CN105645597A - Water body nitrite degradation agent - Google Patents

Water body nitrite degradation agent Download PDF

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Publication number
CN105645597A
CN105645597A CN201610050477.XA CN201610050477A CN105645597A CN 105645597 A CN105645597 A CN 105645597A CN 201610050477 A CN201610050477 A CN 201610050477A CN 105645597 A CN105645597 A CN 105645597A
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China
Prior art keywords
water body
degradation agent
nitrite degradation
parts
water
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CN201610050477.XA
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Chinese (zh)
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耿春茂
刘婷
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Individual
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Individual
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

The invention provides a water body nitrite degradation agent which is composed of auxiliaries and biological strains. The water body nitrite degradation agent is composed of, by mass, 3-5 parts of nitrobacteria, 6-7 parts of aerobic denitrifying bacteria, 3-5 parts of anaerobic denitrifying bacteria, 3-5 parts of oxygenic photosynthetic bacteria, 1-2 parts of bacillus subtilis and 1-5 parts of the auxiliaries. Compared with a biological purification method which is currently published, by means of the water body nitrite degradation agent, the purification effect of an aquatic water body is obviously improved. According to the water body nitrite degradation agent, a biological method is adopted for purification, complex operation steps are not needed, maintenance is simple, and obvious improvement is achieved compared with purification through a chemical method and a special purification device.

Description

A kind of water nitrite degradation agent
Technical field
The invention belongs to aquaculture system nitrite degradation field, be specifically related to a kind of water nitrite degradation agent.
Background technology
Nowadays most of cultured fishes are mostly that wild species is directly entered artificial cultivation, and therefore the quality of artificial cultivation water quality environment directly affects quality and the survival rate of cultured fishes. Breeding water body nitrite, ammonia nitrogen, hydrogen sulfide, pH value, chemical oxygen consumption (COC) equal size height will dominate the quality of cultivation water. In breeding process, if the indexs such as breeding water body nitrite, ammonia nitrogen, hydrogen sulfide, pH value are too high, the aquatic animal giving cultivation is brought very big harm.
Nitrite is the intermediate product that ammonia is converted in nitrate process, the a large amount of excremental accumulation of aquatic animal in the residual bait that stays due to substantial amounts of bait throwing in breeding water body, water body, have to regularly use disinfectant sterilization, but disinfectant can be killed harmful and useful antibacterial all simultaneously, cause that oxygen supply is not enough, the nitrogen nitrifying process causing a large amount of accumulation is obstructed, further result in ammonia nitrogen and content of nitrite in breeding water body high, but owing to the conversion rate of ammonia nitrogen is very fast so that the problem of breeding water body nitrite is the most prominent.
Hydrogen sulfide under anoxic conditions, is decomposed through anaerobic bacteria by the sulfurous organic compound in residual bait or feces and produces, and hydrogen sulfide can be combined formation metal sulfide with the slaine in Sediments, causes blackening at the bottom of pond.
After the nitrite concentration in water runs up to 0.1 mg/litre, the fish of cultivation, shrimp in water body will be produced harm by nitrite. Its mechanism of action, mainly by the Repiration of fish and shrimp, is entered blood by the gill filament, and fish, shrimp erythrocyte number and amount of hemoglobin gradually decrease, and blood oxygen carrying capability lowers gradually, histanoxia occurs. This macrura reevesii, shrimp food ration reduce, and pathological changes, dyspnea, restlessness or bradykinesia occurs in gill tissue, thus causing fish and shrimp anoxia, and even death by suffocation. Nitrite also can react, with secondary amine class, the nitrous acid amine substance generating carcinogenecity, is conducive to inferior ammonium nitrate to be formed when pH value is low. There is fish and shrimp anorexia phenomenon in a lot of ponds, and nitrite is too high is exactly one of the main reasons. The low pH value caused in cultivation fish, shrimp blood of water pH value declines, and weakens its blood oxygen carrying capability, although the dissolved oxygen in water is higher, can cause fish, shrimp physiology anoxia, often raise the nose above water to breathe, and growth retardation or ill. It addition, the pH value in water is too low, the microbial activities in water being caused to be suppressed, Organic substance is not easily decomposed.
In the water of current control pond, the main method of ammonia nitrogen and nitrite is to use special purpose device to remove or chemistry, biological method removal. Chemical method usually adds oxidant such as peroxide complex, in order to oxidation of sulfureted hydrogen, ammonia and nitrite, as Chinese patent CN104556477A discloses the purification technique of a kind of breeding water body, relates to chemical method and purifies. The shortcoming of chemical method is to add a large amount of novel chemical substance at Chi Zhongyou, can increase the weight of the pollution of Chi Shui, serious even result in pond and can not re-use completely. And use special purpose device remove harmful substance, purifying aquaculture pond method also have many reports, pool bottom sludge such as patent CN1164320A processes device, the device etc. integrating nutrient interpolation, pool water treatment of CN1070021C, but these devices are accepted because cost is difficult for raiser, and the defect of the using method of complexity and Operation and Maintenance aspect, actual can not meet the needs of raiser, thus use these devices harmful substance to remove in water almost without aquaculture family. Biological method is to add photosynthetic bacteria, compound probiotic, digestion bacterium, bacillus cereus etc. in pond, to improve the ecological environment in pond. As Chinese patent CN104591482A discloses the aeration treating method of a kind of breeding water body, relate to biological method and improve; And for example Chinese patent CN103539320A discloses a kind of to inorganic salt filter cleaning technique in water quality, wherein also relates to biological method and improves, but is still mainly chemically main in these patented methods.
Summary of the invention
For above-mentioned technical problem, the invention provides a kind of water nitrite degradation agent, it is possible to the nitrite in degraded water body effectively, improve breeding water body environmental quality.
In order to realize the technical purpose of the present invention, the present invention adopts the technical scheme that:
A kind of water nitrite degradation agent, is made up of adjuvant and biological inoculum, by weight, including following components:
Nitrobacteria 3-5 part;
Aerobic denitrifying bacteria 6-7 part;
Anaerobic denitrifying bacteria 3-5 part;
Produce oxygen photosynthetic bacteria 3-5 part;
Bacillus subtilis 1-2 part;
Adjuvant 1-5 part;
The commercially available described nitrobacteria of business is preferably the D004 of Depont company of Germany, the commercially available described anaerobic denitrifying bacteria of business is China North Sea Qun Lin biological engineering company limited product preferably, the commercially available described bacillus subtilis preferably Chinese favorite Bioisystech Co., Ltd of business is favorite and board product, described aerobic denitrifying bacteria cultural method is shown in Chinese invention patent 201010101218.8, and described product oxygen photosynthetic bacteria cultural method is shown in Chinese invention patent 200810222313.6.
Preferably, described adjuvant is that one or more in Semen Maydis powder, wheat flour or glucose powder mix with arbitrary proportion.
Preferably, described each biological inoculum number of viable is respectively as follows: nitrobacteria >=1.0 �� 1010Cfu/g; Aerobic denitrifying bacteria >=2.5 �� 109Cfu/g; Anaerobic denitrifying bacteria >=1.0 �� 1010Cfu/g; Produce oxygen photosynthetic bacteria >=3.2 �� 1010Cfu/g; Bacillus subtilis >=5.0 �� 109cfu/g��
Preferably, the addition of described nitrite degradation agent is the every mu every meter depth of water 200 ~ 300g.
The present invention, by adding nitrobacteria, utilizes Nitrification that by nitration reaction, nitrite is changed into nitrate; Add anaerobic denitrifying bacteria, become nitrogen to enter air nitrate transformation by Denitrification;Add aerobic denitrifying bacteria, become nitrogen to enter air nitrate transformation when there being oxygen by Denitrification; Produce oxygen photosynthetic bacteria by adding, produce oxygen, help nitration reaction and aerobic denitrification reaction, simultaneously also for breeding water body provides dissolved oxygen; Add bacillus subtilis, decompose the poisonous and harmful substance in culturing pool, purify water, residual bait, feces, Organic substance etc. in decomposing pool.
The present invention is compared with prior art, have the advantages that water nitrite degradation agent provided by the invention, biological method is adopted to improve purifying aquatic water water quality, by selecting nitrobacteria, anaerobic denitrifying bacteria, aerobic denitrifying bacteria, product oxygen photosynthetic bacteria and bacillus subtilis to carry out composite, by adjusting the ratio between each strain, compared to disclosed biodegradation method at present, a kind of water nitrite degradation agent disclosed by the invention, breeding water body clean-up effect has clear improvement. It addition, adopt biological method purification, it is not necessary to complicated operating procedure, safeguarding simple, compared with adopting chemical method and the purification of special purification device, tool has made marked progress.
Detailed description of the invention
In order to be better understood from the present invention, below in conjunction with embodiment, invention is described in detail.
Embodiment 1:
For middle mountain aquatic farm, by mass, by 3 parts of nitrobacterias (D004 of De Bang Depont company of Germany), 6 parts of aerobic denitrifying bacterias (cultural method is shown in Chinese patent 201010101218.8), 3 parts of anaerobic denitrifying bacterias (China North Sea Qun Lin biological engineering company limited product), 3 parts are produced oxygen photosynthetic bacteria (cultural method is shown in Chinese patent 200810222313.6), 1 part of bacillus subtilis (Chinese favorite Bioisystech Co., Ltd favorite and board product) and 1 part of Semen Maydis powder mix homogeneously, each biological inoculum number of viable is: nitrobacteria >=1.0 �� 1010Cfu/g; Aerobic denitrifying bacteria >=2.5 �� 109Cfu/g; Anaerobic denitrifying bacteria >=1.0 �� 1010Cfu/g; Produce oxygen photosynthetic bacteria >=3.2 �� 1010Cfu/g; Bacillus subtilis >=5.0 �� 109Cfu/g. By the nitrite degradation agent after mix homogeneously by the consumption of every mu every meter depth of water 300g, uniformly splash in breeding water body after diluting 1000 times, the detection detection each index of water body after 24h.
Embodiment 2:
For middle mountain aquatic farm, by mass, by 5 parts of nitrobacterias (D004 of De Bang Depont company of Germany), 7 parts of aerobic denitrifying bacterias (cultural method is shown in Chinese patent 201010101218.8), 5 parts of anaerobic denitrifying bacterias (China North Sea Qun Lin biological engineering company limited product), 5 parts are produced oxygen photosynthetic bacteria (cultural method is shown in Chinese patent 200810222313.6), 2 parts of bacillus subtilises (Chinese favorite Bioisystech Co., Ltd favorite and board product), 1 part of Semen Maydis powder, 2 portions of wheat flours and 2 parts of glucose powder mix homogeneously, each biological inoculum number of viable is: nitrobacteria >=1.0 �� 1010Cfu/g; Aerobic denitrifying bacteria >=2.5 �� 109Cfu/g; Anaerobic denitrifying bacteria >=1.0 �� 1010Cfu/g; Produce oxygen photosynthetic bacteria >=3.2 �� 1010Cfu/g; Bacillus subtilis >=5.0 �� 109Cfu/g. By the nitrite degradation agent after mix homogeneously by the consumption of every mu every meter depth of water 200g, uniformly splash in breeding water body after diluting 1000 times, the detection detection each index of water body after 24h.
Embodiment 1,2 water body each testing result such as following table:
Table 1 embodiment 1 water body testing result
Embodiment 1 NH4 +-N(mg/L) NO2-N(mg/L) DO(mg/L) pH Transparency (cm) Water temperature
Before using 1.95 2.74 2.4 8.6 19 32
After using 24h 0.10 0.08 4.7 7.0 30 31
Table 2 embodiment 2 water body testing result
Embodiment 2 NH4 +-N(mg/L) NO2-N(mg/L) DO(mg/L) pH Transparency (cm) Water temperature
Before using 2.03 2.68 2.3 8.9 20 30
After using 24h 0.11 0.09 5.6 7.3 33 32
According to table 1, table 2 data it is apparent that the poisonous and harmful substance such as water nitrite degradation agent provided by the invention is improving breeding water body environment, degrading nitrite, have clear improvement on purifying water.Meanwhile, adopting biological method to carry out the purification of breeding water body, it is not necessary to complicated operating procedure, safeguard simple, compared with purifying with employing chemical method and special purification device, tool has made marked progress.
The ultimate principle of the present invention, principal character and advantage have more than been shown and described. Skilled person will appreciate that of the industry, above-described embodiment does not limit the present invention in any form, and all employings are equal to the technical scheme that the mode of replacement or equivalent transformation obtains, and all fall within protection scope of the present invention.

Claims (4)

1. a water nitrite degradation agent, is made up of adjuvant and biological inoculum, it is characterised in that: by weight, including following components:
Nitrobacteria 3-5 part;
Aerobic denitrifying bacteria 6-7 part;
Anaerobic denitrifying bacteria 3-5 part;
Produce oxygen photosynthetic bacteria 3-5 part;
Bacillus subtilis 1-2 part;
Adjuvant 1-5 part.
2. a kind of water nitrite degradation agent according to claim 1, it is characterised in that: described adjuvant is that one or more in Semen Maydis powder, wheat flour or glucose powder mix with arbitrary proportion.
3. a kind of water nitrite degradation agent according to claim 1, it is characterised in that: described each biological inoculum number of viable is respectively as follows: nitrobacteria >=1.0 �� 1010Cfu/g; Aerobic denitrifying bacteria >=2.5 �� 109Cfu/g; Anaerobic denitrifying bacteria >=1.0 �� 1010Cfu/g; Produce oxygen photosynthetic bacteria >=3.2 �� 1010Cfu/g; Bacillus subtilis >=5.0 �� 109cfu/g��
4. a kind of water nitrite degradation agent according to claim 1, it is characterised in that: the addition of described nitrite degradation agent is the every mu every meter depth of water 200 ~ 300g.
CN201610050477.XA 2016-01-26 2016-01-26 Water body nitrite degradation agent Pending CN105645597A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112250184A (en) * 2020-09-29 2021-01-22 南京乐萱生态环境科技有限公司 Degradation agent for efficiently recovering watercourse water transparency, use method and preparation method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4454038A (en) * 1978-02-14 1984-06-12 Chiyoda Chemical Engineering And Construction Co., Ltd. Apparatus for biological treatment of waste water in downflow operation
CN101157892A (en) * 2007-03-06 2008-04-09 扬州市绿科生物技术有限公司 Production method of solid preparation for degradation of ammonia nitrogen and nitrite
CN101962229A (en) * 2010-06-23 2011-02-02 天津生机集团股份有限公司 Water purifying agent for pond culture
CN102963986A (en) * 2012-12-04 2013-03-13 沧州旺发生物技术研究所有限公司 Biological sediment modifier for fishpond

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4454038A (en) * 1978-02-14 1984-06-12 Chiyoda Chemical Engineering And Construction Co., Ltd. Apparatus for biological treatment of waste water in downflow operation
CN101157892A (en) * 2007-03-06 2008-04-09 扬州市绿科生物技术有限公司 Production method of solid preparation for degradation of ammonia nitrogen and nitrite
CN101962229A (en) * 2010-06-23 2011-02-02 天津生机集团股份有限公司 Water purifying agent for pond culture
CN102963986A (en) * 2012-12-04 2013-03-13 沧州旺发生物技术研究所有限公司 Biological sediment modifier for fishpond

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
谢凤行: "《微生态制剂在农业上的应用》", 31 March 2010 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112250184A (en) * 2020-09-29 2021-01-22 南京乐萱生态环境科技有限公司 Degradation agent for efficiently recovering watercourse water transparency, use method and preparation method

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