CN105564082A - Hairbrush and manufacturing process thereof - Google Patents
Hairbrush and manufacturing process thereof Download PDFInfo
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- CN105564082A CN105564082A CN201610008645.9A CN201610008645A CN105564082A CN 105564082 A CN105564082 A CN 105564082A CN 201610008645 A CN201610008645 A CN 201610008645A CN 105564082 A CN105564082 A CN 105564082A
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- hair
- nylon
- pen core
- powder
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K1/00—Nibs; Writing-points
- B43K1/12—Writing-points comprising fibres; Felt pads
Abstract
The invention discloses a hairbrush and a manufacturing process of the hairbrush. By completely optimizing the processing of nylon wool, treatment of animal wool and variety selection and match of the wool, the obtained hairbrush has high elasticity and high ink holding capacity in both writing and painting, a user can write words comfortably, the words written with the hairbrush are vigorous and forceful, stretch long and have a high artistic effect, and the hairbrush varies in hardness when used for writing. The hairbrush has high quality and good market prospects. As the nylon wool technology is improved and damage to the animal wool is reduced by improving the animal wool technology, the hairbrush is more elastic and durable and can be kept for a long period.
Description
Technical field
The present invention relates to a kind of writing brush and manufacture craft thereof, belong to writing implement and make field.
Background technology
Writing brush is the traditional writing implement of China, writing brush can be divided into goat hair brush, wolf hair brush, rabbit hair pen according to pen hair and milli pen of holding concurrently etc. multiple, wolf hair brush is the pen that raw material is made with yellow weasel tail hair; Goat hair brush is the pen that raw material is made with the hair of goat; Mouse must pen be the pen must made with home mouse temples; Milli pen of holding concurrently mixes with several fine, soft fur the writing brush made, and it is hard and soft moderate.When making double milli, the performance of various hair matter, the proportioning of feature is wanted suitably, the ratio of preparation, selection have to be wanted rationally, length, the content of several maos will calculate the result of use that accurately just can reach as scheduled, therefore hold concurrently the technique of milli higher than other technique, be to spend the huge time, human and material resources carry out testing and just can make.
Prior art has people to use nylon hair to mix the research preparing writing brush in animal wool, and the durability of nylon hair and good corrosion resistance, but the poor flexibility of nylon hair, easily disperse, water conservation rate variance, and feel is not as animal wool.
The present invention aims to provide a kind of new writing brush and manufacture craft thereof, the nib of writing brush comprises the pen core attendant of a stage actor and is rolled in and drapes over one's shoulders milli outside pen core, pen core is coniform by making after the mixing of length different, diverse hair, thus obtained good springiness, durable writing brush, and described writing brush vigorous and forceful in process drawn by book, prolong continuous without cease, have artistic effect, and in conjunction with modern crafts, it is more durable, and the holding time is long.
Summary of the invention
Based on the technical problem that background technology exists, a kind of new writing brush of the present invention and manufacture craft thereof, the nib of writing brush comprises the pen core attendant of a stage actor and is rolled in and drapes over one's shoulders milli outside pen core, pen core be make after being mixed by different, the diverse hair of length coniform, thus obtained good springiness, durable writing brush, and described writing brush vigorous and forceful in process drawn by book, prolong continuous without cease, has artistic effect, and in conjunction with modern crafts, it is more durable, and the holding time is long.
Natural Mao Douhui has peak grain husk, and top all naturally can be tapered and come to a point, and nylon hair is man-made hair, therefore cuts sth. askew on top, but the poor flexibility of nylon hair, and easily disperse, water conservation rate variance, feel is not as animal wool.Therefore, the nylon hair of the present invention to writing brush has also carried out modification.Specifically, be carried out blending and modifying, by the various ingredients of nylon 6 and specified particle diameter being mixed, it is special to prepare, the nylon 6 of applicable writing brush.Each material of co-mixing system is added in modification, and particle diameter is all most important, slightly deviation will have a great impact result, and the present inventor is on the basis of numerous experiments, under surprisingly having found this particular modification method, the modification of nylon hair of suitable writing brush can be prepared.
The writing brush pen core made after proportionally being mixed with specific length by multiple specific hair like this can be very full, and do not need to adopt bristles hair, (elasticity is relatively good and thinner than weasel dodds to adopt weasel dodds (having certain degree of hardness and elasticity) and dog shank-feathering, hair is more straight and upright, not easily warpage, can not stick up open outside pen core, more docile) combine the elasticity increasing pen core, elasticity is more natural, write sense better, add the soft very thin rabbit hair simultaneously and can increase blotting amount, dog shank-feathering adopts the shank-feathering of average adult China rural area dog, the milli that drapes over one's shoulders outside pen core adopts pure goats hair.
Tradition normally increases bristles in order to the elasticity increasing pen, and this hair is harder, and not too docile, morely a little will sting out outward, and it is bad to write sense, and affect calligraphy and drawing effect, the fuller elasticity of pen of the present invention is also relatively good.
Technical scheme of the present invention is as follows:
A kind of writing brush, the pen core of described brush writing skill is made up of the raw material of following percentage by weight:
Pen core:
It is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness;
The preparation method of described nylon hair is:
(1) preparation of modification of nylon 6: by nylon 680-85 part, tourmaline powder 2-2.8 part, sericite in powder 1-1.3 part, talcum powder 0.5 part, 0.8 part, nano imvite powder, magnesia 0.5-0.6 part, shitosan 0.3 part adds in high-speed mixer, obtains modification of nylon 6 mixture after high speed dispersion: mixture melt-processed becomes diameter D to be the modification of nylon 6 of 0.10mm;
The particle diameter of described tourmaline powder is 5-8nm; The particle diameter of sericite in powder is 10-15nm, and talcous particle diameter is 18-22nm, and the particle diameter of nano imvite powder is 5-6nm, and magnesian particle diameter is 16-20nm.
(2) swelling abrasion legal system is for nylon hair: it is long by diameter D to be that the modification of nylon 6 of 0.10mm is cut into 65mm, by film wrapped, be rolled into the fibre bundle that diameter is 10mm, one end fiber for mill exposes 23-28mm, fibre bundle is held for mill and soaks 12 seconds in swelling solution, then use conventional method to be immersed in molten mill liquid and grind, rear use 95% ethanol washing full to the brim, be washed to neutrality again, encase with film and shape at 80 DEG C of process 30-50min;
Described swelling solution is, is made into as follows according to volume proportion: 80-85 part phenmethylol, 8 parts of bright sulfur acid, 8 part of 95% ethanol, 2-3 part glacial acetic acid, the sodium chloride solution of 5-6 part 38-40g/L;
Described molten mill liquid is be made into as follows according to volume proportion: 90-95 part phenmethylol, 120 part of 95% ethanol, the sodium chloride solution of 6 parts of 38-40g/L;
Modified nylon technique is major progress of the present invention, especially finds, the proportion of the shitosan added, and the selection of molecular weight is important especially, only has suitable proportioning and molecular weight just can reach unexpected like this water retention (ink absorption ability).Even if other proportions constant of this formula, add the shitosan (large or little) of different molecular weight, the water retention of its modification of nylon hair only has 99% at most.
A system process of described writing brush is:
(1) prepare nylon hair, be divided into a lot of tuftlet;
(2) animal hairs process: soaked by above-mentioned animal wool respectively, with the Tea Saponin aqueous solution of 2% percentage by weight at 50 DEG C, processes 15min under pH=7.0; Hair after process is added respectively 80 DEG C of clarification limewash and carry out ungrease treatment 1min, then taken out by hair, immerse 4-5min in citric acid solution in the mode of level, the pH value of described citric acid solution is 6, and then clear water is cleaned and dried;
(3) mixing manufacture nib: animal wool after treatment, make tuftlet, proportionally tuftlet animal wool and nylon hair are mixed with combing machine for fur, mixed pen core hair picking when making pen core is a branch of, this bundle hair is paved on flat board, through reason hair, and then roll from one end and make coniform, be then in the least wrapped in outside pen core will draping over one's shoulders, drape over one's shoulders milli length and be slightly shorter than pen core length, expose pen core peak grain husk, it is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness.
Drape over one's shoulders the writing brush smooth outer surface that milli mainly makes to make, the pen core made due to the present invention does not have burr too short or really up to the mark and goes out outer surface, therefore drapes over one's shoulders and do not need too thick, and the hair draping over one's shoulders milli requires all higher usually, price is also high, and tradition is at least monolateral 2mm thickness.
Usefulness of the present invention is:
1, this writing brush have elasticity in process drawn by book, store black ability strong, comfortable writing, and vigorous and forceful in using, prolong continuous without cease, have artistic effect, writing soft or hard can take into account; Writing brush quality of the present invention is high, and quality is good, has extraordinary market prospects;
2, the nylon hair technique by improving, make this writing brush more flexible, more durable, and the holding time is very long;
3, the animal wool technique by improving, makes animal wool be hurt little, make this writing brush more flexible, more durable, and the holding time is very long.
Detailed description of the invention
Embodiment 1:
A kind of writing brush, the pen core of described brush writing skill is made up of the raw material of following percentage by weight:
Pen core:
It is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1mm thickness;
The preparation method of described nylon hair is:
(1) preparation of modification of nylon 6: by nylon 683 parts, tourmaline powder 2.6 parts, sericite in powder 1 part, talcum powder 0.5 part, 0.8 part, nano imvite powder, 0.5 part, magnesia, shitosan 0.3 part (molecular weight of described shitosan is 2500-3200); Add in high-speed mixer, after high speed dispersion, obtain modification of nylon 6 mixture: mixture melt-processed becomes diameter D to be the modification of nylon 6 of 0.10mm;
The particle diameter of described tourmaline powder is 8nm; The particle diameter of sericite in powder is 10nm, and talcous particle diameter is 18nm, and the particle diameter of nano imvite powder is 5nm, and magnesian particle diameter is 16nm.
(2) swelling abrasion legal system is for nylon hair: it is long by diameter D to be that the modification of nylon 6 of 0.10mm is cut into 65mm, by film wrapped, be rolled into the fibre bundle that diameter is 10mm, one end fiber for mill exposes 23-28mm, fibre bundle is held for mill and soaks 12 seconds in swelling solution, then use conventional method to be immersed in molten mill liquid and grind, rear use 95% ethanol washing full to the brim, be washed to neutrality again, encase with film and shape at 80 DEG C of process 30-50min;
Described swelling solution is, is made into as follows according to volume proportion: 80 parts of phenmethylols, 8 parts of bright sulfur acid, 8 part of 95% ethanol, 2 parts of glacial acetic acid, the sodium chloride solution of 5 parts of 40g/L;
Described molten mill liquid is be made into as follows according to volume proportion: 90 parts of phenmethylols, 120 part of 95% ethanol, the sodium chloride solution of 6 parts of 38g/L;
The nylon hair surface of making is comparatively smooth, and cone is long is 10mm, and sharp point diameter is 0.0015mm; Water retention, up to 142%, stores black very excellent capacity, and tough and difficult disconnected, hot strength is greater than 4200, and elastic modelling quantity is 15.8 × 10
4/kg.cm
-2.
A system process of described writing brush is:
(1) prepare nylon hair according to the method described above, be divided into a lot of tuftlet;
(2) above-mentioned raw materials animal wool is processed: respectively above-mentioned animal wool is soaked, with the Tea Saponin aqueous solution of 2% percentage by weight at 50 DEG C, under pH=7.0, process 15min; Hair after process is added respectively 80 DEG C of clarification limewash and carry out ungrease treatment 1min, then taken out by hair, immerse 5min in citric acid solution in the mode of level, the pH value of described citric acid solution is 6, and then clear water is cleaned and dried;
(3) mixing manufacture nib: animal wool after treatment, make tuftlet, proportionally tuftlet animal wool and nylon hair are mixed with combing machine for fur, mixed pen core hair picking when making pen core is a branch of, this bundle hair is paved on flat board, through reason hair, and then roll from one end and make coniform, then will drape over one's shoulders and be in the least wrapped in outside pen core, drape over one's shoulders milli length and be slightly shorter than pen core length, expose pen core peak grain husk, it is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness.
Write impression: store black very excellent capacity, neither too hard, nor too soft in process drawn by institute's book, resilient enough, vigorous and forceful, prolong continuous without cease, imposing manner is extensive, has artistic effect, stores black ability strong.
Embodiment 2:
A kind of writing brush, the pen core of described brush writing skill is made up of the raw material of following percentage by weight:
Pen core:
It is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness;
The preparation method of described nylon hair is:
(1) preparation of modification of nylon 6: by nylon 685 parts, tourmaline powder 2.8 parts, sericite in powder 1 part, talcum powder 0.5 part, 0.8 part, nano imvite powder, 0.5 part, magnesia, shitosan 0.3 part (molecular weight of described shitosan is 2500-3200) adds in high-speed mixer, obtains modification of nylon 6 mixture after high speed dispersion: mixture melt-processed becomes diameter D to be the modification of nylon 6 of 0.10mm;
(2) swelling abrasion legal system is for nylon hair: it is long by diameter D to be that the modification of nylon 6 of 0.10mm is cut into 65mm, by film wrapped, be rolled into the fibre bundle that diameter is 10mm, one end fiber for mill exposes 23-28mm, fibre bundle is held for mill and soaks 12 seconds in swelling solution, then use conventional method to be immersed in molten mill liquid and grind, rear use 95% ethanol washing full to the brim, be washed to neutrality again, encase with film and shape at 80 DEG C of process 30min;
The particle diameter of described tourmaline powder is 5nm; The particle diameter of sericite in powder is 12nm, and talcous particle diameter is 20nm, and the particle diameter of nano imvite powder is 6nm, and magnesian particle diameter is 18nm.
Described swelling solution is, is made into as follows according to volume proportion: 82 parts of phenmethylols, 8 parts of bright sulfur acid, 8 part of 95% ethanol, 2 parts of glacial acetic acid, the sodium chloride solution of 5 parts of 38g/L;
Described molten mill liquid is be made into as follows according to volume proportion: 90 parts of phenmethylols, 120 part of 95% ethanol, the sodium chloride solution of 6 parts of 40g/L;
The nylon hair surface of making is comparatively smooth, and cone is long is 9mm, and sharp point diameter is 0.0015mm; Water retention, up to 130%, stores black very excellent capacity, and tough and difficult disconnected, hot strength is greater than 4000, and elastic modelling quantity is 9.9 × 10
4/kg.cm
-2.
A system process of described writing brush is:
(1) prepare nylon hair according to the method described above, be divided into a lot of tuftlet;
(2) above-mentioned raw materials animal wool is processed: respectively above-mentioned animal wool is soaked, with the Tea Saponin aqueous solution of 2% percentage by weight at 50 DEG C, under pH=7.0, process 15min; Hair after process is added respectively 80 DEG C of clarification limewash and carry out ungrease treatment 1min, then taken out by hair, immerse 4min in citric acid solution in the mode of level, the pH value of described citric acid solution is 6, and then clear water is cleaned and dried;
(3) mixing manufacture nib: animal wool after treatment, make tuftlet, proportionally tuftlet animal wool and nylon hair are mixed with combing machine for fur, mixed pen core hair picking when making pen core is a branch of, this bundle hair is paved on flat board, through reason hair, and then roll from one end and make coniform, then will drape over one's shoulders and be in the least wrapped in outside pen core, drape over one's shoulders milli length and be slightly shorter than pen core length, expose pen core peak grain husk, it is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness.
Write impression: store black very excellent capacity, neither too hard, nor too soft in process drawn by institute's book, resilient enough, vigorous and forceful, prolong continuous without cease, imposing manner is extensive, has artistic effect, stores black ability strong.
Embodiment 3:
A kind of writing brush, the pen core of described brush writing skill is made up of the raw material of following percentage by weight:
Pen core:
It is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness;
The preparation method of described nylon hair is:
(1) preparation of modification of nylon 6: by nylon 683 parts, tourmaline powder 2.5 parts, sericite in powder 1 part, talcum powder 0.5 part, 0.8 part, nano imvite powder, 0.5 part, magnesia, shitosan 0.3 part (molecular weight of described shitosan is 2500-3200) adds in high-speed mixer, obtains modification of nylon 6 mixture after high speed dispersion: mixture melt-processed becomes diameter D to be the modification of nylon 6 of 0.10mm;
The particle diameter of described tourmaline powder is 7nm; The particle diameter of sericite in powder is 13nm, and talcous particle diameter is 21nm, and the particle diameter of nano imvite powder is 6nm, and magnesian particle diameter is 18nm.
(2) swelling abrasion legal system is for nylon hair: it is long by diameter D to be that the modification of nylon 6 of 0.10mm is cut into 65mm, by film wrapped, be rolled into the fibre bundle that diameter is 10mm, one end fiber for mill exposes 23-28mm, fibre bundle is held for mill and soaks 12 seconds in swelling solution, then use conventional method to be immersed in molten mill liquid and grind, rear use 95% ethanol washing full to the brim, be washed to neutrality again, encase with film and shape at 80 DEG C of process 30-50min;
Described swelling solution is, is made into as follows according to volume proportion: 81 parts of phenmethylols, 8 parts of bright sulfur acid, 8 part of 95% ethanol, 2 parts of glacial acetic acid, the sodium chloride solution of 5 parts of 40g/L;
Described molten mill liquid is be made into as follows according to volume proportion: 95 parts of phenmethylols, 120 part of 95% ethanol, the sodium chloride solution of 6 parts of 40g/L;
The nylon hair surface of making is comparatively smooth, and cone is long is 9mm, and sharp point diameter is 0.0015mm; Water retention, up to 135%, stores black very excellent capacity, and tough and difficult disconnected, hot strength is greater than 4000, and elastic modelling quantity is 10.2 × 10
4/kg.cm
-2.
A system process of described writing brush is:
(1) prepare nylon hair according to the method described above, be divided into a lot of tuftlet;
(2) above-mentioned raw materials animal wool is processed: respectively above-mentioned animal wool is soaked, with the Tea Saponin aqueous solution of 2% percentage by weight at 50 DEG C, under pH=7.0, process 15min; Hair after process is added respectively 80 DEG C of clarification limewash and carry out ungrease treatment 1min, then taken out by hair, immerse 5min in citric acid solution in the mode of level, the pH value of described citric acid solution is 6, and then clear water is cleaned and dried;
(3) mixing manufacture nib: animal wool after treatment, make tuftlet, proportionally tuftlet animal wool and nylon hair are mixed with combing machine for fur, mixed pen core hair picking when making pen core is a branch of, this bundle hair is paved on flat board, through reason hair, and then roll from one end and make coniform, then will drape over one's shoulders and be in the least wrapped in outside pen core, drape over one's shoulders milli length and be slightly shorter than pen core length, expose pen core peak grain husk, it is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness.
Write impression: store black very excellent capacity, neither too hard, nor too soft in process drawn by institute's book, resilient enough, vigorous and forceful, prolong continuous without cease, imposing manner is extensive, has artistic effect, stores black ability strong.
Embodiment 4:
A kind of writing brush, the pen core of described brush writing skill is made up of the raw material of following percentage by weight:
Pen core:
It is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness;
The preparation method of described nylon hair is:
(1) preparation of modification of nylon 6: by nylon 685 parts, tourmaline powder 2 parts, sericite in powder 1 part, talcum powder 0.5 part, 0.8 part, nano imvite powder, 0.6 part, magnesia, shitosan 0.3 part (molecular weight of described shitosan is 2500-3200) adds in high-speed mixer, obtains modification of nylon 6 mixture after high speed dispersion: mixture melt-processed becomes diameter D to be the modification of nylon 6 of 0.10mm;
The particle diameter of described tourmaline powder is 7nm; The particle diameter of sericite in powder is 12nm, and talcous particle diameter is 20nm, and the particle diameter of nano imvite powder is 5nm, and magnesian particle diameter is 16nm.
(2) swelling abrasion legal system is for nylon hair: it is long by diameter D to be that the modification of nylon 6 of 0.10mm is cut into 65mm, by film wrapped, be rolled into the fibre bundle that diameter is 10mm, one end fiber for mill exposes 23-28mm, fibre bundle is held for mill and soaks 12 seconds in swelling solution, then use conventional method to be immersed in molten mill liquid and grind, rear use 95% ethanol washing full to the brim, be washed to neutrality again, encase with film and shape at 80 DEG C of process 40min;
Described swelling solution is, is made into as follows according to volume proportion: 80 parts of phenmethylols, 8 parts of bright sulfur acid, 8 part of 95% ethanol, 2 parts of glacial acetic acid, the sodium chloride solution of 5 parts of 38g/L;
Described molten mill liquid is be made into as follows according to volume proportion: 90 parts of phenmethylols, 120 part of 95% ethanol, the sodium chloride solution of 6 parts of 39g/L;
The nylon hair surface of making is comparatively smooth, and cone is long is 9mm, and sharp point diameter is 0.0015mm; Water retention, up to 130%, stores black very excellent capacity, and tough and difficult disconnected, hot strength is greater than 4000, and elastic modelling quantity is 10.1 × 10
4/kg.cm
-2.
A system process of described writing brush is:
(1) prepare nylon hair according to the method described above, be divided into a lot of tuftlet;
(2) above-mentioned raw materials animal wool is processed: respectively above-mentioned animal wool is soaked, with the Tea Saponin aqueous solution of 2% percentage by weight at 50 DEG C, under pH=7.0, process 15min; Hair after process is added respectively 80 DEG C of clarification limewash and carry out ungrease treatment 1min, then taken out by hair, immerse 5min in citric acid solution in the mode of level, the pH value of described citric acid solution is 6, and then clear water is cleaned and dried;
(3) mixing manufacture nib: animal wool after treatment, make tuftlet, proportionally tuftlet animal wool and nylon hair are mixed with combing machine for fur, mixed pen core hair picking when making pen core is a branch of, this bundle hair is paved on flat board, through reason hair, and then roll from one end and make coniform, then will drape over one's shoulders and be in the least wrapped in outside pen core, drape over one's shoulders milli length and be slightly shorter than pen core length, expose pen core peak grain husk, it is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness.
Write impression: store black very excellent capacity, neither too hard, nor too soft in process drawn by institute's book, resilient enough, vigorous and forceful, prolong continuous without cease, imposing manner is extensive, has artistic effect, stores black ability strong.
Embodiment 5:
A kind of writing brush, the pen core of described brush writing skill is made up of the raw material of following percentage by weight:
Pen core:
It is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness;
The preparation method of described nylon hair is:
(1) preparation of modification of nylon 6: by nylon 684 parts, tourmaline powder 2 parts, sericite in powder 1.3 parts, talcum powder 0.5 part, 0.8 part, nano imvite powder, 0.5 part, magnesia, shitosan 0.3 part (molecular weight of described shitosan is 2500-3200) adds in high-speed mixer, obtains modification of nylon 6 mixture after high speed dispersion: mixture melt-processed becomes diameter D to be the modification of nylon 6 of 0.10mm;
The particle diameter of described tourmaline powder is 8nm; The particle diameter of sericite in powder is 12nm, and talcous particle diameter is 22nm, and the particle diameter of nano imvite powder is 5nm, and magnesian particle diameter is 19nm.
(2) swelling abrasion legal system is for nylon hair: it is long by diameter D to be that the modification of nylon 6 of 0.10mm is cut into 65mm, by film wrapped, be rolled into the fibre bundle that diameter is 10mm, one end fiber for mill exposes 23-28mm, fibre bundle is held for mill and soaks 12 seconds in swelling solution, then use conventional method to be immersed in molten mill liquid and grind, rear use 95% ethanol washing full to the brim, be washed to neutrality again, encase with film and shape at 80 DEG C of process 30min;
Described swelling solution is, is made into as follows according to volume proportion: 82 parts of phenmethylols, 8 parts of bright sulfur acid, 8 part of 95% ethanol, 3 parts of glacial acetic acid, the sodium chloride solution of 5 parts of 38g/L;
Described molten mill liquid is be made into as follows according to volume proportion: 90 parts of phenmethylols, 120 part of 95% ethanol, the sodium chloride solution of 6 parts of 38g/L;
The nylon hair surface of making is comparatively smooth, and cone is long is 10mm, and sharp point diameter is 0.0015mm; Water retention, up to 138%, stores black very excellent capacity, and tough and difficult disconnected, hot strength is greater than 4000, and elastic modelling quantity is 10.2 × 10
4/kg.cm
-2.
A system process of described writing brush is:
(1) prepare nylon hair according to the method described above, be divided into a lot of tuftlet;
(2) above-mentioned raw materials animal wool is processed: respectively above-mentioned animal wool is soaked, with the Tea Saponin aqueous solution of 2% percentage by weight at 50 DEG C, under pH=7.0, process 15min; Hair after process is added respectively 80 DEG C of clarification limewash and carry out ungrease treatment 1min, then taken out by hair, immerse 4min in citric acid solution in the mode of level, the pH value of described citric acid solution is 6, and then clear water is cleaned and dried;
(3) mixing manufacture nib: animal wool after treatment, make tuftlet, proportionally tuftlet animal wool and nylon hair are mixed with combing machine for fur, mixed pen core hair picking when making pen core is a branch of, this bundle hair is paved on flat board, through reason hair, and then roll from one end and make coniform, then will drape over one's shoulders and be in the least wrapped in outside pen core, drape over one's shoulders milli length and be slightly shorter than pen core length, expose pen core peak grain husk, it is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness.
Write impression: store black very excellent capacity, neither too hard, nor too soft in process drawn by institute's book, resilient enough, vigorous and forceful, prolong continuous without cease, imposing manner is extensive, has artistic effect, stores black ability strong.
Embodiment 6 index is tested and assessed:
Control group: unmodified nylon 6 uses the same method the nylon hair rough surface be prepared into, and water retention is only 78%, stores black ability, tough and difficult disconnected, hot strength is greater than 3600, and elastic modelling quantity is only only 2.3 × 10
4/kg.cm
-2.The present invention is by mixing the various ingredients of nylon 6 and specified particle diameter, and it is special to prepare, the nylon 6 of applicable writing brush.Each material of co-mixing system is added in modification, and particle diameter is all most important, slightly deviation will have a great impact result, and the present inventor is on the basis of numerous experiments, surprisingly find this particular modification method, the modification of nylon hair of suitable writing brush can have been prepared.If use same component, but the material blending and modifying that particle diameter is different, and its elastic modelling quantity is no more than 4.5 × 10
4/kg.cm
-2, this illustrates that the particle diameter of modified material is selected also extremely important.
Easily cause hair dispersion in use with after animal wool mixing of the present invention, poor flexibility, writes the problem of impression difference.
It is 60 degree that the writing brush that embodiment of the present invention 1-5 is obtained is positioned over temperature, tests save-resistant degree under the severe acceleration environment that intensive ultraviolet uninterruptedly irradiates.Result is as described in Table 1.
Situation preserved by table 1
| group | write impression |
| the writing brush of embodiment 1 | within 8 months, start to occur variable color, the phenomenon of hair matter obvious damage. |
| the writing brush of embodiment 2 | within 5 months, start to occur variable color, the phenomenon of hair matter obvious damage. |
| the writing brush of embodiment 3 | within 5 months, start to occur variable color, the phenomenon of hair matter obvious damage. |
| the writing brush of embodiment 4 | within 5 months, start to occur variable color, the phenomenon of hair matter obvious damage. |
| the writing brush of embodiment 5 | within 5 months, start to occur variable color, the phenomenon of hair matter obvious damage. |
| certain commercially available animal writing brush | within 1.5 months, start to occur variable color, the phenomenon of hair matter obvious damage. |
As can be seen here, the writing brush holding time that the present invention obtains is far superior to the writing brush of prior art.
In addition, also observe the writing brush that writing brush durability of the present invention is also obviously better than contrasting, its long-term writing quality does not subtract.
In sum, the present invention is to the processing of nylon hair, the process of animal wool, and comprehensive optimization has been done in the Fruit variety of hair and collocation, this obtained writing brush have elasticity, comfortable writing in process drawn by book, and it is vigorous and forceful in using, prolong continuous without cease, have artistic effect, writing soft or hard can take into account; Writing brush quality of the present invention is high, and quality is good, has extraordinary market prospects; By the nylon hair technique improved, make this writing brush more flexible, more durable, and the holding time is very long; By the animal wool technique improved, animal wool is hurt little, make this writing brush more flexible, more durable, and the holding time is very long.
The above; be only the present invention's preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (2)
1. a writing brush, the pen core of described brush writing skill is made up of the raw material of following percentage by weight:
The rabbit hair 15%
Nylon hair 10%
Weasel dodds 15%
Dog shank-feathering 10%
Wool 40%:
Milli is draped over one's shoulders in nib outside in addition, and described is goats hair, monolateral 1-1.2mm thickness;
Described nylon hair is prepared by following methods:
(1) preparation of modification of nylon 6: according to parts by weight, by nylon 680-85 part, tourmaline powder 2-2.8 part, sericite in powder 1-1.3 part, talcum powder 0.5 part, 0.8 part, nano imvite powder, magnesia 0.5-0.6 part, shitosan 0.3 part adds in high-speed mixer, obtains modification of nylon 6 mixture after high speed dispersion: mixture melt-processed becomes diameter D to be the modification of nylon 6 of 0.10mm;
The particle diameter of described tourmaline powder is 5-8nm; The particle diameter of sericite in powder is 10-15nm, and talcous particle diameter is 18-22nm, and the particle diameter of nano imvite powder is 5-6nm, and magnesian particle diameter is 16-20nm;
The molecular weight of described shitosan is 2500-3200;
(2) swelling abrasion legal system is for nylon hair: it is long by diameter D to be that the modification of nylon 6 of 0.10mm is cut into 65mm, by film wrapped, be rolled into the fibre bundle that diameter is 10mm, one end fiber for mill exposes 23-28mm, fibre bundle is held for mill and soaks 12 seconds in swelling solution, then use conventional method to be immersed in molten mill liquid and grind, rear use 95% ethanol washing full to the brim, be washed to neutrality again, encase with film and shape at 80 DEG C of process 30-50min;
Described swelling solution is, is made into according to following volume proportion: 80-85 part phenmethylol, 8 parts of bright sulfur acid, 8 part of 95% ethanol, 2-3 part glacial acetic acid, the sodium chloride solution of 5-6 part 38-40g/L;
Described molten mill liquid is be made into according to following volume proportion: 90-95 part phenmethylol, 120 part of 95% ethanol, the sodium chloride solution of 6 parts of 38-40g/L.
2. the preparation method of writing brush according to claim 1, the steps include:
(1) prepare nylon hair, be divided into a lot of tuftlet;
(2) animal hairs process: soaked by above-mentioned animal wool respectively, with the Tea Saponin aqueous solution of 2% percentage by weight at 50 DEG C, processes 15min under pH=7.0; Hair after process is added respectively 80 ° of C clarification limewash and carry out ungrease treatment 1min, then taken out by hair, immerse 4-5min in citric acid solution in the mode of level, the pH value of described citric acid solution is 6, and then clear water is cleaned and dried;
(3) mixing manufacture nib: animal wool after treatment makes tuftlet, proportionally tuftlet animal wool and nylon hair are mixed with combing machine for fur, mixed pen core hair picking when making pen core is a branch of, flat board is paved, this bundle hair through reason hair, and then roll from one end make coniform, then will drape over one's shoulders milli be wrapped in outside pen core, drape over one's shoulders milli length be slightly shorter than pen core length, expose pen core peak grain husk, it is goats hair that milli is draped over one's shoulders in nib outside, monolateral 1-1.2mm thickness.
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| CN106079969A (en) * | 2016-07-27 | 2016-11-09 | 湖州南浔善琏盛兴湖笔有限公司 | A kind of brush pen of processing is the mould pasting monolayer thread |
| CN106564328A (en) * | 2016-11-11 | 2017-04-19 | 南浔善琏鑫婷笔庄 | Natural dyeing method for writing brush hair |
| CN106808837A (en) * | 2016-11-17 | 2017-06-09 | 赫拉迪克（厦门）科技有限公司 | A kind of brush writing skill, preparation method and applications |
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| CN106079969A (en) * | 2016-07-27 | 2016-11-09 | 湖州南浔善琏盛兴湖笔有限公司 | A kind of brush pen of processing is the mould pasting monolayer thread |
| CN106564328A (en) * | 2016-11-11 | 2017-04-19 | 南浔善琏鑫婷笔庄 | Natural dyeing method for writing brush hair |
| CN106808837B (en) * | 2016-11-17 | 2020-02-07 | 赫拉迪克（厦门）科技有限公司 | Writing brush head, preparation method and application thereof |
| CN106808837A (en) * | 2016-11-17 | 2017-06-09 | 赫拉迪克（厦门）科技有限公司 | A kind of brush writing skill, preparation method and applications |
| CN107053894A (en) * | 2017-03-01 | 2017-08-18 | 黄太海 | A kind of writing brush being prepared by string and chemical industry fiber |
| CN107287690A (en) * | 2017-07-31 | 2017-10-24 | 枣庄市书源笔业有限公司 | A kind of environmentally friendly writing brush and preparation method thereof |
| CN107443959A (en) * | 2017-07-31 | 2017-12-08 | 枣庄市书源笔业有限公司 | A kind of writing brush and preparation method thereof |
| CN108859502A (en) * | 2018-07-06 | 2018-11-23 | 湖州市南浔善琏艺综湖笔堂 | Milli of pen made of a kind of mink fur and preparation method thereof |
| CN109130587A (en) * | 2018-08-21 | 2019-01-04 | 南浔善琏松柏湖笔厂 | A kind of brush writing skill |
| CN110195260A (en) * | 2019-04-26 | 2019-09-03 | 湖州墨雅轩文化创意有限公司 | A kind of pen hair degreasing process |
| CN110303798A (en) * | 2019-07-16 | 2019-10-08 | 湖州善琏永和风笔斋 | A kind of manufacture craft of peacock writing brush |
| CN110576695A (en) * | 2019-08-28 | 2019-12-17 | 蔡明明 | novel writing brush and manufacturing method thereof |
| CN115230369A (en) * | 2021-04-23 | 2022-10-25 | 山西绛笔笔墨有限公司 | Manufacturing process of writing brush |
| CN115230369B (en) * | 2021-04-23 | 2024-03-15 | 山西绛笔笔墨有限公司 | Writing brush manufacturing process |
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Effective date of registration: 20210917 Address after: No. 99-1, Wangwang Road, Shanlian Town, Nanxun District, Huzhou City, Zhejiang Province 313000 Patentee after: Huzhou Shanlian xinyuanbizhai Co.,Ltd. Address before: 313000 Hubi street, Shanlian Town, Nanxun District, Huzhou City, Zhejiang Province Patentee before: HUZHOU SHANLIAN XINYUAN PEN VEGETARIAN |