The method of comprehensive utilization of banana stem leaves
Technical field
The present invention relates to a kind of comprehensive utilization of plant stem-leaf, particularly relate to the method for comprehensive utilization of banana stem leaves.
Background technology
Southern china and the torrid zone such as Taiwan and Southeast Asia, India, Africa and warm torrid areas are all main places of production of banana.According to incompletely statistics, annual global banana planting area is more than 3,000 ten thousand mu, and total output is more than 400,000,000 tons, and wherein China (containing Taiwan) accounts for 20%.Banana is one of world's " four large fruit ", very popular.
After annual banana is gathered, banana stem leaves just becomes discarded object, and the weight of its cauline leaf is about 2 ~ 4 times of fruit (15 ~ 30kg/).Visible, the substantial amounts of banana stem leaves, various pollutions such as the soil environment, river and the underground water that cause after discarded and grow insect pest, harmful effect is extremely serious.These problems have caused global great attention, and take certain measure and alleviated; How better turning waste into wealth, comprehensive exploitation and effectively utilize the cauline leaf of banana, improves its economic worth, receives much concern always.
Banana is except fruits nutrition is abundant, and its cauline leaf is also " treasured ".First be the juice of banana stem leaves except large quantity of moisture, also containing amino acid, vitamin and Activities of Some Plants albumen, tannin (also known as tannic acid or tannin) rich content wherein, accounts for 1% ~ 3% of juice total amount.Tannin belongs to the active ingredient of water-soluble polyphenols class material, is natural organic compound.Show through inquiry Research Literature, tannin active component is considered to have convergence and protein coagulating effect at field of medicaments, can be used for hemostasis, antidiarrheal, sterilizing and antiviral etc. clinically; Current research also finds that it has the multiple pharmacologically actives such as anti-sudden change, anti peroxidation of lipid, scavenging free radicals, antitumor and anti-AIDS, also has certain sterilizing pesticide evil effect.Visible, the juice of banana stem leaves has tempting application prospect.
In the cauline leaf of banana, except about 90% is except water and tannin composition etc., all the other about 10% are strings, can as papermaking, weave cotton cloth, fibrous raw material and the organic fertilizer such as feed, its economic worth is considerable.
Chinese patent CN101897839A open " a kind of method of comprehensive utilization of banana stalk ", its technique comprises cleaning, fragmentation, screening, immersion, squeezing, filtration, allotment, homogeneous etc., complex manufacturing technology, the i.e. juice of enable extraction banana stem leaves, test shows, only carries out the DeGrain of sterilizing pesticide by tannin composition.
Chinese patent CN201510001181.4 discloses a kind of method that steam blasting pretreatment improves banana stem solid residue anaerobic digestion methane production.Its step comprise get the raw materials ready, steam blasting, rewinding, the process such as anaerobic digestion, be only limitted to banana stem to be converted into biogas, hemicellulose and lignin.
Song Zhiping etc. (Song Zhiping, Cai Junpeng. the exploitation of Banana Stalk-Leaves Resources, development of resources and market, 2005,21 (1)) propose: " banana stem leaves is except can as except forage grass resource;; also can be used for culturing edible fungus, extract salt, medical, papermaking etc., is a kind of crop genetic resource needing Devoting Major Efforts To Developing "; Also point out: " when developing, the removal problem of tannin in banana stem leaves (tannic acid) should be solved ... how removing tannin is the key developing banana stem leaves simultaneously.”
According to literature search, from banana stem leaves, extract juice and the utilization to tannin thereof, had not yet to see industrialized extracting method and practical application example.Its one of the main reasons is that people study and find that the independent exploitation of juice is uneconomical in banana stem leaves, effort of taking a lot of work, and causes having occurred " vacuum " in application or only rests on theoretic exploration; Although two of reason is that some document or disclosed patent it is also proposed the method extracting juice from banana stalk (not containing leaf), that the method extracted exists limitation on the one hand, be difficult to the content effectively extracting tannin from banana stalk, shown by test on the other hand, only be used for the DeGrain of sterilizing pesticide by the tannin composition in juice, therefore be not developed so far.
Summary of the invention
The object of the present invention is to provide the method for comprehensive utilization of banana stem leaves.
The present invention includes following steps:
1) cleaned by banana stem leaves, by the sewage purification after cleaning, the water after purification recycles, and separately takes out dry, as the raw material of bio-feritlizer by the sediment filtered;
2) banana stem leaves after cleaning is squeezed, and cauline leaf slag and juice are carried out separating treatment, the juice sealing after separation;
3) by step 2) cauline leaf slag after separating treatment dissolves;
4) by step 3) dissolve after cauline leaf slag carry out scum juice separation, the sealing of juice after separation;
5) by step 2) and step 4) juice that obtains loads sterilization treatment in high temperature pressure tank after filtering, juice after sterilization treatment is mixed with biological raw material, be placed on again after fermenting in hermetically sealed can, add after stabilizing agent continues fermentation and namely obtain biological agent;
6) by extracting the cauline leaf slag after juice, directly as raw material of papermaking fiber, or by after oxidant bleach as woven fibrous raw material, or as feed and additive thereof after pulverization process.
In step 1) in, described cleaning can adopt giant spraying method to clean, and banana stem leaves scavenging period per ton about needs 10min, and water consumption is about 1m
3.
In step 2) in, described squeezing can adopt squeezer to squeeze; After cauline leaf slag after described separating treatment can be pulverized, by compost fermentation process, as bio-feritlizer (fertilizer).
In step 3) in, described in dissolve and the cauline leaf slag after separating treatment can be dissolved by the heating mode steamed or boil; Described dissolve in can carry out stirring accelerating cauline leaf slag dissolve process; Described steaming or when boiling, the addition of water and cauline leaf slag can be 1: 2 in mass ratio.
In step 4) in, described scum juice is separated and extruding or drying mode can be adopted to carry out scum juice separation.
In step 5) in, described filtration can adopt filter cloth to filter, and described filter cloth can adopt 3927 filter cloths; Described sterilization treatment can in high temperature pressure tank, and carry out sterilization treatment by 150 ~ 200 DEG C of temperature and 0.2MPa pressure to it, the sterilization treatment time can be 30min; Described biological raw material can adopt the biological raw material containing compositions such as nicotine or reed rattan ketone; The mass ratio of described biological raw material and juice can be (1 ~ 2): 1000; The described time of fermenting in hermetically sealed can be 7 ~ 10 days, and environment temperature controls at 20 ~ 30 DEG C, and hermetically sealed can air pressure remains on 0.2MPa; Described stabilizing agent can adopt at least one in pawpaw alcohol, trehalose etc.; The described time of continuing fermentation can be 5 ~ 7 days, and hermetically sealed can air pressure remains on 0.2MPa; Described biological agent comprises sterile biological medicament and desinsection biological agent.
The banana stem leaves of results carries out processing and preparing by the present invention, comprise cleaning, squeeze, dissolve, secondary gets liquid, filtration, sterilizing, mixed culture fermentation, the step such as stable fermentation, allotment, extract the tannin active ingredient in banana stem leaves, and be prepared into the biological agent product of relevant sterilizing pesticide.This product, by test and detection shows, reaches nontoxic, effect safely and efficiently in sterilizing pesticide evil process.
By other techniques, post-processed is carried out to the body refuse etc. on the cauline leaf slag of banana (tree), banana stem leaves, other auxiliary product can be obtained, comprise as papermaking, the string of to weave cotton cloth etc., feed and additive thereof, organic fertilizer etc.
Advantage of the present invention and beneficial effect as follows:
1. achieving the suitability for industrialized production of a large amount of banana stems and leaf being carried out turning waste into wealth, fundamentally eliminating banana stem leaves because piling up the rotten pollution problem caused.Show from disclosed documents and materials, the present invention is the most simple and practical in fully utilizing banana stem leaves for industrialization at present and effective method.
2. propose effectively to extract vegetable tannin active ingredient by methods such as squeezing, dissolve from banana stem leaves, and the composition such as employing and nicotine, reed rattan ketone, pawpaw alcohol, trehalose carries out mixed culture fermentation and stablizes techniques such as fermenting, juice in banana stem leaves is refined into the biological agent of sterilizing pesticide evil, after testing with in tea place, orchard, the place such as vegetables the test of sterilizing pesticide evil show, achieve very good effect, be subject to customer acceptance.
3. cauline leaf (doing) slag after pair extraction juice and the body refuse etc. of the rear deposition of cleaning, because cauline leaf (doing) slag does not retain its toxicity, therefore as long as simple process (processing) is carried out to it, the cauline leaf slag of banana and body refuse can be made all to be utilized, do not stay debris getting, also there will not be secondary environmental pollution problem, really realize environmental protection and economy.
Accompanying drawing explanation
Fig. 1 is the flow chart of the method for comprehensive utilization of the invention process banana stem leaves, comprises and extract the process that sterilizing pesticide evil biological agent is made in juice, fermentation and allotment from banana stem leaves.
Fig. 2 is the Application way of the invention process to banana stem leaves slag, and what be about to extract remaining cauline leaf slag, body refuse etc. in juice process utilizes flow chart.
In fig 1 and 2, respectively be labeled as: 1-cleaning and purification process, 11-delivers to whole the banana stem leaves in preparation place after representing results, the earth that 12-deposits after representing banana stem leaves cleaning and waste material (abbreviation body refuse), and 13-represents whole the banana stem leaves cleaned up; 2-represents squeezing and separation process, and 21-represents that squeezer squeezes whole banana stem leaves, the cauline leaf slag that 22-is separated after representing squeezing, (former) juice that 23-separates after representing squeezing; 3-represents the fusion process after to squeezing, and 31-represents that the banana stem leaves slag after by squeezing puts into melting tank, and 32-represents that use heating apparatus carries out steaming or boiling, and cauline leaf slag is dissolved, and 33-represents the cauline leaf slag liquid mixture after dissolving; 4-represents that secondary gets liquid process, and 41-represents drier (or extruder), and 42-represents the dry slag after separation, and 43-represents the juice after separation; 5-represents filtration and sterilization process, and the juice obtained twice is mixed, and carries out high-temperature sterilization process by filter cloth filtration residue, 51-represents filter cloth, 52-represents the residue after filtration, and 53-represents that the juice after filtration is through high-temperature sterilization, and 54 is sterilizing heating apparatus; 6-represents mixed culture fermentation process, and 61 represent fermentation tank, and 62-represents the special ferment of the biology adding proper proportion in fermentation tank, and 63-represents the juice after mixed culture fermentation; 7-represents stable sweat, and 71-represents fermentation tank, and 72-represents the Biostatic ferment adding proper ratio in fermentation tank, and 73-represents the juice after stable fermentation; 8-represents the allocation process after juice fermentation, and 81-represents and can be formulated into biological sterilization medicament, and 82-represents and is allocated as Biocidal medicament; 9-represents the fiber utilization of banana stem leaves slag, 91-represents and can be used as raw material of papermaking fiber, and 92-represents through industrial bleaching processes, and 93-represents can be used as woven fibrous raw material after bleaching, 94-represents the banana stem leaves slag after pulverizing, and 95-represents as animal feed and additive; 10-represent by cauline leaf cleans the earth (comprising waste material), the juice that stay filter after residue or cauline leaf slag bio-feritlizer of carrying out after pulverizing utilize, 101-represents sweat, and 102-represents as bio-feritlizer; 111-represents the skin of banana.
Detailed description of the invention
The present invention is further illustrated by reference to the accompanying drawings for following examples.
1. dust banana stem leaves is infected with and other dirt, in order to avoid the pure composition of impurity effect subsequent extracted juice.Sewage after cleaning will purify, and on the one hand the water after purification be recycled, to reduce the consumption of running water; On the other hand the foreign material such as the dirt mud filtered are taken out dry, as the raw material of bio-feritlizer.Industrialization cleaning can select giant spraying technique, and cauline leaf scavenging period per ton about needs 10min, and water consumption is about 1m
3, the water reproducible utilization after purification reaches more than 90%.
2. press juicing: the cauline leaf of whole banana after cleaning is directly sent into squeezer and squeezes, and cauline leaf slag and juice are carried out separating treatment.Juice after separation needs to seal, to be oxidized from air impact.Suitability for industrialized production can select the equipment of similar sugar-cane press to squeeze, and the time that every banana stem leaves squeezing and juice are separated is generally 45 ~ 50s.Test shows, the juice of directly squeezing taking-up is about containing 70%, and the composition of tannin is about containing 50%, and the nearly tanning matter of half also remains in cauline leaf slag after the press.
3. cauline leaf slag dissolves: the cauline leaf slag above-mentioned squeezing be separated afterwards is dissolved by the heating mode steamed or boil.The method that cauline leaf slag is dissolved in industrialization can adopt tank or pot class, cauline leaf slag is carried out to the process of decatize or poach, make cauline leaf slag be heated and dissolve according to similar daily cooking, and that can also accelerate cauline leaf slag by agitation as appropriate dissolves process.
4. get liquid two times: after the heating of cauline leaf slag is dissolved, tannin composition can decompose out rapidly from cauline leaf slag, by extrude or drying mode carries out scum juice separation.Solubilized 10 ~ 20 tons of cauline leaf slags of the every tank of suitability for industrialized production (or every pot), dissolve and get the liquid time and be about 30min.When dissolving, the part by weight of clear water and cauline leaf slag is about 1: 2.Equally, the juice after separation also needs encapsulation process.Test shows, by pressing juicing and dissolving 2 procedures getting liquid, juice and the tannin composition thereof of taking-up can reach 96%; Cauline leaf slag after being then separated residual toxicity hardly.
5. filter and sterilization treatment: the juice obtained above-mentioned twice filters through 3927 filter cloths, object removes residue, obtains pure juice.Residue after filtration is follow-up will carry out disposal and utilization.
Pure juice after filtering is loaded in high temperature pressure tank, by 150 DEG C ~ 200 DEG C temperature and 0.2MPa pressure, sterilization treatment is carried out to it.The every tank of suitability for industrialized production can be installed in 10 ~ 20 tons of juice, and each sterilization time is about 30min.Sterilization treatment object is gone mouldy to prevent juice from producing, to keep the active component of tannin.
6. mixed culture fermentation: by through the juice of sterilization treatment and biological raw material in mass ratio 1000: (1 ~ 2) is allocated, and is then placed in hermetically sealed can, carries out the fermentation of 7 ~ 10 days by a definite date.In sweat, environment temperature should be controlled at 25 ± 5 DEG C, hermetically sealed can air pressure remains on 0.2MPa.Here biological raw material main component is the composition such as nicotine, reed rattan ketone, does not add other chemicals, to keep the natural component of juice; Make the tannin of juice and nicotine, reed rattan ketone etc. carry out microbial transformation and synthesis, effectively to promote sterilizing pesticide effect simultaneously.
7. stable fermentation: on the basis of mixed culture fermentation, add stabilizing agent, main component is the stabilizing agent that the pawpaw alcohol, trehalose etc. refined from biological raw material is made, and puts into the fermentation that hermetically sealed can carries out 5 ~ 7 days by a definite date after stirring.This stage main purpose keeps the characteristic of medicament and can not change.In sweat, hermetically sealed can air pressure remains on 0.2MPa, and avoids sunlight direct irradiation.After stable fermentation, the shelf-life of this biological agent is 2 ~ 3 years, stores at normal temperatures.
8. allocate: after above-mentioned fermenting twice, the juice extracted from banana stem leaves is just generated as the biological agent of sterilizing pesticide.On the one hand during the fermentation by feed change proportioning, fermentation time, temperature and pressure, sterile biological medicament and desinsection biological agent can be made respectively.On the other hand for different mushrooms and insects, the proportioning of medicament and water is also different.For the phytopathogen that control is common, the proportioning of water and medicine is generally (200 ~ 500): 1; For the plant pest that control is common, the proportioning of water and medicine is generally (30 ~ 100): 1.This medicament is brown, and the various ways such as sprinkling, pouring, atomization can be adopted to be used.After medicament uses, 5 ~ 15min starts to play a role, and drug effect normal duration is 3 ~ 7 days.
9. cauline leaf slag utilizes: extract the cauline leaf slag after juice, one, can directly as raw material of papermaking fiber; Its two, cauline leaf slag, can as woven fibrous raw material by after oxidant bleach; Its three, after cauline leaf slag is carried out pulverization process, can as feed and additive thereof.
10. slug detect: the residue after the sediment of dust and other dirt on cleaning banana stem leaves and juice being filtered collects, comprises after broken for exhaustless cauline leaf ground-slag, by compost fermentation process, as bio-feritlizer (fertilizer).
Below provide specific embodiment.
Embodiment 1
See Fig. 1, the embodiment of the present invention 1 from banana stem leaves, carries out industrialization extract juice, and make the method for sterilizing pesticide evil medicament by biological fermentation process.First be banana stem leaves is cleaned and purification process 1, by banana whole cauline leaf 11 of results, cleaning showers is carried out with giant, to utilize in subsequent treatment through precipitating the body refuse 12 collected after dirt mud under being rinsed and other foreign material, whole the cauline leaf 13 cleaned up is admitted to the 2nd procedure 2; This operation is squeezing and separation process, and whole banana stem and leaf are directly sent into squeezer and carry out squeezing 21, the juice 23 after expression separation carries out sealing and deposits, and the cauline leaf slag 22 after squeezing delivers into the 3rd procedure; This operation carries out fusion process 3 to the cauline leaf slag do not drained, and cauline leaf slag 22 put into melting tank (or pot) 31, carries out steaming or boiling making it dissolve with heating apparatus 32, then the slag liquid mixture 33 after dissolving delivered to the 4th procedure process; This operation is that secondary gets liquid process 4, scum juice mixture 33 is transported to drier (or extruder) 41, being separated of juice and recrement is carried out by drying (or extruding) mode, dry slag after separation collects 42, be convenient to subsequent development utilize, and the juice 43 after being separated sends into the 5th procedure together with the juice 23 of squeezing; This operation is for filtering and autoclaving process 5, it can adopt 3927 filter cloths 51 to filter, residue 52 after filtration is collected together with the body refuse 12 of cleaning, be convenient to follow-up soil fertility quality, 54 is sterilizing heating apparatus, for carrying out high-temperature sterilization process to juice, after filtering and the 6th procedure sent into by the juice 53 carrying out high-temperature sterilization; This operation is mixed culture fermentation process 6, in the fermentation tank 61 of splendid attire juice 53, add the biofermentation element 62 (main component is the nicotine and reed rattan ketone that extract from plant) of proper proportion, then sealing and fermenting is carried out, fermentation time is generally 10 ~ 15 days, and keep suitable fermentation temperature and humidity, make it obtain sufficient mixed culture fermentation effect, the 7th procedure delivered to by the juice 63 after mixed culture fermentation; This operation is for stablize sweat 7, juice 63 after mixed culture fermentation is loaded the fermentation tank 71 of sealing, and in fermentation tank, add the Biostatic ferment 72 (main component is the stabilizing agent that the pawpaw alcohol, trehalose etc. refined from biological raw material is made) of proper ratio, keep temperature, humidity and pressure that fermentation tank is suitable, stabilization of fermentation time is generally 7 ~ 8 days, and the 8th procedure process sent into by the juice 73 after stable fermentation; This operation is the allocation process 8 after juice fermentation, during the fermentation by changing ferment proportioning, fermentation time, temperature, humidity and pressure, can make sterile biological medicament 81 and desinsection biological agent 82 respectively.Show through test, for the germ that control plant is common, the proportioning of water and medicine is generally (300 ~ 500): 1; For the disease and pest that control plant is common, the proportioning of water and medicine is generally (30 ~ 100): 1, all has good Pesticidal and sterilizing effect.
Embodiment 2
See Fig. 2, the embodiment of the present invention 2 is the Application way to banana stem leaves slag.On the basis of embodiment 1, owing to passing through squeezing and dissolving drying process, place to go is except the tannin of banana stem leaves slag substantially, then banana stem leaves (doing) slag 42 is utilized 9 as string, comprise and just there is not toxicity as feed, can use safely.The first is using the raw material 91 of banana stem leaves slag as paper-making fibre, and it two is by banana stem leaves slag after industrial bleaching 92, as the raw material 93 of woven fibrous; Its three be by pulverize after banana stem leaves slag 94, as feed and additive 95 thereof.In a word, banana stem leaves slag is made to be fully used.
Embodiment 3
See Fig. 2, the embodiment of the present invention 3 is the Application way to banana stem leaves slag and body refuse.On the basis of embodiment 1, respectively to the banana stem leaves slag 94 after pulverizing, clean the body refuse 12 that stays and the residue 52 after filtering, utilize process 10 as bio-feritlizer.Wherein, 101 expressions carry out biofermentation to 94,12 and 52, can be used as organic fertilizer after 102 expression fermentations.Skin 111 for banana also can utilize as animal feed 95 or bio-feritlizer 102.The compost fermentation time of organic fertilizer is generally about 15 days.
In reality utilizes, industrialized preparation facilities all adopts automation equipment, and the measure of application safety examination and controlling, not only ensure refiningization and the standardization of manufacturing process, and ensure safe and the intellectuality of manufacturing process, realize industrialized production in enormous quantities.