CN105613524A - Environment-friendly and multi-effect biopesticide for vegetable planting - Google Patents

Environment-friendly and multi-effect biopesticide for vegetable planting Download PDF

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Publication number
CN105613524A
CN105613524A CN201510973009.5A CN201510973009A CN105613524A CN 105613524 A CN105613524 A CN 105613524A CN 201510973009 A CN201510973009 A CN 201510973009A CN 105613524 A CN105613524 A CN 105613524A
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Prior art keywords
parts
friendly
biological pesticide
growing vegetables
environment
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CN201510973009.5A
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Chinese (zh)
Inventor
曹先艳
王文峰
施亮
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Dong Xun Bio Tech Ltd Granary
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Dong Xun Bio Tech Ltd Granary
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Priority to CN201510973009.5A priority Critical patent/CN105613524A/en
Publication of CN105613524A publication Critical patent/CN105613524A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides an environment-friendly and multi-effect biopesticide for vegetable planting. The biopesticide comprises the constituents as follows: in parts by weight, 10-20 parts of nicotine, 20-30 parts of azadirachtin, 20-30 parts of carvacrol, 10-20 parts of brassinolide, 1-5 parts of terpilenol, 5-10 parts of a surfactant, 1-5 parts of a defoamer, 1-5 parts of an antifreeze agent, 1-5 parts of a thickener, 0.1-1 parts of a preservative, 1-5 parts of a dispersant, 5-10 parts of an emulgator and 100-200 parts of water. The biopesticide has the advantages of reasonable constituent composition and matching, various rich nutrient preparations effective for the vegetables, environment-friendliness, no environment pollution after sprayed, low cost and good economic benefit.

Description

A kind of growing vegetables environment-friendly and green multiple-effect biological pesticide
Technical field
The present invention relates to a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide.
Background technology
Biological pesticide (Biologicalpesticide) refers to and utilizes biological living (fungus, antibacterial, insect viruses, genetically modified organism, natural enemy etc.) or its metabolite (pheromone, auxin, naphthalene acetic acid, 2,4-D etc.) preparation killed or suppress is carried out for agricultural pest. Biological pesticide, also known as natural pesticide, means and non-chemically synthesizes, and from natural chemical substance or life entity, and has the effect of sterilization pesticide and insecticide pesticide. Biological pesticide includes the microorganisms such as the sick pathogenic nematode of worm, antibacterial and virus, botanical derivative and insecticide pheromones etc. Biological pesticide plays the part of important role in integration Pest Management system (IPM) that organic agriculture uses.
As commodity, before biological pesticide the earliest can trace back to more than 200 year, just there is plant pesticide nicotine. Before the forties in 20th century, the biological pesticide such as Nicotiana tabacum L., Radix seu Caulis Derridis Trifoliatae, Pyrethrum, Colophonium becomes the main body in market. Occurring in that the organochlorine pesticide such as Gamma Hexaochlorocyclohexane, DDT from early 1940s, occur in that the organophosphorus pesticides such as parathion after World War II, the beginning of the fifties, carbamate insecticides came out, and made vegetal biological pesticide be replaced gradually. Epoch hence into synthetic organic pesticide. In the process of synthetic organic pesticide development, another kind of biological pesticide-microbial pesticide is quietly given birth to. Gibberellins is microbial pesticide commodity the earliest. Early 1950s produces in a large number. 60 ~ seventies of 20th century, toxicity problem due to organic mercury, organo-arsenic, particularly in Japan, the minamata disease that organomercurial fungicide causes has become " top news " at that time, for this, with Japan for representative, worldwide start the exploitation upsurge of one microbial pesticide, and had a collection of sterilization antibiotic to arise at the historic moment. As a collection of agricultural antibiotic such as kasugarnycin (kasugarnycin), Polyoxin, jingganmycin have put into market, become an important ingredient in pesticide field. To the later stage seventies, due to the successful exploitation of pyrethroid insecticides, the restriction of technological means in addition, make the research of microbial pesticide, exploitation once lower the temperature. To the nineties, along with the mankind are more and more higher to environmental requirement, making the difficulty that chemical pesticide is developed increasing, development cost are more and more expensive, and success rate is also more and more lower. And the development cost of biological pesticide are relatively much lower; biological pesticide comes from nature simultaneously; the compatibility of environment is high; people and animals are safer; in addition microbe-derived extensively, therefore, people are while as possible exploitation chemical pesticide; also biotechnology is actively used to be engaged in the research and development of the biological pesticides such as microorganism, including using the genetic engineering means as crop protection. From then on, the whole world has started again the exploitation upsurge of biological sky, including using biological pesticide as lead compound, do not developed chemical pesticide by structure of modification. At present, biological pesticide is developed with the speed of every annual value of production rising 10 ~ 20%, and biological pesticide is more and more noticeable.
For biological pesticide, domestic at present it is primarily present following patent documentation:
Patent publication No.: CN103828855A, disclose a kind of environmental protection Chinese herbal medicine biological agricultural chemical insecticide, it is made up of the composition of following parts by weight: synergist 1-10 part, Herba Taraxaci 5-20 part, Herba Portulacae 4-10 part, Fructus Xanthii 6-9 part, Pericarpium Granati 10-15 part, Folium Artemisiae Argyi 11-15 part, Fructus Cannabis 20-30 part, Radix Chloranthi Serrati 10-20 part, Hemerocallis citrina Baroni height 15-20 part, Nicotiana tabacum L. 20-30 part, Radix Phytolaccae 10-15 part, Aconitum carmichjaelii Debx. 10-20 part, Herba Houttuyniae 12-18 part, Herba Andrographis 5-18 part, Camphora 4-10 part, Radix Tripterygii Wilfordii 50-70 part, water 100-150 part. One high efficiency of the present invention, specific aim, the feature of environmental protection, without secondary toxicity, noresidue, pollution-free, keep ecological balance, non-harmful novel agrochemical, be realize the ecological agriculture, green ecological agricultural, the important guarantee of green enterprises, there are bright prospects. But, this patent employs too much Chinese medicine ingredients, owing to Chinese medicine belongs to the one of medical material, its acquisition is also required to certain cost, therefore virtually improves manufacture production cost, and is unfavorable for promoting.
Summary of the invention
For solving above-mentioned Problems existing, it is an object of the invention to provide a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide, described biological pesticide, become to be grouped into, arrange in pairs or groups rationally, rich in the effective multiple nutrients preparation of vegetable, and environmentally friendly, do not result in environmental pollution after sprinkling, cheap for manufacturing cost, good in economic efficiency.
For reaching above-mentioned purpose, the technical scheme is that
A kind of growing vegetables environment-friendly and green multiple-effect biological pesticide, described biological pesticide includes the composition of following weight portion: nicotine: 10 ~ 20 parts, nimbin: 20 ~ 30 parts, carvacrol: 20 ~ 30 parts, brassin lactones: 10 ~ 20 parts, terpineol: 1 ~ 5 part, surfactant: 5 ~ 10 parts, defoamer: 1 ~ 5 part, antifreeze: 1 ~ 5 part, thickening agent: 1 ~ 5 part, preservative: 0.1 ~ 1 part, dispersant: 1 ~ 5 part, emulsifying agent: 5 ~ 10 parts, water: 100 ~ 200 parts.
Further, described feedstuff includes the composition of following weight portion: nicotine: 10 ~ 15 parts, nimbin: 25 ~ 30 parts, carvacrol: 20 ~ 25 parts, brassin lactones: 10 ~ 13 parts, terpineol: 1 ~ 3 part, surfactant: 5 ~ 8 parts, defoamer: 1 ~ 3 part, antifreeze: 3 ~ 5 parts, thickening agent: 2 ~ 5 parts, preservative: 0.1 ~ 1 part, dispersant: 2 ~ 3 parts, emulsifying agent: 7 ~ 10 parts, water: 100 ~ 150 parts.
Preferably, described feedstuff includes the composition of following weight portion: nicotine: 13 parts, nimbin: 25 parts, carvacrol: 20 parts, brassin lactones: 12 parts, terpineol: 2 parts, surfactant: 6 parts, defoamer: 2 parts, antifreeze: 4 parts, thickening agent: 3 parts, preservative: 0.5 part, dispersant: 3 parts, emulsifying agent: 8 parts, water: 150 parts.
Separately, it is characterised in that described surfactant is castor oil acid ester polymer, dibenzyl phenol polyethenoxy ether or polyoxyethylene poly-oxygen propylene aether block copolymer.
Separately having, described thickening agent is polydimethylsiloxane or polyvinyl alcohol.
Again, described preservative is 2-bromo-2-nitro-1,3-propylene glycol or sodium benzoate.
Further, described dispersant is selected from one or more in lignosulfonates, naphthalenesulfonic acid-formaldehyde condensate, nekal formaldehyde condensation products, aliphatic alcohol polyoxyethylene sulfonate, alkylphenol polyoxyethylene sulfonate, alkylphenol polyoxyethylene phosphate, dodecylbenzene sodium sulfonate, 1-naphthalene sulfonic aicd sodium salt.
And, described defoamer is silicone oil, bubble enemy, capric acid or amide.
Separately, described emulsifying agent takes the one in polyoxyethylene ether, Nonyl pheno base ether, three phenethyl polyoxyethylene polyoxypropylene base ethers, aliphatic alcohol polyethenoxy base ether selected from calcium dodecyl benzene sulfonate, three phenethyl polyoxyethylene ethers, Diphenethyl polyoxyethylene ether, Oleum Ricini.
The beneficial effects of the present invention is:
Described biological pesticide, becomes to be grouped into, arranges in pairs or groups rationally, rich in the effective multiple nutrients preparation of vegetable, and environmentally friendly, do not result in environmental pollution after sprinkling, cheap for manufacturing cost, good in economic efficiency.
Detailed description of the invention
A kind of growing vegetables environment-friendly and green multiple-effect biological pesticide of the present invention, described biological pesticide includes the composition of following weight portion: nicotine: 10 ~ 20 parts, nimbin: 20 ~ 30 parts, carvacrol: 20 ~ 30 parts, brassin lactones: 10 ~ 20 parts, terpineol: 1 ~ 5 part, surfactant: 5 ~ 10 parts, defoamer: 1 ~ 5 part, antifreeze: 1 ~ 5 part, thickening agent: 1 ~ 5 part, preservative: 0.1 ~ 1 part, dispersant: 1 ~ 5 part, emulsifying agent: 5 ~ 10 parts, water: 100 ~ 200 parts.
Further, described feedstuff includes the composition of following weight portion: nicotine: 10 ~ 15 parts, nimbin: 25 ~ 30 parts, carvacrol: 20 ~ 25 parts, brassin lactones: 10 ~ 13 parts, terpineol: 1 ~ 3 part, surfactant: 5 ~ 8 parts, defoamer: 1 ~ 3 part, antifreeze: 3 ~ 5 parts, thickening agent: 2 ~ 5 parts, preservative: 0.1 ~ 1 part, dispersant: 2 ~ 3 parts, emulsifying agent: 7 ~ 10 parts, water: 100 ~ 150 parts.
Preferably, described feedstuff includes the composition of following weight portion: nicotine: 13 parts, nimbin: 25 parts, carvacrol: 20 parts, brassin lactones: 12 parts, terpineol: 2 parts, surfactant: 6 parts, defoamer: 2 parts, antifreeze: 4 parts, thickening agent: 3 parts, preservative: 0.5 part, dispersant: 3 parts, emulsifying agent: 8 parts, water: 150 parts.
Separately, it is characterised in that described surfactant is castor oil acid ester polymer, dibenzyl phenol polyethenoxy ether or polyoxyethylene poly-oxygen propylene aether block copolymer.
Separately having, described thickening agent is polydimethylsiloxane or polyvinyl alcohol.
Again, described preservative is 2-bromo-2-nitro-1,3-propylene glycol or sodium benzoate.
Further, described dispersant is selected from one or more in lignosulfonates, naphthalenesulfonic acid-formaldehyde condensate, nekal formaldehyde condensation products, aliphatic alcohol polyoxyethylene sulfonate, alkylphenol polyoxyethylene sulfonate, alkylphenol polyoxyethylene phosphate, dodecylbenzene sodium sulfonate, 1-naphthalene sulfonic aicd sodium salt.
And, described defoamer is silicone oil, bubble enemy, capric acid or amide.
Separately, described emulsifying agent takes the one in polyoxyethylene ether, Nonyl pheno base ether, three phenethyl polyoxyethylene polyoxypropylene base ethers, aliphatic alcohol polyethenoxy base ether selected from calcium dodecyl benzene sulfonate, three phenethyl polyoxyethylene ethers, Diphenethyl polyoxyethylene ether, Oleum Ricini.
Wherein, 1 various embodiments of the present invention of table provide a kind of growing vegetables environment-friendly and green multiple-effect biological farm chemical ingredients list.
Table 1(unit: weight portion)
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Nicotine 13 15 10 20 18
Nimbin 25 30 20 23 28
Carvacrol 20 25 30 28 23
Brassin lactones 12 18 15 20 16
Terpineol 2 3 4 1 5
Surfactant 6 8 5 7 10
Defoamer 2 3 5 4 1
Antifreeze 4 3 1 5 2
Thickening agent 3 1 2 4 5
Preservative 0.5 0.8 0.1 0.3 1
Dispersant 3 2 1 4 5
Emulsifying agent 8 7 5 6 10
Water 150 130 100 180 200
Provided by the present invention provided a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide, becomes to be grouped into, arranges in pairs or groups rationally, rich in the effective multiple nutrients preparation of vegetable, and it is environmentally friendly, environmental pollution is not resulted in after sprinkling, cheap for manufacturing cost, good in economic efficiency.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted. Although the present invention being described in detail with reference to preferred embodiment, it will be understood by those within the art that, the technical scheme of invention can being modified or equivalent replacement, without deviating from the scope of technical solution of the present invention, it all should be encompassed in scope of the presently claimed invention.

Claims (9)

1. a growing vegetables environment-friendly and green multiple-effect biological pesticide, it is characterised in that described biological pesticide includes the composition of following weight portion: nicotine: 10 ~ 20 parts, nimbin: 20 ~ 30 parts, carvacrol: 20 ~ 30 parts, brassin lactones: 10 ~ 20 parts, terpineol: 1 ~ 5 part, surfactant: 5 ~ 10 parts, defoamer: 1 ~ 5 part, antifreeze: 1 ~ 5 part, thickening agent: 1 ~ 5 part, preservative: 0.1 ~ 1 part, dispersant: 1 ~ 5 part, emulsifying agent: 5 ~ 10 parts, water: 100 ~ 200 parts.
2. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to claim 1, it is characterised in that described feedstuff includes the composition of following weight portion: nicotine: 10 ~ 15 parts, nimbin: 25 ~ 30 parts, carvacrol: 20 ~ 25 parts, brassin lactones: 10 ~ 13 parts, terpineol: 1 ~ 3 part, surfactant: 5 ~ 8 parts, defoamer: 1 ~ 3 part, antifreeze: 3 ~ 5 parts, thickening agent: 2 ~ 5 parts, preservative: 0.1 ~ 1 part, dispersant: 2 ~ 3 parts, emulsifying agent: 7 ~ 10 parts, water: 100 ~ 150 parts.
3. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to claim 1, it is characterised in that described feedstuff includes the composition of following weight portion: nicotine: 13 parts, nimbin: 25 parts, carvacrol: 20 parts, brassin lactones: 12 parts, terpineol: 2 parts, surfactant: 6 parts, defoamer: 2 parts, antifreeze: 4 parts, thickening agent: 3 parts, preservative: 0.5 part, dispersant: 3 parts, emulsifying agent: 8 parts, water: 150 parts.
4. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to any one of claim 1 ~ 3, it is characterized in that, described surfactant is castor oil acid ester polymer, dibenzyl phenol polyethenoxy ether or polyoxyethylene poly-oxygen propylene aether block copolymer.
5. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to any one of claim 1 ~ 3, it is characterised in that described thickening agent is polydimethylsiloxane or polyvinyl alcohol.
6. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to any one of claim 1 ~ 3, it is characterised in that described preservative is 2-bromo-2-nitro-1,3-propylene glycol or sodium benzoate.
7. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to any one of claim 1 ~ 3, it is characterized in that, described dispersant is selected from one or more in lignosulfonates, naphthalenesulfonic acid-formaldehyde condensate, nekal formaldehyde condensation products, aliphatic alcohol polyoxyethylene sulfonate, alkylphenol polyoxyethylene sulfonate, alkylphenol polyoxyethylene phosphate, dodecylbenzene sodium sulfonate, 1-naphthalene sulfonic aicd sodium salt.
8. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to any one of claim 1 ~ 3, it is characterised in that described defoamer is silicone oil, bubble enemy, capric acid or amide.
9. a kind of growing vegetables environment-friendly and green multiple-effect biological pesticide according to any one of claim 1 ~ 3, it is characterized in that, described emulsifying agent takes the one in polyoxyethylene ether, Nonyl pheno base ether, three phenethyl polyoxyethylene polyoxypropylene base ethers, aliphatic alcohol polyethenoxy base ether selected from calcium dodecyl benzene sulfonate, three phenethyl polyoxyethylene ethers, Diphenethyl polyoxyethylene ether, Oleum Ricini.
CN201510973009.5A 2015-12-23 2015-12-23 Environment-friendly and multi-effect biopesticide for vegetable planting Pending CN105613524A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107996625A (en) * 2017-12-19 2018-05-08 青岛日晟源作物营养有限公司 A kind of plant growth regulator of high-selenium corn utilization rate
CN115093294A (en) * 2022-06-16 2022-09-23 贵州省生物技术研究所(贵州省生物技术重点实验室、贵州省马铃薯研究所、贵州省食品加工研究所) Microbial pesticide preparation for plant protection and growth regulation
IT202100021707A1 (en) * 2021-08-10 2023-02-10 Sipcam Oxon S P A Phytosanitary associations including carvacrol, compositions and their use.
IT202100021710A1 (en) * 2021-08-10 2023-02-10 Sipcam Oxon S P A Emulsifiable concentrated composition comprising carvacrol and/or thymol.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640256A (en) * 2004-01-13 2005-07-20 西安近代化学研究所 Mixed biological pesticide containing nimbin
CN103749549A (en) * 2014-01-14 2014-04-30 浙江农林大学 Plutella xylostella sex pheromone chemical communication disrupter
CN104642317A (en) * 2013-11-20 2015-05-27 成都新朝阳作物科学有限公司 Plant immunizing agent and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640256A (en) * 2004-01-13 2005-07-20 西安近代化学研究所 Mixed biological pesticide containing nimbin
CN104642317A (en) * 2013-11-20 2015-05-27 成都新朝阳作物科学有限公司 Plant immunizing agent and application thereof
CN103749549A (en) * 2014-01-14 2014-04-30 浙江农林大学 Plutella xylostella sex pheromone chemical communication disrupter

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107996625A (en) * 2017-12-19 2018-05-08 青岛日晟源作物营养有限公司 A kind of plant growth regulator of high-selenium corn utilization rate
IT202100021707A1 (en) * 2021-08-10 2023-02-10 Sipcam Oxon S P A Phytosanitary associations including carvacrol, compositions and their use.
IT202100021710A1 (en) * 2021-08-10 2023-02-10 Sipcam Oxon S P A Emulsifiable concentrated composition comprising carvacrol and/or thymol.
WO2023017427A1 (en) * 2021-08-10 2023-02-16 Sipcam Oxon S.P.A. Emulsifiable concentrated composition comprising carvacrol
WO2023017428A1 (en) * 2021-08-10 2023-02-16 Sipcam Oxon S.P.A. Phytosanitary combinations comprising carvacrol, compositions and their use
CN115093294A (en) * 2022-06-16 2022-09-23 贵州省生物技术研究所(贵州省生物技术重点实验室、贵州省马铃薯研究所、贵州省食品加工研究所) Microbial pesticide preparation for plant protection and growth regulation

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