CN105592838A - Hair coloring agent and hair dyeing method - Google Patents
Hair coloring agent and hair dyeing method Download PDFInfo
- Publication number
- CN105592838A CN105592838A CN201480053591.7A CN201480053591A CN105592838A CN 105592838 A CN105592838 A CN 105592838A CN 201480053591 A CN201480053591 A CN 201480053591A CN 105592838 A CN105592838 A CN 105592838A
- Authority
- CN
- China
- Prior art keywords
- eye drip
- package body
- drip container
- eye
- laminate film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003086 colorant Substances 0.000 title abstract 2
- 230000037308 hair color Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title description 6
- 238000004043 dyeing Methods 0.000 title 1
- 239000005001 laminate film Substances 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
- 230000005540 biological transmission Effects 0.000 claims description 35
- 230000035699 permeability Effects 0.000 claims description 22
- 239000003814 drug Substances 0.000 claims description 17
- 238000004806 packaging method and process Methods 0.000 claims description 17
- 238000012360 testing method Methods 0.000 claims description 11
- 229940079593 drug Drugs 0.000 claims description 10
- 238000010998 test method Methods 0.000 claims description 9
- 230000008021 deposition Effects 0.000 claims description 8
- 239000004033 plastic Substances 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract 7
- 239000000975 dye Substances 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 1
- 239000000981 basic dye Substances 0.000 abstract 1
- 239000002082 metal nanoparticle Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 24
- 238000001704 evaporation Methods 0.000 description 16
- 230000008020 evaporation Effects 0.000 description 14
- 239000003889 eye drop Substances 0.000 description 13
- 229940012356 eye drops Drugs 0.000 description 13
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 229920000092 linear low density polyethylene Polymers 0.000 description 4
- 239000004707 linear low-density polyethylene Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000005030 aluminium foil Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052755 nonmetal Inorganic materials 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000006196 drop Substances 0.000 description 2
- 210000004276 hyalin Anatomy 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61J—CONTAINERS SPECIALLY ADAPTED FOR MEDICAL OR PHARMACEUTICAL PURPOSES; DEVICES OR METHODS SPECIALLY ADAPTED FOR BRINGING PHARMACEUTICAL PRODUCTS INTO PARTICULAR PHYSICAL OR ADMINISTERING FORMS; DEVICES FOR ADMINISTERING FOOD OR MEDICINES ORALLY; BABY COMFORTERS; DEVICES FOR RECEIVING SPITTLE
- A61J1/00—Containers specially adapted for medical or pharmaceutical purposes
- A61J1/05—Containers specially adapted for medical or pharmaceutical purposes for collecting, storing or administering blood, plasma or medical fluids ; Infusion or perfusion containers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61J—CONTAINERS SPECIALLY ADAPTED FOR MEDICAL OR PHARMACEUTICAL PURPOSES; DEVICES OR METHODS SPECIALLY ADAPTED FOR BRINGING PHARMACEUTICAL PRODUCTS INTO PARTICULAR PHYSICAL OR ADMINISTERING FORMS; DEVICES FOR ADMINISTERING FOOD OR MEDICINES ORALLY; BABY COMFORTERS; DEVICES FOR RECEIVING SPITTLE
- A61J1/00—Containers specially adapted for medical or pharmaceutical purposes
- A61J1/14—Details; Accessories therefor
- A61J1/16—Holders for containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D31/00—Bags or like containers made of paper and having structural provision for thickness of contents
- B65D31/02—Bags or like containers made of paper and having structural provision for thickness of contents with laminated walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D33/00—Details of, or accessories for, sacks or bags
- B65D33/14—Suspension means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D33/00—Details of, or accessories for, sacks or bags
- B65D33/16—End- or aperture-closing arrangements or devices
- B65D33/25—Riveting; Dovetailing; Screwing; using press buttons or slide fasteners
- B65D33/2508—Riveting; Dovetailing; Screwing; using press buttons or slide fasteners using slide fasteners with interlocking members having a substantially uniform section throughout the length of the fastener; Sliders therefor
- B65D33/2516—Riveting; Dovetailing; Screwing; using press buttons or slide fasteners using slide fasteners with interlocking members having a substantially uniform section throughout the length of the fastener; Sliders therefor comprising tamper-indicating means, e.g. located within the fastener
- B65D33/2533—Riveting; Dovetailing; Screwing; using press buttons or slide fasteners using slide fasteners with interlocking members having a substantially uniform section throughout the length of the fastener; Sliders therefor comprising tamper-indicating means, e.g. located within the fastener the slide fastener being located between the product compartment and the tamper indicating means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/008—Standing pouches, i.e. "Standbeutel"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/80—Medical packaging
Landscapes
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Pharmacology & Pharmacy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Hematology (AREA)
- Packages (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
Abstract
A two-bath type hair coloring agent prepared by mixing a first agent with a second agent, wherein: the first agent comprises a dye component, said dye component comprising a basic dye as a main component, and an alkaline agent; the second agent comprises an aqueous hydrogen peroxide solution as a main component; and the first agent and/or the second agent further comprise metal nanoparticles.
Description
Technical field
The present invention relates to laminate film, the eye drip container that eye drops is housed be packed andThe eye drip container package body becoming.
Background technology
All the time, as the eye drip container package body of accommodating eye drops, known have a following bagDress body: the eye drops of ormal weight is enclosed in resin eye drip container, as required, usedLaminate film is packed this eye drip container, and itself and description are together housed in carton and are obtainedPackage body.
For example, in following patent documentation 1, a kind of medicament for the eyes container packaging body is disclosed,It is that the medicament for the eyes container packaging bag of band clip chain (chuck) that medicament for the eyes is housed is packed,Itself and description are together housed in carton and are obtained, and the described packaging bag with clip chain makesWith thering is the nonmetal character film of the function of avoiding evaporating.
Prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2008-148852 communique
Summary of the invention
Invent problem to be solved
For eye drops, from sides such as the necessity of the maintaining of drug concentration, storage for a long timeFace is considered, need to utilize packing container to suppress the evaporation of eye drops. Particularly, requireIn water vapo(u)r transmission test in plastics drug container test method(s), water vapo(u)r transmissionBelow setting. This water vapo(u)r transmission can be reached by eye drip container separately, alsoCan be that eye drip container package body is reached by eye drip container+laminate film.
Conventionally, the water vapo(u)r transmission of resin eye drip container depends on the material of the resin of useMatter and molding thickness, therefore have water vapo(u)r transmission to a certain degree. Therefore, by makingThe water vapo(u)r transmission of packing to reduce eye drip container package body with laminate film is effective, this kind of embodiment is also disclosed in patent documentation 1.
Use in packaging body at the medicament for the eyes container of patent documentation 1, as nonmetal character film (conventionallyRefer to the hyaline membrane that has used metal oxide), exemplified with can with the barrier of aluminium foil mutuallyEnemy's hyaline membrane. That is, steam permeability and the aluminium foil of this nonmetal character film are equal to, withThe steam permeability of common film, record based on JISK7129 40 DEG C,Steam permeability when relative humidity 90% is less than 0.1g/m2/ day, approach zero. As mentioned above,The only viewpoint from avoiding evaporating, at first sight also can expect that water vapo(u)r transmission is ad infinitum lowPreferred.
But the discovery new according to present inventor, has confirmed at picture patent documentation 1Use like that in the situation of laminate film packaging medicament for the eyes container, if the water vapo(u)r transmission of laminate filmBecome too low, because the steam that sees through medicament for the eyes container can not pass through laminate film, soDewfall in laminate film, produces following new problem: outward appearance when infringement Kaifeng, user willDewfall is thought the leakage of eye drops by mistake, maybe the description being enclosed in is together got wet.
The object of the present invention is to provide the one can to solve above-mentioned problem, restrain eye dropsEvaporate and prevent the eye drops package body of the dewfall in laminate film.
For solving the means of problem
Present inventor find, by be conceived to eye drip container water vapo(u)r transmission,And by the harmony between the water vapo(u)r transmission of laminated film formed packaging bag, can solveAbove-mentioned problem, thus the present invention completed. Particularly, the invention provides following scheme.
(1) an eye drip container package body is to pack and will be equipped with taking laminate film as outermost layerThe eye drip container of eye drops packs the eye drip container package body forming, wherein,
For described eye drip container, according to the water in plastics drug container test method(s)Steam permeability test is under 25 ± 2 DEG C, the relative humidity condition that is 60 ± 5% in temperatureStore water vapo(u)r transmission after 14 days to count and to be greater than 0.15% from the decrement of initial content amountAmount,
The described eye drip obtaining for described eye drip seal of vessel being accommodated with described laminate film holdsDevice package body, described water vapo(u)r transmission is to count 0.04% from the decrement of initial content amountAbove and below 0.10%.
(2) the eye drip container package body as described in (1), wherein, the base of described laminate filmWhat record in JISK7129 at 40 DEG C, steam permeability when relative humidity 90% is0.1～1.0g/m2/ day.
(3) the eye drip container package body as described in (1) or (2), wherein, described layerClosing film is the laminate film with aluminium-vapour deposition layer or aluminium oxide evaporation layer.
(4) the eye drip container package body as described in any one in (1)～(3), wherein,The form of the described eye drip container package body described laminated film formed Self stand bag (standing that serves as reasonspouch)。
The effect of invention
According to the present invention, can provide a kind of and suppress the evaporation of eye drops and prevent laminate filmThe eye drip container package body of interior dewfall.
Brief description of the drawings
Fig. 1 is the three-dimensional sketch that represents an embodiment of eye drip container package body of the present invention.
Detailed description of the invention
Below, on one side describe eye drip container package body of the present invention on one side in detail with reference to accompanying drawingA kind of preferred embodiment.
As shown in Figure 1, in this eye drip container package body 30, in laminate film 20, containEye drip container 10. The eye drops of not shown ormal weight is filled in eye drip container 10. At thisIn embodiment, laminate film 20 forms Self stand bag, and eye drip container package body 30 is independencePackage body. It should be noted that, so-called in the present invention " packaging taking laminate film as outermost layer ",Refer to and further do not use the packaged configuration as outermost layer packaging such as carton.
<eye drip container>
Eye drip container 10 is to form by the past known blow molding, injection moulding etc.Synthetic resin, preferably using can be from outside visual distinguishing as the journey of the eye drops of contentSpend transparent. For the material of eye drip container 10, as long as there is water vapo(u)r transmission described laterCan, be not particularly limited, for example, can preferably enumerate PETG (PET),Merlon (PC), polyarylate (U polymer), polyethylene (PE), polypropylene (PP),And their mixture etc.
For the water vapo(u)r transmission of eye drip container 10, according to plastics drug containerThe test of water vapo(u)r transmission in test method(s) is that 25 ± 2 DEG C, relative humidity are 60 in temperatureUnder ± 5% condition, store water vapo(u)r transmission after 14 days with the decrement from initial content amountCount the amount that is greater than 0.15%, be preferably the amount below 1%. Moisture decrement is greater than 0.15% tableThe water vapo(u)r transmission of showing eye drip container 10 is high, ties in laminate film owing to becoming easilyReveal, so by the laminate film using in combination the present invention, can Antidewing. In addition,Moisture decrement is below 1% time, by adjusting the water vapo(u)r transmission of laminate film described later, and canEffectively Antidewing.
Herein, the water vapo(u)r transmission test in so-called plastics drug container test method(s),That " plastics drug container test method(s) 5 steam are saturating with Pharmacopeia of Japan ordinary test methodThe property crossed test first method " (putting down into eight on March 1,, medicine sends out the three or three No. six) (" プラ ス チ ッ ク System drug container Try test method 5 water steam Genki Tou Over Try test first method "No. 336,, Yao development (put down on March sixteenth, 8)) be the test of benchmark, concrete, be in eye drip container, to add the water of ormal weight and to be 20 ± 2 DEG C, phase in temperatureUnder the condition that is 65 ± 5% to humidity, store water vapo(u)r transmission after 14 days with from initialThe form of the decrement of capacity is expressed as the value of " % ". It should be noted that, according to this standard,It is generally acknowledged that decrement is under the state that is separately eye drip container or at eye drip container+laminate filmBe to be below 0.2% under the state of eye drip container package body. It should be noted that, looking like thisIn the bright situation that has like this laminate film 20, for using laminate film 20 to pack eye drip container 10After state under measured value.
<laminate film>
Select laminate film 20, to make as described later, contain eye drip container 10 to sealThe above-mentioned water vapo(u)r transmission of eye drip container package body 30, with subtracting from initial content amountAmount meter becomes more than 0.04% and below 0.10%.
For steam permeability alone of laminate film 20 (following, for above-mentioned " mouldingExpect the water vapo(u)r transmission of the container in drug container test method(s) processed " distinguish also letterBe called film steam permeability), based on JISK7129 40 DEG C, relative humidity 90%Under condition, be 0.1～1.0g/m2/ sky is preferred. The non-metallic film of patent documentation 1, aluminium foilFilm steam permeability is less than 0.1g/m2/ day, film steam permeability is too low, cannot preventing layerClose the dewfall in film 20. On the other hand, if film steam permeability is greater than 1.0g/m2/ day,Cannot effectively suppress from the evaporation of eye drip container.
As above-mentioned laminate film, can preferably enumerate and there is aluminium-vapour deposition layer, aluminium oxide evaporation layer etc.The laminate film of inorganic oxide layer. Aluminium-vapour deposition layer, aluminium oxide evaporation layer can possess above-mentioned appropriatenessFilm steam permeability, therefore can be suitable for the present invention. In addition, due to aluminium-vapour deposition layerThere is light-proofness, so even in the feelings that formed separately Self stand bag as Fig. 1 by laminate filmUnder condition, also can protect eye drops to make it not be subject to extraneous light (visible ray, ultraviolet light) shadowRing.
It should be noted that, laminate film is preferably the multilayer film at innermost layer with hot sealing layer.Can carry out thus packing based on heat-sealing. Form as concrete layer, can enumerate from outsideSide plays 2 layers into base material/(printed layers)/aluminium-vapour deposition film or aluminium oxide vapor-deposited film/hot sealing layer etc.Preferred 3 layers of above formation above. The gross thickness of laminate film is preferably 20～200 μ m.
<eye drip container package body>
Above-mentioned eye drip container 10 is combined with laminate film 20, can obtain as double casing bodyEye drip container package body 30. Can as required other article such as description together be packed.
As shown in Figure 1, the eye drip container package body 30 in present embodiment is so-called strap clampsChain Self stand bag, by limit, the left and right sides, 2 limits of the bottom of upper side edge, bottom bracing boardForm heat-sealing portion 36, thereby can realize independence. Therefore, do not need existing carton, withPatent documentation 1 is compared, and becomes the package body of simplification. It should be noted that, by utilizingAluminium-vapour deposition film, printing etc., by whole shading of laminate film 20, can be protected as contentPut drops in one's eyes and make it not be subject to visible ray, influence of ultraviolet light.
Central portion at the upper side edge of eye drip container package body 30 is formed with the circle for hangingHole 35. In addition, on the top of eye drip container package body 30, be formed with abreast from otch,The tear-off portion 33 that portion 32 connects and clip chain portion 34. Dispose and can open in clip chain portion 34The clip chain of sealing again of being honored as a queen.
It should be noted that, in the present invention, eye drip container package body can need not to be Self stand bag,Also can be common four limit sealing bags, three limit sealing bags etc.
The above-mentioned water vapo(u)r transmission of this eye drip container package body 30, with from initial content amountDecrement is counted more than 0.04% and below 0.10%. So-called water vapo(u)r transmission is herein upperIn water vapo(u)r transmission test in the plastics drug container test method(s) of stating, use laminatedMeasured value under state after film 20 packs eye drip container 10.
The water vapo(u)r transmission of above-mentioned eye drip container package body, depends on that the water of eye drip container steamsGas permeability, and by the harmony between the water vapo(u)r transmission of laminated film formed packaging bag., in the water vapo(u)r transmission of eye drip container to count and to be greater than from the decrement of initial content amountIn 0.15% relatively large situation, all calculate eye drip by each container (packaging bag)The water vapo(u)r transmission of container is greater than the water vapo(u)r transmission of packaging bag (laminate film), and twoWhile there is big-difference in person, because the evaporation from packaging bag is very few, so there is dewfall. SpeciallyThe packaging body of profit document 1 is equivalent to which. But then, on the contrary, eye drip containerWater vapo(u)r transmission while being less than the water vapo(u)r transmission of packaging bag (laminate film), Wu FayouEffect suppresses evaporation, and it is large that the decrement of eye drops becomes, and becomes the quality that can not keep as putting drops in one's eyes.
Therefore,, in the present invention, by making, the steam of packaging bag (laminate film) is seen throughProperty is set as the eye drip container bag more lower slightly than the water vapo(u)r transmission of the eye drip container of each containerDress body, more specifically, by the water vapo(u)r transmission of eye drip container package body is adjusted toTo count more than 0.04% and below 0.10% from the decrement of initial content amount, thereby suppress from drippingThe evaporation of eye container, and prevent the dewfall in packaging bag (laminate film).
Embodiment
Then, one embodiment of the invention are described, but the present invention is not limited thereto.
[embodiment 1]
<eye drip container>
By be equivalent to eye drip container of the present invention, the poly-virtue of PETGEster hybrid resin container made carries out moulding, adds 12mL pure water and seal to inside. ShouldEye drip container is that water while storing 14 days under 25 DEG C, the humidity condition that is 60% steams in temperatureGas permeability is 0.25%.
<laminate film>
Do NY (polyamide)/aluminium-vapour deposition PET (poly-terephthaldehyde by the laminated legal system of dry typeAcid glycol ester) (film water steam is saturating for the laminate film of/LLDPE (straight-chain low density polyethylene)Be excessively 0.5g/m2/ day (40 DEG C, 90%RH)).
<eye drip container package body>
Taking LLDPE side as inner surface, 4 limits of 2 laminate films are sealed, thus with film notThe surface area of superimposed space segment becomes 0.022215m2Mode carry out close to eye drip containerPackage dress, obtains the eye drip container package body that four limits seal.
[embodiment 2]
As laminate film, use the aluminium oxide evaporation PET making by the laminated method of dry type (to steamSurfacing inner side) (film steam permeability is 0.3g/m for the laminate film of/PE2/ day (40 DEG C,90%RH)), in addition, operation similarly to Example 1, obtains four limits sealingsEye drip container package body.
[embodiment 3]
As laminate film, use the aluminium oxide evaporation PET making by the laminated method of dry type (to steamSurfacing inner side) (film steam permeability is 0.6g/m for the laminate film of/PE2/ day (40 DEG C,90%RH)), in addition, operation similarly to Example 1, obtains four limits sealingsEye drip container package body.
[embodiment 4]
As laminate film, use the PET/ aluminium oxide evaporation of making by the laminated method of dry type(film steam permeability is 1.0g/m to the laminate film of PET/LLDPE2/ day (40 DEG C,90%RH)), in addition, operation similarly to Example 1, obtains four limits sealingsEye drip container package body.
[comparative example 1]
As laminate film, use and make the laminated of PET/ aluminium foil/LLDPE by the laminated legal system of dry type(film steam permeability is 0g/m to film2/ day (40 DEG C, 90%RH)), in addition,Operation similarly to Example 1, obtains the eye drip container package body that four limits seal.
[comparative example 2]
As laminate film, use and make aluminium oxide evaporation PET (evaporation by the laminated legal system of dry typeFace inner side) (film steam permeability is 0.05g/m for the laminate film of/PE2/ day (40 DEG C,90%RH)), in addition, operation similarly to Example 1, obtains four limits sealingsEye drip container package body.
[comparative example 3]
Do not use laminate film and only use eye drip container, in addition, similarly to Example 1Ground operation.
[test example]
For the eye drip container package body of embodiment 1～4 and comparative example 1,2, comparative example 3Eye drip container (being respectively n=20), in the constant temperature perseverance that is set as 25 DEG C of temperature, humidity 60%Storage in wet device, takes out for 14 days afterwards, measures the weight of each sample, calculates water reduction (n=20Mean value), and by whether having produced water droplet in Visual Confirmation bag. The results are shown in table 1.
[table 1]
As shown in Table 1, be 0.3g/m at steam permeability2/ sky～1.0g/m2The laminate film in/skyEmbodiment 1～4 in, can reduce permeable amount, in bag, do not have water droplet to adhere to yet. AnotherAspect is 0.05g/m at steam permeability2In the comparative example 1,2 of the laminate film below/sky,Although can significantly reduce permeable amount, be attached with water droplet in bag. In addition, for outside not havingThe comparative example decrement of 3, the 14 days of side form is larger, is 0.25%.
Description of reference numerals
10 eye drip containers
20 laminate films
30 eye drip container package bodies (Self stand bag)
32 notch
33 tear-off portions
34 clip chain portions
35 holes
Claims (4)
1. an eye drip container package body is that packaging will be equipped with eye drip taking laminate film as outermost layerThe eye drip container of liquid packs the eye drip container package body forming, wherein,
For described eye drip container, according to the water in plastics drug container test method(s)Steam permeability test is under 25 ± 2 DEG C, the relative humidity condition that is 60 ± 5% in temperatureStore water vapo(u)r transmission after 14 days to count and to be greater than 0.15% from the decrement of initial content amountAmount,
The described eye drip obtaining for described eye drip seal of vessel being accommodated with described laminate film holdsDevice package body, described water vapo(u)r transmission is to count 0.04% from the decrement of initial content amountAbove and below 0.10%.
2. eye drip container package body as claimed in claim 1, wherein, described laminate filmWhat record based on JISK7129 at 40 DEG C, steam permeability when relative humidity 90% is0.1～1.0g/m2/ day.
3. eye drip container package body as claimed in claim 1 or 2, wherein, described laminatedFilm is the laminate film with aluminium-vapour deposition layer.
4. the eye drip container package body as described in any one in claim 1～3, wherein, instituteThe form of the stating eye drip container package body described laminated film formed Self stand bag of serving as reasons.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-221456 | 2013-10-24 | ||
| JP2013221456 | 2013-10-24 | ||
| PCT/JP2014/078202 WO2015060377A1 (en) | 2013-10-24 | 2014-10-23 | Eyedrop container package |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105592838A true CN105592838A (en) | 2016-05-18 |
Family
ID=52992966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480053591.7A Pending CN105592838A (en) | 2013-10-24 | 2014-10-23 | Hair coloring agent and hair dyeing method |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP2015107322A (en) |
| CN (1) | CN105592838A (en) |
| HK (1) | HK1223268A1 (en) |
| TW (1) | TW201521710A (en) |
| WO (1) | WO2015060377A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112969647A (en) * | 2018-11-12 | 2021-06-15 | 电化株式会社 | Packaging bag and packaging box for containing phosphor |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6591812B2 (en) * | 2015-07-13 | 2019-10-16 | 株式会社フジシール | Pouch container and pouch container package |
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|---|---|---|---|---|
| JPS5298389A (en) * | 1976-02-13 | 1977-08-18 | Sumitomo Chemical Co | Plastic eyewater container |
| JPS5327874A (en) * | 1976-08-24 | 1978-03-15 | Sumitomo Chemical Co | Container made from transparent polyester resin |
| JP2004051174A (en) * | 2002-07-22 | 2004-02-19 | Mitsubishi Pharma Corp | Transparent packaging bag and liquid pharmaceutical product package externally packaged with transparent packaging bag |
| CN101820836A (en) * | 2007-11-09 | 2010-09-01 | 花王株式会社 | Heat generation device |
| JP2013070947A (en) * | 2011-09-29 | 2013-04-22 | Senju Pharmaceut Co Ltd | Medical container |
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|---|---|---|---|---|
| EP1245217B1 (en) * | 2001-03-27 | 2009-10-28 | Nipro Corporation | Plastic container containing albumin solution |
| JP2008148852A (en) * | 2006-12-15 | 2008-07-03 | Nitto Medeikku Kk | Package for eye dropper |
| JP5286779B2 (en) * | 2007-12-27 | 2013-09-11 | 大日本印刷株式会社 | Packaging bags for medical plastic containers |
| JP5245893B2 (en) * | 2009-02-13 | 2013-07-24 | 凸版印刷株式会社 | Multilayer film and method for producing the same |
-
2014
- 2014-10-23 CN CN201480053591.7A patent/CN105592838A/en active Pending
- 2014-10-23 WO PCT/JP2014/078202 patent/WO2015060377A1/en active Application Filing
- 2014-10-23 JP JP2014216379A patent/JP2015107322A/en active Pending
- 2014-10-23 TW TW103136751A patent/TW201521710A/en unknown
-
2016
- 2016-10-08 HK HK16111669.9A patent/HK1223268A1/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5298389A (en) * | 1976-02-13 | 1977-08-18 | Sumitomo Chemical Co | Plastic eyewater container |
| JPS5327874A (en) * | 1976-08-24 | 1978-03-15 | Sumitomo Chemical Co | Container made from transparent polyester resin |
| JP2004051174A (en) * | 2002-07-22 | 2004-02-19 | Mitsubishi Pharma Corp | Transparent packaging bag and liquid pharmaceutical product package externally packaged with transparent packaging bag |
| JP4550352B2 (en) * | 2002-07-22 | 2010-09-22 | 富山化学工業株式会社 | Transparent packaging bag and liquid preparation package packaged outside with this |
| CN101820836A (en) * | 2007-11-09 | 2010-09-01 | 花王株式会社 | Heat generation device |
| JP2013070947A (en) * | 2011-09-29 | 2013-04-22 | Senju Pharmaceut Co Ltd | Medical container |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112969647A (en) * | 2018-11-12 | 2021-06-15 | 电化株式会社 | Packaging bag and packaging box for containing phosphor |
Also Published As
| Publication number | Publication date |
|---|---|
| HK1223268A1 (en) | 2017-07-28 |
| TW201521710A (en) | 2015-06-16 |
| WO2015060377A1 (en) | 2015-04-30 |
| JP2015107322A (en) | 2015-06-11 |
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