CN105597688B - It is a kind of to be used to remove nicotine, the adsorbent of smoke and preparation and application - Google Patents
It is a kind of to be used to remove nicotine, the adsorbent of smoke and preparation and application Download PDFInfo
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- CN105597688B CN105597688B CN201610135060.3A CN201610135060A CN105597688B CN 105597688 B CN105597688 B CN 105597688B CN 201610135060 A CN201610135060 A CN 201610135060A CN 105597688 B CN105597688 B CN 105597688B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/44—Materials comprising a mixture of organic materials
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
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Abstract
It is used to remove nicotine, the adsorbent of smoke and preparation and application the invention discloses a kind of, which includes the raw material of following parts by weight：80~120 parts of 15~25 parts of Sodium Polyacrylate, 40~60 parts of acrylic acid, 4~6 parts of sodium hydroxide, 3~5 parts of chitosan, 5~10 parts of sucrose stearate, 15~25 parts of pentaerythrite, 30~50 parts of ethyl acetate, 1~2 part of azodiisobutyronitrile, 1~5 part of citric acid, 3~6 parts of ethyl levulinate, 0.5~3 part of air freshener and water.Adsorbent provided by the invention can adsorb the nicotine of cigarette generation, tar, phenol, the harmful substance such as carbon monoxide rapidly, removing taste can also be removed at the same time, play the role of purifying air, reduce the harm that cigarette is brought to smoker and involuntary smoker, have a vast market prospect.
Description
Technical field
It is specifically a kind of to be used to remove nicotine, the adsorbent of smoke and preparation the present invention relates to sorbing material technical field
And application.
Background technology
Contain chemical substance known to kind more than 3800 in the smog discharged during cigarette combustion, wherein there are about 250 kinds has human body
Poison or carcinogenic substance, wherein mainly including tar, nicotine, carbon monoxide etc..Smoking becomes public hazards, the cause of " secondhand smoke, third hand cigarette "
Cancer rate is much higher than smoker.So-called " secondhand smoke " involuntary property smoking, cigarette smoking, i.e. suction point burning smoke indoors grass
When the material that is discharged with smog, be a kind of passive smoking mode, but be also harm most extensively, the room air of most serious
Pollution, is the great cause of death in the whole world.So-called " third hand cigarette ", refer to remain in after smoker's " swallowing clouds and blowing out fog " clothes, wall,
Blanket, furniture even the tobacco residue on the surface such as hair and skin, these residues can have several days, even several months in a few weeks.
Residue nicotine can produce tobacco specific nitrosamines with the nitrite reaction in air, and nitrosamine is most violent carcinogenic substance,
Open a window or open fan when smoking and outdoor smoking, all can not harm that is fully erased and taking precautions against " two, third hand cigarette ".
At present, the research for tar in tobacco, nicotine, carbon monoxide being reduced using adsorbent is reported, most common suction
Attached dose of active charcoal, macroporous absorbent resin, modified natural mineral etc..As 102613704 B of Chinese patent CN disclose a kind of gather
Vinylacetate adsorbs application of the resin on cigarette, is the energy by polyvinyl acetate adsorption resin addition in cigarette filter
Phenol release amount more than 25% in enough selectivity reducing cigarette main flumes, its additive amount is every 10~30mg of filter tip.It is described
Polyvinyl acetate adsorption resin is made by suspension polymerisation, and raw material composition is divinylbenzene, vinylacetate, pore
Agent, initiator, water, inorganic salts and dispersant；This material can effectively adsorb the harmful substance phenol in flue gas, and tar is released
High-volume it is basically unchanged or slightly reduces, while do not have a negative impact to the sucking quality of cigarette, so as to reaches selective reduction
The purpose of phenol release amount in cigarette smoke.Although the polyvinyl acetate adsorption resin that the invention provides can effectively reduce
The content of phenol in cigarette, but there is no suction-operated substantially for tar, nicotine, carbon monoxide, so as to limit in practice
Application.
103861443 B of Chinese patent CN disclose a kind of nicotine for air freshener and smoke tar distintegrant, institute
Stating nicotine disintegrant includes：Salicylic acid, phosphoric acid and oxalic acid, wherein, salicylic acid, phosphoric acid and oxalic acid mass ratio are 2：1 ：1 ；Institute
Stating smoke tar distintegrant includes：Neopelex, EDTA disodiums, Berol226, secondary alcohol polyoxyethylene ether, wherein ten
Dialkyl benzene sulfonic acids sodium, EDTA disodiums, Berol226, secondary alcohol polyoxyethylene ether mass ratio are 10：1 ：30 ：10.The cigarette
When alkali and smoke tar distintegrant are used for air freshener, wherein 100mL air fresheners contain：0.2~0.6g of nicotine disintegrant,
0.5~1.5g of smoke tar distintegrant, 67~69mL of edible ethanol 30mL, plant essence 0.7mL and distilled water.1 common cigarette
The usage amount of middle air freshener is 1~3mL.Nicotine provided by the invention, smoke tar distintegrant can destroy nicotine and cigarette rapidly
Tar, makes the harm of smoker and involuntary smoker's reduction to body.Addition distintegrant in cigarette, although can be so that cigarette
The decline of the harmful components such as alkali, tar content, but have to using the decline of flavor component as cost, so as to limit it in reality
Application in production.
The content of the invention
The present invention, which will provide one kind, can adsorb cigarette harmful-component and smoke rapidly, and will not reduce the absorption of cigarette fragrance
Agent.The adsorbent can reduce body harm of the cigarette to smoker and passive smoking, while can also purify air well,
Have a vast market prospect.
In order to achieve the above object, the technical solution adopted by the present invention is as follows：
It is a kind of to be used to remove nicotine, the adsorbent of smoke, include the raw material of following parts by weight：
15~25 parts of Sodium Polyacrylate, 40~60 parts of acrylic acid, 4~6 parts of sodium hydroxide, 3~5 parts of chitosan, sucrose are hard
5~10 parts of resin acid ester, 15~25 parts of pentaerythrite, 30~50 parts of ethyl acetate, 1~2 part of azodiisobutyronitrile, citric acid 1~5
Part, 3~6 parts of ethyl levulinate, 0.5~3 part of air freshener and 80~120 parts of water.
Preferably, air freshener described above includes one or both of Lavender and osmanthus concrete.
Above be used for remove nicotine, smoke adsorbent preparation method, comprise the following steps：
（1）Take 15~25 parts of Sodium Polyacrylate, 40~60 parts of acrylic acid, 4~6 parts of sodium hydroxide, 3~5 parts of chitosan, sugarcane
Sugared 5~10 parts of stearate, 15~25 parts of pentaerythrite, 30~50 parts of ethyl acetate, 1~2 part of azodiisobutyronitrile；By each original
Material adds blender, is warming up to 50~70 DEG C, and 1~2h is stirred under 100~500rpm rotating speeds, obtains oil phase；
（2）80~120 parts of 1~5 part of citric acid, 3~6 parts of ethyl levulinate, 0.5~3 part of air freshener and water are taken,
50~70 DEG C are warming up to, 10~15min is stirred in the case where rotating speed is 300~500rpm, obtains water phase；
（3）Under agitation, oil phase being added in water phase, stirred evenly, temperature is increased to 75~85 DEG C, isothermal reaction 4~
6h, then heats to 90~95 DEG C, and 2~3h of isothermal reaction, reaction terminates, and filtering, removes liquid phase, obtain spherical little particle；
（4）Spherical little particle is washed 2~4 times with 75~85 DEG C of hot water, then with 15~20h of ethanolic extraction, dry, pack
Or press molding obtains adsorbent.
The application of above-described adsorbent, is that adsorbent is put in ashtray or molten cup, adds suitable quantity of water, places and inhales
Cigarette place.
Compared with prior art, what the present invention obtained has the beneficial effect that：
1st, adsorbent provided by the invention can adsorb rapidly cigarette generation nicotine, tar, phenol, carbon monoxide etc. it is harmful
Material, while removing taste can also be removed, play the role of purifying air, reduce the danger that cigarette is brought to smoker and involuntary smoker
Evil.
2nd, the reference area of this adsorbent is big, the suction-operated to cigarette harmful matter is strong, and environmental protection, nontoxic, cost is low, system
Standby technique is simple, has society, ecology and economic benefit well.
3rd, adsorbent need to be only put in ashtray or molten cup by the application method of this adsorbent, add suitable quantity of water, placed and inhaled
Cigarette place can be used, and therefore, will not change the fragrance of cigarette, can meet the needs of smoker.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but is not limited to protection scope of the present invention.
Embodiment 1
It is a kind of to be used to remove nicotine, the adsorbent of smoke, include the raw material of following parts by weight：
15 parts of Sodium Polyacrylate, 50 parts of acrylic acid, 4 parts of sodium hydroxide, 3 parts of chitosan, 8 parts of sucrose stearate, season penta
15 parts of tetrol, 30 parts of ethyl acetate, 1 part of azodiisobutyronitrile, 1 part of citric acid, 3 parts of ethyl levulinate, Lavender 0.5
80 parts of part, 0.5 part of osmanthus concrete and water.
The preparation method of adsorbent, comprises the following steps：
（1）Take 15 parts of Sodium Polyacrylate, 50 parts of acrylic acid, 4 parts of sodium hydroxide, 3 parts of chitosan, 8 parts of sucrose stearate,
15 parts of pentaerythrite, 30 parts of ethyl acetate, 1 part of azodiisobutyronitrile；Each raw material is added into blender, is warming up to 50 DEG C,
1.5h is stirred under 500rpm rotating speeds, obtains oil phase；
（2）80 parts of 1 part of citric acid, 3 parts of ethyl levulinate, 0.5 part of Lavender, 0.5 part of osmanthus concrete and water are taken,
50 DEG C are warming up to, 15min is stirred in the case where rotating speed is 300rpm, obtains water phase；
（3）Under 300rpm stirrings, oil phase is added in water phase, is stirred evenly, temperature is increased to 75 DEG C, isothermal reaction
6h, then heats to 90 DEG C, and isothermal reaction 3h, reaction terminates, and filtering, removes liquid phase, obtain spherical little particle；
（4）Spherical little particle is washed 3 times with 75 DEG C of hot water, then with the ethanolic extraction 15h that mass concentration is 90%, it is dry,
Pack, up to adsorbent.
Embodiment 2
It is a kind of to be used to remove nicotine, the adsorbent of smoke, include the raw material of following parts by weight：
20 parts of Sodium Polyacrylate, 40 parts of acrylic acid, 5 parts of sodium hydroxide, 4 parts of chitosan, 5 parts of sucrose stearate, season penta
20 parts of tetrol, 40 parts of ethyl acetate, 1.5 parts of azodiisobutyronitrile, 2 parts of citric acid, 4 parts of ethyl levulinate, Lavender
0.5 part and 80 parts of water.
The preparation method of adsorbent, comprises the following steps：
（1）Take 20 parts of Sodium Polyacrylate, 40 parts of acrylic acid, 5 parts of sodium hydroxide, 4 parts of chitosan, 5 parts of sucrose stearate,
20 parts of pentaerythrite, 40 parts of ethyl acetate, 1.5 parts of azodiisobutyronitrile；Each raw material is added into blender, is warming up to 60 DEG C,
1h is stirred under 300rpm rotating speeds, obtains oil phase；
（2）80 parts of 2 parts of citric acid, 4 parts of ethyl levulinate, 0.5 part of Lavender and water are taken, is warming up to 60 DEG C,
Rotating speed is to stir 10min under 500rpm, obtains water phase；
（3）Under 500rpm stirrings, oil phase is added in water phase, is stirred evenly, temperature is increased to 80 DEG C, isothermal reaction
5h, then heats to 95 DEG C, and isothermal reaction 2.5h, reaction terminates, and filtering, removes liquid phase, obtain spherical little particle；
（4）Spherical little particle is washed 2 times with 80 DEG C of hot water, then with the ethanolic extraction 20h that mass concentration is 90%, it is dry,
Pack, up to adsorbent.
Embodiment 3
It is a kind of to be used to remove nicotine, the adsorbent of smoke, include the raw material of following parts by weight：
25 parts of Sodium Polyacrylate, 45 parts of acrylic acid, 6 parts of sodium hydroxide, 5 parts of chitosan, 7 parts of sucrose stearate, season penta
15 parts of tetrol, 50 parts of ethyl acetate, 2 parts of azodiisobutyronitrile, 4 parts of citric acid, 5 parts of ethyl levulinate, Lavender 1
100 parts of part, 1.5 parts of osmanthus concrete and water.
The preparation method of adsorbent, comprises the following steps：
（1）Take 25 parts of Sodium Polyacrylate, 45 parts of acrylic acid, 6 parts of sodium hydroxide, 5 parts of chitosan, 7 parts of sucrose stearate,
15 parts of pentaerythrite, 50 parts of ethyl acetate, 2 parts of azodiisobutyronitrile；Each raw material is added into blender, is warming up to 70 DEG C,
1h is stirred under 100rpm rotating speeds, obtains oil phase；
（2）100 parts of 4 parts of citric acid, 5 parts of ethyl levulinate, 1 part of Lavender, 1.5 parts of osmanthus concrete and water are taken,
70 DEG C are warming up to, 15min is stirred in the case where rotating speed is 500rpm, obtains water phase；
（3）Under 500rpm stirrings, oil phase is added in water phase, is stirred evenly, temperature is increased to 85 DEG C, isothermal reaction
4h, then heats to 90 DEG C, and isothermal reaction 3h, reaction terminates, and filtering, removes liquid phase, obtain spherical little particle；
（4）Spherical little particle is washed 3 times with 85 DEG C of hot water, then with the ethanolic extraction 18h that mass concentration is 90%, it is dry,
Press molding, up to adsorbent.
Embodiment 4
It is a kind of to be used to remove nicotine, the adsorbent of smoke, include the raw material of following parts by weight：
20 parts of Sodium Polyacrylate, 60 parts of acrylic acid, 5 parts of sodium hydroxide, 5 parts of chitosan, 10 parts of sucrose stearate, season penta
25 parts of tetrol, 45 parts of ethyl acetate, 1.5 parts of azodiisobutyronitrile, 5 parts of citric acid, 6 parts of ethyl levulinate, Lavender 1
120 parts of part, 2 parts of osmanthus concrete and water.
The preparation method of adsorbent, comprises the following steps：
（1）Take 20 parts of Sodium Polyacrylate, 60 parts of acrylic acid, 5 parts of sodium hydroxide, 5 parts of chitosan, sucrose stearate 10
Part, 25 parts of pentaerythrite, 45 parts of ethyl acetate, 1.5 parts of azodiisobutyronitrile；Each raw material is added into blender, is warming up to 65 DEG C,
2h is stirred under 300rpm rotating speeds, obtains oil phase；
（2）120 parts of 5 parts of citric acid, 6 parts of ethyl levulinate, 1 part of Lavender, 2 parts of osmanthus concrete and water are taken, is risen
Temperature stirs 15min in the case where rotating speed is 300rpm, obtains water phase to 65 DEG C；
（3）Under 300rpm stirrings, oil phase is added in water phase, is stirred evenly, temperature is increased to 80 DEG C, isothermal reaction
6h, then heats to 95 DEG C, and isothermal reaction 2h, reaction terminates, and filtering, removes liquid phase, obtain spherical little particle；
（4）Spherical little particle is washed 4 times with 80 DEG C of hot water, then with the ethanolic extraction 20h that mass concentration is 95%, it is dry,
Press molding, up to adsorbent.
The application method of adsorbent is described in above example 1-4：Adsorbent is put in ashtray or molten cup, is added suitable
Water is measured, places smoking place, you can the harmful substance such as the rapid nicotine for adsorbing cigarette generation, tar, phenol, carbon monoxide, together
When can also remove removing taste, play the role of purify air, have a vast market prospect.
Claims (4)
1. a kind of be used to remove nicotine, the adsorbent of smoke, it is characterised in that：Include the raw material of following parts by weight：
15~25 parts of Sodium Polyacrylate, 40~60 parts of acrylic acid, 4~6 parts of sodium hydroxide, 3~5 parts of chitosan, sucrose stearate
5~10 parts of ester, 15~25 parts of pentaerythrite, 30~50 parts of ethyl acetate, 1~2 part of azodiisobutyronitrile, 1~5 part of citric acid,
80~120 parts of 3~6 parts of ethyl levulinate, 0.5~3 part of air freshener and water.
It is 2. according to claim 1 a kind of for removing nicotine, the adsorbent of smoke, it is characterised in that：The air is clear
New agent includes one or both of Lavender and osmanthus concrete.
3. it is according to claim 1 it is a kind of be used for remove nicotine, smoke adsorbent preparation method, it is characterised in that：
Comprise the following steps：
Take 15~25 parts of Sodium Polyacrylate, 40~60 parts of acrylic acid, 4~6 parts of sodium hydroxide, 3~5 parts of chitosan, sucrose stearic
5~10 parts of acid esters, 15~25 parts of pentaerythrite, 30~50 parts of ethyl acetate, 1~2 part of azodiisobutyronitrile；Each raw material is added
Blender, is warming up to 50~70 DEG C, and 1~2h is stirred under 100~500rpm rotating speeds, obtains oil phase；
80~120 parts of 1~5 part of citric acid, 3~6 parts of ethyl levulinate, 0.5~3 part of air freshener and water are taken, is warming up to
50~70 DEG C, 10~15min is stirred in the case where rotating speed is 300~500rpm, obtains water phase；
Under agitation, oil phase is added in water phase, stirred evenly, temperature is increased to 75~85 DEG C, 4~6h of isothermal reaction, then
90~95 DEG C are warming up to, 2~3h of isothermal reaction, reaction terminates, and filtering, removes liquid phase, obtain spherical little particle；
Spherical little particle is washed 2~4 times with 75~85 DEG C of hot water, then with 15~20h of ethanolic extraction, dry, pack or pressurization
Shaping obtains adsorbent.
4. it is according to claim 1 it is a kind of be used for remove nicotine, smoke adsorbent application, it is characterised in that：It will inhale
Attached dose is put in ashtray or molten cup, adds suitable quantity of water, places smoking place.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610135060.3A CN105597688B (en) | 2016-03-10 | 2016-03-10 | It is a kind of to be used to remove nicotine, the adsorbent of smoke and preparation and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610135060.3A CN105597688B (en) | 2016-03-10 | 2016-03-10 | It is a kind of to be used to remove nicotine, the adsorbent of smoke and preparation and application |
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| Publication Number | Publication Date |
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| CN105597688A CN105597688A (en) | 2016-05-25 |
| CN105597688B true CN105597688B (en) | 2018-05-01 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108854339A (en) * | 2017-05-09 | 2018-11-23 | 江苏瑞丰科技实业有限公司 | It is a kind of efficiently to remove secondhand smoke spray |
| CN108393078A (en) * | 2018-03-28 | 2018-08-14 | 桂林良物造日用品有限公司 | A kind of adsorbent and preparation method removing removing taste |
| CN111375389A (en) * | 2020-03-20 | 2020-07-07 | 优品优家(深圳)科技有限公司 | Preparation method of smoke removing agent |
| CN111378210A (en) * | 2020-03-24 | 2020-07-07 | 安徽中烟工业有限责任公司 | Preparation method of ternary metal MOFs-chitosan composite material and application of ternary metal MOFs-chitosan composite material in reducing harm of cigarette smoke |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010044815A (en) * | 2001-03-28 | 2001-06-05 | 김종현 | A cigarette filter prepared from kittosan or kittosan fiber |
| CN102613704A (en) * | 2012-03-29 | 2012-08-01 | 中国烟草总公司郑州烟草研究院 | Application of polyvinyl acetate adsorption resin on cigarettes |
| CN103861443A (en) * | 2014-03-14 | 2014-06-18 | 郭涛 | Nicotine and tobacco tar decomposing agent for air freshener |
-
2016
- 2016-03-10 CN CN201610135060.3A patent/CN105597688B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010044815A (en) * | 2001-03-28 | 2001-06-05 | 김종현 | A cigarette filter prepared from kittosan or kittosan fiber |
| CN102613704A (en) * | 2012-03-29 | 2012-08-01 | 中国烟草总公司郑州烟草研究院 | Application of polyvinyl acetate adsorption resin on cigarettes |
| CN103861443A (en) * | 2014-03-14 | 2014-06-18 | 郭涛 | Nicotine and tobacco tar decomposing agent for air freshener |
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| CN105597688A (en) | 2016-05-25 |
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