CN105695145A - Antibacterial dishwashing liquid as well as preparation method and application of antibacterial dishwashing liquid - Google Patents
Antibacterial dishwashing liquid as well as preparation method and application of antibacterial dishwashing liquid Download PDFInfo
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- CN105695145A CN105695145A CN201610160848.XA CN201610160848A CN105695145A CN 105695145 A CN105695145 A CN 105695145A CN 201610160848 A CN201610160848 A CN 201610160848A CN 105695145 A CN105695145 A CN 105695145A
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- liquid detergent
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1206—Water-insoluble compounds free metals, e.g. aluminium grit or flakes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the field of daily chemicals and in particular relates to antibacterial dishwashing liquid as well as a preparation method and application of the antibacterial dishwashing liquid. The antibacterial dishwashing liquid is prepared from the following components: an anionic surfactant, a non-ionic surfactant, sodium carbonate, disodium ethylenediamine tetraacetate, a preservative, sodium chloride, essence, nano copper and water. A copper salt is dissolved into a reaction solvent ethylene glycol or diethylene glycol, and polyacrylic acid is added as a protection agent; a microwave hydrothermal reaction is carried out to obtain the nano copper. On the basis of ensuring the stability of all the components, the added nano copper and the other components have a synergistic facilitation effect, so that common bacteria, such as colibacillus and staphylococcus aureus, on the surfaces of tableware, fruits and vegetables can be effectively inhibited and removed; the dishwashing liquid prepared by the invention is low in cost and good in dirt removing effect, and can be used for effectively removing oil stain.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of Antibiotic liquid detergent and preparation method thereof and application。
Background technology
Liquid detergent is cleaning supplies conventional in daily life, is widely used in the washing of tableware, vegetable, melon and fruit etc.。At present, the requirement of liquid detergent is improved day by day: Environmental Safety, strong detergency, remain low, there is certain bactericidal property。At present in the patent of invention of disclosed Antibiotic liquid detergent, common antibacterial has: sodium dichloro cyanurate (Chinese patent, application number: 201310323733.4), Amolden MCM 400 (Chinese patent, application number: 200410065697.7), but this antibacterial components toxicity is big, poor stability；Plant extraction liquid is such as tea tree ethereal oil (Chinese patent, application number: 201310618880.4), but plant extraction liquid antimicrobial efficiency is not high enough；Nanometer silver (Chinese patent, application number: 201210476613.3；201310443789.3), but nanometer silver is expensive, and Ag with the multiple anionic reactive in water, can be formed the precipitations such as water-fast silver chloride or Argentous sulfide., lose antibacterial activity。
Summary of the invention
In order to overcome the deficiencies in the prior art and shortcoming, the primary and foremost purpose of the present invention is in that to provide a kind of Antibiotic liquid detergent, and the antimicrobial moiety of this liquid detergent selects cheap Nanometer Copper, has has a broad antifungal spectrum, antimicrobial efficiency advantages of higher。
Another object of the present invention is to the preparation method that above-mentioned Antibiotic liquid detergent is provided。
It is still another object of the present invention to provide the application of above-mentioned Antibiotic liquid detergent。
The purpose of the present invention is achieved through the following technical solutions:
A kind of Antibiotic liquid detergent, comprises following component by mass percentage:
Described anion surfactant is preferably at least one in sodium lauryl sulphate, α-sodium olefin sulfonate and dodecyl fatty alcohol-ether sodium sulfate；
Described nonionic surfactant is preferably at least one of cocos nucifera oil acyl diethanolamine and cocamidopropyl propyl amide amine oxide；
Described preservative is preferably MIT；
Described water is preferably deionized water；
The particle diameter of described Nanometer Copper is preferably 12～20nm；
Described Nanometer Copper prepares preferably by microwave-hydrothermal method；
The preparation method of described Nanometer Copper, comprises the steps of:
Being dissolved in by mantoquita in reaction dissolvent ethylene glycol or diethylene glycol, adding polyacrylic acid (PAA) is protective agent, carries out microwave hydrothermal reaction, obtains Nanometer Copper；Wherein, the power of microwave hydrothermal reaction is 600～1000W, and the time of microwave hydrothermal reaction is 10～60min, and the temperature of microwave hydrothermal reaction is 190～240 DEG C；
Described mantoquita is preferably copper nitrate, Schweinfurt green or copper chloride；
Described mantoquita concentration in reaction system is 15～30mmol/L；
Described polyacrylic acid concentration in reaction system is identical with mantoquita concentration；
The preparation method of described Antibiotic liquid detergent, comprises the steps of:
By the component mix homogeneously of above-mentioned Antibiotic liquid detergent, obtain Antibiotic liquid detergent；
The application in household chemicals field of the described Antibiotic liquid detergent；
The present invention has such advantages as relative to prior art and effect:
(1) Antibiotic liquid detergent component provided by the invention is simple, cost is low, containing cheap common metal Nanometer Copper, wherein, sodium carbonate deoils, disodiumedetate chelating removes calcium ions and magnesium ions, sodium chloride adjusts viscosity, guaranteeing between each component on the basis of stability, between Nanometer Copper and other components added, there is collaborative facilitation, it is likely to effectively suppress and remove tableware, the common bacteria (such as the antibacterial such as escherichia coli and staphylococcus aureus) on fruits and vegetables surface, and can effective wipe oil, clean effect is good。
(2) the main antimicrobial component Nanometer Copper used by the present invention, preparation method is simple, with low cost。
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to this。
Embodiment 1
A kind of Antibiotic liquid detergent, comprises following component by mass percentage:
The preparation method of above-mentioned Antibiotic liquid detergent, comprises the steps of:
(1) copper nitrate and polyacrylic acid are dissolved in ethylene glycol, carry out microwave hydrothermal reaction；Wherein, copper nitrate concentration in reaction system is 30mmol/L, and polyacrylic concentration is 30mmol/L, and the power of microwave is 1000W, and the time of reaction is 10min, and reaction temperature is 190 DEG C, can obtain the Nanometer Copper of redness, and its mean diameter is 20nm；
(2) Nanometer Copper that step (1) prepares is mixed homogeneously by above-mentioned mass percent with sodium lauryl sulphate and cocos nucifera oil acyl diethanolamine, sodium carbonate, disodiumedetate, MIT, sodium chloride, essence, deionized water, obtain Antibiotic liquid detergent。
Embodiment 2
A kind of Antibiotic liquid detergent, comprises following component by mass percentage:
The preparation method of above-mentioned Antibiotic liquid detergent, comprises the steps of:
(1) copper chloride and polyacrylic acid are dissolved in diethylene glycol, carry out microwave hydrothermal reaction；Wherein, copper chloride concentration in reaction system is 15mmol/L, and polyacrylic concentration is 15mmol/L, and the power of microwave is 600W, and the time of reaction is 60min, and reaction temperature is 240 DEG C, can obtain the Nanometer Copper of redness, and its mean diameter is 12nm；
(2) Nanometer Copper that step (1) prepares is mixed homogeneously by above-mentioned mass percent with α-sodium olefin sulfonate and cocamidopropyl propyl amide amine oxide, sodium carbonate, disodiumedetate, MIT, sodium chloride, essence, deionized water, obtain Antibiotic liquid detergent。
Embodiment 3
A kind of Antibiotic liquid detergent, comprises following component by mass percentage:
The preparation method of above-mentioned Antibiotic liquid detergent, comprises the steps of:
(1) Schweinfurt green and polyacrylic acid are dissolved in diethylene glycol, carry out microwave hydrothermal reaction；Wherein, Schweinfurt green concentration in reaction system is 20mmol/L, and polyacrylic concentration is 20mmol/L, and the power of microwave is 800W, and the time of reaction is 40min, and reaction temperature is 240 DEG C, can obtain the Nanometer Copper of redness, and its mean diameter is 18nm；
(2) Nanometer Copper that step (1) prepares is mixed homogeneously by above-mentioned mass percent with dodecyl fatty alcohol-ether sodium sulfate and cocamidopropyl propyl amide amine oxide, sodium carbonate, disodiumedetate, MIT, sodium chloride, essence, deionized water, obtain Antibiotic liquid detergent。
Embodiment 4
A kind of Antibiotic liquid detergent, comprises following component by mass percentage:
The preparation method of above-mentioned Antibiotic liquid detergent, comprises the steps of:
(1) copper nitrate and polyacrylic acid are dissolved in diethylene glycol, carry out microwave hydrothermal reaction；Wherein, Schweinfurt green concentration in reaction system is 25mmol/L, and polyacrylic concentration is 25mmol/L, and the power of microwave is 900W, and the time of reaction is 50min, and reaction temperature is 220 DEG C, can obtain the Nanometer Copper of redness, and its mean diameter is 20nm；
(2) Nanometer Copper step (1) prepared and α-sodium olefin sulfonate and dodecyl fatty alcohol-ether sodium sulfate, cocamidopropyl propyl amide amine oxide, sodium carbonate, disodiumedetate, MIT, sodium chloride, essence, deionized water press above-mentioned mass percent mix homogeneously, obtain Antibiotic liquid detergent。
Embodiment 5
A kind of Antibiotic liquid detergent, comprises following component by mass percentage:
The preparation method of above-mentioned Antibiotic liquid detergent, comprises the steps of:
(1) Schweinfurt green and polyacrylic acid are dissolved in diethylene glycol, carry out microwave hydrothermal reaction；Wherein, Schweinfurt green concentration in reaction system is 20mmol/L, and polyacrylic concentration is 20mmol/L, and the power of microwave is 1000W, and the time of reaction is 30min, and reaction temperature is 230 DEG C, can obtain the Nanometer Copper of redness, and its mean diameter is 18nm；
(2) Nanometer Copper step (1) prepared and sodium lauryl sulphate and dodecyl fatty alcohol-ether sodium sulfate, cocamidopropyl propyl amide amine oxide, cocos nucifera oil acyl diethanolamine, sodium carbonate, disodiumedetate, MIT, sodium chloride, essence, deionized water press above-mentioned mass percent mix homogeneously, obtain Antibiotic liquid detergent。
Embodiment 6
A kind of Antibiotic liquid detergent, comprises following component by mass percentage:
The preparation method of above-mentioned Antibiotic liquid detergent, comprises the steps of:
(1) Schweinfurt green and polyacrylic acid are dissolved in ethylene glycol, carry out microwave hydrothermal reaction；Wherein, Schweinfurt green concentration in reaction system is 20mmol/L, and polyacrylic concentration is 20mmol/L, and the power of microwave is 800W, and the time of reaction is 20min, and reaction temperature is 190 DEG C, can obtain the Nanometer Copper of redness, and its mean diameter is 13nm；
(2) Nanometer Copper step (1) prepared and sodium lauryl sulphate, α-sodium olefin sulfonate, dodecyl fatty alcohol-ether sodium sulfate, cocamidopropyl propyl amide amine oxide, cocos nucifera oil acyl diethanolamine, sodium carbonate, disodiumedetate, MIT, sodium chloride, essence, water press above-mentioned mass percent mix homogeneously, obtain Antibiotic liquid detergent。
Effect example
Adopting QB/T2738-2012 " evaluation methodology of daily chemical products antibacterial bacteriostatic effect " that the anti-microbial property of Antibiotic liquid detergent prepared by embodiment 1～6 is tested, the bacterial strain of experiment is escherichia coli (ATCC25922) and staphylococcus aureus (ATCC6538)。With reference to the assay method 2 foam level method of GB9985-2000 " manual dishwashing detergent " Appendix B detergency, the detergency ability of above-mentioned liquid detergent is tested。Antibacterial effect and the clean effect of liquid detergent prepared by each embodiment are as follows:
* note: the detergency index of GB liquid detergent is 2。
Above-described embodiment is the present invention preferably embodiment; but embodiments of the present invention are also not restricted to the described embodiments; the change made under other any spirit without departing from the present invention and principle, modification, replacement, combination, simplification; all should be the substitute mode of equivalence, be included within protection scope of the present invention。
Claims (10)
1. an Antibiotic liquid detergent, it is characterised in that comprise following component by mass percentage:
2. Antibiotic liquid detergent according to claim 1, it is characterised in that:
Described anion surfactant is at least one in sodium lauryl sulphate, α-sodium olefin sulfonate and dodecyl fatty alcohol-ether sodium sulfate。
3. Antibiotic liquid detergent according to claim 1, it is characterised in that:
Described nonionic surfactant is at least one of cocos nucifera oil acyl diethanolamine and cocamidopropyl propyl amide amine oxide。
4. Antibiotic liquid detergent according to claim 1, it is characterised in that:
Described preservative is MIT。
5. Antibiotic liquid detergent according to claim 1, it is characterised in that:
The particle diameter of described Nanometer Copper is 12～20nm。
6. Antibiotic liquid detergent according to claim 1, it is characterised in that:
Described Nanometer Copper is prepared by microwave-hydrothermal method；
The preparation method of described Nanometer Copper, comprises the steps of:
Being dissolved in by mantoquita in reaction dissolvent ethylene glycol or diethylene glycol, addition polyacrylic acid is protective agent, carries out microwave hydrothermal reaction, obtains Nanometer Copper；Wherein, the power of microwave hydrothermal reaction is 600～1000W, and the time of microwave hydrothermal reaction is 20～60min, and the temperature of microwave hydrothermal reaction is 190～240 DEG C。
7. Antibiotic liquid detergent according to claim 6, it is characterised in that:
Described mantoquita is copper nitrate, Schweinfurt green or copper chloride。
8. Antibiotic liquid detergent according to claim 6, it is characterised in that:
Described mantoquita concentration in reaction system is 15～30mmol/L；
Described polyacrylic acid concentration in reaction system is identical with mantoquita concentration。
9. the preparation method of the Antibiotic liquid detergent described in any one of claim 1～8, it is characterised in that comprise the steps of:
By the component mix homogeneously of the Antibiotic liquid detergent described in any one of claim 1～8, obtain Antibiotic liquid detergent。
10. the application in household chemicals field of the Antibiotic liquid detergent described in any one of claim 1～8。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610160848.XA CN105695145A (en) | 2016-03-21 | 2016-03-21 | Antibacterial dishwashing liquid as well as preparation method and application of antibacterial dishwashing liquid |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610160848.XA CN105695145A (en) | 2016-03-21 | 2016-03-21 | Antibacterial dishwashing liquid as well as preparation method and application of antibacterial dishwashing liquid |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107955740A (en) * | 2017-12-17 | 2018-04-24 | 柳州市晟铂贸易有限公司 | A kind of greasy dirt high-efficiency cleaning liquid |
| CN108034520A (en) * | 2017-12-29 | 2018-05-15 | 广州馨香日用化工有限公司 | One kind machine washing cleaning agent for dinnerware |
| CN109576075A (en) * | 2018-11-09 | 2019-04-05 | 东莞仁雪实业有限公司 | A kind of novel nano ferment dish washing liquid |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107955740A (en) * | 2017-12-17 | 2018-04-24 | 柳州市晟铂贸易有限公司 | A kind of greasy dirt high-efficiency cleaning liquid |
| CN108034520A (en) * | 2017-12-29 | 2018-05-15 | 广州馨香日用化工有限公司 | One kind machine washing cleaning agent for dinnerware |
| CN109576075A (en) * | 2018-11-09 | 2019-04-05 | 东莞仁雪实业有限公司 | A kind of novel nano ferment dish washing liquid |
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