CN105648844B - A kind of high abrasion printing dipping paper and preparation method thereof - Google Patents
A kind of high abrasion printing dipping paper and preparation method thereof Download PDFInfo
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- CN105648844B CN105648844B CN201511014370.1A CN201511014370A CN105648844B CN 105648844 B CN105648844 B CN 105648844B CN 201511014370 A CN201511014370 A CN 201511014370A CN 105648844 B CN105648844 B CN 105648844B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
- C08G12/32—Melamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/26—Aminoplasts
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/12—Coating on the layer surface on paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paper (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to dipping paper technical field, a kind of specifically related to high abrasion printing dipping paper and preparation method thereof, including original paper layer, fit in the simulated grain layer of original paper layer upper surface, fit in the wearing layer of simulated grain layer upper surface and fit in the wear-resisting adhesive film of wearing layer upper surface.The high abrasion printing dipping paper of the present invention on original paper layer by setting wear-resisting adhesive film and wearing layer so that the dipping paper manufactured has good anti-wear performance, and simple in construction, low cost is practical.
Description
Technical field
The present invention relates to dipping paper technical field, and in particular to a kind of high abrasion printing dipping paper and preparation method thereof.
Background technology
Dipping paper is mixed by non-woven fabrics wood pulp with PE and string, with superpower absorbability and antilysis energy
In power, the veneer for being widely used in cabinet, wardrobe and composite floor board.
Dipping paper paper roll in the past using non-woven fabrics wood pulp with PE and string due to being mixed, and abrasion resistant effect is not
It is good.
Therefore, prior art is needed to be improved and improved.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of printing of high abrasion
Paper is impregnated, the dipping paper has good anti-wear performance, and simple in construction, low cost is practical.
Another object of the present invention is to provide a kind of preparation method of high abrasion printing dipping paper, the preparation method technique
Simply, convenient operation and control, steady quality, production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of high abrasion printing dipping paper, including original paper layer, laminating
In original paper layer upper surface simulated grain layer, fit in simulated grain layer upper surface wearing layer and fit on wearing layer
The wear-resisting adhesive film on surface.
The high abrasion printing dipping paper of the present invention on original paper layer by setting wear-resisting adhesive film and wearing layer so that manufacture
Dipping paper out has good anti-wear performance, and simple in construction, low cost is practical.
It is preferred that, the simulated grain layer is made by water-based ink through printing.The present invention is by using water-based ink through print
The obtained simulated grain layer of brush, its printing effect is good so that the dipping paper manufactured has good anti-wear performance.
It is preferred that, the water-based ink is made up of the raw material of following percentage by weight：Water-base resin 3%-8%, dispersant
0.15%-0.4%, wetting agent 0.15%-0.4%, pigment 8%-13%, other auxiliary agent 4%-12%, water surplus.
The water-based ink of the present invention strictly controls the weight proportion of each raw material by using above-mentioned raw materials, and it prints effect
It is really good so that the dipping paper manufactured has good anti-wear performance.
It is preferred that, the water-base resin is acrylic resin modified with weight by water soluble acrylic resin and maleic rosin
Compare 2-4:The mixture of 1 composition.
The water-based ink of the present invention using water soluble acrylic resin and maleic rosin are acrylic resin modified by that will make
For water-base resin compounding use, and it is 2-4 to control its weight ratio:1, obtained water-based ink printing effect is good so that produce
The dipping paper come has good anti-wear performance.
The dispersant is to compare 1.8-2.6 by calgon, polyacrylamide and lauryl sodium sulfate with weight:
0.8-1.2:The mixture of 1 composition.
The water-based ink of the present invention is by using calgon, polyacrylamide and lauryl sodium sulfate as scattered
Agent compounding use, and it is 1.8-2.6 to control its weight ratio:0.8-1.2:1, its dispersion effect is good, obtained water-based ink printing
Effect is good so that the dipping paper manufactured has good anti-wear performance.
The wetting agent is by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block
Copolymer compares 1 with weight:0.5-1.5:The mixture of 1.4-2.2 compositions.
The water-based ink of the present invention is poly- by using polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene
Oxypropylene block copolymer is as wetting agent compounding use, and it is 1 to control its weight ratio:0.5-1.5:1.4-2.2, it soaks effect
Really good, obtained water-based ink printing effect is good so that the dipping paper manufactured has good anti-wear performance.
The pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, dark green, carbon black, permanent bordeaux and benzidine yellow.
The water-based ink of the present invention is by using above-mentioned pigment, and its Color is good, obtained water-based ink printing effect
It is good so that the dipping paper manufactured has good anti-wear performance.
Other auxiliary agents are to compare 0.1-0.5 by levelling agent, defoamer and stabilizer with weight：0.4-0.8:1 composition
Mixture.
The water-based ink of the present invention is used by using levelling agent, defoamer and stabilizer as other additive compounds, and
It is 0.1-0.5 to control its weight ratio：0.4-0.8:1, obtained water-based ink printing effect is good so that the dipping paper manufactured
With good anti-wear performance.
Levelling agent, defoamer and the stabilizer that the present invention is used are levelling agent commonly used in the art, defoamer and stably
Agent, can be obtained by commercially available purchase, be not belonging to protection scope of the present invention.
It is preferred that, the raw material of the wearing layer is aluminum oxide.The present invention by using raw material of the aluminum oxide as wearing layer,
Its anti-wear performance is good.
It is preferred that, the raw material of the wear-resisting adhesive film is wear-resisting triamine glue.The present invention is by using wear-resisting triamine glue conduct
The raw material of wear-resisting adhesive film so that the dipping paper manufactured has good anti-wear performance.
It is preferred that, the wear-resisting triamine glue includes the raw material of following parts by weight：3.5-8.5 parts of formaldehyde, melamine 3.5-
8.0 parts, phthalic acid two（2- Octyl Nitrites）1.8-4.2 parts of 0.5-2.5 parts, 0.3-3.2 parts of diethylene glycol (DEG) and water.
The wear-resisting triamine glue of the present invention strictly controls the weight proportion of each raw material by using above-mentioned raw materials, obtained
Wear-resisting triamine glue anti-wear performance is good, good waterproof performance, and chemism is high, and heat endurance is good, boiling water resistance, chemical proofing and electricity
Good insulating.
It is preferred that, the preparation method of the wear-resisting triamine glue comprises the following steps：
（1）Take 3.5-8.5 parts of formaldehyde, 0.5-2.5 parts of phthalic acids two（2- Octyl Nitrites）, 0.3-3.2 portions of diethylene glycol (DEG)s
In 1.8-4.2 parts of water input reactors, uniform stirring to pH value is 9.3-9.5；
（2）3.5-8.0 parts of melamines are added, 89-91 DEG C is heated to, then heats to 90-93 DEG C and be incubated 60-
90min, to water-soluble than being 1:2.5-3.5；
（3）40-45 DEG C is cooled to, to water-soluble than being 1:The wear-resisting triamine glue is made in 1.2-1.8, discharging.
It is preferred that, the proportion of the original paper layer is 70-80g/m2；The proportion of the simulated grain layer is 2-4g/m2；It is described
The proportion of wearing layer is 10-15g/m2；The proportion of the wear-resisting adhesive film is 90-100g/m2。
The preparation method technique of the triamine glue of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, raw
Low cost is produced, can large-scale industrial production.
A kind of preparation method of high abrasion printing dipping paper, comprises the following steps：
A, original paper layer is taken, one layer of water-based ink is printed in the upper surface of original paper layer, simulated grain layer is formed after drying；
B, one layer of aluminum oxide emulsion of upper surface coating in simulated grain layer, wearing layer is formed after drying；
C, one layer of wear-resisting triamine glue of upper surface coating in wearing layer, form wear-resisting adhesive film, high abrasion are made after solidification
Printing dipping paper.
The beneficial effects of the present invention are：The high abrasion printing dipping paper of the present invention on original paper layer by setting wear-resisting glue
Film layer and wearing layer so that the dipping paper manufactured has good anti-wear performance, and simple in construction, low cost is practical.
The preparation method technique of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Can large-scale industrial production.
Brief description of the drawings
Fig. 1 is the partial sectional view of the present invention；
Reference is：1-original paper layer, 2-simulated grain layer, 3-wearing layer, 4-wear-resisting adhesive film.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment and accompanying drawing, 1 couple of present invention makees further
Illustrate, the content that embodiment is referred to not limitation of the invention.
Embodiment 1
See Fig. 1, a kind of high abrasion printing dipping paper, including original paper layer 1, the simulated grain for fitting in the upper surface of original paper layer 1
Layer 2, the wearing layer 3 for fitting in 2 upper surface of simulated grain layer and the wear-resisting adhesive film 4 for fitting in the upper surface of wearing layer 3.
The simulated grain layer 2 is made by water-based ink through printing.
The water-based ink is made up of the raw material of following percentage by weight：Water-base resin 3%, dispersant 0.15%, wetting agent
0.15%th, pigment 8%, other auxiliary agents 4%, water surplus.
The water-base resin is acrylic resin modified with weight ratio 2 by water soluble acrylic resin and maleic rosin:1 group
Into mixture；The dispersant is with weight ratio 1.8 by calgon, polyacrylamide and lauryl sodium sulfate:
0.8:The mixture of 1 composition；The wetting agent is gathered by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene
Oxypropylene block copolymer compares 1 with weight:0.5:The mixture of 1.4 compositions；The pigment is phosphoric acid cobalt violet, phthalocyanine blue, phthalein green grass or young crops
At least one in green, carbon black, permanent bordeaux and benzidine yellow；Other auxiliary agents be by levelling agent, defoamer and stabilizer with
Weight compares 0.1：0.4:The mixture of 1 composition.
The raw material of the wearing layer 3 is aluminum oxide.
The raw material of the wear-resisting adhesive film 4 is wear-resisting triamine glue.
The wear-resisting triamine glue includes the raw material of following parts by weight：3.5 parts of formaldehyde, 3.5 parts of melamine, phthalic acid
Two（2- Octyl Nitrites）1.8 parts of 0.5 part, 0.3 part of diethylene glycol (DEG) and water.
The preparation method of the wear-resisting triamine glue comprises the following steps：
（1）Take 3.5 parts of formaldehyde, 0.5 part of phthalic acid two（2- Octyl Nitrites）, 0.3 portion of diethylene glycol (DEG) and 1.8 parts of water inputs
In reactor, uniform stirring to pH value is 9.3；
（2）3.5 parts of melamines are added, 89 DEG C is heated to, then heats to 90 DEG C and be incubated 60min, are to water-soluble ratio
1:2.5；
（3）40 DEG C are cooled to, to water-soluble than being 1:1.2, the triamine glue is made in discharging.
The proportion of the original paper layer 1 is 70g/m2；The proportion of the simulated grain layer 2 is 2g/m2；The ratio of the wearing layer 3
Weight is 10g/m2；The proportion of the wear-resisting adhesive film 4 is 90g/m2。
A kind of preparation method of high abrasion printing dipping paper, comprises the following steps：
A, original paper layer 1 is taken, one layer of water-based ink is printed in the upper surface of original paper layer 1, simulated grain layer 2 is formed after drying；
B, one layer of aluminum oxide emulsion of upper surface coating in simulated grain layer 2, wearing layer 3 is formed after drying；
C, one layer of wear-resisting triamine glue of upper surface coating in wearing layer 3, form wear-resisting adhesive film 4, are made high resistance to after solidification
Mill printing dipping paper.
Embodiment 2
The difference of the present embodiment and above-described embodiment 1 is：
The water-based ink is made up of the raw material of following percentage by weight：Water-base resin 4%, dispersant 0.2%, wetting agent
0.2%th, pigment 9%, other auxiliary agents 6%, water surplus.
The water-base resin is acrylic resin modified with weight ratio 2.5 by water soluble acrylic resin and maleic rosin:1
The mixture of composition；The dispersant is with weight ratio 2 by calgon, polyacrylamide and lauryl sodium sulfate:
0.9:The mixture of 1 composition；The wetting agent is gathered by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene
Oxypropylene block copolymer compares 1 with weight:0.8:The mixture of 1.6 compositions；The pigment is phosphoric acid cobalt violet, phthalocyanine blue, phthalein green grass or young crops
At least one in green, carbon black, permanent bordeaux and benzidine yellow；Other auxiliary agents be by levelling agent, defoamer and stabilizer with
Weight compares 0.2：0.5:The mixture of 1 composition.
The triamine glue includes the raw material of following parts by weight：5 parts of formaldehyde, 5 parts of melamine, phthalic acid two（2- second
The own ester of base）2.1 parts of 1 part, 1 part of diethylene glycol (DEG) and water.
The preparation method of the triamine glue comprises the following steps：
（1）Take 5 parts of formaldehyde, 1 part of phthalic acid two（2- Octyl Nitrites）, 1 portion of diethylene glycol (DEG) and 2.1 parts of water input reactors
In, uniform stirring to pH value is 9.3-9.5；
（2）5 parts of melamines are added, 90 DEG C is heated to, then heats to 91 DEG C and be incubated 70min, to water-soluble than being 1:
2.8；
（3）41 DEG C are cooled to, to water-soluble than being 1:1.4, the triamine glue is made in discharging.
The proportion of the original paper layer 1 is 72g/m2；The proportion of the simulated grain layer 2 is 2.5g/m2；The wearing layer 3
Proportion is 11g/m2；The proportion of the wear-resisting adhesive film 4 is 92g/m2。
Embodiment 3
The difference of the present embodiment and above-described embodiment 1 is：
The water-based ink is made up of the raw material of following percentage by weight：Water-base resin 5%, dispersant 0.25%, wetting agent
0.25%th, pigment 10%, other auxiliary agents 8%, water surplus.
The water-base resin is acrylic resin modified with weight ratio 3 by water soluble acrylic resin and maleic rosin:1 group
Into mixture；The dispersant is with weight ratio 2.2 by calgon, polyacrylamide and lauryl sodium sulfate:1:1
The mixture of composition；The wetting agent is by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxy third
Alkene block copolymer compares 1 with weight:1:The mixture of 1.8 compositions；The pigment is phosphoric acid cobalt violet, phthalocyanine blue, dark green, charcoal
At least one in black, permanent bordeaux and benzidine yellow；Other auxiliary agents are with weight ratio by levelling agent, defoamer and stabilizer
0.3：0.6:The mixture of 1 composition.
The triamine glue includes the raw material of following parts by weight：6 parts of formaldehyde, 6 parts of melamine, phthalic acid two（2- second
The own ester of base）2.8 parts of 1.5 parts, 1.8 parts of diethylene glycol (DEG) and water.
The preparation method of the triamine glue comprises the following steps：
（1）Take 6 parts of formaldehyde, 1.5 parts of phthalic acids two（2- Octyl Nitrites）, 1.8 portions of diethylene glycol (DEG)s and 2.8 parts of water inputs it is anti-
Answer in kettle, uniform stirring to pH value is 9.4；
（2）6 parts of melamines are added, 90 DEG C is heated to, then heats to 92 DEG C and be incubated 75min, to water-soluble than being 1:
3；
（3）42 DEG C are cooled to, to water-soluble than being 1:1.5, the triamine glue is made in discharging.
The proportion of the original paper layer 1 is 75g/m2；The proportion of the simulated grain layer 2 is 3g/m2；The ratio of the wearing layer 3
Weight is 12g/m2；The proportion of the wear-resisting adhesive film 4 is 95g/m2。
Embodiment 4
The difference of the present embodiment and above-described embodiment 1 is：
The water-based ink is made up of the raw material of following percentage by weight：Water-base resin 7%, dispersant 0.3%, wetting agent
0.3%th, pigment 12%, other auxiliary agents 10%, water surplus.
The water-base resin is acrylic resin modified with weight ratio 3.5 by water soluble acrylic resin and maleic rosin:1
The mixture of composition；The dispersant is with weight ratio 2.4 by calgon, polyacrylamide and lauryl sodium sulfate:
1.1:The mixture of 1 composition；The wetting agent is gathered by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene
Oxypropylene block copolymer compares 1 with weight:1.2:The mixture of 2 compositions；The pigment be phosphoric acid cobalt violet, phthalocyanine blue, dark green,
At least one in carbon black, permanent bordeaux and benzidine yellow；Other auxiliary agents are with weight by levelling agent, defoamer and stabilizer
Than 0.4：0.7:The mixture of 1 composition.
The triamine glue includes the raw material of following parts by weight：7 parts of formaldehyde, 7 parts of melamine, phthalic acid two（2- second
The own ester of base）3.5 parts of 2 parts, 2.5 parts of diethylene glycol (DEG) and water.
The preparation method of the triamine glue comprises the following steps：
（1）Take 7 parts of formaldehyde, 2 parts of phthalic acids two（2- Octyl Nitrites）, 2.5 portions of diethylene glycol (DEG)s and 3.5 parts of water input reactions
In kettle, uniform stirring to pH value is 9.4；
（2）7 parts of melamines are added, 90 DEG C is heated to, then heats to 91 DEG C and be incubated 80min, to water-soluble than being 1:
3.2；
（3）44 DEG C are cooled to, to water-soluble than being 1:1.7, the triamine glue is made in discharging.
The proportion of the original paper layer 1 is 78g/m2；The proportion of the simulated grain layer 2 is 3.5g/m2；The wearing layer 3
Proportion is 1.4g/m2；The proportion of the wear-resisting adhesive film 4 is 98g/m2。
Embodiment 5
The difference of the present embodiment and above-described embodiment 1 is：
The water-based ink is made up of the raw material of following percentage by weight：Water-base resin 8%, dispersant 0.4%, wetting agent
0.4%th, pigment 13%, other auxiliary agents 12%, water surplus.
The water-base resin is acrylic resin modified with weight ratio 4 by water soluble acrylic resin and maleic rosin:1 group
Into mixture；The dispersant is with weight ratio 2.6 by calgon, polyacrylamide and lauryl sodium sulfate:
1.2:The mixture of 1 composition；The wetting agent is gathered by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene
Oxypropylene block copolymer compares 1 with weight:1.5:The mixture of 2.2 compositions；The pigment is phosphoric acid cobalt violet, phthalocyanine blue, phthalein green grass or young crops
At least one in green, carbon black, permanent bordeaux and benzidine yellow；Other auxiliary agents be by levelling agent, defoamer and stabilizer with
Weight compares 0.5：0.8:The mixture of 1 composition.
The triamine glue includes the raw material of following parts by weight：8.5 parts of formaldehyde, 8.0 parts of melamine, phthalic acid two
（2- Octyl Nitrites）4.2 parts of 2.5 parts, 3.2 parts of diethylene glycol (DEG) and water.
The preparation method of the triamine glue comprises the following steps：
（1）Take 8.5 parts of formaldehyde, 2.5 parts of phthalic acids two（2- Octyl Nitrites）, 3.2 portions of diethylene glycol (DEG)s and 4.2 parts of water inputs
In reactor, uniform stirring to pH value is 9.5；
（2）8.0 parts of melamines are added, 91 DEG C is heated to, then heats to 90-93 DEG C and be incubated 90min, to water-soluble ratio
For 1:3.5；
（3）45 DEG C are cooled to, to water-soluble than being 1:1.8, the triamine glue is made in discharging.
The proportion of the original paper layer 1 is 80g/m2；The proportion of the simulated grain layer 2 is 4g/m2；The ratio of the wearing layer 3
Weight is 15g/m2；The proportion of the wear-resisting adhesive film 4 is 100g/m2。
The high abrasion printing dipping paper of the present invention on original paper layer by setting wear-resisting adhesive film and wearing layer so that manufacture
Dipping paper out has good anti-wear performance, and simple in construction, low cost is practical.
The preparation method technique of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Can large-scale industrial production.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (7)
1. a kind of high abrasion printing dipping paper, it is characterised in that：Including original paper layer, fit in the simulated grain of original paper layer upper surface
Layer, the wearing layer for fitting in simulated grain layer upper surface and the wear-resisting adhesive film for fitting in wearing layer upper surface, the printing
Wood grain layer is made by water-based ink through printing, and the water-based ink is made up of the raw material of following percentage by weight：Water-base resin 3%-
8%th, dispersant 0.15%-0.4%, wetting agent 0.15%-0.4%, pigment 8%-13%, other auxiliary agent 4%-12%, water surplus, the water
Property resin is with weight to compare 2-4 by water soluble acrylic resin and maleic rosin are acrylic resin modified:The mixture of 1 composition；
The dispersant is to compare 1.8-2.6 by calgon, polyacrylamide and lauryl sodium sulfate with weight:0.8-1.2:1
The mixture of composition；The wetting agent is by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxy third
Alkene block copolymer compares 1 with weight:0.5-1.5:The mixture of 1.4-2.2 compositions；The pigment be phosphoric acid cobalt violet, phthalocyanine blue,
At least one in dark green, carbon black, permanent bordeaux and benzidine yellow；Other auxiliary agents are by levelling agent, defoamer and stably
Agent compares 0.1-0.5 with weight：0.4-0.8:The mixture of 1 composition.
2. a kind of high abrasion printing dipping paper according to claim 1, it is characterised in that：The raw material of the wearing layer is oxygen
Change aluminium.
3. a kind of high abrasion printing dipping paper according to claim 1, it is characterised in that：The raw material of the wear-resisting adhesive film
For wear-resisting triamine glue.
4. a kind of high abrasion printing dipping paper according to claim 3, it is characterised in that：The wear-resisting triamine glue is included such as
The raw material of lower parts by weight：3.5-8.5 parts of formaldehyde, 3.5-8.0 parts of melamine, phthalic acid two（2- Octyl Nitrites）0.5-
1.8-4.2 parts of 2.5 parts, 0.3-3.2 parts of diethylene glycol (DEG) and water.
5. a kind of high abrasion printing dipping paper according to claim 4, it is characterised in that：The preparation of the wear-resisting triamine glue
Method comprises the following steps：
（1）Take 3.5-8.5 parts of formaldehyde, 0.5-2.5 parts of phthalic acids two（2- Octyl Nitrites）, 0.3-3.2 portions of diethylene glycol (DEG)s and
In 1.8-4.2 parts of water input reactors, uniform stirring to pH value is 9.3-9.5；
（2）3.5-8.0 parts of melamines are added, 89-91 DEG C is heated to, then heats to 90-93 DEG C and be incubated 60-90min, extremely
Water-soluble ratio is 1:2.5-3.5；
（3）40-45 DEG C is cooled to, to water-soluble than being 1:The wear-resisting triamine glue is made in 1.2-1.8, discharging.
6. a kind of high abrasion printing dipping paper according to claim 1, it is characterised in that：The proportion of the original paper layer is
70-80g/m2；The proportion of the simulated grain layer is 2-4g/m2；The proportion of the wearing layer is 10-15g/m2；The wear-resisting glue
The proportion of film layer is 90-100g/m2。
7. a kind of preparation method of high abrasion printing dipping paper as described in claim any one of 1-6, it is characterised in that：Including
Following steps：
A, original paper layer is taken, one layer of water-based ink is printed in the upper surface of original paper layer, simulated grain layer is formed after drying；
B, one layer of aluminum oxide emulsion of upper surface coating in simulated grain layer, wearing layer is formed after drying；
C, one layer of wear-resisting triamine glue of upper surface coating in wearing layer, form wear-resisting adhesive film, high abrasion printing are made after solidification
Impregnate paper.
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| CN107286748A (en) * | 2017-08-31 | 2017-10-24 | 张家港精工包装彩印有限公司 | A kind of wear-resisting printing-ink |
| CN108215255A (en) * | 2017-12-14 | 2018-06-29 | 东莞市亚马电子有限公司 | A kind of cell phone rear cover film and its preparation process |
| CN109551576B (en) * | 2018-12-13 | 2022-01-18 | 柳州市荣森新型材料科技有限公司 | Wear-resistant impregnated bond paper veneer ecological plate and preparation method thereof |
| CN109706783B (en) * | 2018-12-26 | 2021-09-14 | 罗力诚 | High-performance formaldehyde-free wood-grain paper impregnating glue and preparation method thereof |
| CN114059388A (en) * | 2021-11-15 | 2022-02-18 | 杭州中润华源装饰材料有限公司 | Wear-resistant high-color-fastness decorative paper and preparation method thereof |
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| SE504353C2 (en) * | 1995-06-19 | 1997-01-20 | Perstorp Ab | Process for making a decorative thermosetting laminate |
| CN202055113U (en) * | 2011-03-04 | 2011-11-30 | 苏州市建诚装饰材料有限公司 | Abrasion resistant paper impregnated thermosetting resins |
| CN103194121B (en) * | 2013-03-18 | 2015-07-01 | 福建省利得彩环保科技有限公司 | Water-based gravure printing ink for thermal transfer printing |
| CN103613999A (en) * | 2013-11-28 | 2014-03-05 | 张家港威迪森化学有限公司 | Water-based ink |
| CN103911916A (en) * | 2014-03-28 | 2014-07-09 | 苏州市建诚装饰材料有限公司 | Wear-resistant scratch-resistant impregnated paper |
| CN104149151B (en) * | 2014-07-21 | 2016-11-23 | 常州市森尼装饰材料有限公司 | The preparation technology of high abrasion impregnated paper laminated wood floor |
| CN104861778A (en) * | 2015-05-05 | 2015-08-26 | 浙江宜佳新材料有限公司 | Water-based ink for grainy paper printing and preparation method thereof |
| CN105199064B (en) * | 2015-09-25 | 2018-08-24 | 寿光市东宇鸿翔木业有限公司 | A kind of low formaldehyde triamine glue and low formaldehyde triamine glue preparation method |
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Denomination of invention: High-wear-resistance printing impregnated paper and manufacturing method thereof Effective date of registration: 20170919 Granted publication date: 20170718 Pledgee: China Co truction Bank Corp Dongguan branch Pledgor: GUANGDONG FUMEI NEW MATERIAL TECHNOLOGY CO., LTD. Registration number: 2017440000086 |