of 0.5 5 parts by weight, the ammonium persulfate of 0.5 2 parts by weight and 80 95 parts by weight, and the B component is by calcium chloride and water according to weight ratio 1：99~10：90 mix；Component A and B component is are uniformly coated on writing, and dry up by the guard method successively.The archives ballpoint pen writing protective agent of the present invention can effectively completely cut off writing and external environment in writing surface filming, and protection ballpoint pen writing is colour-fast, and oil stain is non-volatile, reaches persistently clearly effect.
Description
Technical field
The invention belongs to archives conservations to repair field, and in particular to a kind of archives ballpoint pen writing protective agent and protection side
Method.
Background technology
The historical record that archives are directly formed." directly being formed " illustrates that archives inherit the primitiveness of file, and " history is recorded
Record " illustrates that archives while file primitiveness is inherited, also inherit the record of file, is the original of representation of the historical true appearance
Beginning document.Just because of archives inherit file original record, there is Historic Reappearance, so archives just have voucher value
Important attribute, and Library data and historical relic are different from this.
Precious original record of the archives as history is the tie of cultural continuity, spread so far a large amount of paper relics by
In after the variation of a variety of different external environments and the change of itself physicochemical property, over time, generally occur
Turn to be yellow, go mouldy, aging, brittle failure, the diseases such as damaged, dusting.Ball pen core oil is generally oil-soluble dyes, more unstable, intolerant to
Soda acid, light fugitive, volatile diffusion, in some archives, the part write using ball pen was just obscured at 20 years or so,
It being not easy to recognize so that fileinfo is difficult to obtain, and the research, investigation to data bring more inconvenient or even causes significant loss,
Therefore, it is most important for the protection of ballpoint pen writing in archives.More writing protective agent use has human body in the prior art
Evil ingredient, the Nano silver solution as used in the patent application No. is 201110359721.8, long-time service can cause silver-colored storage in vivo
Product, have larger damage to human body, for another example application No. is 201010586407.9 patent used in acetone soln, inflammable, Yi Hui
Hair, irritant smell, are unfavorable for health.
Invention content
To solve defect of the existing technology, the present invention is intended to provide a kind of archives ballpoint pen writing protective agent and protection
Method can effectively solve the problem that the problem of ballpoint pen writing is easily obscured, faded, and safe to the human body nontoxic, also have to paper
Bacteriostasis.
To achieve these goals, the technical scheme is that：
A kind of archives ballpoint pen writing protective agent, the protective agent are made of component A and B component, and wherein component A is by 2-8 weights
Measure the sodium alginate of part, the glycerine of 0.5-5 parts by weight, the ammonium persulfate of 0.5-2 parts by weight and 80-95 parts by weight water mixing and
Into the B component is by calcium chloride and water according to weight ratio 1：99~10：90 mix.
The present invention can also have following additional technical feature：
Preferably, the component A by the sodium alginate of 6 parts by weight, the glycerine of 3 parts by weight, 1.5 parts by weight ammonium persulfate
It is mixed with the water of 90 parts by weight, the B component is by calcium chloride and water according to weight ratio 3：97 mix.
Preferably, the component A is that first sodium alginate is dissolved in 60-85 DEG C of water, is sequentially added after being uniformly dissolved
Glycerine, ammonium persulfate stir evenly, cool down and be made.
The invention also includes a kind of archives ballpoint pen writing guard methods, include the following steps：
(1) absorbent cotton is clamped with tweezers, dips the component A described in claims 1 or 2, be uniformly coated on ballpoint pen writing
On, it is dried up with hair-dryer；
(2) clamp absorbent cotton with tweezers, dip the B component described in claims 1 or 2, even spread in step (1) in
On ballpoint pen writing, dried up with hair-dryer.
Beneficial effects of the present invention are：The archives ballpoint pen writing protective agent of the present invention can be effective in writing surface filming
Completely cut off writing and external environment, protection ballpoint pen writing is colour-fast, and oil stain is non-volatile, reaches persistently clearly effect；Due to sea
Mosanom and glycerine are respectively provided with biocidal property, therefore paper can also be made not mouldy；The performance of paper is not destroyed, and can enhance paper
Mechanical strength；Ingredient used is safe to the human body nontoxic, can be safe to use；Material is simple, is easy to industrial production or oneself is matched
It puts.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description
It obtains significantly or is recognized by the practice of the present invention.
Description of the drawings
Fig. 1 is the (right side after unprotected blue ballpoint pen writing (left side) and unprotected blue ballpoint pen writing hydrothermal aging
Side) photo.
Fig. 2 is using the blue ballpoint pen writing (left side) after the protection of 1 method of embodiment and using the protection of 1 method of embodiment
The photo on (right side) after blue ballpoint pen writing hydrothermal aging afterwards.
Fig. 3 is using the red ball-point pen writing (left side) after the protection of 2 method of embodiment and using the protection of 2 method of embodiment
The photo on (right side) after red ball-point pen writing hydrothermal aging afterwards.
Specific embodiment
Below in conjunction with specific example, the present invention is described in detail.
Embodiment 1
The sodium alginate of 6 parts by weight is dissolved in the water of 70 DEG C of 90 parts by weight, it is stirring while adding, after being uniformly dissolved, then according to
It is secondary add in the glycerine of 3 parts by weight, 1.5 parts by weight ammonium persulfate, stir evenly, be cooled to room temperature component A is made；
B component is made in the calcium chloride of 8 parts by weight and the water of 97 parts by weight after mixing.This is formed by component A and B component
A kind of archives ballpoint pen writing protective agent of invention.
When being protected to archives ballpoint pen writing, operate as follows：
(1) absorbent cotton is clamped with tweezers, dips component A, be uniformly coated on archives ballpoint pen writing, blown with hair-dryer
It is dry；
(2) clamp absorbent cotton with tweezers, dip B component, even spread in step (1) in archives ballpoint pen writing on,
It is dried up with hair-dryer.
Embodiment 2
The sodium alginate of 8 parts by weight is dissolved in the water of 80 DEG C of 99 parts by weight, it is stirring while adding, after being uniformly dissolved, then according to
It is secondary add in the glycerine of 5 parts by weight, 2 parts by weight ammonium persulfate, stir evenly, be cooled to room temperature component A is made；
B component is made in the calcium chloride of 1 parts by weight and the water of 99 parts by weight after mixing.
Embodiment 3
The sodium alginate of 2 parts by weight is dissolved in the water of 65 DEG C of 95 parts by weight, it is stirring while adding, after being uniformly dissolved, then according to
It is secondary add in the glycerine of 0.5 parts by weight, 0.5 parts by weight ammonium persulfate, stir evenly, be cooled to room temperature component A is made；
B component is made in the calcium chloride of 10 parts by weight and the water of 99 parts by weight after mixing.
Embodiment 4
The sodium alginate of 5 parts by weight is dissolved in the water of 70 DEG C of 98 parts by weight, it is stirring while adding, after being uniformly dissolved, then according to
It is secondary add in the glycerine of 2 parts by weight, 1 parts by weight ammonium persulfate, stir evenly, be cooled to room temperature component A is made；
B component is made in the calcium chloride of 6 parts by weight and the water of 95 parts by weight after mixing.
5 measuring physical properties of embodiment
Multiple phase same materials, size paper on same ball pen write writing respectively, using made from embodiment 1
A, B component and guard method carry out writing protection, and the sample protected and unprotected sample are compared, are respectively divided into 8
Part, every part carries out cutting the paper slip for growing into 250mm, width as the sufficient amount of 15+0.1mm, to ensure having 10 effective data,
It is required that the smooth non-notch in paper periphery.The style protected and unprotected style are subjected to following four senile experiment respectively.
Paper tensile strength measure, folding test are carried out after each aging, and carries out color difference analysis, paper tensile strength measure is pressed
National standard GB/T453~2002 are measured (constant speed loading method), and folding test is surveyed by national standard GB/T2679.5~1995
Fixed (MIT folding strength instrument method).
(1) xeothermic aging：
The above-mentioned sample protected and each 2 parts of unprotected sample is taken to be put into xeothermic weatherometer, 105 ± 5 DEG C dry
Heat ageing 72 hours takes out balance 2~3 days after the completion of aging.
(2) hydrothermal aging：
The above-mentioned sample protected and each 2 parts of unprotected sample is taken to be put into hydrothermal aging instrument, 105 ± 5 DEG C, relatively wet
The hydrothermal aging of degree 65% 72 hours, takes out balance 2~3 days.
(3) ultraviolet ageing：
The above-mentioned sample protected and each 2 parts of unprotected sample is taken to be put into ultraviolet light and aging chamber, ultraviolet lamp work(
Rate is 60W, and vertical irradiation distance is 5cm, and ultraviolet ageing 12 hours takes out balance 2~3 days.
(4) xenon lamp aging
The above-mentioned sample protected and each 2 parts of unprotected sample is taken to be put into xenon lamp aging case, 42 DEG C of irradiation level are
1.1W/m2, relative humidity 28%, xenon lamp aging 72 hours take out balance 2~3 days.
Above-mentioned test result is shown in Table 1~4.
The various physical properties of ballpoint pen writing paper before and after 1 xeothermic aging of table protection
Note：Experimental data is 10 Validity Test average values in table.
The various physical properties of ballpoint pen writing paper before and after the protection of 2 hydrothermal aging of table
Note：Experimental data is 10 Validity Test average values in table.
The various physical properties of ballpoint pen writing paper before and after the protection of 3 ultraviolet ageing of table
Note：Experimental data is 10 Validity Test average values in table.
The various physical properties of ballpoint pen writing paper before and after the protection of 4 xenon lamp aging of table
Note：Experimental data is 10 Validity Test average values in table.
By table 1~4 as it can be seen that the paper after writing protection has decline relative to the tensile strength before protection and folding strength,
But its paper to the more unprotected writing of the conservation rate of paper tensile strength and folding strength before and after aging is good, the word through overprotection
Aberration is significantly less than the aberration of unprotected writing before and after mark aging.By Fig. 1~3 as it can be seen that in hydrothermal aging, unprotected writing
After weathering, paper has wrinkled bar, writing occur it is fuzzy it is dizzy opens (Fig. 1), and the writing protected, the more unprotected paper of paper
More smooth, writing not open by fuzzy swoon.Therefore, writing shield agent of the invention under the premise of bottom line damages paper for
Writing has preferable protectiveness.
6 antibiotic property of embodiment detects
It, will after the paper of the paper of unprotected writing and the writing protected is placed in UV chamber sterilizing in 1.5 hours
Two kinds of paper are put in same environment, after a week, respectively in four angles of paper and intermediate 5 points of paper slips for cutting 1 × 1cm,
It is placed in sterile water and cleans, sterile water 1ml is taken to carry out tablet setting-out microculture, flat-plate bacterial colony number, each paper are observed after 2 days
Five data of Zhang Pinghang are averaged, and find unprotected paper clump count average out to 48, protection paper clump count is 16, is said
The protective agent of the bright present invention has preferable fungistatic effect to paper.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that：Not
In the case of being detached from the principle of the present invention and objective a variety of change, modification, replacement and modification can be carried out to these embodiments, this
The range of invention is limited by claim and its equivalent.
Claims (4)
1. a kind of archives ballpoint pen writing protective agent, which is characterized in that the protective agent is made of component A and B component, wherein A groups
Divide by the sodium alginate of 2-8 parts by weight, the glycerine of 0.5-5 parts by weight, the ammonium persulfate of 0.5-2 parts by weight and 80-95 parts by weight
Water mix, the B component is by calcium chloride and water according to weight ratio 1：99~10：90 mix.
2. archives ballpoint pen writing protective agent according to claim 1, which is characterized in that the component A is by 6 parts by weight
Sodium alginate, the glycerine of 3 parts by weight, the ammonium persulfate of 1.5 parts by weight and 90 parts by weight water mix, the B component by
Calcium chloride and water are according to weight ratio 3：97 mix.
3. archives ballpoint pen writing protective agent according to claim 1 or 2, which is characterized in that the component A is first will be extra large
Mosanom is dissolved in 60-85 DEG C of water, and glycerine, ammonium persulfate are sequentially added after being uniformly dissolved, and is stirred evenly, is cooled down and be made.
4. a kind of archives ballpoint pen writing guard method, which is characterized in that include the following steps：
（1）Absorbent cotton is clamped with tweezers, the component A described in claims 1 or 2 is dipped, is uniformly coated on ballpoint pen writing, is used
Hair-dryer dries up；
（2）Absorbent cotton is clamped with tweezers, the B component described in claims 1 or 2 is dipped, is uniformly coated on step（1）In ball
On writing, dried up with hair-dryer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610066150.1A CN105713454B (en) | 2016-01-29 | 2016-01-29 | A kind of archives ballpoint pen writing protective agent and guard method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610066150.1A CN105713454B (en) | 2016-01-29 | 2016-01-29 | A kind of archives ballpoint pen writing protective agent and guard method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105713454A CN105713454A (en) | 2016-06-29 |
| CN105713454B true CN105713454B (en) | 2018-07-10 |
Family
ID=56155393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610066150.1A Active CN105713454B (en) | 2016-01-29 | 2016-01-29 | A kind of archives ballpoint pen writing protective agent and guard method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105713454B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251436A (en) * | 2011-06-29 | 2011-11-23 | 陕西师范大学 | Dye-based handwriting protectant for written archives |
-
2016
- 2016-01-29 CN CN201610066150.1A patent/CN105713454B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251436A (en) * | 2011-06-29 | 2011-11-23 | 陕西师范大学 | Dye-based handwriting protectant for written archives |
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| Publication number | Publication date |
|---|---|
| CN105713454A (en) | 2016-06-29 |
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