CN105683230B - 来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯 - Google Patents

来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯 Download PDF

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CN105683230B
CN105683230B CN201480059599.4A CN201480059599A CN105683230B CN 105683230 B CN105683230 B CN 105683230B CN 201480059599 A CN201480059599 A CN 201480059599A CN 105683230 B CN105683230 B CN 105683230B
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polybutadiene
cis
stereoregular diblock
equal
stereoregular
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CN105683230A (zh
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G·里奇
G·莱昂内
A·索玛兹
F·马希
M·F·皮里尼
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Versalis SpA
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Versalis SpA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7095—Cobalt, nickel or compounds thereof
    • C08F4/7096—Cobalt or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
CN201480059599.4A 2013-11-05 2014-11-03 来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯 Active CN105683230B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2013A001828 2013-11-05
IT001828A ITMI20131828A1 (it) 2013-11-05 2013-11-05 Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
PCT/IB2014/065764 WO2015068094A1 (en) 2013-11-05 2014-11-03 Stereoregular diblock polybutadienes having a 1,4-cis/syndiotactic 1,2 structure from stereospecific polymerization

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CN105683230A CN105683230A (zh) 2016-06-15
CN105683230B true CN105683230B (zh) 2018-07-13

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CN201480059599.4A Active CN105683230B (zh) 2013-11-05 2014-11-03 来自立构规整聚合的具有1,4-顺式/间同立构1,2结构的有规立构的二嵌段聚丁二烯

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US (1) US10093763B2 (enExample)
EP (1) EP3066139B1 (enExample)
JP (1) JP6574190B2 (enExample)
KR (1) KR102223300B1 (enExample)
CN (1) CN105683230B (enExample)
BR (1) BR112016009097B1 (enExample)
CA (1) CA2925263C (enExample)
EA (1) EA031540B1 (enExample)
ES (1) ES2726852T3 (enExample)
HR (1) HRP20190874T1 (enExample)
HU (1) HUE043431T2 (enExample)
IT (1) ITMI20131828A1 (enExample)
MX (1) MX377140B (enExample)
MY (1) MY172664A (enExample)
PL (1) PL3066139T3 (enExample)
PT (1) PT3066139T (enExample)
RS (1) RS58772B1 (enExample)
SG (1) SG11201603260WA (enExample)
TR (1) TR201907212T4 (enExample)
TW (1) TWI678379B (enExample)
WO (1) WO2015068094A1 (enExample)

Families Citing this family (3)

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Publication number Priority date Publication date Assignee Title
ITMI20131830A1 (it) * 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
IT201700059763A1 (it) 2017-05-31 2018-12-01 Versalis Spa Copolimeri butadiene-isoprene di-blocco e procedimento per la loro preparazione
IT202000028823A1 (it) 2020-11-27 2022-05-27 Consiglio Nazionale Ricerche Copolimeri dienici a stereoblocchi e relativo processo di preparazione.

Citations (1)

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US5548045A (en) * 1991-04-24 1996-08-20 Japan Synthetic Rubber Co., Ltd. Process for producing polybutadiene

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US3522332A (en) 1967-06-02 1970-07-28 Japan Synthetic Rubber Co Ltd Process for the preparation of 1,2-polybutadiene
JPS4917666B1 (enExample) * 1970-12-25 1974-05-02
JPS4917667B1 (enExample) * 1970-12-25 1974-05-02
US3817968A (en) 1972-11-28 1974-06-18 Bridgestone Tire Co Ltd Method of producing equibinary (cis 1.4-1.2) polybutadiene
DE2447203C3 (de) 1974-10-03 1982-03-18 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Polybutadien
JPS53143685A (en) 1977-05-23 1978-12-14 Japan Synthetic Rubber Co Ltd Preparation of 1,2-polybutadiene
US4255296A (en) 1977-12-02 1981-03-10 Bridgestone Tire Company Limited Polybutadiene rubber composition
DE2911262A1 (de) 1979-03-22 1980-10-02 Bayer Ag Katalysator, dessen herstellung und verfahren zur polymerisation von butadien
DE3000708A1 (de) 1980-01-10 1981-07-16 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von reaktionsprodukten aus konjugierten diolefinen und aromatischen kohlenwasserstoffen
JPS56109204A (en) * 1980-01-31 1981-08-29 Japan Synthetic Rubber Co Ltd Preparation of polybutadiene
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IT1231774B (it) 1989-08-03 1991-12-21 Enichem Anic Spa Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine.
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JP2954351B2 (ja) 1990-06-22 1999-09-27 エクソン・ケミカル・パテンツ・インク オレフィン重合用のアルミニウムを含まないモノシクロペンタジエニルメタロセン触媒
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ITMI20011813A1 (it) 2001-08-24 2003-02-24 Enichem Spa Complessi di cobalto utili nella polimerizzazione del 1,3-butadiene
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ITMI20131830A1 (it) * 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica

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Publication number Publication date
EA201690625A1 (ru) 2016-12-30
BR112016009097B1 (pt) 2021-09-14
ITMI20131828A1 (it) 2015-05-06
ES2726852T3 (es) 2019-10-09
BR112016009097A2 (enExample) 2017-08-01
US10093763B2 (en) 2018-10-09
TR201907212T4 (tr) 2019-06-21
KR20160084854A (ko) 2016-07-14
SG11201603260WA (en) 2016-05-30
US20160264707A1 (en) 2016-09-15
TWI678379B (zh) 2019-12-01
WO2015068094A1 (en) 2015-05-14
MY172664A (en) 2019-12-09
TW201522393A (zh) 2015-06-16
CA2925263C (en) 2021-11-30
EP3066139B1 (en) 2019-02-20
EA031540B1 (ru) 2019-01-31
PT3066139T (pt) 2019-05-31
RS58772B1 (sr) 2019-06-28
JP2016536447A (ja) 2016-11-24
EP3066139A1 (en) 2016-09-14
CN105683230A (zh) 2016-06-15
HK1223386A1 (en) 2017-07-28
HRP20190874T1 (hr) 2019-07-12
KR102223300B1 (ko) 2021-03-05
CA2925263A1 (en) 2015-05-14
JP6574190B2 (ja) 2019-09-11
MX377140B (es) 2025-03-07
HUE043431T2 (hu) 2019-08-28
PL3066139T3 (pl) 2019-08-30
MX2016005664A (es) 2016-12-07

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