CN105686074A - Biodegradable filter tip fragrance rod and preparation method thereof - Google Patents
Biodegradable filter tip fragrance rod and preparation method thereof Download PDFInfo
- Publication number
- CN105686074A CN105686074A CN201610129550.2A CN201610129550A CN105686074A CN 105686074 A CN105686074 A CN 105686074A CN 201610129550 A CN201610129550 A CN 201610129550A CN 105686074 A CN105686074 A CN 105686074A
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- China
- Prior art keywords
- filter tip
- preparation
- temperature
- biodegradable filter
- perfume bar
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
- A24D3/0237—Filter rod forming processes by extrusion
Landscapes
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
The invention relates to a biodegradable filter tip fragrance rod and a preparation method thereof and belongs to the technical field of cigarettes. Cellulose acetate, butylene succinate, a foaming agent and other additives are subject to melt blending to obtain a melt, the obtained melt is extruded into a mold through injection molding, and foaming is performed after molding to obtain a foamed porous rod; a flavoring agent is supported on the foamed porous rod in a spraying, soaking or absorbing mode, namely the filter tip fragrance rod is obtained. The filter tip fragrance rod prepared by means of the preparation method t is of a foamed porous structure, has higher specific surface area and facilitates the adsorption of flavors and fragrances. In addition, smoke aerogel is fully in contact with the fragrance rod to facilitate elution and release of the fragrances during smoking. The porous structure of the fragrance rod itself further has a certain interception effect on smoke, different flavors and tastes can be endowed by adding different flavors and fragrances, and the biodegradable filter tip fragrance rod has a good market application prospect.
Description
Technical field
The invention belongs to technical field of cigarettes, relate to a kind of Biodegradable cellulose acetate foamed porous material filter tip perfume bar with specific appearance and preparation method thereof。
Background technology
Tar content in cigarette smoke has all been made clear and definite law limits by current world many countries, and various countries Nicotiana tabacum L. circle has also all put into very big strength and has been devoted to reduce the research of coke tar in cigarette technology, and makes great progress。In recent years, along with the domestic extensive publicity to smoking with health problem, the quality ideology of production of cigarettes and consumption also be there occurs huge transformation by people, and the safety consciousness of smoker's smoking is greatly improved。Rationally reduce cigarette product tar content and will comply with the requirement of consumers in general, be conducive to improving market adaptability and the competitiveness of product。The tar and the harmful components thereof that how to make Medicated cigarette significantly reduce, and keep again cigarette odor-absorbing to make consumer obtain physiology simultaneously and meet, and are the ultimate challenges that face of Cigarette design。
At present, the application of Medicated cigarette flavouring harm reduction additive is extremely wide, drops Jiao and compensating aroma important role at Harm reduction techniques。Additive is mainly joined in tobacco shred and filter stick by existing adding technique, but adds in tobacco shred, and additive can simultaneously participate in burning with the suction of Medicated cigarette, not only can therefore lose due harm reduction flavouring effect, it is also possible to because cracking produces new harmful substance。And by additive load on perfume bar, then it is compounded in filter rod, so as to burn and suck at Medicated cigarette, sweet substance is discharged in main flume by process, it is possible to reduce the content of harmful chemical component in cigarette smoke, the special fragrance of Medicated cigarette can be given and jealous simultaneously。Additionally can change the outward appearance of perfume bar, thus preparing the filter rod of difformity outward appearance, meet the market requirement to Medicated cigarette differentiation, improving the identification of Medicated cigarette。
Summary of the invention
The invention aims to solve the deficiencies in the prior art, a kind of simple biodegradable filter tip perfume bar of technique and preparation method thereof is provided, this preparation method is simple to operate, the raw material used is cheap, the product appearance prepared is novel, meanwhile, give the different fragrance of Medicated cigarette and jealous by the essence and flavoring agent that load is different, there is good market application foreground。
The technical solution used in the present invention is as follows:
The preparation method of a kind of biodegradable filter tip perfume bar, comprises the steps:
Step (1), according to parts by weight meter, by cellulose acetate 50-95 weight portion, poly butylene succinate 5-50 weight portion, foaming agent 1-20 weight portion and other auxiliary agent 0-15 weight portion, at 160-190 DEG C, melt blending 3-5min, obtain fused mass；
Step (2), carries out extrusion by the fused mass that step (1) obtains and is injected in mould, and after molding, at 200-230 DEG C, foam 1-10min, obtains foamed porous rod；
Step (3), adopts flavouring agent the mode of spraying, dipping or absorption to load on the foamed porous rod that step (2) obtains, namely obtains biodegradable filter tip perfume bar；
Other described auxiliary agent includes plasticizer and stabilizer；
Described flavouring agent is delicate fragrance type flavouring agent and/or fragrant and sweet type flavouring agent。
When the present invention adopts the mode of spraying, dipping or absorption to be loaded to by flavouring agent on the foamed porous rod that step (2) obtains, load capacity does not have concrete requirement, is as the criterion with needs of production。
In technique scheme, the cellulose acetate described in step (1) is a cellulose acetate, cellulose diacetate or Triafol T。
It is further preferred that the foaming agent described in step (1) is AC foaming agent。
It is further preferred that described plasticizer is citric acid ester plasticizer。
It is further preferred that described stabilizer is phosphite-type stabilisers。
It is further preferred that the axial cross sectional shape that is perpendicular to of the mould described in step (2) is circle, pentagon, triangle, cross or polygon。
In technique scheme, the actual conditions of the injection moulding described in step (1) is: inlet temperature 160 DEG C-175 DEG C, first paragraph temperature is 175-185 DEG C, second segment temperature is 185-190 DEG C, 3rd section of temperature is 185-190 DEG C, and the 4th section of temperature is 185-190 DEG C, the 5th section temperature 185-175 DEG C, die temperature is 175-160 DEG C, and screw speed is 10-100r/min。
It is further preferred that described flavouring agent is this Studies of The Aromatic Substances of Nicotiana tabacum L.。
It is further preferred that the fragrance material that described flavouring agent is flowers and plants plant extract。
It is further preferred that described flavouring agent is sweet aroma agent。
Compared with prior art, it has the beneficial effect that the present invention
The perfume bar that preparation method of the present invention prepares is foamed porous structure, has higher specific surface area, is conducive to the absorption of essence and flavoring agent；In addition flue gas aeroge contacts fully with this perfume bar, is easy to the eluting release of fragrance during suction。Flue gas is also had certain rejection effect by this perfume bar loose structure itself, and can obtain the perfume bar of different outward appearance by changing mold shape。Preparation method of the present invention is simple to operate, and the raw material of use is cheap, and the product appearance prepared is novel, meanwhile, gives the different fragrance of Medicated cigarette and jealous by the essence and flavoring agent that load is different, has good market application foreground。
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail。
It will be understood to those of skill in the art that the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention。Unreceipted concrete technology or condition person in embodiment, technology or condition described by the document in this area or carry out according to product description。Agents useful for same or the unreceipted production firm person of instrument, be and can pass through to buy the conventional products obtained。
Embodiment 1
By Triafol T 95g, poly butylene succinate 5g, ETHYL CTTRATE 7g, AC foaming agent 20g and phosphite-type stabilisers 3g, at 190 DEG C, melt blending 5min, obtain fused mass；Then the fused mass obtained is carried out extrusion injection mo(u)lding, being injected into and being perpendicular to axial cross sectional shape is in circular mould, the actual conditions of injection moulding is: inlet temperature 160 DEG C, first paragraph temperature is 175 DEG C, second segment temperature is 185 DEG C, 3rd section of temperature is 185 DEG C, 4th section of temperature is 185 DEG C, the 5th section of temperature 185 DEG C, and die temperature is 175 DEG C, screw speed is 10r/min, after molding, at 230 DEG C, foam 10min, after taking-up, upper this Studies of The Aromatic Substances of Nicotiana tabacum L. of spraying, namely obtains required perfume bar。Being added in filter tip by the circular perfume bar of gained and prepare into Medicated cigarette, its tarry matters in smoke amount reduces, and refrigerant sense strengthens, and flue gas comfort level and elegant sense strengthen。
Embodiment 2
By cellulose diacetate 50g, poly butylene succinate 50g and AC foaming agent 1g, at 160 DEG C, melt blending 3min, obtain fused mass；Then the fused mass obtained is carried out extrusion injection mo(u)lding, it is injected into and is perpendicular in the mould that axial cross sectional shape is triangle, the actual conditions of injection moulding is: inlet temperature 175 DEG C, first paragraph temperature is 185 DEG C, second segment temperature is 190 DEG C, 3rd section of temperature is 190 DEG C, 4th section of temperature is 190 DEG C, the 5th section of temperature 175 DEG C, and die temperature is 160 DEG C, screw speed is 100r/min, after molding, at 200 DEG C, foam 5min, after taking-up, the upper delicate fragrance type flavouring agent of dipping, namely obtains required perfume bar。Being added in filter tip by the triangle perfume bar of gained and prepare into Medicated cigarette, its tarry matters in smoke amount reduces, and perfume quantity increases, and flue gas comfort level and elegant sense strengthen。
Embodiment 3
By a cellulose acetate 70g, poly butylene succinate 30g, tributyl citrate 10g, AC foaming agent 10g and phosphite-type stabilisers 5g, at 180 DEG C, melt blending 4min, obtain fused mass；Then the fused mass obtained is carried out extrusion injection mo(u)lding, being injected into and being perpendicular to axial cross sectional shape is in pentagonal mould, the actual conditions of injection moulding is: inlet temperature 165 DEG C, first paragraph temperature is 180 DEG C, second segment temperature is 190 DEG C, 3rd section of temperature is 188 DEG C, 4th section of temperature is 185 DEG C, the 5th section of temperature 175 DEG C, and die temperature is 160 DEG C, screw speed is 50r/min, after molding, at 230 DEG C, foam 1min, spray the fragrance material of the plant extract such as upper flowers and plants after taking-up, namely obtain required perfume bar。Being added in filter tip by the pentagon perfume bar of gained and prepare into Medicated cigarette, its tarry matters in smoke amount reduces, and perfume quantity increases, and refrigerant sense strengthens, and flue gas comfort level and elegant sense strengthen。
Embodiment 4
By cellulose diacetate 80g, poly butylene succinate 20g, ETHYL CTTRATE 12g, AC foaming agent 15g and phosphite-type stabilisers 2g, at 190 DEG C, melt blending 3min, obtain fused mass；Then the fused mass obtained is carried out extrusion injection mo(u)lding, being injected into and being perpendicular to axial cross sectional shape is in criss-cross mould, the actual conditions of injection moulding is: inlet temperature 170 DEG C, first paragraph temperature is 185 DEG C, second segment temperature is 185 DEG C, 3rd section of temperature is 190 DEG C, 4th section of temperature is 185 DEG C, the 5th section of temperature 175 DEG C, and die temperature is 175 DEG C, screw speed is 75r/min, after molding, at 210 DEG C, foam 5min, after taking-up, the upper fragrant and sweet type flavouring agent of dipping, namely obtains required perfume bar。Being added in filter tip by the cross perfume bar of gained and prepare into Medicated cigarette, its tarry matters in smoke amount reduces, and perfume quantity increases, and refrigerant sense strengthens, and flue gas comfort level and elegant sense strengthen。
Embodiment 5
By Triafol T 60g, poly butylene succinate 40g, ETHYL CTTRATE 8g, AC foaming agent 18g and phosphite-type stabilisers 1g, at 190 DEG C, melt blending 3min, obtain fused mass；Then the fused mass obtained carries out extrusion injection mo(u)lding, and being injected into and being perpendicular to axial cross sectional shape is in polygonal mould, and the actual conditions of injection moulding is: inlet temperature 175 DEG C, first paragraph temperature is 185 DEG C, and second segment temperature is 190 DEG C, and the 3rd section of temperature is 185 DEG C, 4th section of temperature is 188 DEG C, the 5th section of temperature 180 DEG C, and die temperature is 170 DEG C, screw speed is 35r/min, after molding, at 220 DEG C, foam 3min, after taking-up, the upper sweet aroma agent of dipping, namely obtains required perfume bar。Being added in filter tip by the polygon perfume bar of gained and prepare into Medicated cigarette, its tarry matters in smoke amount reduces, and perfume quantity increases, and refrigerant sense strengthens, and flue gas comfort level and elegant sense strengthen。
Being compared by biodegradability fine with vinegar for embodiment of the present invention 1-5, the 45 days weight-loss ratios calculating reference ASTM standard 5209-91 gained of weight-loss ratio, result is as shown in table 1。
Table 1 embodiment 1-5 and vinegar fibre biodegradability (45 days weight-loss ratios with reference to ASTM standard 5209-91 gained)
Claims (10)
1. the preparation method of a biodegradable filter tip perfume bar, it is characterised in that comprise the steps:
Step (1), according to parts by weight meter, by cellulose acetate 50-95 weight portion, poly butylene succinate 5-50 weight portion, foaming agent 1-20 weight portion and other auxiliary agent 0-15 weight portion, at 160-190 DEG C, melt blending 3-5min, obtain fused mass；
Step (2), carries out extrusion by the fused mass that step (1) obtains and is injected in mould, and after molding, at 200-230 DEG C, foam 1-10min, obtains foamed porous rod；
Step (3), adopts flavouring agent the mode of spraying, dipping or absorption to load on the foamed porous rod that step (2) obtains, namely obtains biodegradable filter tip perfume bar；
Other described auxiliary agent includes plasticizer and stabilizer；
Described flavouring agent is delicate fragrance type flavouring agent and/or fragrant and sweet type flavouring agent。
2. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: the cellulose acetate described in step (1) is a cellulose acetate, cellulose diacetate or Triafol T。
3. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: the foaming agent described in step (1) is AC foaming agent。
4. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: described plasticizer is citric acid ester plasticizer。
5. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: described stabilizer is phosphite-type stabilisers。
6. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: the axial cross sectional shape that is perpendicular to of the mould described in step (2) is circle, pentagon, triangle, cross or polygon。
7. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterized in that: the actual conditions of the injection moulding described in step (1) is: inlet temperature 160 DEG C-175 DEG C, first paragraph temperature is 175-185 DEG C, second segment temperature is 185-190 DEG C, 3rd section of temperature is 185-190 DEG C, and the 4th section of temperature is 185-190 DEG C, the 5th section temperature 185-175 DEG C, die temperature is 175-160 DEG C, and screw speed is 10-100r/min。
8. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: described flavouring agent is this Studies of The Aromatic Substances of Nicotiana tabacum L.。
9. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: described flavouring agent is the fragrance material of flowers and plants plant extract。
10. the preparation method of biodegradable filter tip perfume bar according to claim 1, it is characterised in that: described flavouring agent is sweet aroma agent。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610129550.2A CN105686074B (en) | 2016-03-08 | 2016-03-08 | A kind of biodegradable filter tip perfume bar and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610129550.2A CN105686074B (en) | 2016-03-08 | 2016-03-08 | A kind of biodegradable filter tip perfume bar and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105686074A true CN105686074A (en) | 2016-06-22 |
| CN105686074B CN105686074B (en) | 2019-11-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610129550.2A Active CN105686074B (en) | 2016-03-08 | 2016-03-08 | A kind of biodegradable filter tip perfume bar and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109619686A (en) * | 2018-12-28 | 2019-04-16 | 山东圣和塑胶发展有限公司 | The cooling element and preparation method thereof of rodlike porous electronics flue gas product |
| CN113226068A (en) * | 2018-12-21 | 2021-08-06 | 日本烟草国际股份公司 | Method of forming a formed foam containing an agent comprising a tobacco component |
| WO2023092854A1 (en) * | 2021-11-29 | 2023-06-01 | 内蒙古昆明卷烟有限责任公司 | High-efficiency tar-reducing cigarette filter, and preparation method therefor and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1198080A (en) * | 1995-09-29 | 1998-11-04 | 生物技术生物学自然包装有限公司 | Biodegradable filter material and method for its manufacture |
| CN1796445A (en) * | 2004-12-28 | 2006-07-05 | 中国科学院化学研究所 | Expanding foam material based on natural polysaccharide and preparation method |
| CN103102510A (en) * | 2012-02-09 | 2013-05-15 | 芜湖特贝特材料科技有限公司 | Cellulose acetate foamed porous material and supercritical carbon dioxide auxiliary processing method thereof |
| KR20130088498A (en) * | 2012-01-31 | 2013-08-08 | 주식회사 케이티앤지 | Smoke volume improving cigarette filter tip by increment of smoke stream velocity in filter |
-
2016
- 2016-03-08 CN CN201610129550.2A patent/CN105686074B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1198080A (en) * | 1995-09-29 | 1998-11-04 | 生物技术生物学自然包装有限公司 | Biodegradable filter material and method for its manufacture |
| CN1796445A (en) * | 2004-12-28 | 2006-07-05 | 中国科学院化学研究所 | Expanding foam material based on natural polysaccharide and preparation method |
| KR20130088498A (en) * | 2012-01-31 | 2013-08-08 | 주식회사 케이티앤지 | Smoke volume improving cigarette filter tip by increment of smoke stream velocity in filter |
| CN103102510A (en) * | 2012-02-09 | 2013-05-15 | 芜湖特贝特材料科技有限公司 | Cellulose acetate foamed porous material and supercritical carbon dioxide auxiliary processing method thereof |
Non-Patent Citations (2)
| Title |
|---|
| JUERGEN PULS 等: "Degradation of Cellulose Acetate-Based Materials: A Review", 《J POLYM ENVIRON》 * |
| 谭英 等: "加快环境中烟用滤嘴的生物降解", 《中国烟草学报》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113226068A (en) * | 2018-12-21 | 2021-08-06 | 日本烟草国际股份公司 | Method of forming a formed foam containing an agent comprising a tobacco component |
| CN109619686A (en) * | 2018-12-28 | 2019-04-16 | 山东圣和塑胶发展有限公司 | The cooling element and preparation method thereof of rodlike porous electronics flue gas product |
| WO2023092854A1 (en) * | 2021-11-29 | 2023-06-01 | 内蒙古昆明卷烟有限责任公司 | High-efficiency tar-reducing cigarette filter, and preparation method therefor and application thereof |
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| Publication number | Publication date |
|---|---|
| CN105686074B (en) | 2019-11-26 |
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