CN105585277A - Low-cost environment-friendly baking-free brick and preparation method thereof - Google Patents

Low-cost environment-friendly baking-free brick and preparation method thereof Download PDF

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Publication number
CN105585277A
CN105585277A CN201510957882.5A CN201510957882A CN105585277A CN 105585277 A CN105585277 A CN 105585277A CN 201510957882 A CN201510957882 A CN 201510957882A CN 105585277 A CN105585277 A CN 105585277A
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weight portions
weight portion
weight
low
preparation
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CN201510957882.5A
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CN105585277B (en
Inventor
李金顶
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Jinjiang City Min Yi Renewable Resource Co Ltd
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Jinjiang City Min Yi Renewable Resource Co Ltd
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Priority to CN201510957882.5A priority Critical patent/CN105585277B/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention relates to a brick and provides a low-cost environment-friendly baking-free brick which is wide in material source, low in cost, environmentally friendly, high in pressure strength and resistant to corrosion. The low-cost environment-friendly baking-free brick is prepared from, by weight, 30 parts of industrial sludge with the water content being 80%, 15 parts of domestic sludge with the water content being 80%, 40 parts of sintered flyash, 4 parts of coal slags, 4 parts of slags, 0.45 part of lime putty, 5 parts of adhesives, 9.5 parts of lime skin, 0.55 part of sodium silicate, 0.6 part of barium chloride, 0.85 part of sodium chloride, and 0.55 part of calcium oxide. Meanwhile, the invention provides a preparation method of the low-cost environment-friendly baking-free brick. The method comprises the following steps of 1, raw material smashing, 2, forming and 3, drying.

Description

A kind of low-cost environmental-protecting is non-burning brick and preparation method thereof
Technical field
The present invention is that the patent No. is 201310052510.9, and the applying date is 2013 02 month 18Day, name is called the divisional application of the patent of invention of " a kind of environment-friendly baking-free bricks and preparation method thereof ",Relate to a kind of brick, be specifically related to a kind of environment-friendly baking-free bricks and preparation method thereof.
Background technology
Traditional building brick has clay brick, sand lime brick, flyash brick, because China was once sent outTable " strict restriction ruin field bake bricks, actively promote the suggestion of wall reform ", implements " protection agricultureField, save the energy, suit measures to local conditions, gather materials on the spot " development building materials general policy, clay brick is (redBrick) greatly reduce, sand lime brick, flyash brick, the mixed earth piece instead of clay brick of aerating becomeFor main flow; The raw material of sand lime brick are that the exploitation of sand and lime, sand is also subject to strict controlSystem (due to reasons such as stream bed protections) needs to pass through high temperature and high pressure steam after green brick forming simultaneouslyMaintenance, technique is relatively complicated, and when use, sand lime brick is combined with decorative mortar not as common brick,Easily produce crack at metope, and facing comes off, affect attractive in appearance. Above three kinds of bricks are all to burnSystem forms, and need to consume a large amount of resources, is unfavorable for the saving of resource, and production power consumption is high.
The problem that is accompanied by economic fast development, energy shortage and environmental pollution becomes increasingly conspicuous,The green economy of development energy-conserving and environment-protective is emphasis of development of all countries economy, to industrial waste product, and lifeThe recycling of discarded object is also the important component part of green economy.
Non-burning brick, claim again no-firing brick, owing to can avoiding conventional sintering serious waste soil moneyThe problem of discharging SO2 contaminated environment in source and preparation process obtains in building fieldApplication widely, in the prior art, non-burning brick use river sand or river sand is as primary raw material,Then add a certain amount of auxiliary material as cement, flyash, aggregates etc., can after hardening of cementUsing as binding material, flyash is as packing material, and aggregate is as reinforcing material. River sand orRiver sand is a kind of material of resource-constrained, and price is higher, therefore, adopts river sand or river sand systemThe non-burning brick cost that becomes is high and be unfavorable for the saving of the energy.
Summary of the invention
Therefore,, for the problems referred to above, the invention provides that a kind of material source is wide, cost is low, ringProtect, high, the corrosion resistant low-cost environmental-protecting of compressive resistance is non-burning brick, provides a kind of described low simultaneouslyThe preparation method of cost environment-friendly baking-free bricks.
For achieving the above object, the present invention is achieved by the following technical solutions: a kind of low one-tenthThis environment-friendly baking-free bricks, the content of each component and each component is: the industrial sludge 30 of moisture content 80%Weight portion; Domestic sludge 15 weight portions of moisture content 80%; Sintered coal ash 40 weight portions;Cinder 4 weight portions; Slag 4 weight portions; Lime paste 0.45 weight portion; Glue 5 weight portions;Lime skin 9.5 weight portions; Sodium metasilicate 0.55 weight portion; Barium chloride 0.6 weight portion; ChlorinationSodium 0.85 weight portion; Calcium oxide 0.55 weight portion.
The preparation method that low-cost environmental-protecting is non-burning brick, its preparation method, comprises the following steps:
(1) pulverize raw material: by the industrial sludge of moisture content 80% 30 weight portions, moisture content 80%Domestic sludge 15 weight portions, sintered coal ash 40 weight portions, cinder 4 weight portions, slag4 weight portions, lime paste 0.45 weight portion, glue 5 weight portions, lime skin 9.5 weight portions,Sodium metasilicate 0.55 weight portion, barium chloride 0.6 weight portion, sodium chloride 0.85 weight portion, oxidationCalcium 0.55 weight portion mixes, and then carries out pulverization process, makes hybrid particles, described particleDiameter be 2mm;
(2) moulding: the hybrid particles that step (1) is made is sent into forming machine and carry out moulding placeReason, makes moulding adobe;
(3) dry: the moulding adobe after step (2) forming processes is dried to 10 at 80 DEG CHour, make environment-friendly baking-free bricks.
Described step (3) dry is treated to natural drying at least 12 days or 70~89DEG C dry 7~14 hours.
By adopting aforementioned techniques scheme, the invention has the beneficial effects as follows: formula of the present inventionThe consumption of middle industrial sludge and domestic sludge has accounted for greatly, has effectively recycled workIndustry mud and domestic sludge, do not need to use traditional river, river sand, saved resource, protectionEnvironment. Sodium metasilicate, barium chloride, calcium chloride, sodium chloride that the present invention adds, effectively increaseBetween the large main ingredients such as flyash, bridging property, cohesive force and the intensity of each composition, dwindled greatlyDry wet shrinkage factor, and make rib, limit, the angle of finished bricks avoid occurring the phenomenon of differentiation, adopt chlorineChange calcium and also have antifreeze effect, these chemical substance institute expenses used are less, price is equalLower, function admirable. Make adhesive with glue, effectively reduced the consumption of lime paste, reducedCost, has improved intensity. In addition, utilize uncombusted in organic in mud and sintered coal ashCarbon as internal combustion agent, can effectively save the energy, the source of aggregate can be perlite,Lime skin, rice husk, brickbat etc., raw material sources are extensive, and cost is low, has good economic effectBenefit. Preparation method of the present invention, does not need brick to carry out sintering processes, naturally dry at normal temperaturesWithin dry 12 days, can make, or 70~89 DEG C of dry can making for 7~14 hours, saveResource, production power consumption is low.
Detailed description of the invention
Describe embodiments of the present invention in detail below with reference to specific embodiment, whereby to thisInvent how application technology means solve technical problem, and reach the implementation procedure of technique effectCan fully understand and implement according to this.
Embodiment mono-:
A kind of low-cost environmental-protecting is non-burning brick, and the content of each component and each component is: moisture content 75%Industrial sludge 20 weight portions; Domestic sludge 10 weight portions of moisture content 80%; Sintering fine coalAsh 30 weight portions; Cinder 3 weight portions; Slag 2 weight portions; Lime paste 0.2 weight portion;Glue 4 weight portions; Perlite 8 weight portions; Sodium metasilicate 0.5 weight portion; Barium chloride 0.2 weightPart; Sodium chloride 0.2 weight portion; Calcium oxide 0.1 weight portion.
Its preparation method, comprises the following steps:
(1) pulverize raw material: by the industrial sludge of moisture content 75% 20 weight portions, moisture content 80%Domestic sludge 10 weight portions, sintered coal ash 30 weight portions, cinder 3 weight portions, slag2 weight portions, lime paste 0.2 weight portion, glue 4 weight portions, aggregate 8 weight portions, sodium metasilicate0.5 weight portion, barium chloride 0.2 weight portion, sodium chloride 0.2 weight portion, calcium oxide 0.1 weightAmount part is mixed, and then carries out pulverization process, makes hybrid particles, and the diameter of described particle is3mm;
(2) moulding: the hybrid particles that step (1) is made is sent into forming machine and carry out moulding placeReason, makes moulding adobe;
(3) dry: by natural drying 12 days of the moulding adobe after step (2) forming processes,Make environment-friendly baking-free bricks.
Embodiment bis-:
A kind of low-cost environmental-protecting is non-burning brick, and the content of each component and each component is: moisture content 80%Industrial sludge 30 weight portions; Domestic sludge 15 weight portions of moisture content 80%; Sintering fine coalAsh 40 weight portions; Cinder 4 weight portions; Slag 4 weight portions; Lime paste 0.45 weight portion;Glue 5 weight portions; Lime skin 9.5 weight portions; Sodium metasilicate 0.55 weight portion; Barium chloride 0.6Weight portion; Sodium chloride 0.85 weight portion; Calcium oxide 0.55 weight portion.
Its preparation method, comprises the following steps:
(1) pulverize raw material: by the industrial sludge of moisture content 80% 30 weight portions, moisture content 80%Domestic sludge 15 weight portions, sintered coal ash 40 weight portions, cinder 4 weight portions, slag4 weight portions, lime paste 0.45 weight portion, glue 5 weight portions, lime skin 9.5 weight portions,Sodium metasilicate 0.55 weight portion, barium chloride 0.6 weight portion, sodium chloride 0.85 weight portion, oxidationCalcium 0.55 weight portion mixes, and then carries out pulverization process, makes hybrid particles, described particleDiameter be 2mm;
(2) moulding: the hybrid particles that step (1) is made is sent into forming machine and carry out moulding placeReason, makes moulding adobe;
(3) dry: the moulding adobe after step (2) forming processes is dried to 10 at 80 DEG CHour, make environment-friendly baking-free bricks.
Embodiment tri-:
A kind of low-cost environmental-protecting is non-burning brick, and the content of each component and each component is: moisture content 85%Industrial sludge 40 weight portions; Domestic sludge 20 weight portions of moisture content 80%; Sintering fine coalAsh 50 weight portions; Cinder 5 weight portions; Slag 6 weight portions; Lime paste 0.7 weight portion;Glue 6 weight portions; Rice husk 5 weight portions, brickbat 6 weight portions; Sodium metasilicate 6 weight portions; ChlorinationBarium 1 weight portion; Sodium chloride 1.5 weight portions; Calcium oxide 1 weight portion.
Its preparation method, comprises the following steps:
(1) pulverize raw material: by the industrial sludge of moisture content 85% 40 weight portions, moisture content 80%Domestic sludge 20 weight portions, sintered coal ash 50 weight portions, cinder 5 weight portions, slag6 weight portions, lime paste 0.7 weight portion, glue 6 weight portions, aggregate 11 weight portions, silicic acidSodium 6 weight portions, barium chloride 1 weight portion, sodium chloride 1.5 weight portions, calcium oxide 1 weight portionMix, then carry out pulverization process, make hybrid particles, the diameter of described particle is 1mm;
(2) moulding: the hybrid particles that step (1) is made is sent into forming machine and carry out moulding placeReason, makes moulding adobe;
(3) dry: the moulding adobe after step (2) forming processes is dried to 7 at 89 DEG CHour, make environment-friendly baking-free bricks.
Wherein, the source of the aggregate in the present invention can be perlite, lime skin, rice husk, brokenAny one in brick or the two or more mixture with any combination. Described step (1)In the diameter of hybrid particles be less than 5mm; The dry of described step (3) is treated to certainlySo be dried at least 12 days or be dried and all can realize of the present invention in 7~14 hours at 70~89 DEG CObject.
In formula of the present invention, the consumption of industrial sludge and domestic sludge has accounted for greatly, hasEffect recycling industrial sludge and domestic sludge, do not need to use traditional river, river sand,Save resource, protected environment. Sodium metasilicate that the present invention adds, barium chloride, calcium chloride,Sodium chloride, effectively increased each composition between the main ingredients such as flyash bridging property, cohesive force andIntensity, has dwindled dry wet shrinkage factor greatly, and makes rib, limit, the angle of finished bricks avoid occurring dividingThe phenomenon of changing, adopts calcium chloride also to have antifreeze effect, and these chemical substances used are requiredConsumption is less, price is all lower, function admirable. Make adhesive with glue, effectively reduced limeThe consumption of cream, has reduced cost, has improved intensity. In addition, utilize organic in mud and burnIn knot flyash, unburnt carbon, as internal combustion agent, can effectively be saved the energy, aggregateSource can be perlite, lime skin, rice husk, brickbat etc., and raw material sources are extensive, and cost is low,There is good economic benefit. Preparation method of the present invention, does not need brick to carry out sintering processes,Within natural drying 12 days at normal temperatures, can make, or be dried 7~14 hours at 70~89 DEG CCan make, saving resource, production power consumption is low.
Although specifically show and introduced the present invention in conjunction with preferred embodiment, affiliated fieldTechnical staff should be understood that the spirit of the present invention limiting not departing from appended claimsIn scope, can make a variety of changes the present invention in the form and details, be thisBright protection domain.

Claims (3)

1. a low-cost environmental-protecting is non-burning brick, it is characterized in that the content of each component and each componentFor: industrial sludge 30 weight portions of moisture content 80%; Domestic sludge 15 weights of moisture content 80%Amount part; Sintered coal ash 40 weight portions; Cinder 4 weight portions; Slag 4 weight portions; LimeCream 0.45 weight portion; Glue 5 weight portions; Lime skin 9.5 weight portions; Sodium metasilicate 0.55 weightPart; Barium chloride 0.6 weight portion; Sodium chloride 0.85 weight portion; Calcium oxide 0.55 weight portion.
2. the non-burning brick preparation method of low-cost environmental-protecting, is characterized in that: its preparation sideMethod, comprises the following steps:
(1) pulverize raw material: by the industrial sludge of moisture content 80% 30 weight portions, moisture content 80%Domestic sludge 15 weight portions, sintered coal ash 40 weight portions, cinder 4 weight portions, slag4 weight portions, lime paste 0.45 weight portion, glue 5 weight portions, lime skin 9.5 weight portions,Sodium metasilicate 0.55 weight portion, barium chloride 0.6 weight portion, sodium chloride 0.85 weight portion, oxidationCalcium 0.55 weight portion mixes, and then carries out pulverization process, makes hybrid particles, described particleDiameter be 2mm;
(2) moulding: the hybrid particles that step (1) is made is sent into forming machine and carry out moulding placeReason, makes moulding adobe;
(3) dry: the moulding adobe after step (2) forming processes is dried to 10 at 80 DEG CHour, make environment-friendly baking-free bricks.
3. the preparation method of environment-friendly baking-free bricks according to claim 2, is characterized in that:The dry of described step (3) is treated to natural drying at least 12 days or does at 70~89 DEG CDry 7~14 hours.
CN201510957882.5A 2013-02-18 2013-02-18 A kind of low-cost environmental-protecting is non-burning brick and preparation method thereof Expired - Fee Related CN105585277B (en)

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CN201310052510.9A CN103992090B (en) 2013-02-18 2013-02-18 A kind of environment-friendly baking-free bricks and preparation method thereof
CN201510957882.5A CN105585277B (en) 2013-02-18 2013-02-18 A kind of low-cost environmental-protecting is non-burning brick and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN104817300A (en) * 2015-04-25 2015-08-05 安徽阜阳富龙建筑材料有限责任公司 Steam-pressing brick containing sludge
CN107473661A (en) * 2017-08-31 2017-12-15 中冶华天工程技术有限公司 It is a kind of that non-burning brick method is produced as raw material using municipal sludge
CN109574569A (en) * 2019-01-25 2019-04-05 陶祖岐 Non-burning brick and its production method
CN113292286A (en) * 2020-02-23 2021-08-24 石旭艳 Environment-friendly baking-free brick utilizing industrial waste

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1072160A (en) * 1992-08-15 1993-05-19 张维一 Non-burning blocks with building refuse and manufacture method thereof
CN102826796A (en) * 2011-06-14 2012-12-19 北京仁创科技集团有限公司 Brick prepared from composition containing sludge and building waste and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101708983A (en) * 2009-09-07 2010-05-19 中国地质大学(北京) Burning-free geology polymer material of red mud coal ash and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1072160A (en) * 1992-08-15 1993-05-19 张维一 Non-burning blocks with building refuse and manufacture method thereof
CN102826796A (en) * 2011-06-14 2012-12-19 北京仁创科技集团有限公司 Brick prepared from composition containing sludge and building waste and preparation method thereof

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