CN105648844A - High-wear-resistance printing impregnated paper and manufacturing method thereof - Google Patents
High-wear-resistance printing impregnated paper and manufacturing method thereof Download PDFInfo
- Publication number
- CN105648844A CN105648844A CN201511014370.1A CN201511014370A CN105648844A CN 105648844 A CN105648844 A CN 105648844A CN 201511014370 A CN201511014370 A CN 201511014370A CN 105648844 A CN105648844 A CN 105648844A
- Authority
- CN
- China
- Prior art keywords
- layer
- wear
- water
- high abrasion
- resisting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
- C08G12/32—Melamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/26—Aminoplasts
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/12—Coating on the layer surface on paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paper (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to the technical field of impregnated paper, and particularly to high-wear-resistance printing impregnated paper and a manufacturing method thereof. The high-wear-resistance printing impregnated paper comprises a raw paper layer, a wood-grain-printed layer attached to the upper surface of the raw paper layer, a wear-resistant layer attached to the upper surface of the wood-grain-printed layer, and a wear-resistant adhesive film layer attached to the upper surface of the wear-resistant layer. The wear-resistant adhesive film layer and the wear-resistant layer are arranged on the raw paper layer, so the manufactured impregnated paper is excellent in wear resistance and simple in structure. The method is low in cost and high in practicality.
Description
Technical field
The present invention relates to dipping paper technical field, be specifically related to a kind of high abrasion printing dipping paper and preparation method thereof.
Background technology
Dipping paper is mixed with PE and Plant fiber by non-woven fabrics wood pulp, has superpower absorbing power and antilysis ability, is widely used in the veneer of cabinet, wardrobe and composite floor board.
Dipping paper paper roll in the past is owing to adopting non-woven fabrics wood pulp to be mixed with PE and Plant fiber, and abrasion resistant effect is not good.
Therefore, prior art needs to be improved and improves.
Summary of the invention
In order to overcome the shortcoming and defect existed in prior art, it is an object of the invention to provide a kind of high abrasion printing dipping paper, this dipping paper has good anti-wear performance, simple in construction, and cost is low, practical.
Another object of the present invention is to the preparation method providing a kind of high abrasion printing dipping paper, this preparation method technique is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions: a kind of high abrasion printing dipping paper, including original paper layer, fits in the simulated grain layer of original paper layer upper surface, fits in the wearing layer of simulated grain layer upper surface and fit in the wear-resisting adhesive film of wearing layer upper surface.
The high abrasion printing dipping paper of the present invention by arranging wear-resisting adhesive film and wearing layer on original paper layer so that produced dipping paper has good anti-wear performance, simple in construction, and cost is low, practical.
Preferably, described simulated grain layer is prepared through printing by water color ink. The present invention is by adopting water color ink through printing prepared simulated grain layer, and its printing effect is good so that produced dipping paper has good anti-wear performance.
Preferably, described water color ink is made up of the raw material of following percentage by weight: water-base resin 3%-8%, dispersant 0.15%-0.4%, wetting agent 0.15%-0.4%, pigment 8%-13%, other auxiliary agent 4%-12%, water surplus.
The water color ink of the present invention is by adopting above-mentioned raw materials, and strictly controls the weight proportion of each raw material, and its printing effect is good so that produced dipping paper has good anti-wear performance.
Preferably, described water-base resin is acrylic resin modified with the weight ratio 2-4:1 mixture formed by water soluble acrylic resin and maleic rosin.
The water color ink of the present invention will be by adopting water soluble acrylic resin and maleic rosin acrylic resin modified as the composite use of water-base resin, and to control its weight ratio be 2-4:1, the water color ink printing effect prepared is good so that produced dipping paper has good anti-wear performance.
Described dispersant by sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate with the weight ratio 1.8-2.6:0.8-1.2:1 mixture formed.
The water color ink of the present invention is by adopting sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate as the composite use of dispersant, and to control its weight ratio be 1.8-2.6:0.8-1.2:1, its dispersion effect is good, the water color ink printing effect prepared is good so that produced dipping paper has good anti-wear performance.
Described wetting agent by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer with the weight ratio 1:0.5-1.5:1.4-2.2 mixture formed.
The water color ink of the present invention is by adopting polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer as the composite use of wetting agent, and to control its weight ratio be 1:0.5-1.5:1.4-2.2, its wetting effect is good, the water color ink printing effect prepared is good so that produced dipping paper has good anti-wear performance.
Described pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, phthalein viridescent, white carbon black, permanent bordeaux and benzidine yellow.
The water color ink of the present invention is by adopting above-mentioned pigment, and its Color is good, and the water color ink printing effect prepared is good so that produced dipping paper has good anti-wear performance.
Other auxiliary agent described by levelling agent, defoamer and stabilizer with the weight ratio 0.1-0.5:0.4-0.8:1 mixture formed.
The water color ink of the present invention uses as other additive compound by adopting levelling agent, defoamer and stabilizer, and to control its weight ratio be 0.1-0.5:0.4-0.8:1, the water color ink printing effect prepared is good so that produced dipping paper has good anti-wear performance.
Levelling agent that the present invention adopts, defoamer and stabilizer are levelling agent commonly used in the art, defoamer and stabilizer, all can pass through commercially available purchase and obtain, be not belonging to protection scope of the present invention.
Preferably, the raw material of described wearing layer is aluminium oxide. The present invention is by adopting aluminium oxide as the raw material of wearing layer, and its anti-wear performance is good.
Preferably, the raw material of described wear-resisting adhesive film is wear-resisting triamine glue. The present invention is by adopting wear-resisting triamine glue as the raw material of wear-resisting adhesive film so that produced dipping paper has good anti-wear performance.
Preferably, described wear-resisting triamine glue includes the raw material of following weight portion: formaldehyde 3.5-8.5 part, tripolycyanamide 3.5-8.0 part, phthalic acid two (2-Octyl Nitrite) 0.5-2.5 part, diethylene glycol 0.3-3.2 part and water 1.8-4.2 part.
The wear-resisting triamine glue of the present invention is by adopting above-mentioned raw materials, and strictly controls the weight proportion of each raw material, and prepared wear-resisting triamine glue anti-wear performance is good, good waterproof performance, and chemism is high, and Heat stability is good, boiling water resistance, chemical proofing and electrical insulating property are good.
Preferably, the preparation method of described wear-resisting triamine glue comprises the steps:
(1) taking 3.5-8.5 part formaldehyde, 0.5-2.5 part phthalic acid two (2-Octyl Nitrite), 0.3-3.2 part diethylene glycol and 1.8-4.2 part water to put in reactor, uniform stirring to pH value is 9.3-9.5;
(2) adding 3.5-8.0 part tripolycyanamide, heating, to 89-91 DEG C, then heats to 90-93 DEG C and is incubated 60-90min, is 1:2.5-3.5 to water-soluble ratio;
(3) it is cooled to 40-45 DEG C, is 1:1.2-1.8 to water-soluble ratio, discharging, prepare described wear-resisting triamine glue.
Preferably, the proportion of described original paper layer is 70-80g/m2; The proportion of described simulated grain layer is 2-4g/m2; The proportion of described wearing layer is 10-15g/m2; The proportion of described wear-resisting adhesive film is 90-100g/m2��
The preparation method technique of the triamine glue of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, can large-scale industrial production.
The preparation method of a kind of high abrasion printing dipping paper, comprises the steps:
A, taking original paper layer, the upper surface at original paper layer prints one layer of water color ink, dried forms simulated grain layer;
B, simulated grain layer upper surface be coated with one layer of aluminium oxide emulsion, form wearing layer after drying;
C, wearing layer upper surface be coated with one layer of wear-resisting triamine glue, form wear-resisting adhesive film after solidification, prepare high abrasion printing dipping paper.
The beneficial effects of the present invention is: the high abrasion printing dipping paper of the present invention by arranging wear-resisting adhesive film and wearing layer on original paper layer so that produced dipping paper has good anti-wear performance, simple in construction, and cost is low, practical.
The preparation method technique of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, can large-scale industrial production.
Accompanying drawing explanation
Fig. 1 is the partial sectional view of the present invention;
Accompanying drawing is labeled as: 1 original paper layer, 2 simulated grain layers, 3 wearing layers, 4 wear-resisting adhesive films.
Detailed description of the invention
For the ease of the understanding of those skilled in the art, below in conjunction with embodiment and accompanying drawing 1, the present invention is further illustrated, and the content that embodiment is mentioned not is limitation of the invention.
Embodiment 1
See Fig. 1, a kind of high abrasion printing dipping paper, including original paper layer 1, fit in the simulated grain layer 2 of original paper layer 1 upper surface, fit in the wearing layer 3 of simulated grain layer 2 upper surface and fit in the wear-resisting adhesive film 4 of wearing layer 3 upper surface.
Described simulated grain layer 2 is prepared through printing by water color ink.
Described water color ink is made up of the raw material of following percentage by weight: water-base resin 3%, dispersant 0.15%, wetting agent 0.15%, pigment 8%, other auxiliary agent 4%, water surplus.
Described water-base resin is acrylic resin modified with the weight ratio 2:1 mixture formed by water soluble acrylic resin and maleic rosin; Described dispersant by sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate with the weight ratio 1.8:0.8:1 mixture formed; Described wetting agent by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer with the weight ratio 1:0.5:1.4 mixture formed; Described pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, phthalein viridescent, white carbon black, permanent bordeaux and benzidine yellow; Other auxiliary agent described by levelling agent, defoamer and stabilizer with the weight ratio 0.1:0.4:1 mixture formed.
The raw material of described wearing layer 3 is aluminium oxide.
The raw material of described wear-resisting adhesive film 4 is wear-resisting triamine glue.
Described wear-resisting triamine glue includes the raw material of following weight portion: 3.5 parts of formaldehyde, tripolycyanamide 3.5 parts, phthalic acid two (2-Octyl Nitrite) 0.5 part, diethylene glycol 0.3 part and 1.8 parts of water.
The preparation method of described wear-resisting triamine glue comprises the steps:
(1) taking 3.5 parts of formaldehyde, 0.5 part of phthalic acid two (2-Octyl Nitrite), 0.3 portion of diethylene glycol and 1.8 parts of water to put in reactor, uniform stirring to pH value is 9.3;
(2) adding 3.5 parts of tripolycyanamide, heating, to 89 DEG C, then heats to 90 DEG C and is incubated 60min, is 1:2.5 to water-soluble ratio;
(3) it is cooled to 40 DEG C, is 1:1.2 to water-soluble ratio, discharging, prepare described triamine glue.
The proportion of described original paper layer 1 is 70g/m2; The proportion of described simulated grain layer 2 is 2g/m2; The proportion of described wearing layer 3 is 10g/m2; The proportion of described wear-resisting adhesive film 4 is 90g/m2��
The preparation method of a kind of high abrasion printing dipping paper, comprises the steps:
A, taking original paper layer 1, the upper surface at original paper layer 1 prints one layer of water color ink, dried forms simulated grain layer 2;
B, it is coated with one layer of aluminium oxide emulsion at the upper surface of simulated grain layer 2, dried forms wearing layer 3;
C, wearing layer 3 upper surface be coated with one layer of wear-resisting triamine glue, form wear-resisting adhesive film 4 after solidification, prepare high abrasion printing dipping paper.
Embodiment 2
The present embodiment and above-described embodiment 1 are different in that:
Described water color ink is made up of the raw material of following percentage by weight: water-base resin 4%, dispersant 0.2%, wetting agent 0.2%, pigment 9%, other auxiliary agent 6%, water surplus.
Described water-base resin is acrylic resin modified with the weight ratio 2.5:1 mixture formed by water soluble acrylic resin and maleic rosin; Described dispersant by sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate with the weight ratio 2:0.9:1 mixture formed; Described wetting agent by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer with the weight ratio 1:0.8:1.6 mixture formed; Described pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, phthalein viridescent, white carbon black, permanent bordeaux and benzidine yellow; Other auxiliary agent described by levelling agent, defoamer and stabilizer with the weight ratio 0.2:0.5:1 mixture formed.
Described triamine glue includes the raw material of following weight portion: 5 parts of formaldehyde, tripolycyanamide 5 parts, phthalic acid two (2-Octyl Nitrite) 1 part, diethylene glycol 1 part and 2.1 parts of water.
The preparation method of described triamine glue comprises the steps:
(1) taking 5 parts of formaldehyde, 1 part of phthalic acid two (2-Octyl Nitrite), 1 portion of diethylene glycol and 2.1 parts of water to put in reactor, uniform stirring to pH value is 9.3-9.5;
(2) adding 5 parts of tripolycyanamide, heating, to 90 DEG C, then heats to 91 DEG C and is incubated 70min, is 1:2.8 to water-soluble ratio;
(3) it is cooled to 41 DEG C, is 1:1.4 to water-soluble ratio, discharging, prepare described triamine glue.
The proportion of described original paper layer 1 is 72g/m2; The proportion of described simulated grain layer 2 is 2.5g/m2; The proportion of described wearing layer 3 is 11g/m2; The proportion of described wear-resisting adhesive film 4 is 92g/m2��
Embodiment 3
The present embodiment and above-described embodiment 1 are different in that:
Described water color ink is made up of the raw material of following percentage by weight: water-base resin 5%, dispersant 0.25%, wetting agent 0.25%, pigment 10%, other auxiliary agent 8%, water surplus.
Described water-base resin is acrylic resin modified with the weight ratio 3:1 mixture formed by water soluble acrylic resin and maleic rosin; Described dispersant by sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate with the weight ratio 2.2:1:1 mixture formed; Described wetting agent by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer with the weight ratio 1:1:1.8 mixture formed;Described pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, phthalein viridescent, white carbon black, permanent bordeaux and benzidine yellow; Other auxiliary agent described by levelling agent, defoamer and stabilizer with the weight ratio 0.3:0.6:1 mixture formed.
Described triamine glue includes the raw material of following weight portion: 6 parts of formaldehyde, tripolycyanamide 6 parts, phthalic acid two (2-Octyl Nitrite) 1.5 parts, diethylene glycol 1.8 parts and 2.8 parts of water.
The preparation method of described triamine glue comprises the steps:
(1) taking 6 parts of formaldehyde, 1.5 parts of phthalic acids two (2-Octyl Nitrite), 1.8 portions of diethylene glycol and 2.8 parts of water to put in reactor, uniform stirring to pH value is 9.4;
(2) adding 6 parts of tripolycyanamide, heating, to 90 DEG C, then heats to 92 DEG C and is incubated 75min, is 1:3 to water-soluble ratio;
(3) it is cooled to 42 DEG C, is 1:1.5 to water-soluble ratio, discharging, prepare described triamine glue.
The proportion of described original paper layer 1 is 75g/m2; The proportion of described simulated grain layer 2 is 3g/m2; The proportion of described wearing layer 3 is 12g/m2; The proportion of described wear-resisting adhesive film 4 is 95g/m2��
Embodiment 4
The present embodiment and above-described embodiment 1 are different in that:
Described water color ink is made up of the raw material of following percentage by weight: water-base resin 7%, dispersant 0.3%, wetting agent 0.3%, pigment 12%, other auxiliary agent 10%, water surplus.
Described water-base resin is acrylic resin modified with the weight ratio 3.5:1 mixture formed by water soluble acrylic resin and maleic rosin; Described dispersant by sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate with the weight ratio 2.4:1.1:1 mixture formed; Described wetting agent by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer with the weight ratio 1:1.2:2 mixture formed; Described pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, phthalein viridescent, white carbon black, permanent bordeaux and benzidine yellow; Other auxiliary agent described by levelling agent, defoamer and stabilizer with the weight ratio 0.4:0.7:1 mixture formed.
Described triamine glue includes the raw material of following weight portion: 7 parts of formaldehyde, tripolycyanamide 7 parts, phthalic acid two (2-Octyl Nitrite) 2 parts, diethylene glycol 2.5 parts and 3.5 parts of water.
The preparation method of described triamine glue comprises the steps:
(1) taking 7 parts of formaldehyde, 2 parts of phthalic acids two (2-Octyl Nitrite), 2.5 portions of diethylene glycol and 3.5 parts of water to put in reactor, uniform stirring to pH value is 9.4;
(2) adding 7 parts of tripolycyanamide, heating, to 90 DEG C, then heats to 91 DEG C and is incubated 80min, is 1:3.2 to water-soluble ratio;
(3) it is cooled to 44 DEG C, is 1:1.7 to water-soluble ratio, discharging, prepare described triamine glue.
The proportion of described original paper layer 1 is 78g/m2; The proportion of described simulated grain layer 2 is 3.5g/m2; The proportion of described wearing layer 3 is 1.4g/m2; The proportion of described wear-resisting adhesive film 4 is 98g/m2��
Embodiment 5
The present embodiment and above-described embodiment 1 are different in that:
Described water color ink is made up of the raw material of following percentage by weight: water-base resin 8%, dispersant 0.4%, wetting agent 0.4%, pigment 13%, other auxiliary agent 12%, water surplus.
Described water-base resin is acrylic resin modified with the weight ratio 4:1 mixture formed by water soluble acrylic resin and maleic rosin; Described dispersant by sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate with the weight ratio 2.6:1.2:1 mixture formed;Described wetting agent by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer with the weight ratio 1:1.5:2.2 mixture formed; Described pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, phthalein viridescent, white carbon black, permanent bordeaux and benzidine yellow; Other auxiliary agent described by levelling agent, defoamer and stabilizer with the weight ratio 0.5:0.8:1 mixture formed.
Described triamine glue includes the raw material of following weight portion: 8.5 parts of formaldehyde, tripolycyanamide 8.0 parts, phthalic acid two (2-Octyl Nitrite) 2.5 parts, diethylene glycol 3.2 parts and 4.2 parts of water.
The preparation method of described triamine glue comprises the steps:
(1) taking 8.5 parts of formaldehyde, 2.5 parts of phthalic acids two (2-Octyl Nitrite), 3.2 portions of diethylene glycol and 4.2 parts of water to put in reactor, uniform stirring to pH value is 9.5;
(2) adding 8.0 parts of tripolycyanamide, heating, to 91 DEG C, then heats to 90-93 DEG C and is incubated 90min, is 1:3.5 to water-soluble ratio;
(3) it is cooled to 45 DEG C, is 1:1.8 to water-soluble ratio, discharging, prepare described triamine glue.
The proportion of described original paper layer 1 is 80g/m2; The proportion of described simulated grain layer 2 is 4g/m2; The proportion of described wearing layer 3 is 15g/m2; The proportion of described wear-resisting adhesive film 4 is 100g/m2��
The high abrasion printing dipping paper of the present invention by arranging wear-resisting adhesive film and wearing layer on original paper layer so that produced dipping paper has good anti-wear performance, simple in construction, and cost is low, practical.
The preparation method technique of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, can large-scale industrial production.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can also realize by alternate manner, and any apparent replacement is all within protection scope of the present invention without departing from the inventive concept of the premise.
Claims (10)
1. a high abrasion printing dipping paper, it is characterised in that: include original paper layer, fit in the simulated grain layer of original paper layer upper surface, fit in the wearing layer of simulated grain layer upper surface and fit in the wear-resisting adhesive film of wearing layer upper surface.
2. a kind of high abrasion printing dipping paper according to claim 1, it is characterised in that: described simulated grain layer is prepared through printing by water color ink.
3. a kind of high abrasion printing dipping paper according to claim 2, it is characterized in that: described water color ink is made up of the raw material of following percentage by weight: water-base resin 3%-8%, dispersant 0.15%-0.4%, wetting agent 0.15%-0.4%, pigment 8%-13%, other auxiliary agent 4%-12%, water surplus.
4. a kind of high abrasion printing dipping paper according to claim 3, it is characterised in that: described water-base resin is acrylic resin modified with the weight ratio 2-4:1 mixture formed by water soluble acrylic resin and maleic rosin; Described dispersant by sodium hexameta phosphate, polyacrylamide and sodium lauryl sulphate with the weight ratio 1.8-2.6:0.8-1.2:1 mixture formed; Described wetting agent by polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer with the weight ratio 1:0.5-1.5:1.4-2.2 mixture formed; Described pigment is at least one in phosphoric acid cobalt violet, phthalocyanine blue, phthalein viridescent, white carbon black, permanent bordeaux and benzidine yellow; Other auxiliary agent described by levelling agent, defoamer and stabilizer with the weight ratio 0.1-0.5:0.4-0.8:1 mixture formed.
5. a kind of high abrasion printing dipping paper according to claim 1, it is characterised in that: the raw material of described wearing layer is aluminium oxide.
6. a kind of high abrasion printing dipping paper according to claim 1, it is characterised in that: the raw material of described wear-resisting adhesive film is wear-resisting triamine glue.
7. a kind of high abrasion printing dipping paper according to claim 6, it is characterised in that: described wear-resisting triamine glue includes the raw material of following weight portion: formaldehyde 3.5-8.5 part, tripolycyanamide 3.5-8.0 part, phthalic acid two (2-Octyl Nitrite) 0.5-2.5 part, diethylene glycol 0.3-3.2 part and water 1.8-4.2 part.
8. a kind of high abrasion printing dipping paper according to claim 7, it is characterised in that: the preparation method of described wear-resisting triamine glue comprises the steps:
(1) taking 3.5-8.5 part formaldehyde, 0.5-2.5 part phthalic acid two (2-Octyl Nitrite), 0.3-3.2 part diethylene glycol and 1.8-4.2 part water to put in reactor, uniform stirring to pH value is 9.3-9.5;
(2) adding 3.5-8.0 part tripolycyanamide, heating, to 89-91 DEG C, then heats to 90-93 DEG C and is incubated 60-90min, is 1:2.5-3.5 to water-soluble ratio;
(3) it is cooled to 40-45 DEG C, is 1:1.2-1.8 to water-soluble ratio, discharging, prepare described wear-resisting triamine glue.
9. a kind of high abrasion printing dipping paper according to claim 1, it is characterised in that: the proportion of described original paper layer is 70-80g/m2; The proportion of described simulated grain layer is 2-4g/m2; The proportion of described wearing layer is 10-15g/m2; The proportion of described wear-resisting adhesive film is 90-100g/m2��
10. the preparation method of a kind of high abrasion printing dipping paper as described in any one of claim 1-9, it is characterised in that: comprise the steps:
A, taking original paper layer, the upper surface at original paper layer prints one layer of water color ink, dried forms simulated grain layer;
B, simulated grain layer upper surface be coated with one layer of aluminium oxide emulsion, form wearing layer after drying;
C, wearing layer upper surface be coated with one layer of wear-resisting triamine glue, form wear-resisting adhesive film after solidification, prepare high abrasion printing dipping paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511014370.1A CN105648844B (en) | 2015-12-31 | 2015-12-31 | A kind of high abrasion printing dipping paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511014370.1A CN105648844B (en) | 2015-12-31 | 2015-12-31 | A kind of high abrasion printing dipping paper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105648844A true CN105648844A (en) | 2016-06-08 |
| CN105648844B CN105648844B (en) | 2017-07-18 |
Family
ID=56478414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511014370.1A Active CN105648844B (en) | 2015-12-31 | 2015-12-31 | A kind of high abrasion printing dipping paper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105648844B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286748A (en) * | 2017-08-31 | 2017-10-24 | 张家港精工包装彩印有限公司 | A kind of wear-resisting printing-ink |
| CN108215255A (en) * | 2017-12-14 | 2018-06-29 | 东莞市亚马电子有限公司 | A kind of cell phone rear cover film and its preparation process |
| CN109551576A (en) * | 2018-12-13 | 2019-04-02 | 柳州市荣森新型材料科技有限公司 | A kind of wear-resistant impregnated bond paper facing ecological board and preparation method thereof |
| CN109706783A (en) * | 2018-12-26 | 2019-05-03 | 罗力诚 | A kind of formaldehydeless woodgrained paper dipping glue of high-performance and preparation method |
| CN114059388A (en) * | 2021-11-15 | 2022-02-18 | 杭州中润华源装饰材料有限公司 | Wear-resistant high-color-fastness decorative paper and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6106654A (en) * | 1995-06-19 | 2000-08-22 | Perstorp Ab | Process for the manufacturing of a decorative thermo-setting plastic laminate |
| CN202055113U (en) * | 2011-03-04 | 2011-11-30 | 苏州市建诚装饰材料有限公司 | Abrasion resistant paper impregnated thermosetting resins |
| CN103194121A (en) * | 2013-03-18 | 2013-07-10 | 福建省利得彩环保科技有限公司 | Water-based gravure printing ink for thermal transfer printing |
| CN103613999A (en) * | 2013-11-28 | 2014-03-05 | 张家港威迪森化学有限公司 | Water-based ink |
| CN103911916A (en) * | 2014-03-28 | 2014-07-09 | 苏州市建诚装饰材料有限公司 | Wear-resistant scratch-resistant impregnated paper |
| CN104149151A (en) * | 2014-07-21 | 2014-11-19 | 常州市森尼装饰材料有限公司 | Producing process of high-wear-resistance impregnated paper laminated wood floor |
| CN104861778A (en) * | 2015-05-05 | 2015-08-26 | 浙江宜佳新材料有限公司 | Water-based ink for grainy paper printing and preparation method thereof |
| CN105199064A (en) * | 2015-09-25 | 2015-12-30 | 寿光市东宇鸿翔木业有限公司 | Low-formaldehyde triamine adhesive and method for preparing same |
-
2015
- 2015-12-31 CN CN201511014370.1A patent/CN105648844B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6106654A (en) * | 1995-06-19 | 2000-08-22 | Perstorp Ab | Process for the manufacturing of a decorative thermo-setting plastic laminate |
| CN202055113U (en) * | 2011-03-04 | 2011-11-30 | 苏州市建诚装饰材料有限公司 | Abrasion resistant paper impregnated thermosetting resins |
| CN103194121A (en) * | 2013-03-18 | 2013-07-10 | 福建省利得彩环保科技有限公司 | Water-based gravure printing ink for thermal transfer printing |
| CN103613999A (en) * | 2013-11-28 | 2014-03-05 | 张家港威迪森化学有限公司 | Water-based ink |
| CN103911916A (en) * | 2014-03-28 | 2014-07-09 | 苏州市建诚装饰材料有限公司 | Wear-resistant scratch-resistant impregnated paper |
| CN104149151A (en) * | 2014-07-21 | 2014-11-19 | 常州市森尼装饰材料有限公司 | Producing process of high-wear-resistance impregnated paper laminated wood floor |
| CN104861778A (en) * | 2015-05-05 | 2015-08-26 | 浙江宜佳新材料有限公司 | Water-based ink for grainy paper printing and preparation method thereof |
| CN105199064A (en) * | 2015-09-25 | 2015-12-30 | 寿光市东宇鸿翔木业有限公司 | Low-formaldehyde triamine adhesive and method for preparing same |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286748A (en) * | 2017-08-31 | 2017-10-24 | 张家港精工包装彩印有限公司 | A kind of wear-resisting printing-ink |
| CN108215255A (en) * | 2017-12-14 | 2018-06-29 | 东莞市亚马电子有限公司 | A kind of cell phone rear cover film and its preparation process |
| CN109551576A (en) * | 2018-12-13 | 2019-04-02 | 柳州市荣森新型材料科技有限公司 | A kind of wear-resistant impregnated bond paper facing ecological board and preparation method thereof |
| CN109706783A (en) * | 2018-12-26 | 2019-05-03 | 罗力诚 | A kind of formaldehydeless woodgrained paper dipping glue of high-performance and preparation method |
| CN109706783B (en) * | 2018-12-26 | 2021-09-14 | 罗力诚 | High-performance formaldehyde-free wood-grain paper impregnating glue and preparation method thereof |
| CN114059388A (en) * | 2021-11-15 | 2022-02-18 | 杭州中润华源装饰材料有限公司 | Wear-resistant high-color-fastness decorative paper and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105648844B (en) | 2017-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105648844A (en) | High-wear-resistance printing impregnated paper and manufacturing method thereof | |
| CN106928901A (en) | Colorful environmentally friendly dust suppressant and its preparation and application | |
| CN102838897B (en) | Disperse dye ink for cold transfer printing and application method thereof | |
| CN103525211B (en) | A kind of exterior wall latex coating | |
| CN102431327B (en) | Waterborne date printing ribbon and preparation method thereof | |
| CN104861778A (en) | Water-based ink for grainy paper printing and preparation method thereof | |
| CN109913109A (en) | A kind of water-fast high pressure resistant water paint and preparation method thereof | |
| CN102850928A (en) | Light cured wear resistant and anti-corrosive coating and preparation method thereof | |
| CN102691217A (en) | Dispersed dye steaming-free printing paste | |
| CN103045140A (en) | Low formaldehyde resin adhesive for decorative impregnating paper and preparation method thereof | |
| CN105648843A (en) | Glossy impregnated paper and manufacturing method thereof | |
| CN102644215B (en) | Preparation method of offset paper | |
| CN105603829A (en) | High-stain-resisting impregnated paper and preparation method thereof | |
| CN105648845B (en) | A kind of high light-fast printing dipping paper and preparation method thereof | |
| CN106032653A (en) | Fading-resistant textile pigment | |
| CN105648846A (en) | Eco-friendly impregnated paper and manufacturing method thereof | |
| CN104497861A (en) | Wear-resistant paint | |
| CN105602323A (en) | Composition for poster paint and preparation method thereof | |
| CN103540190B (en) | PVC wood grain film printing-ink | |
| CN104312403A (en) | Single-component low-temperature curing environment-friendly waterborne OP protective coating and preparation method thereof | |
| CN105713429A (en) | Printing plate protective adhesive and preparation method thereof | |
| CN104479547A (en) | Wear-resistant paint with SiC powder and preparation method thereof | |
| CN110105808B (en) | Chinese painting ink with transparent ink marks and preparation method thereof | |
| CN107217510A (en) | A kind of chemical ＆ blended fabric environment-friendly high-efficiency levelling agent | |
| CN105838135A (en) | Environment-friendly black ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-wear-resistance printing impregnated paper and manufacturing method thereof Effective date of registration: 20170919 Granted publication date: 20170718 Pledgee: China Co truction Bank Corp Dongguan branch Pledgor: GUANGDONG FUMEI NEW MATERIAL TECHNOLOGY CO., LTD. Registration number: 2017440000086 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |