CN105566681A - Auxiliary capable of improving printing performance of composite ivory board and preparation method thereof - Google Patents
Auxiliary capable of improving printing performance of composite ivory board and preparation method thereof Download PDFInfo
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- CN105566681A CN105566681A CN201510966600.8A CN201510966600A CN105566681A CN 105566681 A CN105566681 A CN 105566681A CN 201510966600 A CN201510966600 A CN 201510966600A CN 105566681 A CN105566681 A CN 105566681A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses an auxiliary capable of improving printing performance of a composite ivory board and a preparation method thereof. The auxiliary is prepared from, by weight, 10-20 parts of inorganic zinc salt, 10-20 parts of inorganic additive, 0.5-1 part of surfactant, 0.5-1 part of dispersant and 60-80 parts of deionized water. ZnO nano acanthosphere particles after surface modification are adopted as the auxiliary in the process of printing the composite ivory board; the ZnO nano acanthosphere particles have siphon microstructure, and an active agent is adopted for chemical surface modification, so that ink absorptivity of the composite ivory board can be further improved.
Description
Technical field
The present invention relates to pulp technology for making paper, particularly a kind of compound ivory board that promotes prints auxiliary agent of absorbency and preparation method thereof.
Background technology
Paper is that the mankind learn, work, one of indispensable important articles for use of living, traditional papermaking to bring the destruction of high degree due to the three wastes that produce in overcut trees and traditional paper industry production technique to ecotope, the cry that the feature of environmental protection of people to papermaking starting material used and the paper product course of processing requires is more and more higher.Compound ivory board, i.e. stone paper are a kind of type materials between paper and plastics, and both alternative traditional part functionalities paper, professional paper, can substitute again traditional most of plastic packing article.And have the advantages that cost is low, controllability is degraded, can save a large amount of costs for user, and can not produce pollution, be the important substitute replacing traditional plant fibrous paper.
The oil absorbency of paper affects its important printability index as print quality.Owing to containing a large amount of non-polar component in stone paper, be difficult to attachment and printing, usually need special ink, improve the cost of printing, and namely use special ink, ink attachment fastness is also undesirable, paper is too little to absorption of inks ability, then the rate of drying of the printing product surface ink that can slow down, and print speed slows down, cause printed matter set-off simultaneously, especially for by the dry letterpress of infiltration and high speed printing more very.In addition, adopt the paper that ink receptivity is poor, after its inking, ink sorptive performance is also poor.And then improving the absorbency of stone paper and the printing performance such as antistatic, is an important topic in stone paper R&D and production process.
In prior art, China Patent Publication No. 101768893A discloses a kind of stone paper coating and production method, this coatings is formed a kind of new stone paper on the stone paper films such as PP, BOPP, PVC, PET, general mode of printing and general ink can be applicable to.But those skilled in the art are in implementation process, find to occur the phenomenon that paint aging comes off affecting printing effect in coatings inequality and stone paper use procedure.
China Patent Publication No. 102363572A discloses a kind of functional additive for stone paper, functional adsorption group is introduced by grafting after carrying out chemistry and physically modified to nano silicon and nano alumina surface, after additive application is in stone paper, on the surface of paper with ink affinity group, enhance the adsorptivity in stone paper printing process, improve the printing quality of stone paper.But, those skilled in the art find in implementation process spherical nano silicon and nano alumina surface smooth, although introduce blotting group, because blotting group long-term exposure is in air, the microbes corrosion blotting group of electrostatic adhesion, cause ink easily aging, coming off of coating, affects printing quality.
Summary of the invention
In order to solve compound ivory board difficult attachment and printing in printing process, need special ink and in printing process, also there is the large defect of electrostatic, the absorbency of further raising compound ivory board in printing process, the embodiment of the present invention provides a kind of auxiliary agent and the preparation method that promote compound ivory board printing performance, by adopting the ZnO nano acanthosphere particle after preparing surface modification, there is siphon microstructure, adopt promoting agent to carry out chemical surface modification, and then the present invention can improve the absorbency of compound ivory board further simultaneously.
The invention provides a kind of auxiliary agent promoting compound ivory board printing performance, it is characterized in that, described auxiliary agent is prepared according to the component of following weight part:
Inorganic zinc salt 10-20 part
Inorganic additives 10-20 part
Tensio-active agent 0.5-1 part
Dispersion agent 0.5-1 part
Deionized water 60-80 part
Wherein, described inorganic zinc salt is ZnCl
2, ZnSO
4, Zn(AC)
2in at least one, described inorganic additives is strong base-weak acid salt NaHCO
3, Na
2cO
3, Na
2sO
3in at least one, described dispersion agent is ethanol, acetone, at least one in pimelinketone, and described tensio-active agent is silicane tensio-active agent.
The invention provides a kind of preparation method promoting the auxiliary agent of compound ivory board printing performance on the other hand, it is characterized in that, described preparation method comprises the steps:
1) making ZnO nanometer acanthosphere particle;
2) finishing is carried out to ZnO nano acanthosphere particle;
Wherein, described ZnO nano acanthosphere spine diameter is 20-100nm, and length is 80-150 μm.
Preferably, step 1) making ZnO nanometer acanthosphere particle, specifically comprises:
Under deionized water temperature being risen to the condition of 30-90 DEG C, the high-purity argon gas that purity is 99.95% is passed in described deionized water, aeration time is 0.5-5h, after the oxygen in removing pure water, adds inorganic zinc salt, and constantly stir, arranging stirring velocity is 800-1500rpm, and churning time is 0.2-0.5h, then adds dispersion agent, stirring 0.2-0.5h allows solution mix, and obtains mixed liquor A;
Inorganic additives is added in described mixed liquor A, adjust pH is to 8-9, continue to stir 0.3-0.5h, and pass into argon gas in described mixed liquor A, described mixed liquor A is heated, after steaming the moisture in mixed liquor A, backflow is cooled to room temperature, obtains the solution B containing ZnO nano acanthosphere particle, wherein, arranging heating rate is 6-8 DEG C/min, and arranging rate of temperature fall is 5-8 DEG C/min.
Preferably, step 2) finishing is carried out to ZnO nano acanthosphere particle, specifically comprise:
Tensio-active agent and acetone is added in described solution B, ultrasonic 30min, centrifugation 3-5 time, with ultrapure water and dehydrated alcohol alternately washing 4-5 time, heating also, after drying, obtains the ZnO nano acanthosphere particle powder of finishing, as the additive in ivory board preparation process, wherein, Heating temperature is 60-80 DEG C.
Above-mentioned one or more technical scheme in the embodiment of the present application, at least has one or more technique effects following:
1, owing to passing through in the present invention to adopt making ZnO nanometer acanthosphere particle, again compound ivory board printing performance auxiliary agent is prepared to the technique means that ZnO nano acanthosphere particle carries out finishing, because the ZnO nano acanthosphere particle of preparation has siphon microstructure, simultaneously, ZnO nano acanthosphere particle surface has carried out the auxiliary agent that chemical graft is used as compound ivory board, be compared to the means of prior art by means of only chemical graft, the present invention can improve the absorbency of compound ivory board further.
2, owing to adopting ZnO nano acanthosphere particle to carry out grafting to it in the present invention, because nanometer acanthosphere grain pattern has larger surface-area, and then nano grain surface grafting number can be increased, after additive application is in compound ivory board, more multi-band can be formed on the surface of paper and have ink affinity group, ZnO surface, inherently from hydroxyl polar group, increases paper anti-static function, thus improves the printing performance of compound ivory board.
3, owing to adopting ZnO nano acanthosphere particle in the present invention, the end of acanthosphere particle possesses spine structure, and the microbial cell wall easily piercing through absorption kills microorganism, makes ivory board also have antimicrobial characteristic.Meanwhile, spine also easily pierces through droplet of ink, and ink wetting property is increased.
4, to promote preparation method's technique of compound ivory board printing performance auxiliary agent simple and easy to control in the present invention, can meet scale operation needs, have certain market using value.
Embodiment
By embodiment, the present invention is described in further detail, but this should be interpreted as scope of the present invention is only limitted to following example.When not departing from aforesaid method thought of the present invention, the various replacement made according to ordinary skill knowledge and customary means or change, all should be within the scope of the present invention.
Embodiment one
The present embodiment comprises the steps:
1) making ZnO nanometer acanthosphere particle;
Under deionized water temperature being risen to the condition of 30 DEG C, the high-purity argon gas that purity is 99.95% is passed in described deionized water, aeration time is 0.5h, after the oxygen in removing pure water, adds inorganic zinc salt, and constantly stir, arranging stirring velocity is 800rpm, and churning time is 0.2h, then adds dispersion agent, stirring 0.2h allows solution mix, and obtains mixed liquor A;
Inorganic additives is added in described mixed liquor A, adjust pH to 8, continue to stir 0.3h, and pass into argon gas in described mixed liquor A, described mixed liquor A is heated, after steaming the moisture in mixed liquor A, backflow is cooled to room temperature, obtains the solution B containing ZnO nano acanthosphere particle, wherein, arranging heating rate is 6-8 DEG C/min, and arranging rate of temperature fall is 5-8 DEG C/min.
2) finishing is carried out to ZnO nano acanthosphere particle;
Tensio-active agent and acetone is added in described solution B, ultrasonic 30min, centrifugation 3 times, washing is replaced 4 times with ultrapure water and dehydrated alcohol, 65 DEG C of heating after drying, obtain the ZnO nano acanthosphere particle powder of finishing, ZnO nano acanthosphere spine diameter is 20nm, length is 80 μm, has prepared as the additive in ivory board preparation process.
3) stone paper is prepared
By step 2) auxiliary agent 10 weight part obtained, calcium carbonate 80 weight part, polypropylene 10 weight part mixes in high-speed mixer, by banburying formula three spiro rod reaction type forcing machine extruding pelletization, prepare by rolling press the compound ivory board that thickness is 0.25mm, its performance as shown in Table 1.
Embodiment two
The present embodiment comprises the steps:
1) making ZnO nanometer acanthosphere particle;
Under deionized water temperature being risen to the condition of 50 DEG C, the high-purity argon gas that purity is 99.95% is passed in described deionized water, aeration time is 1h, after the oxygen in removing pure water, adds inorganic zinc salt, and constantly stir, arranging stirring velocity is 1000rpm, and churning time is 0.2h, then adds dispersion agent, stirring 0.2h allows solution mix, and obtains mixed liquor A;
Inorganic additives is added in described mixed liquor A, adjust pH to 8.5, continue to stir 0.4h, and pass into argon gas in described mixed liquor A, described mixed liquor A is heated, after steaming the moisture in mixed liquor A, backflow is cooled to room temperature, obtains the solution B containing ZnO nano acanthosphere particle, wherein, arranging heating rate is 6-8 DEG C/min, and arranging rate of temperature fall is 5-8 DEG C/min.
2) finishing is carried out to ZnO nano acanthosphere particle;
Tensio-active agent and acetone is added in described solution B, ultrasonic 30min, centrifugation 3 times, washing is replaced 4 times with ultrapure water and dehydrated alcohol, 65 DEG C of heating after drying, obtain the ZnO nano acanthosphere particle powder of finishing, ZnO nano acanthosphere spine diameter is 50nm, length is 100 μm, has prepared as the additive in ivory board preparation process.
3) stone paper is prepared
By step 2) auxiliary agent 10 weight part obtained, calcium carbonate 80 weight part, polypropylene 10 weight part mixes in high-speed mixer, by banburying formula three spiro rod reaction type forcing machine extruding pelletization, prepare by rolling press the compound ivory board that thickness is 0.25mm, its performance as shown in Table 1.
Embodiment three
The present embodiment comprises the steps:
1) making ZnO nanometer acanthosphere particle;
Under deionized water temperature being risen to the condition of 70 DEG C, the high-purity argon gas that purity is 99.95% is passed in described deionized water, aeration time is 1h, after the oxygen in removing pure water, adds inorganic zinc salt, and constantly stir, arranging stirring velocity is 1500rpm, and churning time is 0.2h, then adds dispersion agent, stirring 0.2h allows solution mix, and obtains mixed liquor A;
Inorganic additives is added in described mixed liquor A, adjust pH to 9, continue to stir 0.5h, and pass into argon gas in described mixed liquor A, described mixed liquor A is heated, after steaming the moisture in mixed liquor A, backflow is cooled to room temperature, obtains the solution B containing ZnO nano acanthosphere particle, wherein, arranging heating rate is 6-8 DEG C/min, and arranging rate of temperature fall is 5-8 DEG C/min.
2) finishing is carried out to ZnO nano acanthosphere particle;
Tensio-active agent and acetone is added in described solution B, ultrasonic 30min, centrifugation 5 times, washing is replaced 4 times with ultrapure water and dehydrated alcohol, 75 DEG C of heating after drying, obtain the ZnO nano acanthosphere particle powder of finishing, ZnO nano acanthosphere spine diameter is 80nm, length is 80 μm, has prepared as the additive in ivory board preparation process.
3) stone paper is prepared
By step 2) auxiliary agent 10 weight part obtained, calcium carbonate 80 weight part, polypropylene 10 weight part mixes in high-speed mixer, by banburying formula three spiro rod reaction type forcing machine extruding pelletization, prepare by rolling press the compound ivory board that thickness is 0.25mm, its performance as shown in Table 1.
Embodiment four
The present embodiment comprises the steps:
1) making ZnO nanometer acanthosphere particle;
Under deionized water temperature being risen to the condition of 80 DEG C, the high-purity argon gas that purity is 99.95% is passed in described deionized water, aeration time is 3h, after the oxygen in removing pure water, adds inorganic zinc salt, and constantly stir, arranging stirring velocity is 800rpm, and churning time is 0.4h, then adds dispersion agent, stirring 0.4h allows solution mix, and obtains mixed liquor A;
Inorganic additives is added in described mixed liquor A, adjust pH to 9, continue to stir 0.4h, and pass into argon gas in described mixed liquor A, described mixed liquor A is heated, after steaming the moisture in mixed liquor A, backflow is cooled to room temperature, obtains the solution B containing ZnO nano acanthosphere particle, wherein, arranging heating rate is 6-8 DEG C/min, and arranging rate of temperature fall is 5-8 DEG C/min.
2) finishing is carried out to ZnO nano acanthosphere particle;
Tensio-active agent and acetone is added in described solution B, ultrasonic 30min, centrifugation 3 times, washing is replaced 4 times with ultrapure water and dehydrated alcohol, 65 DEG C of heating after drying, obtain the ZnO nano acanthosphere particle powder of finishing, ZnO nano acanthosphere spine diameter is 80nm, length is 150 μm, has prepared as the additive in ivory board preparation process.
3) stone paper is prepared
By step 2) auxiliary agent 10 weight part obtained, calcium carbonate 80 weight part, polypropylene 10 weight part mixes in high-speed mixer, by banburying formula three spiro rod reaction type forcing machine extruding pelletization, prepare by rolling press the compound ivory board that thickness is 0.25mm, its performance as shown in Table 1.
Embodiment five
The present embodiment comprises the steps:
1) making ZnO nanometer acanthosphere particle;
Under deionized water temperature being risen to the condition of 80 DEG C, the high-purity argon gas that purity is 99.95% is passed in described deionized water, aeration time is 3h, after the oxygen in removing pure water, adds inorganic zinc salt, and constantly stir, arranging stirring velocity is 1400rpm, and churning time is 0.5h, then adds dispersion agent, stirring 0.4h allows solution mix, and obtains mixed liquor A;
Inorganic additives is added in described mixed liquor A, adjust pH to 9, continue to stir 0.5h, and pass into argon gas in described mixed liquor A, described mixed liquor A is heated, after steaming the moisture in mixed liquor A, backflow is cooled to room temperature, obtains the solution B containing ZnO nano acanthosphere particle, wherein, arranging heating rate is 6-8 DEG C/min, and arranging rate of temperature fall is 5-8 DEG C/min.
2) finishing is carried out to ZnO nano acanthosphere particle;
Tensio-active agent and acetone is added in described solution B, ultrasonic 30min, centrifugation 3 times, washing is replaced 4 times with ultrapure water and dehydrated alcohol, 80 DEG C of heating after drying, obtain the ZnO nano acanthosphere particle powder of finishing, ZnO nano acanthosphere spine diameter is 100nm, length is 100 μm, has prepared as the additive in ivory board preparation process.
3) stone paper is prepared
By step 2) auxiliary agent 10 weight part obtained, calcium carbonate 80 weight part, polypropylene 10 weight part mixes in high-speed mixer, by banburying formula three spiro rod reaction type forcing machine extruding pelletization, prepare by rolling press the compound ivory board that thickness is 0.25mm, its performance as shown in Table 1.
Table one
Although describe the preferred embodiments of the present invention, those skilled in the art once obtain the basic creative concept of cicada, then can make other change and amendment to these embodiments.So claims are intended to be interpreted as comprising preferred embodiment and falling into all changes and the amendment of the scope of the invention.
Obviously, those skilled in the art can carry out various change and modification to the present invention and not depart from the spirit and scope of the present invention.Like this, if these amendments of the present invention and modification belong within the scope of the claims in the present invention and equivalent technologies thereof, then the present invention is also intended to comprise these change and modification.
Claims (4)
1. promote an auxiliary agent for compound ivory board printing performance, it is characterized in that, described auxiliary agent is prepared according to the component of following weight part:
Inorganic zinc salt 10-20 part
Inorganic additives 10-20 part
Tensio-active agent 0.5-1 part
Dispersion agent 0.5-1 part
Deionized water 60-80 part
Wherein, described inorganic zinc salt is ZnCl
2, ZnSO
4, Zn (CH
3cOO)
2in at least one, described inorganic additives is strong base-weak acid salt NaHCO
3, Na
2cO
3, Na
2sO
3in at least one, described dispersion agent is ethanol, acetone, at least one in pimelinketone, and described tensio-active agent is silicane tensio-active agent.
2. promote a preparation method for compound ivory board printing performance auxiliary agent, it is characterized in that, described preparation method comprises the steps:
1) making ZnO nanometer acanthosphere particle;
2) finishing is carried out to ZnO nano acanthosphere particle;
Wherein, described ZnO nano acanthosphere spine diameter is 20-100nm, and length is 80-150 μm.
3. preparation method as claimed in claim 2, it is characterized in that, step 1) making ZnO nanometer acanthosphere particle, specifically comprises:
Under deionized water temperature being risen to the condition of 30-90 DEG C, the high-purity argon gas that purity is 99.95% is passed in described deionized water, aeration time is 0.5-5h, after the oxygen in removing pure water, adds inorganic zinc salt, and constantly stir, arranging stirring velocity is 800-1500rpm, and churning time is 0.2-0.5h, then adds dispersion agent, stirring 0.2-0.5h allows solution mix, and obtains mixed liquor A;
Inorganic additives is added in described mixed liquor A, adjust pH is to 8-9, continue to stir 0.3-0.5h, and pass into argon gas in described mixed liquor A, described mixed liquor A is heated, after steaming the moisture in mixed liquor A, backflow is cooled to room temperature, obtains the solution B containing ZnO nano acanthosphere particle, wherein, arranging heating rate is 6-8 DEG C/min, and arranging rate of temperature fall is 5-8 DEG C/min.
4. preparation method as claimed in claim 2, is characterized in that, step 2) finishing is carried out to ZnO nano acanthosphere particle, specifically comprise:
Tensio-active agent and acetone is added in described solution B, ultrasonic 30min, centrifugation 3-5 time, with ultrapure water and dehydrated alcohol alternately washing 4-5 time, heating also, after drying, obtains the ZnO nano acanthosphere particle powder of finishing, as the additive in ivory board preparation process, wherein, Heating temperature is 60-80 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510966600.8A CN105566681B (en) | 2015-12-22 | 2015-12-22 | A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof |
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|---|---|---|---|
| CN201510966600.8A CN105566681B (en) | 2015-12-22 | 2015-12-22 | A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof |
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| CN105566681B CN105566681B (en) | 2018-03-16 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107142787A (en) * | 2017-05-24 | 2017-09-08 | 常德金德镭射科技股份有限公司 | A kind of preparation method of mould proof coating paper |
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Cited By (1)
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| CN107142787A (en) * | 2017-05-24 | 2017-09-08 | 常德金德镭射科技股份有限公司 | A kind of preparation method of mould proof coating paper |
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