CN105629353A - Wear-resisting cell phone cover plate for blue light filtering and manufacturing method thereof - Google Patents

Wear-resisting cell phone cover plate for blue light filtering and manufacturing method thereof Download PDF

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Publication number
CN105629353A
CN105629353A CN201511029263.6A CN201511029263A CN105629353A CN 105629353 A CN105629353 A CN 105629353A CN 201511029263 A CN201511029263 A CN 201511029263A CN 105629353 A CN105629353 A CN 105629353A
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rete
film material
substrate
membrane layer
evaporation
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吴晓彤
方俊勇
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Ott Road (zhangzhou) Optical Technology Co Ltd
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Ott Road (zhangzhou) Optical Technology Co Ltd
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Priority to CN201511029263.6A priority Critical patent/CN105629353A/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/10Glass or silica
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • C23C14/28Vacuum evaporation by wave energy or particle radiation
    • C23C14/30Vacuum evaporation by wave energy or particle radiation by electron bombardment
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/12Optical coatings produced by application to, or surface treatment of, optical elements by surface treatment, e.g. by irradiation
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04MTELEPHONIC COMMUNICATION
    • H04M1/00Substation equipment, e.g. for use by subscribers
    • H04M1/02Constructional features of telephone sets
    • H04M1/0202Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • Signal Processing (AREA)
  • Physical Vapour Deposition (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a wear-resisting cell phone cover plate for blue light filtering and a manufacturing method thereof. The cell phone cover plate comprises a substrate. A first film layer, a second film layer, a third film layer and a fourth film layer are successively arranged from inside to outside on the outer surface of the substrate. The first film layer is a trititanium pentoxide layer. The second film layer is a silicon dioxide layer. The third film layer is a metal layer. The fourth film layer is a high-rigidity layer. The manufacturing method comprises following steps of 1) cleaning the substrate; and 2) coating a film on the outer surface of the substrate. According to the invention, over 33% of harmful blue light can be effectively filtered; the whole definition of the cell phone cover plate is high; the manufacturing method contributes to visual definition and authenticity; visual fatigues can be effectively relieved by filtering the harmful blue light; and the cell phone cover plate has quite high wear resistance.

Description

The wear-resistant mobile phone cover plate of a kind of filter blue light and manufacture method thereof
Technical field
The present invention relates to the wear-resistant mobile phone cover plate of a kind of filter blue light and manufacture method thereof.
Background technology
Along with commonly using of modern life mobile phone, and the life of people increasingly be unable to do without hands machine, the result that mobile phone brings that uses having a lot of people regular is that eyes appearance is sour and astringent, pain, the uncomfortable symptom such as shed tears, more serious appearance visual deterioration, these uncomfortable symptoms are because eyes for a long time to mobile phone screen, caused by the harmful light come out by mobile phone screen, the formidable enemy of the just eyes that mobile phone screen sends, general mobile phone screen supplier is in order to embody color contrast and the saturation of mobile phone screen, mobile phone screen lamplight brightness behind can be improved, screen surface so can be made to seem there is texture as having filled a sheet glass, improve definition, it also can reflect light glass-like equally, but light line reflection can be increased when light is pointed into screen, especially when evening consumer use mobile phone time, LED lamplight is pointed into mobile phone screen can increase light line reflection, so it is easy to be hurt eyes by these light, and produce the symptom of visual fatigue, meeting slowly causes the health problem of visual deterioration and headache, , " uncomfortable light " our eyes of prolonged exposure that mobile phone screen produces also can cause visual system to lack of proper care, the uncomfortable high energy shortwave blue light being because containing a large amount of irregular frequency inside these light of light let us eyes that mobile phone screen sends, these shortwave blue lights have energy can penetrate our through retina of eyeglass, shortwave blue light prolonged exposure retina can produce a large amount of radical ion, these radical ions can make amphiblestroid pigment epithelium cell become feeble and die, epithelial declining can make photoreceptor cell��photosensory cell lack nutrient and cause vision impairment, these shortwave blue lights be also cause macular diseases act primarily as because of, our every days, the long-time blue light produced in the face of mobile phone screen stimulated, hardly realize that the short energy of blue light wavelength is high, easily cause early onset cataract, the spontaneity macular diseases such as dry and astringent, photophobia, fatigue on ocular vision. blue light accounts for the 50 ~ 60% of visible ray, and blue light is also the one of the main reasons causing macular diseases, seriously may result in blind. blue light can stimulate retina to produce a large amount of radical ions, make the atrophy of retinal pigment epithelium, cause the decline of photaesthesia cell again, this is because we residing be the information age, the work of people all be unable to do without mobile phone with study, more and more longer in the face of the time of mobile phone screen, also more and more higher by the frequency of eye. eyes start sour and astringent, pain, shed tears, its plaintive teaching that: our eyes have had been subjected to injury, it is necessary to protected when using mobile phone. blue light that current mobile phone screen sends, electromagnetic wave, free electron they all eyes can be damaged, in order to protect eyes, must be filtered, and the method filtering mobile phone screen blue light at present is to paste layer protecting film on mobile phone screen surface, after film for mobile phone screen, light transmittance often declines, and the film pasted easily produces cut affects visual effect, and filter blue light effect is still not ideal enough. it addition, protecting film wears no resistance, it is easy to scratch, affect visual effect.
Summary of the invention
It is an object of the invention to provide the wear-resistant mobile phone cover plate of a kind of filter blue light and manufacture method thereof, the produced hand-set lid of the method is prevented from the harmful blue light injury to human body, and has high-wearing feature.
For achieving the above object, the present invention is by the following technical solutions:
A kind of wear-resistant mobile phone cover plate of filter blue light, including substrate, the outer surface of described substrate is sequentially provided with the first rete, the second rete, third membrane layer and the 4th rete from the inside to surface, and described first rete is five oxidation three titanium layers, and the thickness of the first rete is 10-100nm; Described second rete is silicon dioxide layer, and the thickness of the second rete is 50-100nm; Third membrane layer is metal level, and the thickness of third membrane layer is 5-20nm; Described 4th rete is high rigidity layer, and the thickness of the 4th rete is 10-50mm.
The film material of described metal level is gold, silver, platinum, neodymium, copper, zinc or nickel, and is deposited with molding by electron gun.
The film material of described metal level is billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, and is deposited with molding by electron gun.
The film material of described high rigidity layer is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, and is deposited with molding by electron gun.
Described substrate is resin or glass ware forming.
When the substrate of described hand-set lid is resin forming, the manufacture method of the wear-resistant mobile phone cover plate of this filter blue light specifically includes following steps:
1) outer surface of substrate is carried out;
2) outer surface of substrate is carried out plated film;
, plate the first rete:
Vacuum in vacuum coating cabin is adjusted to more than or equal to 5.0 �� 10-3Handkerchief, and control the temperature in vacuum coating cabin and be 50-70 DEG C, electron gun is adopted to bombard the film material of the first rete, it is deposited on the outer surface of substrate with nanoscale molecular form after the film material evaporation of the first rete, the speed simultaneously controlling the first rete evaporation is 2.5/S, first rete ultimately form after thickness be 10-100nm, wherein the film material of the first rete is five oxidation Tritanium/Trititaniums, formed five oxidation three titanium layers;
B, plate the second rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, electron gun is adopted to bombard the film material of the second rete, the surface being deposited in above-mentioned steps the first rete with nanoscale molecular form after the film material evaporation of the second rete, the speed simultaneously controlling the second rete evaporation is 7/S, second rete ultimately form after thickness be 50-100nm, wherein the film material of the second rete is silicon dioxide, formed silicon dioxide layer;
C, plating third membrane layer:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, adopt the film material of electron gun bombardment third membrane layer, the surface being deposited in above-mentioned steps B the second rete with nanoscale molecular form after the film material evaporation of third membrane layer, the speed simultaneously controlling third membrane layer evaporation is 1/S, third membrane layer ultimately form after thickness be 5-20nm, wherein the film material of third membrane layer is gold, silver, platinum, neodymium, copper, zinc, nickel, billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, forms metal level.
D, plating the 4th rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, adopt the film material of electron gun bombardment the 4th rete, the surface being deposited in above-mentioned steps C third membrane layer with nanoscale molecular form after the film material evaporation of the 4th rete, the speed simultaneously controlling the 4th rete evaporation is 7/S, 4th rete ultimately form after thickness be 10-50nm, wherein the film material of the 4th rete is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, formed high rigidity layer.
In described step 1), the concrete grammar that outer surface of substrate is cleaned is as follows: be placed in vacuum chamber by substrate, bombards the outer surface 3 minutes of substrate with ion gun.
When the substrate of described hand-set lid is glass ware forming, the described manufacture method of the wear-resistant mobile phone cover plate of this filter blue light specifically includes following steps:
1) outer surface of substrate is carried out;
2) outer surface of substrate is carried out plated film;
, plate the first rete:
Vacuum in vacuum coating cabin is adjusted to more than or equal to 5.0 �� 10-3Handkerchief, and control the temperature in vacuum coating cabin and be 200-300 DEG C, electron gun is adopted to bombard the film material of the first rete, it is deposited on the outer surface of substrate with nanoscale molecular form after the film material evaporation of the first rete, the speed simultaneously controlling the first rete evaporation is 2.5/S, first rete ultimately form after thickness be 10-100nm, wherein the film material of the first rete is five oxidation Tritanium/Trititaniums, formed five oxidation three titanium layers;
B, plate the second rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, electron gun is adopted to bombard the film material of the second rete, the surface being deposited in above-mentioned steps the first rete with nanoscale molecular form after the film material evaporation of the second rete, the speed simultaneously controlling the second rete evaporation is 7/S, second rete ultimately form after thickness be 50-100nm, wherein the film material of the second rete is silicon dioxide, formed silicon dioxide layer;
C, plating third membrane layer:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, adopt the film material of electron gun bombardment third membrane layer, the surface being deposited in above-mentioned steps B the second rete with nanoscale molecular form after the film material evaporation of third membrane layer, the speed simultaneously controlling third membrane layer evaporation is 1/S, third membrane layer ultimately form after thickness be 5-20nm, wherein the film material of third membrane layer is gold, silver, platinum, neodymium, copper, zinc, nickel, billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, forms metal level;
D, plating the 4th rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, adopt the film material of electron gun bombardment the 4th rete, the surface being deposited in above-mentioned steps C third membrane layer with nanoscale molecular form after the film material evaporation of the 4th rete, the speed simultaneously controlling the 4th rete evaporation is 7/S, 4th rete ultimately form after thickness be 10-50nm, wherein the film material of the 4th rete is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, formed high rigidity layer.
In described step 1), the concrete grammar that outer surface of substrate is cleaned is as follows: be placed in vacuum chamber by substrate, bombards outer surface 5-10 minute of substrate with ion gun.
The present invention adopts the principle of electron beam vacuum evaporation, charged particle is utilized after accelerating in the electric field, to have the feature of certain kinetic energy, ion is guided into the electrode being intended to be made by the substrate of plated film, and by high purity metal, metal alloy or other oxide that electron gun with high temperature bombardment simple substance exists, the nano molecular being evaporated makes it move to substrate the method finally depositing film forming on substrate along certain direction. This invention technology is combined with the trajectory of electron motion in the special distributed controll electric field in magnetic field, and with this technique improving plated film so that coating film thickness and uniformity are controlled, and the rete compactness of preparation is good, cohesive force strong and high purity.
Five oxidation three titanium layers that the present invention is coated with on the substrate of hand-set lid, silicon dioxide layer and metal level can filter 23 more than 3% harmful blue light effectively, metal level can also promote the definition of hand-set lid effectively simultaneously, definition and verity for vision have good contribution, by the filtration of harmful blue light can effectively be alleviated visual fatigue, and high rigidity layer can significantly improve the wearability of hand-set lid.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is described in further details:
Fig. 1 is the exploded view of the wear-resistant mobile phone cover plate of filter blue light of the present invention.
Detailed description of the invention
As it is shown in figure 1, the present invention includes substrate 1, the outer surface of substrate 1 is sequentially provided with first rete the 2, second rete 3, third membrane layer 4 and the 4th rete 5 from the inside to surface, and the first rete 2 is five oxidation three titanium layers, and the thickness of the first rete 2 is 10-100nm; Second rete 3 is silicon dioxide layer, and the thickness of the second rete 3 is 50-100nm; Third membrane layer 4 is metal level, and the thickness of third membrane layer 4 is 5-20nm; 4th rete 5 is high rigidity layer, and the thickness of the 4th rete 5 is 10-50mm.
Wherein, the film material of metal level is gold, silver, platinum, neodymium, copper, zinc or nickel, and is deposited with molding by electron gun. The film material of metal level can also be billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, and is deposited with molding by electron gun.
The film material of high rigidity layer is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, and is deposited with molding by electron gun.
It addition, substrate 1 is resin or glass ware forming.
Embodiment 1, when the substrate 1 of hand-set lid is resin forming, the manufacture method of this hand-set lid specifically includes following steps:
1) outer surface of substrate 1 is carried out;
2) outer surface of substrate 1 is carried out plated film;
, plate the first rete 2:
Vacuum in vacuum coating cabin is adjusted to more than or equal to 5.0 �� 10-3Handkerchief, and control the temperature in vacuum coating cabin and be 50-70 DEG C, electron gun is adopted to bombard the film material of the first rete 2, it is deposited on the outer surface of substrate 1 with nanoscale molecular form after the film material evaporation of the first rete 2, the speed simultaneously controlling the first rete evaporation is 2.5/S, first rete 2 ultimately form after thickness be 10-100nm, wherein the film material of the first rete 2 is five oxidation Tritanium/Trititaniums, formed five oxidation three titanium layers;
B, plate the second rete 3:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, electron gun is adopted to bombard the film material of the second rete 3, the surface being deposited in above-mentioned steps the first rete 2 with nanoscale molecular form after the film material evaporation of the second rete 3, the speed simultaneously controlling the second rete evaporation is 7/S, second rete 3 ultimately form after thickness be 50-100nm, wherein the film material of the second rete 3 is silicon dioxide, formed silicon dioxide layer;
C, plating third membrane layer 4:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, adopt the film material of electron gun bombardment third membrane layer 4, the surface being deposited in above-mentioned steps B the second rete 3 with nanoscale molecular form after the film material evaporation of third membrane layer 4, the speed simultaneously controlling third membrane layer evaporation is 1/S, third membrane layer 4 ultimately form after thickness be 5-20nm, wherein the film material of third membrane layer 4 is gold, silver, platinum, neodymium, copper, zinc, nickel, billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, forms metal level;
D, plating the 4th rete 5:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, adopt the film material of electron gun bombardment the 4th rete 5, the surface being deposited in above-mentioned steps C third membrane layer with nanoscale molecular form after the film material evaporation of the 4th rete 5, the speed simultaneously controlling the 4th rete evaporation is 7/S, 4th rete 5 ultimately form after thickness be 10-50nm, wherein the film material of the 4th rete 5 is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, formed high rigidity layer.
In step 1), the cleaning tool body method of substrate 1 outer surface is as follows: substrate 1 is placed in vacuum chamber, the outer surface 3 minutes of substrate 1 is bombarded with ion gun.
Being 2-4hrs by the adhesive force when subzero 20 DEG C of each rete on the hand-set lid that said method prepares, the adhesive force when 80 DEG C is 2-4hrs, has very strong adhesive ability, and the compactness of each rete is good simultaneously, high purity. And, this hand-set lid can filter 23 more than 3% harmful blue light effectively, and overall definition, definition and verity for vision have good contribution, by the filtration of harmful blue light can effectively be alleviated visual fatigue. Meanwhile, this hand-set lid has higher wearability.
Embodiment 2, when the substrate 1 of hand-set lid is glass ware forming, the manufacture method of this hand-set lid specifically includes following steps:
1) outer surface of substrate 1 is carried out;
2) outer surface of substrate 1 is carried out plated film;
, plate the first rete 2:
Vacuum in vacuum coating cabin is adjusted to more than or equal to 5.0 �� 10-3Handkerchief, and control the temperature in vacuum coating cabin and be 200-300 DEG C, electron gun is adopted to bombard the film material of the first rete 2, it is deposited on the outer surface of substrate 1 with nanoscale molecular form after the film material evaporation of the first rete 2, the speed simultaneously controlling the first rete evaporation is 2.5/S, first rete 2 ultimately form after thickness be 10-100nm, wherein the film material of the first rete 2 is five oxidation Tritanium/Trititaniums, formed five oxidation three titanium layers;
B, plate the second rete 3:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, electron gun is adopted to bombard the film material of the second rete 3, the surface being deposited in above-mentioned steps the first rete 2 with nanoscale molecular form after the film material evaporation of the second rete 3, the speed simultaneously controlling the second rete evaporation is 7/S, second rete 3 ultimately form after thickness be 50-100nm, wherein the film material of the second rete 3 is silicon dioxide, formed silicon dioxide layer;
C, plating third membrane layer 4:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, adopt the film material of electron gun bombardment third membrane layer 4, the surface being deposited in above-mentioned steps B the second rete 3 with nanoscale molecular form after the film material evaporation of third membrane layer 4, the speed simultaneously controlling third membrane layer evaporation is 1/S, third membrane layer 4 ultimately form after thickness be 5-20nm, wherein the film material of third membrane layer 4 is gold, silver, platinum, neodymium, copper, zinc, nickel, billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, forms metal level;
D, plating the 4th rete 5:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, adopt the film material of electron gun bombardment the 4th rete 5, the surface being deposited in above-mentioned steps C third membrane layer with nanoscale molecular form after the film material evaporation of the 4th rete 5, the speed simultaneously controlling the 4th rete evaporation is 7/S, 4th rete 5 ultimately form after thickness be 10-50nm, wherein the film material of the 4th rete 5 is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, formed high rigidity layer.
In step 1), the cleaning tool body method of substrate 1 outer surface is as follows: substrate 1 is placed in vacuum chamber, outer surface 5-10 minute of substrate 1 is bombarded with ion gun.
Being 6-9hrs by the adhesive force when subzero 20 DEG C of each rete on the hand-set lid that said method prepares, the adhesive force when 80 DEG C is 6-9hrs, has very strong adhesive ability, and the compactness of each rete is good simultaneously, high purity. And, this hand-set lid can filter 23 more than 3% harmful blue light effectively, and overall definition, definition and verity for vision have good contribution, by the filtration of harmful blue light can effectively be alleviated visual fatigue. Meanwhile, this hand-set lid has higher wearability.

Claims (9)

1. the wear-resistant mobile phone cover plate of a filter blue light, including substrate, it is characterized in that: the outer surface of described substrate is sequentially provided with the first rete, the second rete, third membrane layer and the 4th rete from the inside to surface, described first rete is five oxidation three titanium layers, and the thickness of the first rete is 10-100nm; Described second rete is silicon dioxide layer, and the thickness of the second rete is 50-100nm; Third membrane layer is metal level, and the thickness of third membrane layer is 5-20nm; Described 4th rete is high rigidity layer, and the thickness of the 4th rete is 10-50mm.
2. the wear-resistant mobile phone cover plate of a kind of filter blue light according to claim 1, it is characterised in that: the film material of described metal level is gold, silver, platinum, neodymium, copper, zinc or nickel, and is deposited with molding by electron gun.
3. the wear-resistant mobile phone cover plate of a kind of filter blue light according to claim 1, it is characterised in that: the film material of described metal level is billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, and is deposited with molding by electron gun.
4. the wear-resistant mobile phone cover plate of a kind of filter blue light according to claim 1, it is characterised in that: the film material of described high rigidity layer is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, and is deposited with molding by electron gun.
5. the wear-resistant mobile phone cover plate of a kind of filter blue light according to claim 1, it is characterised in that: described substrate is resin or glass ware forming.
6. the manufacture method of hand-set lid according to claim 5, it is characterised in that: when the substrate of described hand-set lid is resin forming, described manufacture method specifically includes following steps:
1) outer surface of substrate is carried out;
2) outer surface of substrate is carried out plated film;
, plate the first rete:
Vacuum in vacuum coating cabin is adjusted to more than or equal to 5.0 �� 10-3Handkerchief, and control the temperature in vacuum coating cabin and be 50-70 DEG C, electron gun is adopted to bombard the film material of the first rete, it is deposited on the outer surface of substrate with nanoscale molecular form after the film material evaporation of the first rete, the speed simultaneously controlling the first rete evaporation is 2.5/S, first rete ultimately form after thickness be 10-100nm, wherein the film material of the first rete is five oxidation Tritanium/Trititaniums, formed five oxidation three titanium layers;
B, plate the second rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, electron gun is adopted to bombard the film material of the second rete, the surface being deposited in above-mentioned steps the first rete with nanoscale molecular form after the film material evaporation of the second rete, the speed simultaneously controlling the second rete evaporation is 7/S, second rete ultimately form after thickness be 50-100nm, wherein the film material of the second rete is silicon dioxide, formed silicon dioxide layer;
C, plating third membrane layer:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, adopt the film material of electron gun bombardment third membrane layer, the surface being deposited in above-mentioned steps B the second rete with nanoscale molecular form after the film material evaporation of third membrane layer, the speed simultaneously controlling third membrane layer evaporation is 1/S, third membrane layer ultimately form after thickness be 5-20nm, wherein the film material of third membrane layer is gold, silver, platinum, neodymium, copper, zinc, nickel, billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, forms metal level;
D, plating the 4th rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 50-70 DEG C, adopt the film material of electron gun bombardment the 4th rete, the surface being deposited in above-mentioned steps C third membrane layer with nanoscale molecular form after the film material evaporation of the 4th rete, the speed simultaneously controlling the 4th rete evaporation is 7/S, 4th rete ultimately form after thickness be 10-50nm, wherein the film material of the 4th rete is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, formed high rigidity layer.
7. the manufacture method of the wear-resistant mobile phone cover plate of a kind of filter blue light according to claim 6, it is characterized in that: in described step 1), the concrete grammar that outer surface of substrate is cleaned is as follows: be placed in vacuum chamber by substrate, bombards the outer surface 3 minutes of substrate with ion gun.
8. the manufacture method of hand-set lid according to claim 5, it is characterised in that: when the substrate of described hand-set lid is glass ware forming, described manufacture method specifically includes following steps:
1) outer surface of substrate is carried out;
2) outer surface of substrate is carried out plated film;
, plate the first rete:
Vacuum in vacuum coating cabin is adjusted to more than or equal to 5.0 �� 10-3Handkerchief, and control the temperature in vacuum coating cabin and be 200-300 DEG C, electron gun is adopted to bombard the film material of the first rete, it is deposited on the outer surface of substrate with nanoscale molecular form after the film material evaporation of the first rete, the speed simultaneously controlling the first rete evaporation is 2.5/S, first rete ultimately form after thickness be 10-100nm, wherein the film material of the first rete is five oxidation Tritanium/Trititaniums, formed five oxidation three titanium layers;
B, plate the second rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, electron gun is adopted to bombard the film material of the second rete, the surface being deposited in above-mentioned steps the first rete with nanoscale molecular form after the film material evaporation of the second rete, the speed simultaneously controlling the second rete evaporation is 7/S, second rete ultimately form after thickness be 50-100nm, wherein the film material of the second rete is silicon dioxide, formed silicon dioxide layer;
C, plating third membrane layer:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, adopt the film material of electron gun bombardment third membrane layer, the surface being deposited in above-mentioned steps B the second rete with nanoscale molecular form after the film material evaporation of third membrane layer, the speed simultaneously controlling third membrane layer evaporation is 1/S, third membrane layer ultimately form after thickness be 5-20nm, wherein the film material of third membrane layer is gold, silver, platinum, neodymium, copper, zinc, nickel, billon, silver alloy, platinum alloy, neodymium alloy, copper alloy, kirsite or nickel alloy, forms metal level;
D, plating the 4th rete:
Keep the vacuum in vacuum coating cabin more than or equal to 5.0 �� 10-3Handkerchief, it is maintained with the temperature in vacuum coating cabin and is 200-300 DEG C, adopt the film material of electron gun bombardment the 4th rete, the surface being deposited in above-mentioned steps C third membrane layer with nanoscale molecular form after the film material evaporation of the 4th rete, the speed simultaneously controlling the 4th rete evaporation is 7/S, 4th rete ultimately form after thickness be 10-50nm, wherein the film material of the 4th rete is aluminium sesquioxide, zirconium oxide, silica crystals or silicon monoxide crystal, formed high rigidity layer.
9. the manufacture method of the wear-resistant mobile phone cover plate of a kind of filter blue light according to claim 8, it is characterized in that: in described step 1), the concrete grammar that outer surface of substrate is cleaned is as follows: be placed in vacuum chamber by substrate, bombards outer surface 5-10 minute of substrate with ion gun.
CN201511029263.6A 2015-12-31 2015-12-31 Wear-resisting cell phone cover plate for blue light filtering and manufacturing method thereof Pending CN105629353A (en)

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Application Number Priority Date Filing Date Title
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008032874A (en) * 2006-07-27 2008-02-14 Epson Toyocom Corp Antireflection film, optical low-pass filter, solid state image sensor, and digital still camera
CN103439802A (en) * 2013-09-04 2013-12-11 杏晖光学(厦门)有限公司 Manufacturing method for blue-light resistant lens
CN103984045A (en) * 2014-05-30 2014-08-13 奥特路(漳州)光学科技有限公司 Mobile phone screen cover plate preventing blue light and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008032874A (en) * 2006-07-27 2008-02-14 Epson Toyocom Corp Antireflection film, optical low-pass filter, solid state image sensor, and digital still camera
CN103439802A (en) * 2013-09-04 2013-12-11 杏晖光学(厦门)有限公司 Manufacturing method for blue-light resistant lens
CN103984045A (en) * 2014-05-30 2014-08-13 奥特路(漳州)光学科技有限公司 Mobile phone screen cover plate preventing blue light and manufacturing method thereof

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