CN105670439A - Interior wall latex paint and preparation method thereof - Google Patents
Interior wall latex paint and preparation method thereof Download PDFInfo
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- CN105670439A CN105670439A CN201610185616.XA CN201610185616A CN105670439A CN 105670439 A CN105670439 A CN 105670439A CN 201610185616 A CN201610185616 A CN 201610185616A CN 105670439 A CN105670439 A CN 105670439A
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- latex paint
- wall latex
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- interiro wall
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an interior wall latex paint and a preparation method thereof and belongs to the technical field of building materials. The interior wall latex paint comprises 15-40 parts of pure acrylic emulsion, 25-50 parts of nano talcum powder, 15-40 parts of nano silica powder, 5-15 parts of heavy calcium carbonate, 0.5-3 parts of cobalt-modified zinc phosphate, 0.8-10 parts of carboxyl linear polyester resin, 0.1-2 parts of ammonium metavanadate, 0.2-1.5 parts of modified organic silicon resin, 0.8-3 parts of a polycarboxylate, 0.1-2 parts of polycarboxylate essential oil, 2-8 parts of tarragon, 0.5-6 parts of Herba Lysimachiae Capillipis, 5-12 parts of Herba seu Radix Polygoni, and 15-40 parts of water. In the invention, the matched use of the cobalt-modified zinc phosphate and the carboxyl linear polyester resin imparts excellent cracking resistance to the interior wall latex paint; the matched use of the tarragon, the Herba Lysimachiae Capillipis and the Herba seu Radix Polygoni imparts good antibacterial and mold-proof effects to the interior wall latex.
Description
Technical field
The present invention relates to building material technical field, particularly to a kind of interiro wall latex paint and preparation method thereof.
Background technology
Emulsion paint is being commonly called as of latex paint, is born in nineteen seventies the next period, be representative with acrylate copolymer emulsion a big class synthetic resin emulsion coating. Emulsion paint is water-dispersible paint, and it is with synthetic resin emulsion for base material, and filler adds the coating that various auxiliary agent is refined after grinding distribution.
Emulsion paint has possessed the many merits different from conventional wall coating materials, as be prone to brushing, dry rapidly, paint film is water-fast, scrub resistance is good.
In China, people are base material synthetic resin emulsion traditionally, with water for disperse medium, add pigment, filler (also known as extender pigment) and auxiliary agent, through the coating that certain technical process is made, are called emulsion paint, are also latex paint.
Along with the development of building industry, the range of application of interiro wall latex paint is increasingly wider, and kind gets more and more, and performance is more and more superior. But still there is problem easy to crack in interiro wall latex paint of the prior art. Problem easy to crack after interiro wall latex paint is dry, is not addressed so far.
It addition, in prior art, interiro wall latex paint metope is easily mouldy after making moist, and affects attractive in appearance, and affects the healthy of people.
Summary of the invention
In order to make up the deficiencies in the prior art, the invention provides that a kind of anti-cracking performance is superior and the interiro wall latex paint with antibacterial and mouldproof effect and preparation method thereof.
The technical scheme is that
A kind of interiro wall latex paint, including pure-acrylic emulsion, nanomete talc powder, nano-silica powder, ground calcium carbonate, cobalt improved zinc phosphate, carboxyl linear polyester resin, ammonium metavanadate, modified organic silicone resin, polycarboxylate, osmanthus essential oil, Tarragon, Herba lysimachiae capillipedis, Herba Polygoni gracilis and water.
Preferably, described interiro wall latex paint, according to parts by weight meter, including 15-40 part pure-acrylic emulsion, 25-50 part nanomete talc powder, 15-40 part nano-silica powder, 5-15 part ground calcium carbonate, zinc phosphate that 0.5-3 part is cobalt improved, 0.8-10 part carboxyl linear polyester resin, 0.1-2 part ammonium metavanadate, 0.2-1.5 part modified organic silicone resin, 0.8-3 part polycarboxylate, 0.1-2 part osmanthus essential oil, 2-8 part Tarragon, 0.5-6 part Herba lysimachiae capillipedis, 5-12 part Herba Polygoni gracilis, 15-40 part water.
Preferably, described interiro wall latex paint, according to parts by weight meter, including 20-30 part pure-acrylic emulsion, 30-42 part nanomete talc powder, 20-30 part nano-silica powder, 8-12 part ground calcium carbonate, zinc phosphate that 0.8-2 part is cobalt improved, 1.5-5 part carboxyl linear polyester resin, 0.5-1 part ammonium metavanadate, 0.5-1 part modified organic silicone resin, 1.2-2 part polycarboxylate, 0.5-1 part osmanthus essential oil, 3-6 part Tarragon, 1-4 part Herba lysimachiae capillipedis, 6-10 part Herba Polygoni gracilis, 20-30 part water.
Further, described interiro wall latex paint, according to parts by weight meter, including 25 parts of pure-acrylic emulsions, 36 parts of nanomete talc powders, 25 parts of nano-silica powders, 10 parts of ground calcium carbonate, zinc phosphate 1 part cobalt improved, 3 parts of carboxyl linear polyester resins, 0.8 part of ammonium metavanadate, 0.8 part of modified organic silicone resin, 1.6 parts of polycarboxylates, 0.8 part of osmanthus essential oil, 5 parts of Tarragons, 3 parts of Herba lysimachiae capillipedis, 8 parts of Herba Polygoni gracilis, 30 parts of water.
The preparation method of described interiro wall latex paint, including step:
1) take Tarragon, Herba lysimachiae capillipedis, Herba Polygoni gracilis, pulverize, and add soak by water lixiviate, filter medicinal residues and obtain Chinese medicine infusion;
2) pure-acrylic emulsion, nanomete talc powder, nano-silica powder, ground calcium carbonate, cobalt improved zinc phosphate, carboxyl linear polyester resin, ammonium metavanadate, modified organic silicone resin, polycarboxylate, osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with deionized water, dispersed, obtain interiro wall latex paint finished product.
Preferably, in step 1), boiling water decocts lixiviate, and extraction time is 50-80min.
In the present invention:
Nanomete talc powder and nano-silica powder are as body constitution filler.
Pure-acrylic emulsion is as film former.
The effect that ground calcium carbonate plays and prevents sedimentation, easily dispersion, glossiness is good.
Modified organic silicone resin is as defoamer.
Polycarboxylate is as dispersant.
Cobalt improved zinc phosphate and carboxyl linear polyester resin with the use of, make the emulsion paint of the present invention have extraordinary anti-cracking performance; Wherein, cobalt improved zinc phosphate plays and helps peptizaiton, makes each component disperse evenly; And carboxyl linear polyester resin adds the elasticity of emulsion paint, after emulsion paint is dry, flexible, not easy to crack.
Ammonium metavanadate is as drier, and the emulsion paint making the present invention is quick-dry type emulsion paint; Ammonium metavanadate also serves as the cosolvent of cobalt improved zinc phosphate simultaneously.
Osmanthus essential oil gives the taste of the emulsion paint delicate fragrance of the present invention.
Tarragon, staphylococcus aureus, diphtheria corynebacterium, anthrax bacillus, Bacillus typhi, Pseudomonas aeruginosa, escherichia coli, bacillus subtilis, meningococcus etc. is inhibited; Herba lysimachiae capillipedis, has the effect of antiviral, and water decoction infected by influenza first 3 type, B-mode, the third type and parainfluenza I type celestial platform strain produce inhibitory action; Herba Polygoni gracilis, staphylococcus aureus, group B streptococcus, diphtheria corynebacterium, anthrax bacillus, Bacillus typhi, dysentery bacterium, Pseudomonas aeruginosa, escherichia coli, Bacillus proteus, bacillus typhi murium, bacillus subtilis, wax-shaped bacillus and eight folded bacillus etc. are had stronger antibacterial action by herb decoct. Empirical tests, Tarragon, Herba lysimachiae capillipedis, Herba Polygoni gracilis three with the use of, there is the effect of Synergistic, three is with the use of using sterilizing scope wide than single dose and the lethality of antibacterial etc. being strengthened.
The invention have the benefit that
In the present invention, cobalt improved zinc phosphate is fabulous with the use of the interiro wall latex paint anti-cracking performance making the present invention with carboxyl linear polyester resin; And Tarragon, Herba lysimachiae capillipedis, Herba Polygoni gracilis three with the use of the interiro wall latex paint making the present invention, there is extraordinary antibacterial and mouldproof effect.
Present invention process is simple, and properties of product are superior, and solves two hang-ups that interiro wall latex paint exists.
Detailed description of the invention
Embodiment 1
A kind of interiro wall latex paint, including 35kg pure-acrylic emulsion, 45kg nanomete talc powder, 35kg nano-silica powder, 12kg ground calcium carbonate, zinc phosphate cobalt improved for 3kg, 9kg carboxyl linear polyester resin, 2kg ammonium metavanadate, 1.5kg modified organic silicone resin, 3kg polycarboxylate, 2kg osmanthus essential oil, 8kg Tarragon, 6kg Herba lysimachiae capillipedis, 12kg Herba Polygoni gracilis, 40kg water.
The preparation method of described interiro wall latex paint, including step:
1) take 8kg Tarragon, 6kg Herba lysimachiae capillipedis, 12kg Herba Polygoni gracilis, pulverize, and add 50kg water, boil, decoct lixiviate 50-80min, be 25kg to discharge reduction; Filter medicinal residues and obtain Chinese medicine infusion;
2) 35kg pure-acrylic emulsion, 45kg nanomete talc powder, 35kg nano-silica powder, 12kg ground calcium carbonate, zinc phosphate cobalt improved for 3kg, 9kg carboxyl linear polyester resin, 2kg ammonium metavanadate, 1.5kg modified organic silicone resin, 3kg polycarboxylate, 2kg osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with 15kg deionized water, dispersed, obtain interiro wall latex paint finished product.
Embodiment 2
A kind of interiro wall latex paint, including 18kg pure-acrylic emulsion, 28kg nanomete talc powder, 18kg nano-silica powder, 6kg ground calcium carbonate, zinc phosphate cobalt improved for 0.9kg, 0.9kg carboxyl linear polyester resin, 0.3kg ammonium metavanadate, 0.4kg modified organic silicone resin, 0.9kg polycarboxylate, 0.2kg osmanthus essential oil, 3kg Tarragon, 1kg Herba lysimachiae capillipedis, 6kg Herba Polygoni gracilis, 20kg water.
The preparation method of described interiro wall latex paint, including step:
1) take 3kg Tarragon, 1kg Herba lysimachiae capillipedis, 6kg Herba Polygoni gracilis, pulverize, and add 30kg water, boil, decoct lixiviate 50-80min and be reduced to 10kg to water, filter medicinal residues and obtain Chinese medicine infusion;
2) 18kg pure-acrylic emulsion, 28kg nanomete talc powder, 18kg nano-silica powder, 6kg ground calcium carbonate, zinc phosphate cobalt improved for 0.9kg, 0.9kg carboxyl linear polyester resin, 0.3kg ammonium metavanadate, 0.4kg modified organic silicone resin, 0.9kg polycarboxylate, 0.2kg osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with 10kg deionized water, dispersed, obtain interiro wall latex paint finished product.
Embodiment 3
A kind of interiro wall latex paint, including 30kg pure-acrylic emulsion, 42kg nanomete talc powder, 30kg nano-silica powder, 12kg ground calcium carbonate, zinc phosphate cobalt improved for 2kg, 5kg carboxyl linear polyester resin, 1kg ammonium metavanadate, 1kg modified organic silicone resin, 2kg polycarboxylate, 1kg osmanthus essential oil, 6kg Tarragon, 4kg Herba lysimachiae capillipedis, 10kg Herba Polygoni gracilis, 30kg water.
The preparation method of described interiro wall latex paint, including step:
1) take 6kg Tarragon, 4kg Herba lysimachiae capillipedis, 10kg Herba Polygoni gracilis, pulverize, and add 60kg water, boil, decoct lixiviate 50-80min and be reduced to 20kg to water, filter medicinal residues and obtain Chinese medicine infusion;
2) 30kg pure-acrylic emulsion, 42kg nanomete talc powder, 30kg nano-silica powder, 12kg ground calcium carbonate, zinc phosphate cobalt improved for 2kg, 5kg carboxyl linear polyester resin, 1kg ammonium metavanadate, 1kg modified organic silicone resin, 2kg polycarboxylate, 1kg osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with 10kg deionized water, dispersed, obtain interiro wall latex paint finished product.
Embodiment 4
A kind of interiro wall latex paint, including 20kg pure-acrylic emulsion, 30kg nanomete talc powder, 20kg nano-silica powder, 8kg ground calcium carbonate, zinc phosphate cobalt improved for 0.8kg, 1.5kg carboxyl linear polyester resin, 0.5kg ammonium metavanadate, 0.5kg modified organic silicone resin, 1.2kg polycarboxylate, 0.5kg osmanthus essential oil, 3kg Tarragon, 1kg Herba lysimachiae capillipedis, 6kg Herba Polygoni gracilis, 25kg water.
The preparation method of described interiro wall latex paint, including step:
1) take 3kg Tarragon, 1kg Herba lysimachiae capillipedis, 6kg Herba Polygoni gracilis, pulverize, and add 30kg water, boil, decoct lixiviate 50-80min and be reduced to 10kg to water, filter medicinal residues and obtain Chinese medicine infusion;
2) 20kg pure-acrylic emulsion, 30kg nanomete talc powder, 20kg nano-silica powder, 8kg ground calcium carbonate, zinc phosphate cobalt improved for 0.8kg, 1.5kg carboxyl linear polyester resin, 0.5kg ammonium metavanadate, 0.5kg modified organic silicone resin, 1.2kg polycarboxylate, 0.5kg osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with 15kg deionized water, dispersed, obtain interiro wall latex paint finished product; Wherein, the water in Chinese medicine infusion is 15-40kg with the quality summation of deionized water.
Embodiment 5
A kind of interiro wall latex paint, including 22kg pure-acrylic emulsion, 35kg nanomete talc powder, 28kg nano-silica powder, 13kg ground calcium carbonate, zinc phosphate cobalt improved for 2kg, 7kg carboxyl linear polyester resin, 1.6kg ammonium metavanadate, 1.1kg modified organic silicone resin, 1.3kg polycarboxylate, 1.8kg osmanthus essential oil, 7kg Tarragon, 2kg Herba lysimachiae capillipedis, 8kg Herba Polygoni gracilis, 32kg water.
The preparation method of described interiro wall latex paint, including step:
1) take 7kg Tarragon, 2kg Herba lysimachiae capillipedis, 8kg Herba Polygoni gracilis, pulverize, and add 40kg water, boil, decoct lixiviate 50-80min and be reduced to 10kg to water, filter medicinal residues and obtain Chinese medicine infusion;
2) 22kg pure-acrylic emulsion, 35kg nanomete talc powder, 28kg nano-silica powder, 13kg ground calcium carbonate, zinc phosphate cobalt improved for 2kg, 7kg carboxyl linear polyester resin, 1.6kg ammonium metavanadate, 1.1kg modified organic silicone resin, 1.3kg polycarboxylate, 1.8kg osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with 22kg deionized water, dispersed, obtain interiro wall latex paint finished product.
Embodiment 6
A kind of interiro wall latex paint, including including 25kg pure-acrylic emulsion, 36kg nanomete talc powder, 25kg nano-silica powder, 10kg ground calcium carbonate, zinc phosphate cobalt improved for 1kg, 3kg carboxyl linear polyester resin, 0.8kg ammonium metavanadate, 0.8kg modified organic silicone resin, 1.6kg polycarboxylate, 0.8kg osmanthus essential oil, 5kg Tarragon, 3kg Herba lysimachiae capillipedis, 8kg Herba Polygoni gracilis, 30kg water.
The preparation method of described interiro wall latex paint, including step:
1) take 5kg Tarragon, 3kg Herba lysimachiae capillipedis, 8kg Herba Polygoni gracilis, pulverize, and add 50kg water, boil, decoct lixiviate 50-80min and be reduced to 16kg to water, filter medicinal residues and obtain Chinese medicine infusion;
2) 25kg pure-acrylic emulsion, 36kg nanomete talc powder, 25kg nano-silica powder, 10kg ground calcium carbonate, zinc phosphate cobalt improved for 1kg, 3kg carboxyl linear polyester resin, 0.8kg ammonium metavanadate, 0.8kg modified organic silicone resin, 1.6kg polycarboxylate, 0.8kg osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with 14kg deionized water, dispersed, obtain interiro wall latex paint finished product.
Comparative example 1
Compared with embodiment 6, it does not have cobalt improved zinc phosphate and carboxyl linear polyester resin, all the other are identical.
Comparative example 2
Compared with embodiment 6, it does not have Tarragon, Herba lysimachiae capillipedis and Herba Polygoni gracilis, all the other are identical.
Through overtesting:
, namely there is cracking situation after complete a year and a half of constructing in the interiro wall latex paint of comparative example 1; And embodiment 6 gained interiro wall latex paint, have not yet to see cracking after constructing complete 3 years.Illustrate that the interiro wall latex paint anti-cracking performance of the present invention is fabulous.
The interiro wall latex paint of comparative example 2, after construction, aims at certain block metope spraying water vapor, and water spray just finds black mildew the later moon; And embodiment 6 gained interiro wall latex paint, after construction, aim at certain block metope spraying water vapor, spray water latter 2 months and have no any mildew.
Claims (6)
1. an interiro wall latex paint, it is characterised in that: include pure-acrylic emulsion, nanomete talc powder, nano-silica powder, ground calcium carbonate, cobalt improved zinc phosphate, carboxyl linear polyester resin, ammonium metavanadate, modified organic silicone resin, polycarboxylate, osmanthus essential oil, Tarragon, Herba lysimachiae capillipedis, Herba Polygoni gracilis and water.
2. interiro wall latex paint as claimed in claim 1, it is characterized in that: according to parts by weight meter, including 15-40 part pure-acrylic emulsion, 25-50 part nanomete talc powder, 15-40 part nano-silica powder, 5-15 part ground calcium carbonate, zinc phosphate that 0.5-3 part is cobalt improved, 0.8-10 part carboxyl linear polyester resin, 0.1-2 part ammonium metavanadate, 0.2-1.5 part modified organic silicone resin, 0.8-3 part polycarboxylate, 0.1-2 part osmanthus essential oil, 2-8 part Tarragon, 0.5-6 part Herba lysimachiae capillipedis, 5-12 part Herba Polygoni gracilis, 15-40 part water.
3. interiro wall latex paint as claimed in claim 1 or 2, it is characterized in that: according to parts by weight meter, including 20-30 part pure-acrylic emulsion, 30-42 part nanomete talc powder, 20-30 part nano-silica powder, 8-12 part ground calcium carbonate, zinc phosphate that 0.8-2 part is cobalt improved, 1.5-5 part carboxyl linear polyester resin, 0.5-1 part ammonium metavanadate, 0.5-1 part modified organic silicone resin, 1.2-2 part polycarboxylate, 0.5-1 part osmanthus essential oil, 3-6 part Tarragon, 1-4 part Herba lysimachiae capillipedis, 6-10 part Herba Polygoni gracilis, 20-30 part water.
4. interiro wall latex paint as claimed in claim 3, it is characterized in that: according to parts by weight meter, including 25 parts of pure-acrylic emulsions, 36 parts of nanomete talc powders, 25 parts of nano-silica powders, 10 parts of ground calcium carbonate, zinc phosphate 1 part cobalt improved, 3 parts of carboxyl linear polyester resins, 0.8 part of ammonium metavanadate, 0.8 part of modified organic silicone resin, 1.6 parts of polycarboxylates, 0.8 part of osmanthus essential oil, 5 parts of Tarragons, 3 parts of Herba lysimachiae capillipedis, 8 parts of Herba Polygoni gracilis, 30 parts of water.
5. the preparation method of interiro wall latex paint as claimed in claim 1, it is characterised in that include step:
1) take Tarragon, Herba lysimachiae capillipedis, Herba Polygoni gracilis, pulverize, and add soak by water lixiviate, filter medicinal residues and obtain Chinese medicine infusion;
2) pure-acrylic emulsion, nanomete talc powder, nano-silica powder, ground calcium carbonate, cobalt improved zinc phosphate, carboxyl linear polyester resin, ammonium metavanadate, modified organic silicone resin, polycarboxylate, osmanthus essential oil, step 1) gained Chinese medicine infusion are mixed with deionized water, dispersed, obtain interiro wall latex paint finished product.
6. the preparation method of interiro wall latex paint as claimed in claim 5, it is characterised in that: in step 1), boiling water decocts lixiviate, and extraction time is 50-80min.
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| CN201610185616.XA CN105670439A (en) | 2016-03-29 | 2016-03-29 | Interior wall latex paint and preparation method thereof |
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| CN201610185616.XA CN105670439A (en) | 2016-03-29 | 2016-03-29 | Interior wall latex paint and preparation method thereof |
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| CN106221338A (en) * | 2016-07-29 | 2016-12-14 | 首钢水城钢铁(集团)赛德建设有限公司 | A kind of interiro wall latex paint and preparation method thereof |
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| CN106221338A (en) * | 2016-07-29 | 2016-12-14 | 首钢水城钢铁(集团)赛德建设有限公司 | A kind of interiro wall latex paint and preparation method thereof |
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Application publication date: 20160615 |