CN105543927A - Anodic oxidation system - Google Patents

Anodic oxidation system Download PDF

Info

Publication number
CN105543927A
CN105543927A CN201510993822.9A CN201510993822A CN105543927A CN 105543927 A CN105543927 A CN 105543927A CN 201510993822 A CN201510993822 A CN 201510993822A CN 105543927 A CN105543927 A CN 105543927A
Authority
CN
China
Prior art keywords
electrolyzer
anodic oxidation
monitor
electrode
electrolytic solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510993822.9A
Other languages
Chinese (zh)
Other versions
CN105543927B (en
Inventor
王天宇
邱乐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Evenwin Precision Technology Co Ltd
Original Assignee
Guangdong Evenwin Precision Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Evenwin Precision Technology Co Ltd filed Critical Guangdong Evenwin Precision Technology Co Ltd
Priority to CN201510993822.9A priority Critical patent/CN105543927B/en
Publication of CN105543927A publication Critical patent/CN105543927A/en
Application granted granted Critical
Publication of CN105543927B publication Critical patent/CN105543927B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/005Apparatus specially adapted for electrolytic conversion coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/06Suspending or supporting devices for articles to be coated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/10Agitating of electrolytes; Moving of racks

Abstract

The invention relates to the technical field of surface treatment, in particular to an anodic oxidation system. The anodic oxidation system comprises an electrolytic cell, a stirring piece, a grabbing piece and a monitor. A first electrode is arranged at the bottom of the electrolytic cell. The stirring piece is arranged in the electrolytic cell. The grabbing piece comprises a mechanical arm and a mechanical claw which is arranged at the end of the mechanical arm and provided with a second electrode. The mechanical arm is used for driving the mechanical claw to move to be stored in the electrolytic cell during work. The monitor is arranged on the electrolytic cell and used for monitoring the position of the mechanical claw in the electrolytic cell. According to the anodic oxidation system, an electronic circuit is formed through the first electrode, an electrolyte and the second electrode; after a workpiece to be oxidized is grabbed through the mechanical claw, the workpiece to be oxidized is electrically connected with the second electrode, an electrochemical reaction is conducted between the workpiece to be oxidized and the electrolyte under the action of currents, and an oxidation film is formed on the surface of the workpiece to be oxidized. Due to the facts that all components in the electrolyte are mixed uniformly and the workpiece to be oxidized is grabbed in a mechanical way, the efficiency of oxidation film formation of the workpiece to be oxidized is improved.

Description

Anodic oxidation system
Technical field
The present invention relates to technical field of surface, particularly relate to anodic oxidation system.
Background technology
Aluminium alloy is a most widely used metalloid structured material in industry, widely applies in Aeronautics and Astronautics, automobile, machinofacture, boats and ships and chemical industry.Be that anode is placed in electrolyte solution with Al-alloy products, utilize electrolytic action, make its surface form the process of aluminum oxide film, be called the anodic oxidation treatment of aluminium alloy.Alloy product through anodic oxidation treatment is called aluminum alloy anode product.
At present, in anodised process, by controlling the temperature etc. of the concentration of the electrolytic solution in electrolyzer, oxidization time and electrochemical reaction, obtain the oxide film of even compact; But in traditional device, due to the uneven concentration of electrolytic solution, the reason such as the temperature of oxidization time and electrochemical reaction is restive, causes the efficiency of the anodic oxidation treatment of aluminum products lower, and then have impact on production efficiency.
Summary of the invention
Based on this, be necessary for the problems referred to above, a kind of high efficiency anodic oxidation system is provided.
A kind of anodic oxidation system, comprising:
Electrolyzer, described electrolyzer is used for splendid attire electrolytic solution, is provided with the first electrode bottom it;
Stirring parts, described stirring parts is arranged in described electrolyzer, for stirring described electrolytic solution;
Grippers, described grippers comprises for being fixed on outside mechanical arm and being arranged on the gripper with the second electrode of described mechanical arm end,
Described mechanical arm drives described gripper activity to be contained in described electrolyzer when being used for work;
Monitor, described monitor is arranged on described electrolyzer, for monitoring described gripper in the position of described electrolyzer.
Wherein in an embodiment, described electrolyzer is provided with connection bit, and described monitor is arranged in described connection bit.
Wherein in an embodiment, described connection bit is arranged at the notch peripheral region of described electrolyzer.
Wherein in an embodiment, described monitor is removable installed in described connection bit.
Wherein in an embodiment, described connection bit is the female blind hole of tool.
Wherein in an embodiment, described monitor is spirally connected by screw and described connection bit.
Wherein in an embodiment, described connection bit is jack.
Wherein in an embodiment, described monitor is by pin and described connection bit grafting.
Wherein in an embodiment, the probe of described monitor is arranged in described electrolyzer, for obtaining the distance between described gripper and the liquid level of electrolytic solution.
Wherein in an embodiment, described monitor is infrared range-measurement system.
Above-mentioned anodic oxidation system, by the first above-mentioned electrode, between electrolytic solution and the second electrode, form electronic circuit, after gripper captures workpiece to be oxidized, workpiece to be oxidized and the second electrode are electrically connected, workpiece to be oxidized and electrolytic solution generation electrochemical reaction under the effect of electric current, workpiece surface to be oxidized forms oxide film.Because each component in electrolytic solution mixes, and mechanically capture workpiece to be oxidized, improve the efficiency that workpiece to be oxidized forms oxide film.
Accompanying drawing explanation
Fig. 1 is the structural representation of one embodiment of the invention anodic oxidation system;
Fig. 2 is the structural representation of one embodiment of the invention electrolyzer;
Fig. 3 is the syndeton schematic diagram of one embodiment of the invention stirring parts and electrolyzer;
Fig. 4 is the structural representation of one embodiment of the invention stirring parts;
Fig. 5 is the structure for amplifying schematic diagram of part A embodiment illustrated in fig. 4;
Fig. 6 is the structure for amplifying schematic diagram of part B embodiment illustrated in fig. 4;
Fig. 7 is one embodiment of the invention thermoswitch and the tester of liquid concentration position view at electrolyzer;
Fig. 8 is the position view of one embodiment of the invention second electrode at mechanical arm; And
Fig. 9 is the position view of one embodiment of the invention monitor at electrolyzer.
Embodiment
For enabling above-mentioned purpose of the present invention, feature and advantage become apparent more, are described in detail the specific embodiment of the present invention below in conjunction with accompanying drawing.Set forth a lot of detail in the following description so that fully understand the present invention.But the present invention can be much different from alternate manner described here to implement, those skilled in the art can when without prejudice to doing similar improvement when intension of the present invention, therefore the present invention is by the restriction of following public specific embodiment.
It should be noted that, when element is called as " being fixed on ", " being arranged at " another element, directly can there is element placed in the middle in it on another element or also.When an element is considered to " connection " another element, it can be directly connected to another element or may there is centering elements simultaneously.Term as used herein " vertical ", " level ", "left", "right" and similar statement just for illustrative purposes, do not represent it is unique embodiment.
Refer to Fig. 1, it is the structural representation of one embodiment of the invention anodic oxidation system 10, and anodic oxidation system 10 comprises: electrolyzer 110, stirring parts 120 and grippers 130.
Electrolyzer 110 is for splendid attire electrolytic solution.Composition graphs 2, the bottom of electrolyzer 110 is provided with the first electrode 111.Such as, the first electrode 111 connects the negative electrode of external dc power.In one embodiment, the first electrode 111 comprises negative plate.Negative plate is for connecting the negative electrode of external dc power.
Stirring parts 120 is arranged in electrolyzer 110, for stirring electrolytic solution, each component in electrolytic solution is mixed, to form the higher oxide film of compactness.
Grippers 130 comprises mechanical arm 131 and is arranged on the gripper 132 of mechanical arm 131 end, and when mechanical arm 131 works, driving mechanical pawl 132 activity is contained in electrolyzer 110.
Mechanical arm 131 is fixed on outside, and such as, mechanical arm 131 is fixed on lathe.Composition graphs 8, gripper 132 has the second electrode 133.Such as, the second electrode 133 connects the anode of external dc power.In one embodiment, the second electrode 133 comprises positive plate.Positive plate is for connecting the anode of external dc power.Such as, mechanical arm adopts existing techniques in realizing, repeats no more herein.The first above-mentioned electrode 111, between electrolytic solution and the second electrode 133, form turning circuit, after gripper 132 captures workpiece to be oxidized, workpiece to be oxidized and the second electrode 133 are electrically connected, workpiece to be oxidized and electrolytic solution generation electrochemical reaction under the effect of electric current, workpiece surface to be oxidized forms oxide film.
Be appreciated that because each component in electrolytic solution mixes, and mechanically capture workpiece to be oxidized, improve the efficiency that workpiece to be oxidized forms oxide film.
Refer to Fig. 2, electrolyzer 110 is the rectangular parallelepiped of the hollow of a side opening.Composition graphs 3, electrolyzer 110 is provided with installation position 112, and stirring parts 120 is arranged at installation position 112.Such as, installation position is arranged at the middle part of the sidewall of described electrolyzer.Such as, installation position described in a pair is set.Such as, installation position 112 is arranged at the sidewall of electrolyzer 110.For making stirring parts 120 have rotation space, installation position 112 is arranged on the region intermediate of the sidewall of electrolyzer 110.Such as, electrolyzer 110 is the right cylinder of the hollow of one end open.Such as, electrolyzer 110 is the square of the hollow of a side opening.
In order to weight reduction, such as, electrolyzer is provided with hollow aluminium alloy frame body, and is covered in the anti-corrosion layer of internal surface of hollow aluminium alloy frame body; Such as, anti-corrosion layer is plumbous or synthetic resins or rubber etc., and its thickness is 2 ~ 4 millimeters; Such design, greatly alleviates the weight of electrolyzer, improves its steadiness, also reduces cost.Preferably, the outside surface of hollow aluminium alloy frame body covers at least partly and arranges described anti-corrosion layer.Preferably, the outside of hollow aluminium alloy frame body is also provided with fixed sturcture, for fixedly mounting electrolyzer.
Electrolyzer 110 is for splendid attire electrolytic solution.In the present embodiment, as shown in Figure 2, electrolyzer 110 has accommodating cavity 113.In an oxidising process, accommodating cavity 113 contains electrolytic solution, and the first electrode 111 soaks in the electrolytic solution.In one embodiment, negative plate and positive plate all adopt graphite material to make.That is, the plate that graphite material makes negative plate and positive plate has the shape and structure of coupling, makes both mutually corresponding.
It is pointed out that the present embodiment is relative to traditional anode oxidation process, the second electrode 133 is set separately highlightedly, and the shape and structure of the second electrode 133 in plate.Preferably, the shape size of the second electrode 133 is identical with the shape size of workpiece to be oxidized, workpiece to be oxidized is made to fit in the second electrode 133, when the second electrode 133 is parallel with the first electrode 111, workpiece to be oxidized also with the first electrode 111 in parastate, make the surface of workpiece opposite first pole 111 to be oxidized form the oxide film of even compact.
In one embodiment, electrolyzer 110 is the rectangular parallelepiped of the hollow of a side opening, and has scale in the side wall markings of electrolyzer 110, and such as this scale direction is straight down, and such as, shown in this scale is volumetric values.
It is pointed out that the volumetric values indicated by this scale is corresponding adaptive according to the size of electrolyzer 110, that is, when the plane at liquid levels place is positioned at a certain scale place, namely this scale value reflects the size of current liquid volume.
In one embodiment, electrolytic solution be 55% ~ 70% sulphuric acid soln, massfraction be 5% ~ 10% phosphoric acid and massfraction be 2% oxalic acid mixing solutions.Corresponding, anodised condition is: voltage 10V, temperature 19 ~ 21 DEG C, time 20 ~ 40min.Already oxidised workpiece after anodic oxidation treatment is washed, after drying, obtain the already oxidised workpiece of surface evening light, and surface is without heterochromatic.
Preferably, electrolytic solution to be sulphuric acid soln, the massfraction of 65% be 8% phosphoric acid and massfraction be 2% oxalic acid mixing solutions.Corresponding, anodised condition is: voltage 10V, temperature 19 DEG C, time 25min.
In one embodiment, the sulphuric acid soln of electrolytic solution to be concentration be 180 ~ 240g/L.Corresponding, anodised condition is: voltage 10V, temperature 19 ~ 21 DEG C, time 20 ~ 40min.Already oxidised workpiece after anodic oxidation treatment is washed, after drying, obtain the already oxidised workpiece of surface evening light, and surface is without heterochromatic.
Preferably, the sulphuric acid soln of electrolytic solution to be concentration be 220g/L.Corresponding, anodised condition is: voltage 10V, temperature 21 DEG C, time 30min.Compare through being amplified to 100 times, the process workpiece obtained like this, surface finish, higher than currently available products, there is no rough position, and surface is without heterochromatic.
Because the particle radius in the various component of electrolytic solution there are differences each other, when causing mixing rear formation electrolytic solution, there is the phenomenon of precipitation in the meeting that particle radius is larger.For preventing the generation of this phenomenon, affecting the efficiency of anodic oxidation reactions, being stirred in real time by the electrolytic solution in stirring parts 120 pairs of electrolyzers 110, some components precipitate can be avoided on the one hand, each component in electrolytic solution can be made to mix on the other hand.
As shown in Figure 3, electrolyzer 110 is provided with motor 114.The rotor of motor 114 is connected with installation position 112.When being provided with stirring parts 120 in installation position 112, motor 114 works and namely drives stirring parts 120 to rotate, thus is stirred in real time by stirring parts 120 pairs of electrolytic solution.
Be appreciated that the rotating speed of stirring parts 120 should remain in rational scope, and, also should mate with the volume of electrolyzer 110, avoid spattering from electrolyzer 110 at rotation process electrolytic solution.Preferably, electrolyzer 110 is provided with rotational speed governor, and rotational speed governor is connected with motor 114.Rotational speed governor has input terminus, accepts user and inputs default tachometer value, when driving stirring parts 120 to rotate to make motor 114, maintains in this tachometer value.Such as, stirring parts has wavy cross-section, and below the middle part that is all positioned at electrolyzer, its two ends or middle part, and the maximum width of stirring parts is 4% ~ 12% of the electrolyzer degree of depth, and the maximum speed of revolution of stirring parts is less than 180rpm.
For ease of controlling the rotating speed of stirring parts 120 in real time, in an embodiment, rotational speed governor is provided with WiFi module.WiFi module is connected with outside terminating unit by WiFi agreement, such as, after the mobile phone of user is connected by WiFi agreement and WiFi module, real-time tachometer value is inputted to WiFi module by the application program of mobile phone, motor 114 is after receiving this real-time tachometer value, and real-time response adjusts rotating speed.
It is pointed out that outside terminating unit can also comprise the telepilot with WiFi host-host protocol or ZigBee transport protocol capabilities of flat board, computer, remote server and customization.
For ease of controlling the rotating speed of stirring parts 120 in real time, in an embodiment, rotational speed governor is provided with ZigBee module.ZigBee module is connected with outside terminating unit by Zigbee protocol, such as, after the mobile phone of user is connected by Zigbee protocol and ZigBee module, real-time tachometer value is inputted to ZigBee module by the application program of mobile phone, motor 114 is after receiving this real-time tachometer value, real-time response adjustment rotating speed, is adjusted in real time to make stirring parts 120.
Like this, by keeping stirring parts 120 in rational speed range, can avoid spattering from electrolyzer 110 at rotation process electrolytic solution.But in a whipping process, the reasonableness that stirring parts 120 constructs affects electrolytic solution whether to spatter important factor from electrolyzer 110.Therefore, as shown in Figure 4, in one embodiment, for making stirring parts 120 more gentle with the contact of electrolytic solution, stirring parts 120 is the rod of rounded, the overall undulate in cross section.
Be appreciated that stirring parts 120 should possess acid resistance, to avoid reacting with electrolytic solution.Such as, stirring parts outer setting has acid-resistant layer; In one embodiment, stirring parts 120 adopts graphite material to make.In one embodiment, stirring parts 120 adopts tetrafluoroethylene to make.
Due to the rectangular parallelepiped that the electrolyzer 110 in the present embodiment is the hollow of a side opening.As shown in Figure 3, the length of the length coupling electrolyzer 110 of stirring parts 120, and be installed on the central region of electrolyzer 110.In the present embodiment, the two ends of stirring parts 120 are provided with outside screw, are screwed onto respectively in installation position 112.
The object of the electrochemical reaction of the present embodiment is: generate oxide film at the default surface oxidation of workpiece to be oxidized, oxide film is solid, and therefore in reaction process, the content of oxygen element can reduce gradually.For supplementing the oxygen element in electrolytic solution in time, improve oxidation efficiency, as shown in Figure 4 and Figure 5, stirring parts 120 offers air guide channel 121.Air guide channel 121 extends along the bending of stirring parts 120 and extending direction.
In one embodiment, installation position 112 offers the air guide port be communicated with the gas blower of outside, and air guide channel 121 is communicated with air guide port.During gas blower work, send into extraneous air toward air guide port, extraneous air enters air guide channel 121.For importing in electrolytic solution by extraneous air in time, think electrolytic solution delivery of supplemental oxygen element, as shown in Figure 4 and Figure 6, stirring parts 120 is provided with some escape pipes 122, escape pipe 122 is communicated with air guide channel 121, and each escape pipe 122 offers some air outlets 123.
Like this, outside air, via after air guide channel 121, is assigned on each escape pipe 122, and is distributed in electrolytic solution under the effect of some air outlets 123.Electrolytic solution is the chemical reaction delivery of supplemental oxygen element of self after absorbing the oxygen of the few part in air, thus improves oxidation efficiency.
It should be noted that, some escape pipes 122 shown in Fig. 4 are only distributed on the side of stirring parts 120, it is the function understanding escape pipe 122 for the ease of user, during specific to production, the position of escape pipe 122 can carry out converting according to the understanding of reality, such as concentrate to a certain region delivery of supplemental oxygen element time, each escape pipe is obliquely installed, to make all air outlets all uniformly towards this region.
Refer to Fig. 7, in one embodiment, electrolyzer 110 is provided with thermoswitch 115 and tester of liquid concentration 116.Thermoswitch 115 and tester of liquid concentration 116 are all connected with outside by pedestal 117.Such as, pedestal 117 is arranged on the bottom land of electrolyzer 110, and and for example, pedestal 117 is arranged near the first electrode 111.Thermoswitch 115 for absorbing the heat in electrolyzer 110, to reduce the temperature in electrolyzer 110.Preferably, thermoswitch 115 comprises frozen water equipment.
Electrolytic solution in use for some time, such as, because chemical reaction needs to consume a certain composition in electrolytic solution, oxygen element, for maintaining the concentration of electrolytic solution, electrolytic solution in electrolyzer 110 is remained within the scope of default concentration value, is necessary the concentration value obtaining electrolytic solution in time accurately.Such as, tester of liquid concentration 116 is arranged on the bottom land of electrolyzer 110, and and for example, tester of liquid concentration 116 is arranged near the first electrode 111.So, the concentration of the detection electrolytic solution utilizing tester of liquid concentration real-time, to obtain the concentration value of electrolytic solution in time accurately, improves electrolytic efficiency.
For obtaining the good oxide film of compactness, such as, anodic oxygen makeup comprises spectral interference film thickness gauge.Such as, spectral interference film thickness gauge is arranged at the bottom land of electrolyzer 110.Such as, two of spectral interference film thickness gauge restraints second electrode 133 of incident lights towards grippers 130, and two bundle reflected light after peroxide film are split, interference film thickness gauge receives, due to the existence of thickness, two bundle reflected light and two are restrainted between incident light exists phase differential, therefore, utilize fourier transform algorithm or characteristic curve fitting algorithm, namely can be regarded as to obtain the thickness of oxide film.
It is to be noted, spectral interference film thickness gauge is the principle utilizing white light interferometric method, namely record the reflectance data of different wave length with a broadband light source, because reflectivity n and k changes with the difference of film, carry out curve fitting according to this characteristic thus try to achieve thickness.The relevant parameter of different kind of material is described by different models, thus ensure that the accuracy of different kind of material film thickness measuring.
Refer to Fig. 9, in one embodiment, anodic oxidation system comprises monitor 140.Such as, monitor 140 is arranged on electrolyzer 110, for monitoring gripper 132 in the position of electrolyzer 110.Such as, the probe of monitor 140 is arranged in electrolyzer 110, for obtaining the distance between gripper 132 and the liquid level of electrolytic solution.Such as, monitor 140 is infrared range-measurement system.
Such as, electrolyzer 110 is provided with connection bit 118, and monitor 140 is arranged in connection bit 118.Such as, connection bit 118 is arranged at the notch peripheral region of electrolyzer 110.
Such as, monitor 140 is removable installed in connection bit 118.Such as, connection bit 118 is the female blind hole of tool.Such as, monitor 140 is spirally connected by screw and connection bit 118.Such as, connection bit 118 is jack.Such as, monitor 140 is by pin and connection bit 118 grafting.
Each technical characteristic of the above embodiment can combine arbitrarily, for making description succinct, the all possible combination of each technical characteristic in above-described embodiment is not all described, but, as long as the combination of these technical characteristics does not exist contradiction, be all considered to be the scope that this specification sheets is recorded.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be construed as limiting the scope of the patent.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (10)

1. an anodic oxidation system, is characterized in that, comprising:
Electrolyzer, described electrolyzer is used for splendid attire electrolytic solution, is provided with the first electrode bottom it;
Stirring parts, described stirring parts is arranged in described electrolyzer, for stirring described electrolytic solution;
Grippers, described grippers comprises for being fixed on outside mechanical arm and being arranged on the gripper with the second electrode of described mechanical arm end,
Described mechanical arm drives described gripper activity to be contained in described electrolyzer when being used for work;
Monitor, described monitor is arranged on described electrolyzer, for monitoring described gripper in the position of described electrolyzer.
2. anodic oxidation system according to claim 1, is characterized in that, described electrolyzer is provided with connection bit, and described monitor is arranged in described connection bit.
3. anodic oxidation system according to claim 2, is characterized in that, described connection bit is arranged at the notch peripheral region of described electrolyzer.
4. anodic oxidation system according to claim 3, is characterized in that, described monitor is removable installed in described connection bit.
5. anodic oxidation system according to claim 4, is characterized in that, described connection bit is the female blind hole of tool.
6. anodic oxidation system according to claim 5, is characterized in that, described monitor is spirally connected by screw and described connection bit.
7. anodic oxidation system according to claim 4, is characterized in that, described connection bit is jack.
8. anodic oxidation system according to claim 7, is characterized in that, described monitor is by pin and described connection bit grafting.
9. anodic oxidation system according to claim 8, is characterized in that, the probe of described monitor is arranged in described electrolyzer, for obtaining the distance between described gripper and the liquid level of electrolytic solution.
10. anodic oxidation system according to claim 9, is characterized in that, described monitor is infrared range-measurement system.
CN201510993822.9A 2015-12-23 2015-12-23 anodic oxidation system Active CN105543927B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510993822.9A CN105543927B (en) 2015-12-23 2015-12-23 anodic oxidation system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510993822.9A CN105543927B (en) 2015-12-23 2015-12-23 anodic oxidation system

Publications (2)

Publication Number Publication Date
CN105543927A true CN105543927A (en) 2016-05-04
CN105543927B CN105543927B (en) 2018-05-04

Family

ID=55823475

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510993822.9A Active CN105543927B (en) 2015-12-23 2015-12-23 anodic oxidation system

Country Status (1)

Country Link
CN (1) CN105543927B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106086972A (en) * 2016-08-10 2016-11-09 松阳县恒亮不锈钢制品有限公司 A kind of open-type steel bowl automatization electroplanting device in batches
CN108624937A (en) * 2018-05-11 2018-10-09 王康 A kind of magnesium alloy workpiece anode oxidation method
CN108950621A (en) * 2018-08-28 2018-12-07 王志伟 A kind of connection rod of automobile engine automation electro-brush plating prosthetic device
CN110372258A (en) * 2019-07-08 2019-10-25 杭州三耐环保科技股份有限公司 A kind of stirred tank and preparation method thereof

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0261098A (en) * 1988-08-24 1990-03-01 Kawasaki Steel Corp Treatment of metallic material and equipment
CN1124304A (en) * 1994-03-17 1996-06-12 株式会社半导体能源研究所 Apparatus and method for anodic sxidation
CN1188820A (en) * 1996-11-28 1998-07-29 佳能株式会社 Anodizing processing apparatus and method associated with the same
US20040231993A1 (en) * 2000-12-21 2004-11-25 Price Joseph K. Anodizing system with a coating thickness monitor and an anodized product
US20050139159A1 (en) * 2003-12-30 2005-06-30 Price Joseph K. Anodizing system with a coating thickness monitor and an anodized product
CN2760053Y (en) * 2004-10-26 2006-02-22 中国科学院上海技术物理研究所 Gripping holder for anodized electrode on chip surface of semiconductor device
CN201292415Y (en) * 2008-10-31 2009-08-19 比亚迪股份有限公司 Anode oxidization apparatus for titanium and its alloy
CN102181894A (en) * 2011-04-02 2011-09-14 潘俊安 Device and method for carrying out single spraying on power battery case
CN202336871U (en) * 2011-11-14 2012-07-18 天津市聚兴电镀有限公司 Mechanical arm for electroplating assembly line
CN202556411U (en) * 2012-05-16 2012-11-28 浙江瑞丰机械设备有限公司 Frame roller manipulator
CN203451637U (en) * 2013-04-24 2014-02-26 东莞丰裕电机有限公司 Anodic oxidation production line
CN204058622U (en) * 2014-08-15 2014-12-31 深圳市鑫承诺科技有限公司 A kind of surface by micro-arc oxidation treatment unit of aluminum magnesium alloy
CN204281883U (en) * 2014-11-28 2015-04-22 涟水县苏杭科技有限公司 The anti-error extension system of wiring board nitre hang device
CN204311149U (en) * 2014-12-03 2015-05-06 昆山博古特机电设备有限公司 Anode hang tool goes up product facility automatically

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0261098A (en) * 1988-08-24 1990-03-01 Kawasaki Steel Corp Treatment of metallic material and equipment
CN1124304A (en) * 1994-03-17 1996-06-12 株式会社半导体能源研究所 Apparatus and method for anodic sxidation
CN1188820A (en) * 1996-11-28 1998-07-29 佳能株式会社 Anodizing processing apparatus and method associated with the same
US20040231993A1 (en) * 2000-12-21 2004-11-25 Price Joseph K. Anodizing system with a coating thickness monitor and an anodized product
US20050139159A1 (en) * 2003-12-30 2005-06-30 Price Joseph K. Anodizing system with a coating thickness monitor and an anodized product
CN2760053Y (en) * 2004-10-26 2006-02-22 中国科学院上海技术物理研究所 Gripping holder for anodized electrode on chip surface of semiconductor device
CN201292415Y (en) * 2008-10-31 2009-08-19 比亚迪股份有限公司 Anode oxidization apparatus for titanium and its alloy
CN102181894A (en) * 2011-04-02 2011-09-14 潘俊安 Device and method for carrying out single spraying on power battery case
CN202336871U (en) * 2011-11-14 2012-07-18 天津市聚兴电镀有限公司 Mechanical arm for electroplating assembly line
CN202556411U (en) * 2012-05-16 2012-11-28 浙江瑞丰机械设备有限公司 Frame roller manipulator
CN203451637U (en) * 2013-04-24 2014-02-26 东莞丰裕电机有限公司 Anodic oxidation production line
CN204058622U (en) * 2014-08-15 2014-12-31 深圳市鑫承诺科技有限公司 A kind of surface by micro-arc oxidation treatment unit of aluminum magnesium alloy
CN204281883U (en) * 2014-11-28 2015-04-22 涟水县苏杭科技有限公司 The anti-error extension system of wiring board nitre hang device
CN204311149U (en) * 2014-12-03 2015-05-06 昆山博古特机电设备有限公司 Anode hang tool goes up product facility automatically

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106086972A (en) * 2016-08-10 2016-11-09 松阳县恒亮不锈钢制品有限公司 A kind of open-type steel bowl automatization electroplanting device in batches
CN108624937A (en) * 2018-05-11 2018-10-09 王康 A kind of magnesium alloy workpiece anode oxidation method
CN108624937B (en) * 2018-05-11 2019-09-13 安徽明辉电气有限公司 A kind of magnesium alloy workpiece anode oxidation method
CN108950621A (en) * 2018-08-28 2018-12-07 王志伟 A kind of connection rod of automobile engine automation electro-brush plating prosthetic device
CN110372258A (en) * 2019-07-08 2019-10-25 杭州三耐环保科技股份有限公司 A kind of stirred tank and preparation method thereof

Also Published As

Publication number Publication date
CN105543927B (en) 2018-05-04

Similar Documents

Publication Publication Date Title
CN105543927A (en) Anodic oxidation system
CN105463550A (en) Anodic oxidation device
CN102191529B (en) Honeycomb ordered titanium dioxide nanotube array film and preparation method thereof
Lahan et al. An approach to improve the Al 3+ Ion intercalation in Anatase Tio 2 nanoparticle for aqueous aluminum-ion battery
CN101651046B (en) Preparation method of Al2O3/TiO2 compound dielectric film aluminum electrode foil
CN104634842A (en) Method for preparing electrode modified by copper/graphene nanocomposite and application of modified electrode
Park et al. Electrodeposited ruthenium oxide (RuO 2) films for electrochemical supercapacitors
Gajdosova et al. Remarkable differences in the voltammetric response towards hydrogen peroxide, oxygen and Ru (NH 3) 6 3+ of electrode interfaces modified with HF or LiF-HCl etched Ti 3 C 2 T x MXene
CN102505449A (en) Electrochemical modification treatment method of carbon fiber surface
Ghalmi et al. Capacitance performance of NiO thin films synthesized by direct and pulse potentiostatic methods
CN105642903B (en) The process for dispersing that a kind of nickel nanowire surface non-covalent modification is modified
CN105040062B (en) Cu2O nano-particles are sensitized TiO2The method of nanotube array photoelectrode
CN108946798A (en) A kind of threadiness hierarchical structure lithium titanate material and preparation and application
CN207798811U (en) A kind of hydrographic water resource monitoring device
CN101976741B (en) Ultrasonic wave dispersing and gel irrigating technology of gel battery
CN109326791A (en) A kind of porous lithium titanate material of threadiness and its preparation and product
CN103578784B (en) Nanometer copper oxide composite material and preparation method thereof and super-capacitor electrode and super-capacitor
CN107829127A (en) A kind of magnesium alloy differential arc oxidation treatment fluid, collocation method and its application containing rare earth compounding
CN105702466B (en) A kind of preparation method of high-k formed aluminum foil
CN103236354A (en) Method for manufacturing MnO<2> supercapacitor materials by template-free electrodeposition process
CN110042409A (en) Tungsten oxide/pucherite heterojunction photovoltaic anode preparation method and self-powered photoelectrolysis water system
CN104810549B (en) The porous gel method for preparing polymer electrolytes of doped compound nano particle
CN102401633A (en) Detection method for detecting thickness of barrier layer of porous alumina film
CN208230556U (en) A kind of aluminum section extruder
CN106206077A (en) A kind of preparation method and its usage of nanometer niobium pentaoxide/FTO aqueous super capacitor electrode material

Legal Events

Date Code Title Description
PB01 Publication
C06 Publication
SE01 Entry into force of request for substantive examination
C10 Entry into substantive examination
GR01 Patent grant
GR01 Patent grant