CN105686074B - A kind of biodegradable filter tip perfume bar and preparation method thereof - Google Patents
A kind of biodegradable filter tip perfume bar and preparation method thereof Download PDFInfo
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- CN105686074B CN105686074B CN201610129550.2A CN201610129550A CN105686074B CN 105686074 B CN105686074 B CN 105686074B CN 201610129550 A CN201610129550 A CN 201610129550A CN 105686074 B CN105686074 B CN 105686074B
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- filter tip
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- perfume
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
- A24D3/0237—Filter rod forming processes by extrusion
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- Extrusion Moulding Of Plastics Or The Like (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
The present invention relates to a kind of biodegradable filter tip perfume bars and preparation method thereof, belong to technical field of cigarettes.By cellulose acetate, poly butylene succinate, foaming agent and other auxiliary agents, melt blending, obtains fusant together, and obtained fusant is then carried out extrusion and is molded into mold, foams after molding, obtains foamed porous stick；Flavouring agent is loaded on foamed porous stick by the way of spraying, dipping or absorption to get to filter tip perfume bar of the invention again.Perfume bar made from preparation method of the present invention is foamed porous structure, specific surface area with higher, conducive to the absorption of flavors and fragrances；Furthermore flue gas aeroge contacts sufficiently with the perfume bar, is discharged when suction convenient for the elution of fragrance.Porous structure of the perfume bar itself also has certain rejection effect to flue gas, can assign the different fragrance of cigarette and jealous by loading different flavors and fragrances, have good market application prospect.
Description
Technical field
The invention belongs to technical field of cigarettes, are related to a kind of Biodegradable cellulose acetate foaming with specific appearance
Porous material filter tip perfume bar and preparation method thereof.
Background technique
World many countries have all made specific law limits, various countries tobacco to the tar content in cigarette smoke at present
Boundary has also all put into very big strength and has been dedicated to reducing the research of coke tar in cigarette technology, and makes great progress.In recent years
Come, the quality ideology of production of cigarettes and consumption also has occurred in the extensive publicity with the country to smoking and health problem, people
The awareness of safety of huge transformation, smoker's smoking is greatly improved.Rationally reduction cigarette product tar content will be complied with vast
The requirement of consumer is conducive to the market adaptability and the competitiveness that improve product.How to make cigarette tar and its it is harmful at
Dividing significantly reduces, while keeping cigarette odor-absorbing that consumer is made to obtain physiology satisfaction again, is the ultimate challenge that Cigarette design faces.
Currently, cigarette flavouring harm reduction additive using extremely wide, risen in terms of Harm reduction techniques tar reduction and compensating aroma
Important function.Additive is mainly added in pipe tobacco and filter stick by existing adding technique, but is added in the tobacco, additive meeting
Burning is simultaneously participated in the suction of cigarette, not only can therefore lose due harm reduction flavouring effect, it is also possible to because cracking produces
Raw new harmful substance.And additive is supported on perfume bar, then is compounded in filter rod, it is allowed to during cigarette is burnt and sucked
Sweet substance is discharged into main flume, can reduce the content of harmful chemical component in cigarette smoke, while can assign
The special fragrance of cigarette and jealous.In addition it can change the appearance of perfume bar, so that the filter rod of different shape appearance is prepared,
Meet requirement of the market to cigarette differentiation, improves the identification of cigarette.
Summary of the invention
It is an object of the present invention to solve the deficiency of the existing technology and provide a kind of biodegradable filters of simple process
Mouth perfume bar and preparation method thereof, the preparation method is easy to operate, and the raw material used is cheap, and product appearance obtained is novel, together
When, the different fragrance of cigarette and jealous is assigned by loading different flavors and fragrances, there is good market application prospect.
The technical solution adopted by the invention is as follows:
A kind of preparation method of biodegradable filter tip perfume bar, includes the following steps:
Step (1), in parts by weight, by cellulose acetate 50-95 parts by weight, poly butylene succinate 5-50 weight
Part, foaming agent 1-20 parts by weight and other auxiliary agent 0-15 parts by weight are measured, at 160-190 DEG C, melt blending 3-5min is melted
Melt object；
The fusant that step (1) obtains is carried out extrusion and is molded into mold, after molding, at 200-230 DEG C by step (2)
Under, foam 1-10min, obtains foamed porous stick；
Flavouring agent is loaded to the foamed porous that step (2) obtains by step (3) by the way of spraying, dipping or absorption
On stick to get arrive biodegradable filter tip perfume bar；
Other auxiliary agents include plasticizer and stabilizer；
The flavouring agent is delicate fragrance type flavouring agent and/or fragrant and sweet type flavouring agent.
Flavouring agent is loaded to the foamed porous stick that step (2) obtains by the way of spraying, dipping or absorption by the present invention
When upper, load capacity is not required specifically, is subject to needs of production.
In above-mentioned technical proposal, cellulose acetate described in step (1) is a cellulose acetate, cellulose diacetate or three
Cellulose acetate.
It is further preferred that foaming agent described in step (1) is AC foaming agent.
It is further preferred that the plasticizer is citric acid ester plasticizer.
It is further preferred that the stabilizer is phosphite-type stabilisers.
It is further preferred that mold described in step (2) perpendicular to axial cross sectional shape be circle, pentagon,
Triangle, cross or polygon.
In above-mentioned technical proposal, the actual conditions of injection molding described in step (1) are as follows: 160 DEG C -175 DEG C of inlet temperature, first
Duan Wendu is 175-185 DEG C, and second segment temperature is 185-190 DEG C, and third section temperature is 185-190 DEG C, and the 4th section of temperature is
185-190 DEG C, the 5th section 185-175 DEG C of temperature, die temperature is 175-160 DEG C, and screw speed is 10-100 r/min.
It is further preferred that the flavouring agent is this Studies of The Aromatic Substances of tobacco.
It is further preferred that the flavouring agent is the fragrance material of flowers and plants plant extract.
It is further preferred that the flavouring agent is sweet aroma agent.
Compared with prior art, the present invention has the advantages that:
Perfume bar made from preparation method of the present invention is foamed porous structure, and specific surface area with higher is conducive to perfume (or spice)
The absorption of smart fragrance；Furthermore flue gas aeroge contacts sufficiently with the perfume bar, is discharged when suction convenient for the elution of fragrance.The fragrance
Stick porous structure itself also has certain rejection effect to flue gas, and can obtain different appearances by changing mold shape
Perfume bar.Preparation method of the present invention is easy to operate, and the raw material used is cheap, and product appearance obtained is novel, meanwhile, by negative
It carries different flavors and fragrances and assigns the different fragrance of cigarette and jealous, there is good market application prospect.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail.
It will be understood to those of skill in the art that the following example is merely to illustrate the present invention, and it should not be regarded as limiting this hair
Bright range.In the examples where no specific technique or condition is specified, described technology or conditions according to the literature in the art
Or it is carried out according to product description.Reagents or instruments used without specified manufacturer is that can be obtained by purchase
Conventional products.
Embodiment 1
By Triafol T 95g, poly butylene succinate 5g, ETHYL CTTRATE 7g, AC foaming agent 20g and phosphorous acid
Esters stabilizer 3g, at 190 DEG C, melt blending 5min obtains fusant；Then obtained fusant is subjected to extrusion injection molding
Molding, being molded into perpendicular to axial cross sectional shape is the actual conditions of injection molding in circular mold are as follows: 160 DEG C of inlet temperature,
First segment temperature is 175 DEG C, and second segment temperature is 185 DEG C, and third section temperature is 185 DEG C, and the 4th section of temperature is 185 DEG C, the 5th
185 DEG C of Duan Wendu, die temperature is 175 DEG C, and screw speed is 10 r/min, and after molding, at 230 DEG C, foam 10min, is taken
Upper this Studies of The Aromatic Substances of tobacco is sprayed after out to get required perfume bar is arrived.Resulting round perfume bar is added in filter tip and is prepared into
Cigarette, tarry matters in smoke amount are reduced, refrigerant sense enhancing, flue gas comfort level and elegant sense enhancing.
Embodiment 2
By cellulose diacetate 50g, poly butylene succinate 50g and AC foaming agent 1g, at 160 DEG C, melt blending
3min obtains fusant；Then obtained fusant is subjected to extrusion injection molding, be molded into perpendicular to axial cross sectional shape
For in the mold of triangle, the actual conditions of injection molding are as follows: 175 DEG C of inlet temperature, first segment temperature is 185 DEG C, second segment temperature
It is 190 DEG C, third section temperature is 190 DEG C, and the 4th section of temperature is 190 DEG C, and the 5th section 175 DEG C of temperature, die temperature is 160 DEG C,
Screw speed is 100 r/min, and after molding, at 200 DEG C, foam 5min, and upper delicate fragrance type flavouring agent is impregnated after taking-up to get arriving
Required perfume bar.Resulting triangle perfume bar is added in filter tip and is prepared into cigarette, tarry matters in smoke amount is reduced, perfume quantity
Increase, flue gas comfort level and elegant sense enhancing.
Embodiment 3
By a cellulose acetate 70g, poly butylene succinate 30g, tributyl citrate 10g, AC foaming agent 10g and Asia
Phosphoric acid ester stabilizer 5g, at 180 DEG C, melt blending 4min obtains fusant；Then obtained fusant is squeezed out
Injection molding, being molded into perpendicular to axial cross sectional shape is the actual conditions of injection molding are as follows: inlet temperature in pentagonal mold
165 DEG C, first segment temperature is 180 DEG C, and second segment temperature is 190 DEG C, and third section temperature is 188 DEG C, and the 4th section of temperature is 185
DEG C, the 5th section 175 DEG C of temperature, die temperature is 160 DEG C, and screw speed is 50 r/min, after molding, at 230 DEG C, and foaming
1min sprays the fragrance material of the plant extracts such as upper flowers and plants to get required perfume bar is arrived after taking-up.Resulting pentagon is fragrant
Charge bar is added in filter tip and is prepared into cigarette, and tarry matters in smoke amount is reduced, and perfume quantity increases, refrigerant sense enhancing, flue gas comfort level and
Elegant sense enhancing.
Embodiment 4
By cellulose diacetate 80g, poly butylene succinate 20g, ETHYL CTTRATE 12g, AC foaming agent 15g and phosphorous
Esters of gallic acid stabilizer 2g, at 190 DEG C, melt blending 3min obtains fusant；Then obtained fusant is subjected to extrusion note
It is moulded into type, being molded into perpendicular to axial cross sectional shape is the actual conditions of injection molding are as follows: inlet temperature in criss-cross mold
170 DEG C, first segment temperature is 185 DEG C, and second segment temperature is 185 DEG C, and third section temperature is 190 DEG C, and the 4th section of temperature is 185
DEG C, the 5th section 175 DEG C of temperature, die temperature is 175 DEG C, and screw speed is 75 r/min, after molding, at 210 DEG C, and foaming
5min impregnates upper fragrant and sweet type flavouring agent to get required perfume bar is arrived after taking-up.Filter tip is added in resulting cross perfume bar
In be prepared into cigarette, tarry matters in smoke amount is reduced, and perfume quantity increases, and refrigerant sense enhancing, flue gas comfort level and elegant sense enhance.
Embodiment 5
By Triafol T 60g, poly butylene succinate 40g, ETHYL CTTRATE 8g, AC foaming agent 18g and phosphorous
Esters of gallic acid stabilizer 1g, at 190 DEG C, melt blending 3min obtains fusant；Then obtained fusant is subjected to extrusion note
It is moulded into type, being molded into is the actual conditions of injection molding are as follows: inlet temperature in the mold of polygon perpendicular to axial cross sectional shape
175 DEG C, first segment temperature is 185 DEG C, and second segment temperature is 190 DEG C, and third section temperature is 185 DEG C, and the 4th section of temperature is 188
DEG C, the 5th section 180 DEG C of temperature, die temperature is 170 DEG C, and screw speed is 35 r/min, after molding, at 220 DEG C, and foaming
3min impregnates upper sweet aroma agent to get required perfume bar is arrived after taking-up.Resulting polygon perfume bar is added in filter tip
It is prepared into cigarette, tarry matters in smoke amount is reduced, and perfume quantity increases, refrigerant sense enhancing, flue gas comfort level and elegant sense enhancing.
1-5 of the embodiment of the present invention is compared with the biodegradability of vinegar fibre, the calculating of weight-loss ratio is marked referring to ASTM
The quasi- resulting 45 days weight-loss ratios of 5209-91, the results are shown in Table 1.
1 embodiment 1-5 of table and vinegar fibre biodegradability (referring to the resulting 45 days weight-loss ratios of ASTM standard 5209-91)
Claims (8)
1. a kind of preparation method of biodegradable filter tip perfume bar, which comprises the steps of:
Step (1), in parts by weight, by cellulose acetate 50-95 parts by weight, poly butylene succinate 5-50 weight
Part, foaming agent 1-20 parts by weight and other auxiliary agent 0-15 parts by weight, at 160-190 DEG C, melt blending 3-5min is melted
Object；
The fusant that step (1) obtains is carried out extrusion and is molded into mold by step (2), after molding, at 200-230 DEG C, and hair
1-10min is steeped, foamed porous stick is obtained；
Step (3) loads to flavouring agent on the foamed porous stick that step (2) obtains by the way of spraying, dipping or absorption,
Obtain biodegradable filter tip perfume bar；
Other auxiliary agents include plasticizer and stabilizer；
The flavouring agent is delicate fragrance type flavouring agent and/or fragrant and sweet type flavouring agent;
Cellulose acetate described in step (1) is a cellulose acetate, cellulose diacetate or Triafol T；
The actual conditions of the injection molding are as follows: 160 DEG C -175 DEG C of inlet temperature, first segment temperature is 175-185 DEG C, second segment temperature
Degree is 185-190 DEG C, and third section temperature is 185-190 DEG C, and the 4th section of temperature is 185-190 DEG C, the 5th section of temperature 185-175
DEG C, die temperature is 175-160 DEG C, screw speed 10-100r/min.
2. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: step (1)
The foaming agent is AC foaming agent.
3. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: the increasing
Modeling agent is citric acid ester plasticizer.
4. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: described is steady
Determining agent is phosphite-type stabilisers.
5. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: step (2)
The mold is round or polygon perpendicular to axial cross sectional shape.
6. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: the perfume (or spice)
Taste agent is this Studies of The Aromatic Substances of tobacco.
7. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: the perfume (or spice)
Taste agent is the fragrance material of flowers and plants plant extract.
8. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: the perfume (or spice)
Taste agent is sweet aroma agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610129550.2A CN105686074B (en) | 2016-03-08 | 2016-03-08 | A kind of biodegradable filter tip perfume bar and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610129550.2A CN105686074B (en) | 2016-03-08 | 2016-03-08 | A kind of biodegradable filter tip perfume bar and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105686074A CN105686074A (en) | 2016-06-22 |
| CN105686074B true CN105686074B (en) | 2019-11-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610129550.2A Active CN105686074B (en) | 2016-03-08 | 2016-03-08 | A kind of biodegradable filter tip perfume bar and preparation method thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020127261A1 (en) * | 2018-12-21 | 2020-06-25 | Jt International S.A. | Method of forming a shaped foam containing a tobacco ingredient containing agent |
| CN109619686A (en) * | 2018-12-28 | 2019-04-16 | 山东圣和塑胶发展有限公司 | The cooling element and preparation method thereof of rodlike porous electronics flue gas product |
| CN114081205A (en) * | 2021-11-29 | 2022-02-25 | 内蒙古昆明卷烟有限责任公司 | Efficient tar-reducing cigarette filter tip and preparation method and application thereof |
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| CN1198080A (en) * | 1995-09-29 | 1998-11-04 | 生物技术生物学自然包装有限公司 | Biodegradable filter material and method for producing same |
| CN1796445A (en) * | 2004-12-28 | 2006-07-05 | 中国科学院化学研究所 | Expanding foam material based on natural polysaccharide and preparation method |
| CN103102510A (en) * | 2012-02-09 | 2013-05-15 | 芜湖特贝特材料科技有限公司 | Cellulose acetate foamed porous material and supercritical carbon dioxide auxiliary processing method thereof |
| KR20130088498A (en) * | 2012-01-31 | 2013-08-08 | 주식회사 케이티앤지 | Smoke volume improving cigarette filter tip by increment of smoke stream velocity in filter |
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2016
- 2016-03-08 CN CN201610129550.2A patent/CN105686074B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1198080A (en) * | 1995-09-29 | 1998-11-04 | 生物技术生物学自然包装有限公司 | Biodegradable filter material and method for producing same |
| CN1796445A (en) * | 2004-12-28 | 2006-07-05 | 中国科学院化学研究所 | Expanding foam material based on natural polysaccharide and preparation method |
| KR20130088498A (en) * | 2012-01-31 | 2013-08-08 | 주식회사 케이티앤지 | Smoke volume improving cigarette filter tip by increment of smoke stream velocity in filter |
| CN103102510A (en) * | 2012-02-09 | 2013-05-15 | 芜湖特贝特材料科技有限公司 | Cellulose acetate foamed porous material and supercritical carbon dioxide auxiliary processing method thereof |
Non-Patent Citations (2)
| Title |
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| 加快环境中烟用滤嘴的生物降解;谭英 等;《中国烟草学报》;20030331;第9卷(第1期);13-18 * |
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