CN105647072A - 一种阻燃效果好的普通塑料薄膜 - Google Patents

一种阻燃效果好的普通塑料薄膜 Download PDF

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CN105647072A
CN105647072A CN201610213701.2A CN201610213701A CN105647072A CN 105647072 A CN105647072 A CN 105647072A CN 201610213701 A CN201610213701 A CN 201610213701A CN 105647072 A CN105647072 A CN 105647072A
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parts
plastic film
common plastic
cadmium
good flame
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徐春华
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Suzhou New District Huashida Engineering Plastic Co Ltd
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Suzhou New District Huashida Engineering Plastic Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2451/04—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

本发明公开了一种阻燃效果好的普通塑料薄膜，包括的组分有聚氯乙烯、邻苯二甲酸二烯丙酯、MBS树脂、液体钡镉稳定剂、硬脂酸钡镉和二异丙苯磷酸酯，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯30-50份、MBS树脂5-7份、液体钡镉稳定剂1-2份、硬脂酸钡镉3-5份、二异丙苯磷酸酯10-12份。通过上述方式，本发明的阻燃效果好的普通塑料薄膜，阻燃效果具有耐候性和持久性，在作为包装材料的长期使用中阻燃效果不会消失，确保无毒害，使用上具有安全性，对人体不会造成伤害。

Description

一种阻燃效果好的普通塑料薄膜
技术领域
本发明涉及改性塑料塑胶领域，特别是涉及一种阻燃效果好的普通塑料薄膜。
背景技术
用纸、铝箔、纤维、塑料薄膜以及它们的复合物所制成的各种袋、盒、套、包封等均为软包装。其中塑料薄膜能满足各种物品的包装要求，是用于包装易存、易放的方便食品、生活用品、超市市场的小包装商品的理想材料。以塑料薄膜为主的软包装印刷在包装印刷中占有重要地位。现有的塑料薄膜阻燃性能不好，着火时很容易燃烧，不具有安全性。
发明内容
本发明主要解决的技术问题是提供一种阻燃效果好的普通塑料薄膜，能有效防止塑料薄膜的燃烧。
为解决上述技术问题，本发明采用的一个技术方案是：提供一种阻燃效果好的普通塑料薄膜，包括的组分有聚氯乙烯、邻苯二甲酸二烯丙酯、MBS树脂、液体钡镉稳定剂、硬脂酸钡镉和二异丙苯磷酸酯，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯30-50份、MBS树脂5-7份、液体钡镉稳定剂1-2份、硬脂酸钡镉3-5份、二异丙苯磷酸酯10-12份。
在本发明一个较佳实施例中，所述阻燃效果好的普通塑料薄膜的断裂伸长率为150-170%。
在本发明一个较佳实施例中，所述MBS树脂是甲基丙烯酸甲酯、丁二烯和苯乙烯的三元共聚物。
在本发明一个较佳实施例中，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯40份、MBS树脂6份、液体钡镉稳定剂1.5份、硬脂酸钡镉4份、二异丙苯磷酸酯11份。
本发明的有益效果是：本发明的阻燃效果好的普通塑料薄膜，阻燃效果具有耐候性和持久性，在作为包装材料的长期使用中阻燃效果不会消失，确保无毒害，使用上具有安全性，对人体不会造成伤害。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
实施例一：
提供一种阻燃效果好的普通塑料薄膜，包括的组分有聚氯乙烯、邻苯二甲酸二烯丙酯、MBS树脂、液体钡镉稳定剂、硬脂酸钡镉和二异丙苯磷酸酯，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯40份、MBS树脂6份、液体钡镉稳定剂1.5份、硬脂酸钡镉4份、二异丙苯磷酸酯11份。所述阻燃效果好的普通塑料薄膜的断裂伸长率为160%。所述MBS树脂是甲基丙烯酸甲酯、丁二烯和苯乙烯的三元共聚物。
实施例二：
提供一种阻燃效果好的普通塑料薄膜，包括的组分有聚氯乙烯、邻苯二甲酸二烯丙酯、MBS树脂、液体钡镉稳定剂、硬脂酸钡镉和二异丙苯磷酸酯，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯50份、MBS树脂5份、液体钡镉稳定剂2份、硬脂酸钡镉3份、二异丙苯磷酸酯12份。所述阻燃效果好的普通塑料薄膜的断裂伸长率为150%。所述MBS树脂是甲基丙烯酸甲酯、丁二烯和苯乙烯的三元共聚物。
实施例三：
提供一种阻燃效果好的普通塑料薄膜，包括的组分有聚氯乙烯、邻苯二甲酸二烯丙酯、MBS树脂、液体钡镉稳定剂、硬脂酸钡镉和二异丙苯磷酸酯，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯30份、MBS树脂7份、液体钡镉稳定剂1份、硬脂酸钡镉5份、二异丙苯磷酸酯10份。所述阻燃效果好的普通塑料薄膜的断裂伸长率为170%。所述MBS树脂是甲基丙烯酸甲酯、丁二烯和苯乙烯的三元共聚物。
本发明的有益效果是：
一、所述阻燃效果好的普通塑料薄膜具有耐候性和持久性，在作为包装材料的长期使用中阻燃效果不会消失；
二、所述阻燃效果好的普通塑料薄膜确保无毒害，使用上具有安全性，对人体不会造成伤害。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其它相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (4)

1.一种阻燃效果好的普通塑料薄膜，其特征在于，包括的组分有聚氯乙烯、邻苯二甲酸二烯丙酯、MBS树脂、液体钡镉稳定剂、硬脂酸钡镉和二异丙苯磷酸酯，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯30-50份、MBS树脂5-7份、液体钡镉稳定剂1-2份、硬脂酸钡镉3-5份、二异丙苯磷酸酯10-12份。
2.根据权利要求1所述的阻燃效果好的普通塑料薄膜，其特征在于，所述阻燃效果好的普通塑料薄膜的断裂伸长率为150-170%。
3.根据权利要求1所述的阻燃效果好的普通塑料薄膜，其特征在于，所述MBS树脂是甲基丙烯酸甲酯、丁二烯和苯乙烯的三元共聚物。
4.根据权利要求1所述的阻燃效果好的普通塑料薄膜，其特征在于，所述阻燃效果好的普通塑料薄膜以重量份计，包括的组分有：聚氯乙烯100份、邻苯二甲酸二烯丙酯40份、MBS树脂6份、液体钡镉稳定剂1.5份、硬脂酸钡镉4份、二异丙苯磷酸酯11份。
CN201610213701.2A 2016-04-08 2016-04-08 一种阻燃效果好的普通塑料薄膜 Pending CN105647072A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107652507A (zh) * 2017-09-28 2018-02-02 广西华洋矿源材料有限公司 一种阻燃的塑料薄膜的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2363431A1 (en) * 2010-02-25 2011-09-07 Reagens S.p.A. Composition comprising alkali metal carboxylates for stabilizing halogen-containing polymers
CN103993717A (zh) * 2014-04-29 2014-08-20 宁波华宝石节能科技股份有限公司 用于室内墙面装饰的贴片石及其制备方法
CN104356555A (zh) * 2014-11-26 2015-02-18 天津市天塑科技集团有限公司第四塑料制品厂 高弹聚氯乙烯耐候阻燃超透水晶膜片及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2363431A1 (en) * 2010-02-25 2011-09-07 Reagens S.p.A. Composition comprising alkali metal carboxylates for stabilizing halogen-containing polymers
CN103993717A (zh) * 2014-04-29 2014-08-20 宁波华宝石节能科技股份有限公司 用于室内墙面装饰的贴片石及其制备方法
CN104356555A (zh) * 2014-11-26 2015-02-18 天津市天塑科技集团有限公司第四塑料制品厂 高弹聚氯乙烯耐候阻燃超透水晶膜片及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107652507A (zh) * 2017-09-28 2018-02-02 广西华洋矿源材料有限公司 一种阻燃的塑料薄膜的制备方法

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