CN105695167A - Efficient environment-friendly multifunctional cleaning agent and preparation method thereof - Google Patents

Efficient environment-friendly multifunctional cleaning agent and preparation method thereof Download PDF

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Publication number
CN105695167A
CN105695167A CN201610018252.6A CN201610018252A CN105695167A CN 105695167 A CN105695167 A CN 105695167A CN 201610018252 A CN201610018252 A CN 201610018252A CN 105695167 A CN105695167 A CN 105695167A
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CN
China
Prior art keywords
abluent
preparation
environmental protection
high effective
effective environmental
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201610018252.6A
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Chinese (zh)
Inventor
李国超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sino Clean (dalian) Environmental Protection Technology Co Ltd
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Individual
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Priority to CN201610018252.6A priority Critical patent/CN105695167A/en
Publication of CN105695167A publication Critical patent/CN105695167A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/40Mounting or supporting mixing devices or receptacles; Clamping or holding arrangements therefor
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/06Hydroxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/268Carbohydrates or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/2305Mixers of the two-component package type, i.e. where at least two components are separately stored, and are mixed in the moment of application

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an efficient environment-friendly multifunctional cleaning agent and a preparation method thereof.The multifunctional cleaning agent is prepared from, by mass, 20-30% of coconut oil, 13-17% of sodium carbonate, 14-19% of citric acid, 12-16% of CMC, 11-15% of baking soda and 10-20% of sodium percarbonate.The multifunctional cleaning agent not only can clean fruits and tableware, but also can be used for cleaning ornaments or used as glassy water, and is good in cleaning effect, mild in performance and free of pollution to the environment and the human body.

Description

High effective environmental protection multifunctional abluent and preparation method thereof
Technical field
The present invention relates to a kind of abluent, especially relate to a kind of high effective environmental protection multifunctional abluent。
Background technology
Raising along with quality of life, people are also more and more higher to the hygienic requirements of tableware, fruit etc., will clean with abluent before using tableware, edible fruits, but major part detergent uses petrochemistry lotion to make in the market, not only can be healthy at tableware surface remaining influence, and environment can be caused severe contamination after entering sewer and then entering water circulation system, it is therefore desirable to a kind of more environmentally-friendly abluent product is provided。The modern life needs the article cleaned to get more and more simultaneously, if every kind of article all individually configure a kind of abluent and also can take big quantity space, it is therefore desirable to provide a kind of multi-functional abluent that disclosure satisfy that different occasion and applied environment。
Summary of the invention
It is an object of the invention to provide a kind of can high effective environmental protection multifunctional abluent that effectively decontamination is deoiled and preparation method thereof。
For solving the problems referred to above, the preparation method that one aspect of the present invention provides a kind of high effective environmental protection multifunctional abluent, including:
Step 1, prepares material by following components and weight ratio,
Step 2, puts into stirring 25-35min in blender by Oleum Cocois, soda, citric acid, CMC;
Step 3, puts into stirring 30-40min in blender by sodium bicarbonate, sodium carbonate peroxide。
Preferably, described preparation process step 2, step 3 all stir with the rotating speed of 380-460r/min。
Preferably, described preparation process step 2, step 3 all carry out in the temperature range of 25-26 DEG C。
Preferably, described preparation process step 2, step 3 mixing time be 30 minutes。
Preferably, described preparation process also includes step 4, and the intermediate products that step 3 is prepared carry out homogenizing process。
On the other hand, the present invention relates to a kind of blender, including: support, support is provided with vertical beam behind, the centre position of vertical beam is provided with support plate, the platform part installing agitator tank it is provided with at support place, platform part is made up of movable device and fixed mechanism, movable device includes being arranged on the orbit determination that support is anterior, it is arranged on the slide rail that orbit determination can be slided on orbit determination, slide rail has the breach matched with agitator tank external diameter, it is provided with elastic device between slide rail and set pattern, fixed mechanism is arranged on support and opposed with movable device, fixed mechanism has the breach matched with agitator tank external diameter, agitator tank is positioned between slide rail and the breach of fixed mechanism;Outstanding platform, is arranged on the guide rail of vertical beam, can control the raising and lowering of outstanding platform by being located at the turn-screw of support plate;Outstanding platform is provided with the rotating shaft downwardly extended, and rotating shaft is connected with stirring turbine, and drives stirring turbine to rotate。
On the other hand, the present invention provides a kind of high effective environmental protection multifunctional abluent, it is characterised in that prepared by following components in percentage by weight:
Preferably, the high effective environmental protection multifunctional abluent of the present invention is prepared by following components in percentage by weight:
In component involved in the present invention, soda is also known as sodium carbonate, and molecular formula is Na2CO3;Citric acid is also known as 2-hydroxy propane tricarboxylic acid, and molecular formula is C6H8O7;CMC is also known as carboxymethyl cellulose;Sodium bicarbonate is also known as sodium bicarbonate, and molecular formula is NaHCO3;Sodium carbonate peroxide is also known as SODIUM PERCARBONATE, and molecular formula is Na2CO3·3H2O2
The abluent of the present invention is placed in refrigerator with-7 DEG C and places 24h, recover after taking-up to room temperature, nodeless mesh, nothing precipitation;With 40 DEG C of nothing layerings after placement 24h in couveuse, without muddiness, also free from extraneous odour;Adding water under 20 DEG C of conditions and be modulated into the solution of 1% concentration, its pH value is alkalescence, to no skin irritation;With deoiling, detergency is measured by rate method, and the rate of deoiling reaches more than 60%;Gross activity thing content reaches about 25%, its high comprehensive performance。
Empirical tests, the abluent of the present invention can effectively remove the pesticide residues of veterinary antibiotics, and fruit is soaked 2 minutes after being watered by abluent, rinses rear surface both non agricultural chemical residuums a little also without abluent component residue;Washed fruit is put into refrigerator cold-storage two days, with microscope it has been observed that the fruit cleaned relative to common abluent, the fruit surface antibacterial cleaned with the abluent of the present invention be only its 1/5, it was shown that the abluent of the present invention has bacteriostasis。
The abluent of the present invention has considerable degree of antibacterial, disinfective action, can feel at ease, for cleaning tableware and articles for babies, easily to rinse noresidue, it is not necessary to the problem worrying petrochemical industry composition health risk。
Take 500cc water and add the abluent of the 5g present invention, jewelry etc. are put into and wherein stands 2 minutes, it has been found that out, jewelry light is as new for the dirt automatic dissolving in jewelry gap。
It addition, the abluent of the present invention becomes alkalescence, will not corroding metal, the abluent adding the 20g present invention with the clear water of 2000cc can be used as bath of glass, the outer light of pane of glass, effect highly significant after cleaning。
The abluent of the present invention is without petrochemistry lotion ingredient, and its composition soda, citric acid etc. are natural formula, and environment and human body is pollution-free, can feel at ease to use, abnormal flavour can be completely eliminated when being used for cleaning medicated clothing。
Accompanying drawing explanation
Fig. 1 is the schematic diagram of blender involved in the present invention。
Detailed description of the invention
Below by the embodiment making 1kg abluent, present disclosure is described in detail。
Embodiment 1
The first step, prepares material, prepares material by following percentage by weight:
Second step, puts into stirring 30min in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min。
Embodiment 2
The first step, prepares material, prepares material by following percentage by weight:
Second step, puts into stirring 30min in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min。
Embodiment 3
The first step, prepares material, prepares material by following percentage by weight:
Second step, puts into stirring 30min in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min。
Embodiment 4
The first step, prepares material, prepares material by following percentage by weight:
Second step, puts into stirring 30min in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min。
Embodiment 5
The first step, prepares material, prepares material by following percentage by weight:
Second step, puts into stirring 30min in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min。
Embodiment 6
The first step, prepares material, prepares material by following percentage by weight:
Second step, puts into stirring 30min in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min, and temperature controls at 25 DEG C;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min, and temperature controls to be 25 DEG C and obtains abluent finished product。
Embodiment 7
The first step, prepares material, prepares material by following percentage by weight:
Second step, puts into stirring 30min in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min, and temperature controls at 25 DEG C;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min, and temperature controls to be 25 DEG C and obtains abluent finished product。
The embodiment 1-7 abluent prepared is placed in refrigerator placement 24h with-7 DEG C respectively, take out observe when recovering to room temperature have nodeless mesh, with or without precipitation, measure its low-temperature stability;Place in couveuse with 40 DEG C observe after 24h with or without layering, with or without muddy, have free from extraneous odour, measure its high-temperature stability;Add water its pH value of measured in solution being modulated into 1% concentration under 20 DEG C of conditions;By rate method of deoiling, detergency is measured respectively;Measure the gross activity thing content of abluent respectively, measurement result be recorded in table 1, for stability consider be divided into excellent, good, in, differ from four grades, result shows that the combination property of abluent prepared in embodiment 3 is optimum。
Table 1 embodiment 1-7 prepares the performance of abluent
Embodiment 8
The abluent function that embodiment 1-7 surface is prepared with material percentage ratio in embodiment 3 is best, for improving its performance further, embodiment 8 prepares material according to the ratio of embodiment 3, but the temperature conditions of preparation process is controlled by and carries out many experiments, second step and the 3rd step adopt identical temperature, temperature is increased to 30 DEG C from 20 DEG C by many experiments gradually, increases by 1 DEG C every time。It is shown that the highest with abluent 25-26 DEG C prepared rate of deoiling, respectively reaching 75.2% and 75.7%, the relation record of measured preparation temperature and the rate of deoiling is in table 2.
Table 2 preparation temperature and the rate of deoiling
Temperature (DEG C) 20 21 22 23 24 25 26 27 28 29 30
Rate of deoiling (%) 70.3 70.9 72.4 73.1 73.8 75.2 75.7 71.6 71.2 70.5 69.1
Embodiment 9
The first step, prepares material by the material ratio of embodiment 3;
Second step, puts into stirring 30 minutes in blender by Oleum Cocois, soda, citric acid, CMC, and mixing speed is 420r/min, and temperature controls at 25 DEG C;
3rd step, puts into stirring 30min in blender by sodium bicarbonate, sodium carbonate peroxide, and mixing speed is 420r/min, and temperature controls at 25 DEG C;
4th step, carries out homogenizing process to the product prepared in the 3rd step, obtains abluent finished product。
The abluent finished product of preparation is measured, and relative to embodiment 3, its stability is improved, and each index of high-temperature stability and low-temperature stability all reaches excellent。
Embodiment 10
The basis of embodiment 3 changes mixing speed, second step and the 3rd step adopt identical mixing speed, respectively with 300,340,380,420,460, the mixing speed of 500r/min test, test result indicate that the effect of the abluent that rotating speed prepared when being 380-460r/min is best。
Table 3 rotating speed and stability
Embodiment 11
The mixing time changing second step on the basis of embodiment 3 is repeatedly tested, and the abluent performance of preparation and the relation of mixing time are as shown in table 4, and result shows that the resultant effect of the abluent that second step mixing time prepared when being 25-35min is optimum。
Table 4 second step mixing time and performance
Embodiment 12
Changing the mixing time of the 3rd step on the basis of embodiment 3, the abluent performance of preparation and the relation of mixing time are as shown in table 4, and result shows that the resultant effect of the abluent that the 3rd step mixing time prepared when being 30-40min is optimum。
Table 5 the 3rd step mixing time and performance
Comparative example 1
The first step, prepares material by the material ratio of embodiment 3;
All materials are put in blender and stir 30 minutes with the rotating speed of 420r/min by second step。
Result is that the abluent prepared has crystallization and precipitation to produce in low-temperature stability is tested, and relatively muddy。
The blender specific configuration used in above-described embodiment is as it is shown in figure 1, include:
Support 1, support 1 is provided with vertical beam 2 behind, the centre position of vertical beam 2 is fixed with support plate 3, the platform part installing agitator tank 4 it is provided with at support 1 place, platform part is made up of movable device and fixed mechanism, movable device includes being arranged on the orbit determination that support is anterior, it is arranged on orbit determination and the slide rail that can slide on orbit determination, slide rail has the breach matched with agitator tank 4 external diameter, it is provided with elastic device between slide rail and set pattern, fixed mechanism is arranged on support and opposed with movable device, fixed mechanism has the breach matched with agitator tank 4 external diameter, agitator tank 4 is positioned between slide rail and the breach of fixed mechanism;
Outstanding platform 5, is arranged on the guide rail 6 of vertical beam, can control the raising and lowering of outstanding platform 5 by being located at the turn-screw 7 of support plate 3;
Outstanding platform 5 is provided with the rotating shaft 8 downwardly extended, and rotating shaft 8 is connected with stirring turbine 9, and drives stirring turbine 9 to rotate, and namely stirring turbine 9 can with outstanding platform 5 raising and lowering。
Above in conjunction with accompanying drawing, the preferred embodiments of the disclosure and embodiment are explained in detail, but the present invention is not limited to the above-described embodiment and examples, in the ken that those skilled in the art possess, it is also possible to make various change without departing from the inventive concept of the premise。

Claims (8)

1. the preparation method of a high effective environmental protection multifunctional abluent, it is characterised in that preparation process includes:
The first step, prepares material by following components and weight ratio,
Second step, puts into stirring 25-35 minute in blender by Oleum Cocois, soda, citric acid, CMC;
3rd step, puts into stirring 30-40 minute in blender by sodium bicarbonate, sodium carbonate peroxide。
2. the preparation method of high effective environmental protection multifunctional abluent according to claim 1, it is characterised in that described second step, the 3rd step preparation process system stir with the rotating speed of 380-460r/min。
3. the preparation method of high effective environmental protection multifunctional abluent according to claim 1, it is characterised in that described second step, the 3rd step preparation process carry out in the temperature range of 25-26 DEG C。
4. the preparation method of high effective environmental protection multifunctional abluent according to claim 1, it is characterised in that described second step, the 3rd step mixing time be 30 minutes。
5. the preparation method of the high effective environmental protection multifunctional abluent according to any of the above claim, it is characterised in that described preparation process also includes:
4th step, the intermediate products that the 3rd step is prepared carry out homogenizing process。
6. the preparation method of the high effective environmental protection multifunctional abluent according to any claim in claim 1-5, wherein, described blender includes:
Support, support is provided with vertical beam behind, the centre position of vertical beam is provided with support plate, the platform part installing agitator tank it is provided with at support place, platform part is made up of movable device and fixed mechanism, movable device includes being arranged on the orbit determination that support is anterior, it is arranged on the slide rail that orbit determination can be slided on orbit determination, slide rail has the breach matched with agitator tank external diameter, it is provided with elastic device between slide rail and set pattern, fixed mechanism is arranged on support and opposed with movable device, fixed mechanism has the breach matched with agitator tank external diameter, agitator tank is positioned between slide rail and the breach of fixed mechanism;
Outstanding platform, is arranged on the guide rail of vertical beam, can control the raising and lowering of outstanding platform by being located at the turn-screw of support plate;
Outstanding platform is provided with the rotating shaft downwardly extended, and rotating shaft is connected with stirring turbine, and drives stirring turbine to rotate。
7. a high effective environmental protection multifunctional abluent, it is characterised in that prepared by following components in percentage by weight:
8. high effective environmental protection multifunctional abluent according to claim 7, it is characterised in that prepared by following components in percentage by weight:
CN201610018252.6A 2016-01-12 2016-01-12 Efficient environment-friendly multifunctional cleaning agent and preparation method thereof Pending CN105695167A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108419770A (en) * 2018-04-12 2018-08-21 徐晔 Oneself foaming bait of aeration-type and preparation method thereof
CN111662789A (en) * 2020-06-01 2020-09-15 王悦秋 Pure natural pollution-free environment-friendly detergent and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4808330A (en) * 1988-04-26 1989-02-28 Chung C S Non-toxic detergent for cleaning fruit and vegetables
CN1405288A (en) * 2001-08-20 2003-03-26 潘灿平 Detergent composition
CN1509704A (en) * 2002-12-25 2004-07-07 朱素真 Artificial tooth cleaning agent
CN104031782A (en) * 2014-06-26 2014-09-10 上海应用技术学院 Special dish washing agent for dishwasher and preparation method of washing agent
CN204564027U (en) * 2015-03-12 2015-08-19 上海川易设备工程有限公司 The explosion-proof mixing plant of batching

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4808330A (en) * 1988-04-26 1989-02-28 Chung C S Non-toxic detergent for cleaning fruit and vegetables
CN1405288A (en) * 2001-08-20 2003-03-26 潘灿平 Detergent composition
CN1509704A (en) * 2002-12-25 2004-07-07 朱素真 Artificial tooth cleaning agent
CN104031782A (en) * 2014-06-26 2014-09-10 上海应用技术学院 Special dish washing agent for dishwasher and preparation method of washing agent
CN204564027U (en) * 2015-03-12 2015-08-19 上海川易设备工程有限公司 The explosion-proof mixing plant of batching

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108419770A (en) * 2018-04-12 2018-08-21 徐晔 Oneself foaming bait of aeration-type and preparation method thereof
CN111662789A (en) * 2020-06-01 2020-09-15 王悦秋 Pure natural pollution-free environment-friendly detergent and preparation method thereof

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Effective date of registration: 20170921

Address after: 116000, Liaoning Dalian Pulandian Economic Development Zone, the District store Fort community

Applicant after: Sino clean (Dalian) Environmental Protection Technology Co., Ltd.

Address before: 116000 Liaoning Province, Shahekou District of Dalian City, No. 594 Zhongshan Road Jinyu No. 1 building 2-1301 Xinghai

Applicant before: Li Guochao

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Application publication date: 20160622