CN105713435A - Antifouling compound for water-based paints - Google Patents

Antifouling compound for water-based paints Download PDF

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Publication number
CN105713435A
CN105713435A CN201610262401.3A CN201610262401A CN105713435A CN 105713435 A CN105713435 A CN 105713435A CN 201610262401 A CN201610262401 A CN 201610262401A CN 105713435 A CN105713435 A CN 105713435A
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CN
China
Prior art keywords
parts
water
antifouling
based paints
antifouling compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610262401.3A
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Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Zhigu Ruituo Technology Service Co Ltd
Original Assignee
Wuxi Zhigu Ruituo Technology Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Zhigu Ruituo Technology Service Co Ltd filed Critical Wuxi Zhigu Ruituo Technology Service Co Ltd
Priority to CN201610262401.3A priority Critical patent/CN105713435A/en
Publication of CN105713435A publication Critical patent/CN105713435A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1606Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612Non-macromolecular compounds
    • C09D5/1625Non-macromolecular compounds organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to an antifouling compound for water-based paints, particularly an antifouling water-based paint which is prepared from the following raw materials in parts by weight: 50-120 parts of acrylate emulsion, 20-30 parts of inorganic thickener, 10-30 parts of leveling agent, 20-30 parts of wetting agent, 10-30 parts of defoaming agent, 20-30 parts of film former, 10-30 parts of antifouling compound and 100-300 parts of water. The antifouling water-based paint has favorable antifouling effects, and has wide prospects in industrial application.

Description

A kind of water paint anti-fouling agent
Technical field
The present invention relates to paint field, specifically, the present invention relates to a kind of water paint anti-fouling agent.
Background technology
Along with the development of human industry, the application of anti-soil technology becomes increasingly extensive.In the used all anti-soil technologies of the mankind, using antifouling paint is a kind of method the most ripe, most economical, most widely used.The organotin self polishing copolymer antifouling paint of 20 century 70 developments because of its efficiently and light spectrality and be applied widely.But research subsequently shows that organotin can endanger the health of ecology and the mankind.Traditional coating is all using organic solvent as solvent, can discharge the healthy of volatile organic compounds (VOC), contaminated environment and injury workman.Therefore, exploitation high-efficiency low-toxicity, antifouling paint nontoxic, Water-borne modification has just become the developing direction that following antifouling paint is inevitable.
Summary of the invention
It is an object of the invention to provide a kind of water paint anti-fouling agent.
In order to realize the purpose of the present invention, the present invention provides the chloro-4-of 5-[1-(3-luorobenzyl)-1H-benzimidazole-6-base]-N-[2-(5-methyl-4H-1,2,4-triazole-3-bases) ethyl] pyridine-2-amine is as the purposes in anti-fouling agent.
Preferably, described anti-fouling agent can make powder or granule.
Antifouling water paint of the present invention has good anti-fouling effect, has broad prospects in commercial Application.
Detailed description of the invention
Below by way of the description of detailed description of the invention, the invention will be further described, but this is not limitation of the present invention, those skilled in the art's basic thought according to the present invention, various modifications may be made or improves, but without departing from the basic thought of the present invention, all within the scope of the present invention.
Embodiment 1
Weigh acrylic acid ester emulsion (model DC-W10, purchased from Dechang, Beijing great achievement architectural engineering technology company limited) 90 kilograms, 25 kilograms of kieselguhr, butyl cellulose 20 kilograms, BD-303225 kilogram, polydimethylsiloxane 20 kilograms, the chloro-4-of 5-[1-(3-luorobenzyl)-1H-benzimidazole-6-base]-N-[2-(5-methyl-4H-1, 2, 4-triazole-3-base) ethyl] pyridine-2-amine 20 kilograms and 200 kilograms of water, mixing 20 minutes it is sufficiently stirred under 500r/min, pour in cone mill and be ground, cross 100 mesh sieves, it is subsequently adding alcohol ester 12 kilograms, at 900r/min, stir 30 minutes at temperature 55 DEG C, it is cooled to room temperature and get final product.
Embodiment 2
Antifouling water paint is prepared according to the mode identical with embodiment 1, it is different in that and does not use the chloro-4-of 5-[1-(3-luorobenzyl)-1H-benzimidazole-6-base]-N-[2-(5-methyl-4H-1,2,4-triazole-3-bases) ethyl] pyridine-2-amine.
Experimental example
The low carbon steel plate of 150 × 70 × 2mm is as sample base plate, after polishing and processing of rust removing, and acetone oil removing.By the coating application prepared in embodiment to above, so as to form nonpolluting coating.Adopt the SL200D type contact angle tester of Solon (Shanghai) Information Technology Co., Ltd., adopt sessile drop method (sea water) that described nonpolluting coating has carried out the test of contact angle.It is shown that the contact angle of the antifouling paint of embodiment 1 can reach 169 °, and the contact angle of the antifouling paint of embodiment 2 is only 113 °, and both compare has significant difference (P < 0.05).Contact angle is more big, and soil resistance is more strong, it can be seen that, the coating of the present invention has stronger soil resistance.

Claims (2)

  1. The chloro-4-of 1.5-[1-(3-luorobenzyl)-1H-benzimidazole-6-base]-N-[2-(5-methyl-4H-1,2,4-triazole-3-base) ethyl] pyridine-2-amine is as the purposes in anti-fouling agent.
  2. 2. purposes according to claim 1, it is characterised in that described anti-fouling agent can make powder or granule.
CN201610262401.3A 2016-04-25 2016-04-25 Antifouling compound for water-based paints Withdrawn CN105713435A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610262401.3A CN105713435A (en) 2016-04-25 2016-04-25 Antifouling compound for water-based paints

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610262401.3A CN105713435A (en) 2016-04-25 2016-04-25 Antifouling compound for water-based paints

Publications (1)

Publication Number Publication Date
CN105713435A true CN105713435A (en) 2016-06-29

Family

ID=56162066

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610262401.3A Withdrawn CN105713435A (en) 2016-04-25 2016-04-25 Antifouling compound for water-based paints

Country Status (1)

Country Link
CN (1) CN105713435A (en)

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PB01 Publication
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WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20160629