CN105566681B - A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof - Google Patents

A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof Download PDF

Info

Publication number
CN105566681B
CN105566681B CN201510966600.8A CN201510966600A CN105566681B CN 105566681 B CN105566681 B CN 105566681B CN 201510966600 A CN201510966600 A CN 201510966600A CN 105566681 B CN105566681 B CN 105566681B
Authority
CN
China
Prior art keywords
acanthosphere
parts
particle
zno nano
auxiliary agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510966600.8A
Other languages
Chinese (zh)
Other versions
CN105566681A (en
Inventor
彭海三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guizhou Jinma packaging materials Co., Ltd.
Original Assignee
Guizhou Jinma Packaging Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guizhou Jinma Packaging Materials Co Ltd filed Critical Guizhou Jinma Packaging Materials Co Ltd
Priority to CN201510966600.8A priority Critical patent/CN105566681B/en
Publication of CN105566681A publication Critical patent/CN105566681A/en
Application granted granted Critical
Publication of CN105566681B publication Critical patent/CN105566681B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of auxiliary agent for lifting compound white card printing absorbency and preparation method thereof, the auxiliary agent is prepared according to the component of following parts by weight：10 20 parts of inorganic zinc salt, 10 20 parts of inorganic additive, 0.5 1 parts of surfactant, 0.5 1 parts of dispersant, 60 80 parts of deionized water.By using preparing the modified ZnO nano acanthosphere particle in surface as the auxiliary agent in compound art post paperboard printing process, because ZnO nano acanthosphere particle has siphon micro-structural, chemical surface modification is carried out using activating agent simultaneously, and then the present invention can further improve the absorbency of compound art post paperboard.

Description

A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof
Technical field
The present invention relates to pulp technology for making paper, more particularly to a kind of auxiliary agent for lifting compound art post paperboard printing absorbency and its Preparation method.
Background technology
Paper be the mankind learn, work, one of indispensable important articles for use of living, traditional papermaking due to excessively felling The caused three wastes bring the destruction of high degree to ecological environment in trees and traditional paper industry production technology, and people are to making The cry more and more higher of the feature of environmental protection requirement of raw material and paper product process used in paper.Compound art post paperboard, i.e. stone paper, it is A kind of new material between paper and plastics, both alternative traditional part functionalities paper, professional paper, and can Substitute traditional most of plastic packing article.And can be that user saves largely with the characteristics of cost is low, controllability is degraded Cost, and pollution will not be produced, be the important replacement for substituting traditional plant fibrous paper.
The oil absorbency of paper is to influence its important printability index as print quality.Due to stone Contain a large amount of non-polar components in paper, it is difficult to adhere to and print, it usually needs special ink, the cost of printing is improved, and Special ink is used, ink attachment fastness is also undesirable, and paper is too small to ink absorbability, then can slow down printing product surface oil The rate of drying of ink, print speed printing speed slows down, while causes printed matter set-off, especially for by the dry letterpress of infiltration With high speed printing more very.In addition, using the poor paper of ink absorption, ink absorption property is also poor after its inking.And then carry The absorbency of high stone paper and the printing performance such as antistatic, are an important topics during stone paper R＆D and production.
In the prior art, China Patent Publication No. 101768893A discloses a kind of stone paper coating and production method, will The coatings form a kind of new stone paper on the stone paper film such as PP, BOPP, PVC, PET, can be applied to general Mode of printing and in general ink.But those skilled in the art have found coatings inequality and stone in implementation process Occur the phenomenon that paint aging comes off during paper use, influence printing effect.
China Patent Publication No. 102363572A discloses a kind of functional additive for stone paper, by nanometer Silica and nano alumina surface carry out chemistry and introduce feature adsorption group with grafting after physical modification, as additive After in stone paper, ink affinity group is carried on the surface of paper, enhances the adsorptivity in stone paper printing process, improved The printing quality of stone paper.But those skilled in the art have found spherical nano silicon and received in implementation process Rice oxidation aluminium surface it is smooth, although introducing blotting group, due to blotting group for a long time be exposed to air in, Electrostatic Absorption it is micro- Biology can corrode blotting group, cause the easy aging of ink, coming off for coating, influence printing quality.
The content of the invention
In order to solve compound art post paperboard in printing process difficult attachment and printing, it is necessary to special ink and in printing process In the defects of electrostatic is big also be present, further improve absorbency of the compound art post paperboard in printing process, the embodiment of the present invention carries For a kind of auxiliary agent and preparation method for lifting compound art post paperboard printing performance, received by using the modified ZnO in surface is prepared Rice acanthosphere particle has siphon micro-structural, while carries out chemical surface modification using activating agent, and then the present invention can be further Improve the absorbency of compound art post paperboard.
The present invention provides a kind of auxiliary agent for lifting compound art post paperboard printing performance, it is characterised in that the auxiliary agent is according to such as It is prepared by the component of lower parts by weight：
Inorganic zinc salt 10-20 parts
Inorganic additive 10-20 parts
Surfactant 0.5-1 parts
Dispersant 0.5-1 parts
Deionized water 60-80 parts
Wherein, the inorganic zinc salt is ZnCl2, ZnSO4, Zn（AC）2At least one of, the inorganic additive is strong Alkali salt of weak acid NaHCO3, Na2CO3, Na2SO3At least one of, the dispersant is ethanol, acetone, at least one in cyclohexanone Kind, the surfactant is silanes surfactant.
On the other hand the present invention provides a kind of preparation method for the auxiliary agent for lifting compound art post paperboard printing performance, and its feature exists In the preparation method comprises the following steps：
1）Prepare ZnO nano acanthosphere particle；
2）Surface modification is carried out to ZnO nano acanthosphere particle；
Wherein, a diameter of 20-100nm of ZnO nano acanthosphere spine, length are 80-150 μm.
Preferably, step 1）ZnO nano acanthosphere particle is prepared, is specifically included：
Under conditions of deionized water temperature is risen into 30-90 DEG C, it is 99.95% that purity is passed through into the deionized water High-purity argon gas, duration of ventilation 0.5-5h, after removing the oxygen in pure water, inorganic zinc salt is added, and be stirred continuously, stirring is set Speed is 800-1500rpm, mixing time 0.2-0.5h, adds dispersant, and stirring 0.2-0.5h allows solution to be well mixed, Obtain mixed liquor A；
Add inorganic additive into the mixed liquor A, adjust pH values to 8-9, continue to stir 0.3-0.5h, and to Argon gas is passed through in the mixed liquor A, the mixed liquor A is heated, after the moisture in mixed liquor A is steamed, backflow is cooled to room temperature, The solution B containing ZnO nano acanthosphere particle is obtained, wherein, the setting rate of heat addition is 6-8 DEG C/min, and setting rate of temperature fall is 5-8 ℃/min。
Preferably, step 2）Surface modification is carried out to ZnO nano acanthosphere particle, specifically included：
Surfactant and acetone are added into the solution B, 30 min of ultrasound, centrifuges 3-5 times, uses ultra-pure water With absolute ethyl alcohol alternately washing 4-5 times, after heating and drying, the ZnO nano acanthosphere particle powder of surface modification is obtained, as Additive in art post paperboard preparation process, wherein, heating-up temperature is 60-80 DEG C.
Said one or multiple technical schemes in the embodiment of the present application, at least there is following one or more technology effects Fruit：
1st, due to by using preparing ZnO nano acanthosphere particle, then carrying out surface to ZnO nano acanthosphere particle in the present invention The technological means of modification prepares compound art post paperboard printing performance auxiliary agent, because the ZnO nano acanthosphere particle of preparation has siphon Micro-structural, meanwhile, ZnO nano acanthosphere particle surface has carried out the auxiliary agent that chemical graft is used as compound art post paperboard, is compared to Prior art only can further improve the absorbency of compound art post paperboard by the means of chemical graft, the present invention.
2nd, due to being grafted in the present invention using ZnO nano acanthosphere particle to it, because nanometer acanthosphere grain structure has There is bigger surface area, and then nano grain surface grafting number can be increased, as additive application in compound art post paperboard Afterwards, it can be formed on the surface of paper and more carry ink affinity group, ZnO surfaces inherently from hydroxyl polar group, increase paper Anti-static function is opened, so as to improve the printing performance of compound art post paperboard.
3rd, due to using ZnO nano acanthosphere particle in the present invention, the end of acanthosphere particle possesses spine structure, easily pierces through The cell membrane of the microorganism of absorption kills microorganism so that art post paperboard also has antibacterial characteristics.Meanwhile spine also easily pierces through oil Black liquid is dripped so that the increase of ink wellability.
4th, the preparation method technique of the compound art post paperboard printing performance auxiliary agent of present invention lifting is simple and easy to control, disclosure satisfy that big rule Mould production needs, and has certain market application value.
Embodiment
By embodiment, the present invention is described in further detail, but this should not be interpreted as to the model of the present invention Enclose and be only limitted to following example.In the case where not departing from above method thought of the present invention, according to ordinary skill knowledge The various replacements or change made with customary means, should be included in the scope of the present invention.
Embodiment one
The present embodiment comprises the following steps：
1）Prepare ZnO nano acanthosphere particle；
Under conditions of deionized water temperature is risen into 30 DEG C, be passed through into the deionized water purity be 99.95% it is high-purity Argon gas, duration of ventilation 0.5h, after removing the oxygen in pure water, inorganic zinc salt is added, and be stirred continuously, setting mixing speed is 800rpm, mixing time 0.2h, add dispersant, and stirring 0.2h allows solution to be well mixed, obtains mixed liquor A；
Inorganic additive is added into the mixed liquor A, adjusts pH values to continue to stir 0.3h, and mix to described to 8 Close in liquid A and be passed through argon gas, the mixed liquor A is heated, after the moisture in mixed liquor A is steamed, backflow is cooled to room temperature, is contained Have the solution B of ZnO nano acanthosphere particle, wherein, the setting rate of heat addition is 6-8 DEG C/min, set rate of temperature fall be 5-8 DEG C/ min。
2）Surface modification is carried out to ZnO nano acanthosphere particle；
Surfactant and acetone are added into the solution B, 30 min of ultrasound, is centrifuged 3 times, with ultra-pure water with Absolute ethyl alcohol alternately washing 4 times, after 65 DEG C are heated and dried, obtain the ZnO nano acanthosphere particle powder of surface modification, ZnO The nanometer a diameter of 20nm of acanthosphere spine, length are 80 μm, are prepared for as the additive in art post paperboard preparation process.
3）Prepare stone paper
By step 2）The obtained parts by weight of auxiliary agent 10, the parts by weight of calcium carbonate 80, the parts by weight of polypropylene 10 are in mixed at high speed It is well mixed in machine, by the spiro rod reaction type extruder extruding pelletization of banburying formula three, thickness, which is prepared, by calender is 0.25mm compound art post paperboard, its performance is as shown in Table 1.
Embodiment two
The present embodiment comprises the following steps：
1）Prepare ZnO nano acanthosphere particle；
Under conditions of deionized water temperature is risen into 50 DEG C, be passed through into the deionized water purity be 99.95% it is high-purity Argon gas, duration of ventilation 1h, after removing the oxygen in pure water, inorganic zinc salt is added, and be stirred continuously, setting mixing speed is 1000rpm, mixing time 0.2h, add dispersant, and stirring 0.2h allows solution to be well mixed, obtains mixed liquor A；
Add inorganic additive into the mixed liquor A, adjust pH values to 8.5, continue to stir 0.4h, and to described Argon gas is passed through in mixed liquor A, the mixed liquor A is heated, after the moisture in mixed liquor A is steamed, backflow is cooled to room temperature, obtains Solution B containing ZnO nano acanthosphere particle, wherein, the setting rate of heat addition is 6-8 DEG C/min, set rate of temperature fall be 5-8 DEG C/ min。
2）Surface modification is carried out to ZnO nano acanthosphere particle；
Surfactant and acetone are added into the solution B, 30 min of ultrasound, is centrifuged 3 times, with ultra-pure water with Absolute ethyl alcohol alternately washing 4 times, after 65 DEG C are heated and dried, obtain the ZnO nano acanthosphere particle powder of surface modification, ZnO The nanometer a diameter of 50nm of acanthosphere spine, length are 100 μm, are prepared for as the additive in art post paperboard preparation process.
3）Prepare stone paper
By step 2）The obtained parts by weight of auxiliary agent 10, the parts by weight of calcium carbonate 80, the parts by weight of polypropylene 10 are in mixed at high speed It is well mixed in machine, by the spiro rod reaction type extruder extruding pelletization of banburying formula three, thickness, which is prepared, by calender is 0.25mm compound art post paperboard, its performance is as shown in Table 1.
Embodiment three
The present embodiment comprises the following steps：
1）Prepare ZnO nano acanthosphere particle；
Under conditions of deionized water temperature is risen into 70 DEG C, be passed through into the deionized water purity be 99.95% it is high-purity Argon gas, duration of ventilation 1h, after removing the oxygen in pure water, inorganic zinc salt is added, and be stirred continuously, setting mixing speed is 1500rpm, mixing time 0.2h, add dispersant, and stirring 0.2h allows solution to be well mixed, obtains mixed liquor A；
Inorganic additive is added into the mixed liquor A, adjusts pH values to continue to stir 0.5h, and mix to described to 9 Close in liquid A and be passed through argon gas, the mixed liquor A is heated, after the moisture in mixed liquor A is steamed, backflow is cooled to room temperature, is contained Have the solution B of ZnO nano acanthosphere particle, wherein, the setting rate of heat addition is 6-8 DEG C/min, set rate of temperature fall be 5-8 DEG C/ min。
2）Surface modification is carried out to ZnO nano acanthosphere particle；
Surfactant and acetone are added into the solution B, 30 min of ultrasound, is centrifuged 5 times, with ultra-pure water with Absolute ethyl alcohol alternately washing 4 times, after 75 DEG C are heated and dried, obtain the ZnO nano acanthosphere particle powder of surface modification, ZnO The nanometer a diameter of 80nm of acanthosphere spine, length are 80 μm, are prepared for as the additive in art post paperboard preparation process.
3）Prepare stone paper
By step 2）The obtained parts by weight of auxiliary agent 10, the parts by weight of calcium carbonate 80, the parts by weight of polypropylene 10 are in mixed at high speed It is well mixed in machine, by the spiro rod reaction type extruder extruding pelletization of banburying formula three, thickness, which is prepared, by calender is 0.25mm compound art post paperboard, its performance is as shown in Table 1.
Example IV
The present embodiment comprises the following steps：
1）Prepare ZnO nano acanthosphere particle；
Under conditions of deionized water temperature is risen into 80 DEG C, be passed through into the deionized water purity be 99.95% it is high-purity Argon gas, duration of ventilation 3h, after removing the oxygen in pure water, inorganic zinc salt is added, and be stirred continuously, setting mixing speed is 800rpm, mixing time 0.4h, add dispersant, and stirring 0.4h allows solution to be well mixed, obtains mixed liquor A；
Inorganic additive is added into the mixed liquor A, adjusts pH values to continue to stir 0.4h, and mix to described to 9 Close in liquid A and be passed through argon gas, the mixed liquor A is heated, after the moisture in mixed liquor A is steamed, backflow is cooled to room temperature, is contained Have the solution B of ZnO nano acanthosphere particle, wherein, the setting rate of heat addition is 6-8 DEG C/min, set rate of temperature fall be 5-8 DEG C/ min。
2）Surface modification is carried out to ZnO nano acanthosphere particle；
Surfactant and acetone are added into the solution B, 30 min of ultrasound, is centrifuged 3 times, with ultra-pure water with Absolute ethyl alcohol alternately washing 4 times, after 65 DEG C are heated and dried, obtain the ZnO nano acanthosphere particle powder of surface modification, ZnO The nanometer a diameter of 80nm of acanthosphere spine, length are 150 μm, are prepared for as the additive in art post paperboard preparation process.
3）Prepare stone paper
By step 2）The obtained parts by weight of auxiliary agent 10, the parts by weight of calcium carbonate 80, the parts by weight of polypropylene 10 are in mixed at high speed It is well mixed in machine, by the spiro rod reaction type extruder extruding pelletization of banburying formula three, thickness, which is prepared, by calender is 0.25mm compound art post paperboard, its performance is as shown in Table 1.
Embodiment five
The present embodiment comprises the following steps：
1）Prepare ZnO nano acanthosphere particle；
Under conditions of deionized water temperature is risen into 80 DEG C, be passed through into the deionized water purity be 99.95% it is high-purity Argon gas, duration of ventilation 3h, after removing the oxygen in pure water, inorganic zinc salt is added, and be stirred continuously, setting mixing speed is 1400rpm, mixing time 0.5h, add dispersant, and stirring 0.4h allows solution to be well mixed, obtains mixed liquor A；
Inorganic additive is added into the mixed liquor A, adjusts pH values to continue to stir 0.5h, and mix to described to 9 Close in liquid A and be passed through argon gas, the mixed liquor A is heated, after the moisture in mixed liquor A is steamed, backflow is cooled to room temperature, is contained Have the solution B of ZnO nano acanthosphere particle, wherein, the setting rate of heat addition is 6-8 DEG C/min, set rate of temperature fall be 5-8 DEG C/ min。
2）Surface modification is carried out to ZnO nano acanthosphere particle；
Surfactant and acetone are added into the solution B, 30 min of ultrasound, is centrifuged 3 times, with ultra-pure water with Absolute ethyl alcohol alternately washing 4 times, after 80 DEG C are heated and dried, obtain the ZnO nano acanthosphere particle powder of surface modification, ZnO The nanometer a diameter of 100nm of acanthosphere spine, length are 100 μm, are prepared for as the additive in art post paperboard preparation process.
3）Prepare stone paper
By step 2）The obtained parts by weight of auxiliary agent 10, the parts by weight of calcium carbonate 80, the parts by weight of polypropylene 10 are in mixed at high speed It is well mixed in machine, by the spiro rod reaction type extruder extruding pelletization of banburying formula three, thickness, which is prepared, by calender is 0.25mm compound art post paperboard, its performance is as shown in Table 1.
Table one
Although preferred embodiments of the present invention have been described, but those skilled in the art once know basic creation Property concept, then can make other change and modification to these embodiments.So appended claims be intended to be construed to include it is excellent Select embodiment and fall into having altered and changing for the scope of the invention.
Obviously, those skilled in the art can carry out the essence of various changes and modification without departing from the present invention to the present invention God and scope.So, if these modifications and variations of the present invention belong to the scope of the claims in the present invention and its equivalent technologies Within, then the present invention is also intended to comprising including these changes and modification.

Claims (1)

  1. A kind of 1. auxiliary agent for lifting compound art post paperboard printing performance, it is characterised in that the auxiliary agent according to following parts by weight group Divide and prepare：
    Inorganic zinc salt 10-20 parts
    Inorganic additive 10-20 parts
    Surfactant 0.5-1 parts
    Dispersant 0.5-1 parts
    Deionized water 60-80 parts
    Wherein, the inorganic zinc salt is ZnCl2, ZnSO4, Zn (CH3COO)2At least one of, the inorganic additive is highly basic Salt of weak acid NaHCO3, Na2CO3, Na2SO3At least one of, the dispersant is ethanol, acetone, at least one in cyclohexanone Kind, the surfactant is silanes surfactant；
    Its preparation method comprises the following steps：
    1）Prepare ZnO nano acanthosphere particle；
    2）Surface modification is carried out to ZnO nano acanthosphere particle；
    Wherein, a diameter of 20-100nm of ZnO nano acanthosphere spine, length are 80-150 μm；
    Step 1）ZnO nano acanthosphere particle is prepared, is specifically included：
    Under conditions of deionized water temperature is risen into 30-90 DEG C, be passed through into the deionized water purity be 99.95% it is high-purity Argon gas, duration of ventilation 0.5-5h, after removing the oxygen in pure water, inorganic zinc salt is added, and be stirred continuously, mixing speed is set For 800-1500rpm, mixing time 0.2-0.5h, dispersant is added, stirring 0.2-0.5h allows solution to be well mixed, obtained Mixed liquor A；
    Inorganic additive is added into the mixed liquor A, adjusts pH value to continue to stir 0.3-0.5h, and mix to described to 8-9 Close in liquid A and be passed through argon gas, the mixed liquor A is heated, after the moisture in mixed liquor A is steamed, backflow is cooled to room temperature, obtains Solution B containing ZnO nano acanthosphere particle, wherein, the setting rate of heat addition is 6-8 DEG C/min, set rate of temperature fall be 5-8 DEG C/ min；
    Step 2）Surface modification is carried out to ZnO nano acanthosphere particle, specifically included：
    Surfactant and acetone are added into the solution B, ultrasonic 30min, is centrifuged 3-5 times, with ultra-pure water and anhydrous Ethanol alternately washing 4-5 times, after heating and drying, obtains the ZnO nano acanthosphere particle powder of surface modification, as art post paperboard Additive in preparation process, wherein, heating-up temperature is 60-80 DEG C.
CN201510966600.8A 2015-12-22 2015-12-22 A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof Active CN105566681B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510966600.8A CN105566681B (en) 2015-12-22 2015-12-22 A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510966600.8A CN105566681B (en) 2015-12-22 2015-12-22 A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105566681A CN105566681A (en) 2016-05-11
CN105566681B true CN105566681B (en) 2018-03-16

Family

ID=55877357

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510966600.8A Active CN105566681B (en) 2015-12-22 2015-12-22 A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105566681B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142787A (en) * 2017-05-24 2017-09-08 常德金德镭射科技股份有限公司 A kind of preparation method of mould proof coating paper

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1491895A (en) * 2003-09-09 2004-04-28 中国科学院上海技术物理研究所 Process for preparing nano zinc oxide material
CN1511889A (en) * 2002-12-27 2004-07-14 北京服装学院 Surface modified nano zinc oxide water dispersion and its preparing method and use
CN1533985A (en) * 2003-03-31 2004-10-06 上海大学 Preparation method of nano-grade zinc oxide powder
CN101249979A (en) * 2008-04-01 2008-08-27 西南交通大学 Atmospheric preparation method of prickly sphere zinc oxide
CN103085526A (en) * 2011-11-03 2013-05-08 中国科学院化学研究所 Printing plate material for ink-jet printing direct-to-plate and preparation method of printing plate material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1511889A (en) * 2002-12-27 2004-07-14 北京服装学院 Surface modified nano zinc oxide water dispersion and its preparing method and use
CN1533985A (en) * 2003-03-31 2004-10-06 上海大学 Preparation method of nano-grade zinc oxide powder
CN1491895A (en) * 2003-09-09 2004-04-28 中国科学院上海技术物理研究所 Process for preparing nano zinc oxide material
CN101249979A (en) * 2008-04-01 2008-08-27 西南交通大学 Atmospheric preparation method of prickly sphere zinc oxide
CN103085526A (en) * 2011-11-03 2013-05-08 中国科学院化学研究所 Printing plate material for ink-jet printing direct-to-plate and preparation method of printing plate material

Also Published As

Publication number Publication date
CN105566681A (en) 2016-05-11

Similar Documents

Publication Publication Date Title
KR101776373B1 (en) A composition and method for controlling the wettability of surfaces
CN107556684B (en) A kind of anti-aging plastic packaging bag and preparation method thereof
CA2800647A1 (en) A process for the production of a composition of microfibrillated cellulose and pigment
CN110835377B (en) Hydrophobic modified nano-cellulose and preparation method and application thereof
CN103590282A (en) Coating and coating used coated paper
CN109689760A (en) Resin, which is strengthened, uses packing material and resin combination
WO2007110639A1 (en) Method for producing particulate inorganic material
CN106280218B (en) A kind of preparation method of the composition for being used to prepare antimicrobial composite material and antimicrobial composite material
CN105131747A (en) Weak solvent type inkjet media and preparation method thereof
CN105899628A (en) Lignin-based waterproof coating
AU2020102808A4 (en) Hydrophobic enhanced painting and calligraphy paper and preparation method thereof
CN108976574A (en) A kind of breathable polyethylene film
CN106496622A (en) A kind of nano-cellulose composite antibacterial material and preparation method thereof
CN105566681B (en) A kind of auxiliary agent for lifting compound art post paperboard printing performance and preparation method thereof
CN107140910A (en) A kind of tile grout of adsorbable formaldehyde and preparation method thereof
KR20050109898A (en) Unusually narrow particle size distribution calcined kaolins
CN109161043A (en) A kind of preparation method of high-barrier antibacterial composite package film
CN102966006A (en) Preparation technology of light coated paper and coating coated on paper
CN110804900B (en) Hydrophobic enhanced painting and calligraphy paper and preparation method thereof
US20080267851A1 (en) High Whiteness Metakaolin and High Whiteness Fully Calcined Kaolin
CN107556329A (en) A kind of porous metals organic framework materials and preparation method thereof
CN105482343B (en) A kind of plant fiber powder surface treatment auxiliary agent and preparation method thereof
CN108129066B (en) Preparation method of silver-loaded palygorskite heat-resistant liquid wallpaper
CN109181076A (en) A kind of preparation method of mould proof antifog polyethylene preservative film
CN112048034B (en) Antibacterial acrylic emulsion for water-based pigment and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Peng Haisan

Inventor before: Chen Qing

Inventor before: Zeng Juntang

Inventor before: Ye Renhai

Inventor before: Chen Bing

TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20180208

Address after: No. 43, No. 1, No. 3, Fu Shui North Road, Yunyan District, Guiyang, Guizhou Province, No. 1

Applicant after: Guizhou Jinma packaging materials Co., Ltd.

Address before: Qingyang District of Chengdu City, Sichuan province 610091 Dragon Industrial Port East Road 4

Applicant before: Chengdu Xinkeli Chemical Sci-Tech Co., Ltd.

GR01 Patent grant
GR01 Patent grant