CN105552283A - Dual-partition polar plate assembly suitable for lead-acid storage battery - Google Patents

Dual-partition polar plate assembly suitable for lead-acid storage battery Download PDF

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Publication number
CN105552283A
CN105552283A CN201510924303.7A CN201510924303A CN105552283A CN 105552283 A CN105552283 A CN 105552283A CN 201510924303 A CN201510924303 A CN 201510924303A CN 105552283 A CN105552283 A CN 105552283A
Authority
CN
China
Prior art keywords
partition
plate
dividing plate
negative
positive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510924303.7A
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Chinese (zh)
Inventor
孟祥辉
祁永军
孟凡刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEBEI ALLGRAND POWER Co Ltd
Original Assignee
HEBEI ALLGRAND POWER Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HEBEI ALLGRAND POWER Co Ltd filed Critical HEBEI ALLGRAND POWER Co Ltd
Priority to CN201510924303.7A priority Critical patent/CN105552283A/en
Publication of CN105552283A publication Critical patent/CN105552283A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • H01M10/14Assembling a group of electrodes or separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/46Separators, membranes or diaphragms characterised by their combination with electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/463Separators, membranes or diaphragms characterised by their shape
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention relates to a dual-partition polar plate assembly. The dual-partition polar plate assembly comprises multiple positive plates and negative plates that are arranged in parallel mutually, wherein the positive plates and the negative plates are alternatively distributed; a first partition and a second partition are arranged between adjacent positive plate and the negative plate; the first partition is an absorbing type partition capable of absorbing and penetrating an electrolyte, and positioned on the negative plate side; the second partition is a filtering type partition capable of penetrating the electrolyte, and positioned on the positive plate side; the first partition can adopt an AGM; and the second partition can adopt a PE filtering membrane, and is bag-shaped or sheet-shaped for wrapping the corresponding negative plate. According to the dual-partition polar plate assembly, the thickness of the AGM and the spacings between the positive plates and the negative plates can be further reduced on the basis of the prior art; short circuits and micro short circuits caused by fall-off of active substances can be reduced or avoided; and therefore, the capacity of a storage battery can be improved, and the service life of the storage battery can be prolonged.

Description

Be suitable for two dividing plate pole plate assemblies of lead acid accumulator
Technical field
The present invention relates to a kind of two dividing plate pole plate assemblies that mainly can be used for lead acid accumulator.
Background technology
The pole plate assembly of lead acid accumulator is primarily of some positive plates arranged in parallel and negative plate composition, positive and negative pole plate is alternately distributed, dividing plate can be provided with between adjacent both positive and negative polarity, such as glass fibre separator (AbsorptiveGlassMat, be called for short AGM), for valve controlled sealed lead-acid accumulator, electrolyte to be received and is stored in glass fibre separator and pole plate, by the setting of glass fibre separator, the short circuit between positive/negative plate can be prevented, be conducive to reducing volume, be conducive to reducing pole plate vibration, be conducive to realizing lean solution design.
But, along with expansion and the technological progress of range of application, the requirement of pole plate assembly is improved constantly.Such as, for controlling fuel-engined vehicle to the impact of atmospheric environment, electric automobile develops rapidly in recent years, need to increase battery capacity for improving distance travelled, against the background of the prior art, a kind of effective technology path increases quantity of polar plate exactly under certain volume, therefore not only need to add sheet to pole plate is thinning, but also the thickness of AGM dividing plate should be reduced, but in order to avoid short-circuit between plates, under existing the pole plate component structure that AGM dividing plate is set, AGM block board thickness has its lower thickness limit value, the use affecting storage battery can be hindered because of short circuit lower than after lower thickness limit value.And for example, along with the requirement of national energy-saving environmental protection, solar energy photovoltaic system has been listed state key in and has been helped project, wherein supporting with it storage battery is the chief component of photovoltaic system, also be one of whole system life-span minimum composition, the major reason affecting its useful life is exactly in photovoltaic system runs, due to reasons such as weather, battery recycles under being often in low retained storage capacity for a long time, and under low capacity, lead plaster/lead powder isoreactivity material very easily comes off and is distributed in electrolyte, causes battery short circuit or micro-short circuit.
Summary of the invention
In order to overcome the above-mentioned defect of prior art, the invention provides a kind of two dividing plate pole plate assembly, for the pole plate assembly that AGM dividing plate (single dividing plate) is set relative to existing, this pole plate assembly allows the spacing reduced further between AGM thickness and positive/negative plate, quantity of polar plate can be increased further when constancy of volume, improve battery capacity, and be conducive to reducing or avoid to come off the short circuit and micro-short circuit caused because of active material, adopt the battery capacity of this pole plate assembly high, long service life.
The technical solution adopted in the present invention is: a kind of two dividing plate pole plate assemblies being suitable for lead acid accumulator, comprise the some positive plates and negative plate that are parallel to each other, described positive plate and negative plate are alternately distributed, the first dividing plate and second partition is provided with between adjacent positive plate and negative plate, described first dividing plate is can receive and receive formula dividing plate through electrolyte, and described second partition is can through the filtering type dividing plate of electrolyte.
The invention has the beneficial effects as follows: owing to there is positive/negative plate being provided with the second partition of filter capacity and not requiring that second partition receives and stores electrolyte, therefore its thickness can much smaller than the thickness of the first dividing plate (1/10 of such as the first block board thickness), and alleviate the filtering requirement even eliminated the first dividing plate, the thickness of the first dividing plate being reduced to single layer separator structure descends below the lower thickness limit value of the first dividing plate (1/3 of such as this lower thickness limit value) still can ensure that the active material come off from pole plate can not cause short circuit and the micro-short circuit of positive and negative electrode, therefore the gross thickness of the first dividing plate and second partition can be made to be significantly less than the lower thickness limit value of lower first dividing plate of single layer separator structure, saved space may be used for the quantity increasing pole plate, storage battery thus under same volume can have larger capacity, and due to against the background of the prior art, second partition can adopt strainability etc. to be obviously better than the thin-film material of AGM, can more effective and reliably stop that on pole plate, lead powder isoreactivity material is taken off and penetrates in AGM dividing plate, greatly reduce thus, alleviate the short circuit and/or micro-short circuit that even avoid and cause because active material comes off, significantly enhance the useful life of storage battery, according to the contrast experiment of applicant, when being used as energy-storage battery in solar energy photovoltaic system, can make longer cell life 1-3 doubly, life termination, dissect as the complete argillization of lead plaster and grid corrosion fracture cause, do not find short circuit and micro-short circuit phenomenon.The present invention is mainly applicable to lead acid accumulator, also may be used for other similar applications.
Accompanying drawing explanation
Fig. 1 is the organigram of pole plate assembly of the present invention.
Embodiment
See Fig. 1, provided by the invention pair of dividing plate pole plate assembly comprises the some positive plates 2 and negative plate 1 that are parallel to each other, described positive plate and negative plate are alternately distributed, the first dividing plate 4 and second partition 3 is provided with between adjacent positive plate and negative plate, described first dividing plate is can receive and receive formula dividing plate through electrolyte, and described second partition is can through the filtering type dividing plate of electrolyte.Owing to being provided with the second partition being exclusively used in filtration, the filtering requirement reducing or eliminate the first dividing plate, the active material particle come off from negative plate is blocked in negative plate side, dividing plate and the first baffle contacts cannot be passed, even if the active material particle come off from positive plate enters or through the first dividing plate, also cannot contact with negative plate, serve the effect preventing short circuit and micro-short circuit thus.
Preferably, described first dividing plate is positioned at positive plate side, and described second partition is positioned at negative plate side, is beneficial to the substance transfer of discharge and recharge course of reaction.
Preferably, the two sides (two large faces) of described first dividing plate is the plane of not establishing groove.
Preferably, described second partition adopts the thin-film material of uniform thickness.
Preferably, described positive plate adjacent according to this, second partition, the minim gap not staying gap between the first dividing plate and negative plate or only leave needed for I& M, be not only conducive to reducing volume thus, but also be conducive to lean solution design.
Preferably, described second partition is bag-shaped or chip, and described negative plate is preferably close in second partition,
Preferably, described first dividing plate takes the shape of the letter U or sheet, and when described first dividing plate takes the shape of the letter U, described positive plate is positioned at the first dividing plate of described U-shaped.
Preferably, when described second partition is bag-shaped, described negative plate is positioned at described bag-shaped second partition.In the case, effectively can prevent or reduce active material and come off from negative plate.
When described first dividing plate is bag-shaped, described positive plate is positioned at described the first bag-shaped dividing plate.In the case, can effectively to prevent or the material that takes in sail comes off from positive plate.
Preferably, the thickness of described second partition is less than the thickness of described first dividing plate.Such as, the thickness of described second partition is not more than 1/5 or 1/10 of described first block board thickness.
Described first dividing plate can adopt AGM.
Described second partition can be made up of PE material, to meet the material performance requirement under corresponding environment for use, ensures reliability, increases the service life.
Described second partition can adopt PE filter membrane, such as miillpore filter, to utilize current material, reduces preparation cost.
The lower thickness limit value of lower first dividing plate of single layer separator structure alleged by this specification refers to and only arrange the first dividing plate between positive/negative plate, ensureing the minimum value allowing the first block board thickness adopted in accumulator property and/or quality requirement situation, this lower limit can be dependent on the first dividing plate material therefor and battery designs requirement.
Particle alleged by this specification comprises the particle of solid particle, paste/colloidal particle and other forms.
Alleged the referring to through electrolyte of this specification allows the composition in electrolyte to transfer to opposite side from side, composition in described electrolyte comprises the ion and molecular chaperones that are formed by solvent and solute in electrolyte, also ion and the molecular chaperones of discharge and recharge reaction formation is comprised, through the porous that mode can utilize porous material self to have, also can be utilize the through hole that dividing plate processes, or above-mentioned both.
Each preferred and optional technological means disclosed by the invention, unless otherwise indicated and one preferably or alternatives means be outside the further restriction of another technological means, all can combination in any, form some different technical schemes.

Claims (9)

1. one kind is suitable for two dividing plate pole plate assemblies of lead acid accumulator, comprise the some positive plates and negative plate that are parallel to each other, described positive plate and negative plate are alternately distributed, it is characterized in that being provided with the first dividing plate and second partition between adjacent positive plate and negative plate, described first dividing plate is can receive and receive formula dividing plate through electrolyte, and described second partition is can through the filtering type dividing plate of electrolyte.
2. pole plate assembly as claimed in claim 1, is characterized in that the thickness of described second partition is less than the thickness of described first dividing plate.
3. pole plate assembly as claimed in claim 2, it is characterized in that described first dividing plate is positioned at positive plate side, described second partition is positioned at negative plate side.
4. pole plate assembly as claimed in claim 3, it is characterized in that described second partition is bag-shaped or chip, described negative plate is close in second partition.
5. pole plate assembly as claimed in claim 4, it is characterized in that described first dividing plate takes the shape of the letter U or sheet, when described first dividing plate takes the shape of the letter U, described positive plate is positioned at the first dividing plate of described U-shaped.
6. pole plate assembly as claimed in claim 5, is characterized in that the thickness of described second partition is not more than described first block board thickness.
7. the pole plate assembly as described in claim 1,2,3,4,5,6 or 7, is characterized in that described first dividing plate adopts AGM.
8. pole plate assembly as claimed in claim 8, is characterized in that described second partition is made up of PE material.
9. pole plate assembly as claimed in claim 9, is characterized in that described second partition adopts PE filter membrane.
CN201510924303.7A 2015-12-14 2015-12-14 Dual-partition polar plate assembly suitable for lead-acid storage battery Pending CN105552283A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510924303.7A CN105552283A (en) 2015-12-14 2015-12-14 Dual-partition polar plate assembly suitable for lead-acid storage battery

Publications (1)

Publication Number Publication Date
CN105552283A true CN105552283A (en) 2016-05-04

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106531942A (en) * 2016-12-02 2017-03-22 常熟市万隆电源技术研发有限公司 Separator plate for lead acid battery
TWI794712B (en) * 2020-12-28 2023-03-01 希世比能源科技股份有限公司 Sealed valve regulated lead-acid battery

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201682021U (en) * 2010-04-23 2010-12-22 林景穆 Novel structure colloid sealed accumulator
CN203277575U (en) * 2013-04-17 2013-11-06 理士电池私人有限公司 Lead-acid storage battery

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201682021U (en) * 2010-04-23 2010-12-22 林景穆 Novel structure colloid sealed accumulator
CN203277575U (en) * 2013-04-17 2013-11-06 理士电池私人有限公司 Lead-acid storage battery

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106531942A (en) * 2016-12-02 2017-03-22 常熟市万隆电源技术研发有限公司 Separator plate for lead acid battery
CN106531942B (en) * 2016-12-02 2019-07-02 常熟市万隆电源技术研发有限公司 A kind of baffle plate of lead acid storage battery
TWI794712B (en) * 2020-12-28 2023-03-01 希世比能源科技股份有限公司 Sealed valve regulated lead-acid battery

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Application publication date: 20160504