CN105670815B - A kind of tea seed cleanser and its preparation process - Google Patents
A kind of tea seed cleanser and its preparation process Download PDFInfo
- Publication number
- CN105670815B CN105670815B CN201610020051.XA CN201610020051A CN105670815B CN 105670815 B CN105670815 B CN 105670815B CN 201610020051 A CN201610020051 A CN 201610020051A CN 105670815 B CN105670815 B CN 105670815B
- Authority
- CN
- China
- Prior art keywords
- cake
- filter residue
- camellia oleifera
- drying
- tea seed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 241001122767 Theaceae Species 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims description 4
- 241000526900 Camellia oleifera Species 0.000 claims abstract description 33
- 238000001035 drying Methods 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 238000004806 packaging method and process Methods 0.000 claims abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 16
- 239000003208 petroleum Substances 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000000605 extraction Methods 0.000 abstract description 32
- 239000004519 grease Substances 0.000 abstract description 26
- 239000001397 quillaja saponaria molina bark Substances 0.000 abstract description 13
- 229930182490 saponin Natural products 0.000 abstract description 13
- 150000007949 saponins Chemical class 0.000 abstract description 13
- 235000018597 common camellia Nutrition 0.000 abstract description 5
- 241000209507 Camellia Species 0.000 abstract description 2
- 238000004458 analytical method Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 240000001548 Camellia japonica Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 239000010908 plant waste Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
A kind of tea seed cleanser through drying, crushing, extraction de-oiling, filters using the cake of camellia oleifera seeds after squeezing as raw material, obtains the processes such as re-dry, crushing, packaging after filter residue, finally obtain product.It is up to 98.21% using the technique grease removal efficiency；Saponin content 15.32%, moisture 6.88%, meets product standard；Up to 17.32, brown, uniform free from admixture does not lump, free from extraneous odour, has camellia smell prepared tea seed cleanser detergency.
Description
Technical field
The invention belongs to plant wastes to utilize technical field, and in particular to a kind of tea seed cleanser and its prepare work
Skill.
Background technology
Tea-cake dregs are camellia seed kernels through oil expression a treated blob of slag, about 500,000 tons of the cake of camellia oleifera seeds of the annual output in China, absolutely
It is mostly used in feed or is directly dropped.Tea Saponin containing 10%-13% in cake of camellia oleifera seeds is a kind of natural table of function admirable
Face activating agent has the properties such as good emulsification, dispersion, moistening, foaming, foam stabilizing, decontamination, but at present not yet by reasonable development.
Invention content
For the above problem present in background technology, the object of the present invention is to provide a kind of tea seed cleanser and its systems
Standby technique, i.e., prepare a kind of tea seed powder that dirt-removing power is strong by raw material of cake of camellia oleifera seeds.
The technical solution adopted by the present invention is as follows：
A kind of tea seed cleanser, it is characterised in that it is prepared by following technique：
1）Raw material selects：Select the cake of camellia oleifera seeds after squeezing for raw material；
2）Pretreatment of raw material：The impurity in cake of camellia oleifera seeds is removed, drying to constant weight through 50 DEG C, smashes it through 40 mesh sieve, 50-
60 DEG C of dryings to moisture is less than 3%, obtains cake of camellia oleifera seeds powder；
3）Extract de-oiling：Cake of camellia oleifera seeds powder is weighed, is placed in Soxhlet extractor, using petroleum ether as solvent, in extraction temperature
Spend 50 DEG C, solid-liquid ratio 1：5（M：V）Under the conditions of extract 3h；Then it is filtered at vacuum degree 0.06-0.08MPa, retains filter residue；
4）Filter residue and drying：Filter residue is placed in baking oven dry 2-4 h under the conditions of 70-90 DEG C；Preferably：70 DEG C of dry 3h；
5）Filter residue crushes：Filter residue after drying is smashed it through into 60 mesh sieve again, obtains tea seed cleanser；
6）Packaging：Obtain finished product.
A kind of application of the above-mentioned tea seed cleanser on cleaning clothing.
Using above technical scheme, grease removal efficiency is up to 98.21%, saponin content 15.32%, obtained tea seed is gone
For the detergency of dirty powder up to 17.32, dirt-removing power has pole to dramatically increase than founding white liquid detergent（p<0.01）；The acid-base value of tea seed powder
Be more suitable for the skin of human body, the irritation of opponent is small, modest viscosity, product is brown, uniform free from admixture, do not lump, free from extraneous odour,
With camellia smell.
Description of the drawings
Fig. 1：Influence of the extraction temperature to grease removal efficiency in cake of camellia oleifera seeds；
Fig. 2：Influence of the extraction time to grease removal efficiency in cake of camellia oleifera seeds；
Fig. 3：Influence of the solid-liquid ratio to grease removal efficiency in cake of camellia oleifera seeds；
Fig. 4：Influence of the granular size to detergency in cake of camellia oleifera seeds.
Specific implementation mode
Below by specific embodiment, the present invention is described in further detail.
Embodiment 1
（1）MATERIALS METHODS
Raw material and reagent
Cake of camellia oleifera seeds：Resid amount 9.14%, Jinhua, Zhejiang Kingsoft grease Co., Ltd.
Reagent：Tea Saponin standard items：Purity 98%, Shanghai Yuan Ye Bioisystech Co., Ltd；Petroleum ether（Boiling range 30-60
℃）, vanillic aldehyde, absolute ethyl alcohol, sulfuric acid etc. is that analysis is pure.
Equipment
HR 1727/06/BC type blenders, HH-4 type digital display thermostat water baths, DK-S26 type electric-heated thermostatic water baths,
DGG-9053AD type electric heating constant-temperature blowing drying boxes, 7220 type spectrophotometers of VIS-, 40 mesh, 60 mesh, 80 mesh, 100 mesh, 120
Mesh standard sieve, ZK-801 type mini desktop vacuum pumps, RE-2000 Rotary Evaporators, NDJ-5s type rotational viscometers.
Test method
Index and performance measurement
Fat：With reference to GB/T5009.6-2003《Fatty measurement in food》；Saponin：According to vanillic aldehyde-sulphate method inspection
Survey the content of Tea Saponin；Moisture：With reference to GB 50093-2010《The measurement of moisture in food》It carries out；Detergency：With reference to Zhang Shixin
Detergency experiment carries out；PH value measures：Clean product solution is washed in preparation 1%, is measured using pH meter；Stability Determination：Stability
（Fluid product）It is placed in -3-10 DEG C of refrigerator for 24 hours, takes out the when of restoring to room temperature and observe nodeless mesh, no precipitation；(40±1)
DEG C incubator in place for 24 hours, taking-up observe immediately it is not stratified, it is haze-free, and do not change smell；Viscosimetric analysis：It takes suitable
Test specimen pours into 200 milliliters of beaker in tall form, with turning viscosimeter determination sample in 0 DEG C, 25 DEG C, 40 DEG C of viscosity.
Technological process
Cake of camellia oleifera seeds → drying → crushing → extraction de-oiling → suction filtration（It is concentrated in vacuo, vacuum degree 0.06-0.08MPa）→ filter
Slag → filter residue and drying → filter residue crushing → packaging → product
Pretreatment of raw material：The impurity in cake of camellia oleifera seeds is removed, drying to constant weight through 50 DEG C, smashes it through 40 mesh sieve, 50-60
DEG C drying（Final moisture content<3%）.
Extract de-oiling：A certain amount of cake of camellia oleifera seeds powder is weighed, is placed in Soxhlet extractor, using petroleum ether as solvent, is ground
Study carefully the influence that extracting condition washes cake of camellia oleifera seeds grease removal efficiency in clean product.
Process optimization
1.3.3.1 grouts Residual oil technique
In de-oiling technique, using grease removal efficiency as index, extraction temperature is studied（30-60℃）, extraction time（2-8h）、
Solid-liquid ratio（m：V, 1：3-1：7）To grease removal efficiency in grouts（Calculation formula is carried out by formula 1）Influence, and it is true with Orthogonal Method
Surely the extracting technology of Residual oil in grouts is removed.
Filter residue and drying technique
Using baking oven, drying temperature is studied（50-110℃）, drying time（1h-4h）To Tea Saponin content and moisture
Influence.
Filter residue crushes
With product particle degree size（40 mesh, 60 mesh, 80 mesh, 100 mesh, 120 mesh）For its shadow to detergency of Elements research
It rings.
Data analysis
All experiments 3 times are parallel, are averaged and standard deviation, SPSS17.0 softwares carry out variance analysis.
（2）As a result with analysis
Influence of the extraction temperature to grease removal efficiency in cake of camellia oleifera seeds
The dry oil-tea-cake meal 10g to constant weight is weighed, by solid-liquid ratio 1：5（M：V）It is molten as extracting that petroleum ether is added
Agent, respectively under conditions of extraction temperature is 30,40,50,60 DEG C, it is de- to grease to investigate different extraction temperatures by extraction time 3h
Except the influence of rate, the result is shown in Figure 1.
As seen from Figure 1, within the scope of 40-50 DEG C, grease removal efficiency increases very fast（p<0.01）, and in extraction temperature
When degree is 50 DEG C, grease removal efficiency reaches maximum value 98.22%；Continue to increase temperature, grease removal efficiency has small size reduction（p>
0.05）.Therefore, 50 DEG C or so of Extracting temperature selection is more suitable.
Influence of the extraction time to grease removal efficiency in cake of camellia oleifera seeds
The dry oil-tea-cake meal 10g to constant weight is weighed, by solid-liquid ratio 1：5（M：V）It is molten as extracting that petroleum ether is added
Agent, under conditions of extraction temperature is 50 DEG C, extraction time is respectively 2,3,4,5,6,7,8h, investigate different extraction times
Influence to grease removal efficiency, is as a result shown in Fig. 2.
Extraction time has more significant influence to cake of camellia oleifera seeds grease removal efficiency, and with the extension of extraction time, grease is de-
Except rate is continuously improved（p<0.01）, for extraction time in 3h, grease removal efficiency reaches 98.26%；Extraction time is more than 3h, grease
Removal efficiency amplitude of variation slows down（p>0.05）, big many greases of sauce has all been extracted.Therefore, it is more suitable to be selected as 3h for extraction time
Preferably.
Influence of the solid-liquid ratio to grease removal efficiency in cake of camellia oleifera seeds
With 50 DEG C of extraction temperature, under conditions of extraction time 3h, research solid-liquid ratio is 1：3、1：4、1：5、1：6、1：7 pairs of oil
The influence of tea-cake dregs grease removal efficiency, test result are shown in Fig. 3.
With the increase of petroleum ether dosage, cake of camellia oleifera seeds residua content is reduced, and grease removal efficiency pole dramatically increases（p<
0.01）, when solid-liquid ratio is more than 1:When 5, grease removal efficiency tends towards stability（p>0.05）, it is 98.23 when grease removal efficiency maximum.
The optimization of cake of camellia oleifera seeds extracting technology
It uses petroleum ether as Extraction solvent, chooses solid-liquid ratio, extraction temperature, three factor of extraction time as influence Oil-tea-cake
The principal element of dregs of rice grease removal efficiency, and three factor L are designed with this9（33）Orthogonal test, orthogonal experiment data and analysis result are shown in
Table 1.
As shown in Table 1, the principal element sequence for influencing cake of camellia oleifera seeds extracting technology is B ＞ A ＞ C, optimum extraction process
Item is A2B2C2, i.e. 50 DEG C of Extracting temperature, solid-liquid ratio 1：5（M：V）, extraction time 3h.This optimum process condition combines not
Occur in table, so 3 confirmatory experiments are carried out to it, cake of camellia oleifera seeds Residual oil fat removal efficiency average out to 98.21%, higher than above-mentioned
Test result shows A2B2C2For optimum extraction condition, grouts residual oil content is 1.89% with this condition<2.0%, meet initially
One of product standard of formulation.
Influence of the drying condition to the content of Tea Saponin
Grouts utilizes oven drying, research drying temperature after de-oiling is filtered（50-110℃）, drying time（1h-4h）
Influence to the content of Tea Saponin and moisture, experimental result are shown in Table 2.
As can be seen from Table 2 under the conditions of different disposal, saponin content and moisture have different degrees of variation.9
Saponin content under a treatment conditions is all higher than 10% and complies with standard, wherein 70 DEG C of dry 3h and 4h highests, but dry 4h compares drying
The saponin content variation of 3h is little（p>0.05）, while moisture with this condition<8%, meet the technical indicator of product, but
In view of economic benefit, therefore final drying condition selects 70 DEG C of drying temperature, time 3h.
Influence of the milling product granularity size to detergency
Grouts after de-oiling are crushed, 40 mesh, 60 mesh, 80 mesh, 100 mesh and 120 mesh sieve, granular size is crossed respectively and corresponds to respectively
0.420mm, 0.250mm, 0.178mm, 0.150mm and 0.124mm, study the influence to product detergency, and measurement result is shown in figure
4。
As seen from Figure 4, as tea seed grouts particle is smaller, detergency improves rapidly（p<0.01）, reach
17.32, after being sieved to 60 mesh（Granularity<0.250mm）Tea seed powder detergency effect it is preferable, but amplitude of variation is little（p>
0.05）.
Tea seed powder properties of product
The tea seed powder prepared according to optimum process is measured its performance, and measurement result is shown in Table 3.
As can be seen from Table 3, the 1% of same 1kg washes clean solution, and the dirt-removing power of tea seed powder has extremely significantly than founding white liquid detergent
Increase（p<0.01）；The acid-base value of tea seed powder is more suitable for the skin of human body, and the irritation of opponent is small；Tea seed powder under different temperatures
Viscosity differences are very big, and temperature is higher, and viscosity is lower, but after 25 DEG C, and the amplitude that viscosity reduces becomes smaller.Tea seed powder ratio of viscosities is vertical
White liquid detergent is low, and the stability of viscosity is relatively poor, but this has no effect on its dirt-removing power, and at normal temperatures, tea seed powder is washed clean
The viscosity of product is more moderate.Product is brown, uniform free from admixture, do not lump, free from extraneous odour, has camellia smell.
（3）Conclusion
Using petroleum ether as extraction solvent, it is to carry to remove oil tea to squeeze the optimum process condition of grouts Residual oil by extraction
Take temperature 50 C, solid-liquid ratio 1：5（m：V）, extraction time 3h, with this condition oil tea squeezing grouts grease removal efficiency be
98.22%, the residual oil content in grouts is only 1.77%（<2.0%）.
Under the conditions of 70 DEG C of drying temperature, time 3h, saponin content is 15.32%（>10%）, moisture 6.88%（<
8%）.
Cross 60 mesh sieve（Granularity 0.250mm）Tea seed powder detergency effect it is preferable, viscosity, stability are than vertical
White product is good and smaller to human skin irritation.Final brown, the uniform free from admixture of product does not lump, free from extraneous odour, has
Camellia smell.
Claims (4)
1. a kind of tea seed cleanser, it is characterised in that it is prepared by following technique：
1）Raw material selects：Select the cake of camellia oleifera seeds after squeezing for raw material；
2）Pretreatment of raw material：The impurity in cake of camellia oleifera seeds is removed, drying to constant weight through 50 DEG C, smashes it through 40 mesh and sieves, 50-60 DEG C
It is dry to be less than 3% to moisture, obtain cake of camellia oleifera seeds powder；
3）Extract de-oiling：Cake of camellia oleifera seeds powder is weighed, is placed in Soxhlet extractor, using petroleum ether as solvent, in Extracting temperature 50
DEG C, solid-liquid ratio 1：5（M：V）Under the conditions of extract 3h；Then it is filtered at vacuum degree 0.06-0.08MPa, retains filter residue；
4）Filter residue and drying：Filter residue is placed in baking oven dry 2-4 h under the conditions of 70-90 DEG C；
5）Filter residue crushes：Filter residue after drying is smashed it through into 60 mesh sieve again, obtains tea seed cleanser；
6）Packaging：Obtain finished product.
2. a kind of tea seed cleanser according to claim 1, it is characterised in that step 4）Middle filter residue and drying condition is：70
DEG C dry 3h.
3. a kind of preparation process of tea seed cleanser, it is characterised in that it mainly includes the following steps：
1）Raw material selects：Select the cake of camellia oleifera seeds after squeezing for raw material；
2）Pretreatment of raw material：The impurity in cake of camellia oleifera seeds is removed, drying to constant weight through 50 DEG C, smashes it through 40 mesh and sieves, 50-60 DEG C
It is dry to be less than 3% to moisture, obtain cake of camellia oleifera seeds powder；
3）Extract de-oiling：Cake of camellia oleifera seeds powder is weighed, is placed in Soxhlet extractor, using petroleum ether as solvent, in Extracting temperature 50
DEG C, solid-liquid ratio 1：5（M：V）Under the conditions of extract 3h；Then it is filtered at vacuum degree 0.06-0.08MPa, retains filter residue；
4）Filter residue and drying：Filter residue is placed in baking oven dry 3h under the conditions of 70 DEG C；
5）Filter residue crushes：Filter residue after drying is smashed it through into 60 mesh sieve again, obtains tea seed cleanser；
6）Packaging：Obtain finished product.
4. a kind of application of the tea seed cleanser according to claim 1 or 2 on cleaning clothing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610020051.XA CN105670815B (en) | 2016-01-13 | 2016-01-13 | A kind of tea seed cleanser and its preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610020051.XA CN105670815B (en) | 2016-01-13 | 2016-01-13 | A kind of tea seed cleanser and its preparation process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105670815A CN105670815A (en) | 2016-06-15 |
| CN105670815B true CN105670815B (en) | 2018-08-14 |
Family
ID=56300298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610020051.XA Expired - Fee Related CN105670815B (en) | 2016-01-13 | 2016-01-13 | A kind of tea seed cleanser and its preparation process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105670815B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190609A (en) * | 2016-07-05 | 2016-12-07 | 武汉轻工大学 | The preparation method of high active ingredient tea cake powder detergent and tea cake powder detergent |
| CN107043658A (en) * | 2017-05-15 | 2017-08-15 | 湖南农业大学 | A kind of evaluation method of duck's egg cleaning agent decontamination bacteria-eliminating efficacy |
| CN110003999B (en) * | 2019-03-25 | 2021-11-05 | 苏州优养健康科技有限公司 | Camellia seed cleaning powder and preparation process thereof |
| CN111304662A (en) * | 2020-04-10 | 2020-06-19 | 湖南淳湘农林科技有限公司 | Preparation method of tea seed cake cleaning agent |
| CN112076878A (en) * | 2020-09-01 | 2020-12-15 | 湖南杨家将茶油股份有限公司 | Method for making tea seed cake food washing product |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063306A (en) * | 1991-10-31 | 1992-08-05 | 中国科学院广州化学研究所 | Withering tea powder detergent |
| US7977290B1 (en) * | 2008-06-05 | 2011-07-12 | Jeffrey Alan Deane | Body cleansing composition |
| CN102260316A (en) * | 2011-05-23 | 2011-11-30 | 井冈山茶油有限公司 | Method for purifying tea saponin from oil tea seed cake pulp |
| CN103232902A (en) * | 2013-04-25 | 2013-08-07 | 覃永良 | Camellia saponin detergent powder for removing greasy dirt of natural plants |
-
2016
- 2016-01-13 CN CN201610020051.XA patent/CN105670815B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063306A (en) * | 1991-10-31 | 1992-08-05 | 中国科学院广州化学研究所 | Withering tea powder detergent |
| US7977290B1 (en) * | 2008-06-05 | 2011-07-12 | Jeffrey Alan Deane | Body cleansing composition |
| CN102260316A (en) * | 2011-05-23 | 2011-11-30 | 井冈山茶油有限公司 | Method for purifying tea saponin from oil tea seed cake pulp |
| CN103232902A (en) * | 2013-04-25 | 2013-08-07 | 覃永良 | Camellia saponin detergent powder for removing greasy dirt of natural plants |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105670815A (en) | 2016-06-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105670815B (en) | A kind of tea seed cleanser and its preparation process | |
| CN103045356B (en) | Production method for linseed oil | |
| CN107115242A (en) | A kind of maca is combined the preparation method of buckwheat starch moisturizing lotion | |
| Termrittikul et al. | The application of ohmic heating for inulin extraction from the wet-milled and dry-milled powders of Jerusalem artichoke (Helianthus tuberosus L.) tuber | |
| CN109105822A (en) | A kind of processing method of konjaku powder | |
| CN103833866B (en) | A kind of method extracting grifolan based on ultrasonic wave-vacuum impregnation assist efficient | |
| CN109985097A (en) | A kind of preparation method of Compound Jinyinhua Granules | |
| CN106866840A (en) | A kind of method of pectin in surfactant synergy microwave extraction passion fruit skin | |
| CN102172364A (en) | Method for extracting general flavone from peas in ultrasound-assisted way | |
| CN109432302A (en) | A kind of extracting method of dendrobium candidum phenol | |
| CN105968080A (en) | Method for extracting anthocyanidin from black chokeberries | |
| CN102276455B (en) | Method for extracting effective ingredients from dry cinnamomum burmannii fruits | |
| CN103074153A (en) | Method for leaching vegetable oil by vegetable oil materials through protease enzymolysis | |
| CN116103083A (en) | Preparation method of zanthoxylum oil with low peroxide value | |
| CN102675912B (en) | Method for preparing purple sweet potato pigment | |
| CN110003999B (en) | Camellia seed cleaning powder and preparation process thereof | |
| CN111592578B (en) | Process for extracting tea saponin from camellia sinensis dregs and application of tea saponin in amino acid facial soap | |
| CN109288734B (en) | Washing-free seaweed oil makeup removing cream and preparation method thereof | |
| CN102845587A (en) | Extrusion puffing and ultramicro crushing combined isolated soybean protein production method | |
| Krishnamurti et al. | Preparation, purification and composition of pectins from Indian fruits and vegetables | |
| CN112063458A (en) | Method for extracting cinnamon essential oil by using eutectic solvent | |
| CN105582132A (en) | Preparation method and application of liquorice root formulation granules | |
| CN107955728B (en) | Edible detergent containing natural plant saponin component and preparation method thereof | |
| Tabibian et al. | Optimization of microwave assisted acid extraction and characterization of pectin from saffron flower waste (Crocus sativus L.) | |
| CN104356252A (en) | Technological method for simultaneously preparing basella rubra vegetable gelatin and basella rubra sodium copper chlorophyllin from basella rubra |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180814 Termination date: 20210113 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |