CN105523830A - Preparation method of bioavailable mineral ion chelate artificial mineral solution - Google Patents
Preparation method of bioavailable mineral ion chelate artificial mineral solution Download PDFInfo
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- CN105523830A CN105523830A CN201510942065.2A CN201510942065A CN105523830A CN 105523830 A CN105523830 A CN 105523830A CN 201510942065 A CN201510942065 A CN 201510942065A CN 105523830 A CN105523830 A CN 105523830A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention relates to a preparation method of a bioavailable mineral ion chelate artificial mineral solution. On a land or in a water area where minerals which are essential to growth of animals and plants are insufficient, mineral-containing iron steel mineral slag and an ion chelate undergo ion chelation in a water solution so as to form the bioavailable mineral ion chelate artificial mineral solution; and pH value of the bioavailable mineral ion chelate artificial mineral solution is controlled to below 9. The invention has the following beneficial effect: the product is used for improving the natural circulation function on a land or in a water area where minerals which are essential to animals, plants and microbes are insufficient.
Description
Technical field
What the present invention relates to is a kind of land or waters of mineral deficiency needed for animals and plants, mix mutually with ion chelating material with the material containing mineral substance, the method of artificial mineral's matter solution of the mineral ion inner complex of a kind of biological effectiveness of preparation, quantitative continuous provides biological effectiveness mineral substance nutrient for animals and plants, improves the material cycle function of the ecosystem.
Background technology
Affect by public work and acid rain etc., in the soil in some region, the necessary trace mineral of animals and plants is not enough.In addition, in waters, also there will be the situation of the necessary mineral deficiencies of aquatic animals and plants such as algae, pasture and water and microorganism, thus cause the minimizing of the groups such as algae, pasture and water and microorganism even to disappear.
For the region of such mineral deficiency, liquid fertilizer can be adopted to apply fertilizer.Having existed a kind of is that the alkaline liquid fertilizer of main raw material carries out soil improvement with shell.Animal residue adds organic acid soln, maintains PH below 5.7, make it corruption not occur, and the method making liquid fertilizer is suggested.After utilizing caustic digestion animal residue, then its pH is made to be down to less than 3.0, to improve the manufacture method of liquid fertilizer filterableness.After the residue caustic digestion produced when W-Gum is manufactured, add phosphoric acid solution and make its pH maintain less than 7.0, make liquid fertilizer maintain stable method and be also suggested.
The technology of the carbonating iron steel slag compound ion chelating material manufacturing artificial mineral substance liquid fertilizer containing mineral substance and using method is utilized also not to occur.
Summary of the invention
That the present invention proposes is a kind of preparation method of mineral ion inner complex artificial mineral matter solution of biological effectiveness, its object is intended to utilize mineral substance abundant in carbonating iron steel slag to make liquid fertilizer, this fertilizer is supplied, to promote vegeto-animal growing to animals and plants.
Technical Solving of the present invention: the preparation method of the mineral ion inner complex artificial mineral matter solution of biological effectiveness, carbonating iron steel slag material containing mineral substance is mixed with ion exchange material, regulate the pH2.0-9.0 of this mixture and dissolve and form artificial mineral's matter solution, wherein calcium, magnesium, phosphorus, iron ore material just present the form that animals and plants are easy to absorb.
Beneficial effect of the present invention:
In land or the waters of the required mineral deficiency of animals and plants, microorganism, in order to improve natural circulation function.
Accompanying drawing explanation
Fig. 1 be land arrange containing the material of mineral substance and ion exchange material mixture time, the reference illustration of the supply method of artificial mineral's matter solution.
To be rainwater, 2 be in figure 1 be retaining wall, 4 are artificial mineral's matter lysates, 5 containing the mixture, 3 of mineral material and ion exchange material is plants.
Embodiment
The preparation method of the mineral ion inner complex artificial mineral matter solution of biological effectiveness, the land of mineral deficiency or waters needed for animal and plant growth, ion chelating is carried out in aqueous by the iron steel slag material and ion chelating material that contain mineral substance, form artificial mineral's matter solution with the mineral ion inner complex of biological effectiveness, control its pH value below 9.
Described artificial mineral's matter solution contains the acid-treated iron steel slag of carbon, a kind of or several mineral filler, can promote the ion exchange material of sequestering action, can promote the acid solid of sequestering action and liquid, can promote the artificial vegetable mould of ion exchange or artificial extracting solution humous.
Described artificial humic is native as cow dung compost, peat, leaf-humidified soil; Undecomposed vegetation, sewage excess sludge, cattle waste, obtain the humic substance mix products after Acidic organic matter fermentative processing, in order to process mineral raw material by fermentative processing.
Described artificial mineral's matter solution, containing ion exchange material, C/N is than more than 12, and organic content more than 65%, pH value scope is at 2.0-9.0, and conductance is at below 2.0ms/cm.
Accommodate with water-permeable container that is bag-shaped and film like, to ensure that animals and plants are in the growing environment with the supply of persistent mineral matter after adding jelling agent, thickening material, paste, stablizer in described artificial mineral's matter solution.
The use procedure of the mineral ion inner complex artificial mineral matter solution of biological effectiveness, comprising:
(1) plant 5 is near an inclined-plane, rainwater 1 flows through the position of preserving containing the material of mineral substance and the mixture 2 of ion exchange material downwards from this incline apex, this mixture 2 is that simple placement is also passable, in order to improve dissolving sequestration efficiency, also can use retaining wall 3;
(2) have passed through rainfall, rainwater 1, in contacting with mixture 2 mixing of ion exchange material containing the material of mineral substance, makes this mixture 2 dissolve, and generates artificial mineral's matter solution 4, namely waters the liquid fertilizer spilt to animals and plants;
(3) artificial mineral's matter solution 4 supplies the animals and plants 5 of below to absorb along with rainwater 1 goes downstream;
(4) liquid fertilizer is to animals and plants, waters plant absorption, comprises
1) liquid fertilizer absorbs to animals and plants, artificial mineral's matter solution is put into there is water-permeable, the container of film like accommodates, then be buried in the earth slowly-releasing and absorb for animals and plants; Container makes material available chlorine ethene, polyethylene, polyester, urethane organic chemical, or vegetable fibre natural organic; Use the soil method of burying to be plant feeding liquid fertilizer, the seepage discharge of adjustable mineral substance, thus provide lasting mineral substance supply to Soil Surrounding, go back the machine watering of using spray machine, also available pump watering, method is not limit;
2) liquid fertilizer is to waters plant absorption, by the artificial mineral's matter solution after being dissolved by rainwater containing the material of mineral substance and the mixture of ion chelating material, put into and there is water-permeable, pack bag-shaped, accommodate in the container of film like, be placed in fresh water, the bank such as seawater, the water surface or the bottom, the seepage discharge of this container adjustable mineral substance, thus provide lasting mineral substance supply to surrounding body; The making material available chlorine ethene of this container, polyethylene, polyester, urethane organic chemical and vegetable fibre natural organic, synthetic Water permeable film, except the material that can pollute waters, the material of above-mentioned effect can be completed, the method of adjustment mineral substance stripping quantity, with having water-permeable, is packed bag-shaped, the container of film like with not there is the bag-shaped of water-permeable, film like container combination adjusts;
(5) with mass ratio be 1 ~ 50% gelating agent or tackifier, thickening material or stablizer to mix with artificial mineral's matter solution and make its gelation, material after gel reaction is with having water-permeable, pack bag-shaped, the container collecting of film like, can provide lasting mineral substance supply to vegeto-animal growing environment.
The method of described gelation is: use the vegetalitas phlegmatic temperaments such as alginates, gelatin, carrageenin, pectin such as algin acid esters, starch, Mierocrystalline cellulose, glycogen tackifier, thickening material, gum stabilizers.
Iron and steel slag used, comprises from blast-furnace slags such as blast-furnace slag, blast-furnace cinder, blast furnace slow cooling slags; The slag (desulfurization slag, desiliconization slag, dephosphorization slag) of molten pig iron; Converter slag; Electric furnace slag; The slag formed during the molten steels such as stainless steel slag.Ion chelating material, is in conjunction with mineral substance, generates the mixed solution with high biological effectiveness, so that vegeto-animal absorption and utilization.
Adopt the process of iron and steel slag carbonating, so-called carbonating process, when being under having water to coexist, calcium oxide in iron and steel slag and Calucium Silicate powder and carbon dioxide exposure form the treating processes of calcium carbonate, this process, can allow mineral substance dissolved chelating well beyond calcium, thus extract silicon, phosphorus, iron, the magnesium mineral prime element in iron and steel slag.
Promote material mainly some acid liquid or solids of sequestering action.For example, the vinegar such as wood vinegar, bamboo vinegar liquid liquid, hydrochloric acid, sulfuric acid, nitric acid, acetic acid mineral acid, acetic acid, citric acid carboxylic acid-based compound, the organo phosphorous compounds such as phosphoric acid, phosphonic acids, sulfonic group compound acidic liquid, and artificial humic's soil, cow dung compost, leaf-humidified soil, red clay acidic substance (not limiting).
Ion exchange material is a kind of liquid with ion chelating function by obtaining after the extraction of artificial humic's soil origin.
In the present invention, rainwater, spring, underground water, seawater, river, lake and pond natural water form this artificial mineral's matter solution with containing the material of mineral substance contacts rear dissolving with the mixture of ion exchange material, and this solution is flowed to animals and plants and microorganism, thus enables to obtain and absorb this liquid fertilizer.
Artificial mineral's matter solution of the present invention to the vegeto-animal supply method in land is: the animals and plants and the microorganism that are supplied to land after the mixture keeping material and ion exchange material containing mineral substance to form is dissolved by rainwater.
Embodiment (use), as shown in Figure 1,
Plant 5 is near an inclined-plane, and rainwater 1 flows through the position of preserving containing the material of mineral substance and the mixture 2 of ion exchange material downwards from this incline apex, and this mixture 2 is that simple placement is also passable, in order to improve dissolving sequestration efficiency, also can use retaining wall 3.
Through rainfall, rainwater 1, in contacting with mixture 2 mixing of ion exchange material containing the material of mineral substance, makes this mixture 2 dissolve, and artificial mineral's matter solution 4 supplies the animals and plants 5 of below to absorb along with rainwater 1 goes downstream.As for watering the method for spilling this liquid fertilizer to animals and plants, artificial mineral's matter solution can be put into there is water-permeable, the container of film like accommodates, then be buried in the earth slowly-releasing and absorb for animals and plants.Container makes material available chlorine ethene, polyethylene, polyester, the organic chemical such as urethane, or the natural organic such as vegetable fibre, and synthetic Water permeable film, except the material that can pollute soil, can complete the material of above-mentioned effect.Use the soil method of burying to be plant feeding liquid fertilizer, the seepage discharge of adjustable mineral substance, thus provide lasting mineral substance supply to Soil Surrounding.The also machine watering of using spray machine, also available pump watering, method is not limit.
The supply method of artificial mineral's matter solution of the present invention to waters plant is: by the artificial mineral's matter solution after being dissolved by rainwater containing the material of mineral substance and the mixture of ion chelating material, put into and there is water-permeable, pack bag-shaped, accommodate in the container of film like, be placed in fresh water, the bank such as seawater, the water surface or the bottom, the seepage discharge of this container adjustable mineral substance, thus provide lasting mineral substance supply to surrounding body.The making material available chlorine ethene of this container, polyethylene, polyester, urethane organic chemical and vegetable fibre natural organic, synthetic Water permeable film, except the material that can pollute waters, the material of above-mentioned effect can be completed.The method of adjustment mineral substance stripping quantity, with having water-permeable, is packed bag-shaped, the container of film like with not there is the bag-shaped of water-permeable, film like container combination adjusts.
The present invention's mass ratio be 1 ~ 50% gelating agent or tackifier, thickening material or stablizer mix with artificial mineral's matter solution and make its gelation, reacted material is with having water-permeable, pack bag-shaped, the container collecting of film like, can provide lasting mineral substance supply to vegeto-animal growing environment.The method of artificial mineral's matter solution gels is: use the vegetalitas phlegmatic temperaments such as alginates, gelatin, carrageenin, pectin such as algin acid esters, starch, Mierocrystalline cellulose, glycogen tackifier, thickening material, the stablizers such as natural gum.
The present invention is for continuing to provide mineral substance in Insufficient land or waters, and the improvement making land-based area or waters reduce the natural circulation function even disappeared becomes possibility.
Claims (7)
1. the preparation method of the mineral ion inner complex artificial mineral matter solution of biological effectiveness, it is characterized in that land or the waters of mineral deficiency needed for animal and plant growth, ion chelating is carried out in aqueous by the iron steel slag material and ion chelating material that contain mineral substance, form artificial mineral's matter solution with the mineral ion inner complex of biological effectiveness, control its pH value below 9.
2. the preparation method of the mineral ion inner complex artificial mineral matter solution of biological effectiveness according to claim 1, is characterized in that artificial mineral's matter solution contains the acid-treated iron steel slag of carbon, a kind of or several mineral filler, can promote the ion exchange material of sequestering action, can promote the acid solid of sequestering action and liquid, can promote the artificial vegetable mould of ion exchange or artificial extracting solution humous.
3. the preparation method of the mineral ion inner complex artificial mineral matter solution of biological effectiveness according to claim 1, is characterized in that described artificial humic's soil is as cow dung compost, peat, leaf-humidified soil; Undecomposed vegetation, sewage excess sludge, cattle waste, obtain the humic substance mix products after Acidic organic matter fermentative processing, in order to process mineral raw material by fermentative processing.
4. the preparation method of the mineral ion inner complex artificial mineral matter solution of biological effectiveness according to claim 1, it is characterized in that described artificial mineral's matter solution, containing ion exchange material, C/N is than more than 12, organic content more than 65%, pH value scope is at 2.0-9.0, and conductance is at below 2.0ms/cm.
5. the preparation method of the mineral ion inner complex artificial mineral matter solution of biological effectiveness according to claim 1, accommodate with water-permeable container that is bag-shaped and film like, to ensure that animals and plants are in the growing environment with the supply of persistent mineral matter after it is characterized in that adding jelling agent, thickening material, paste, stablizer in described artificial mineral's matter solution.
6. the use of the mineral ion inner complex artificial mineral matter solution of biological effectiveness as claimed in claim 1, is characterized in that comprising,
(1) plant is near an inclined-plane, rainwater 1 flows through the position of preserving containing the material of mineral substance and the mixture of ion exchange material downwards from this incline apex, this mixture is that simple placement is also passable, in order to improve dissolving sequestration efficiency, also can use retaining wall;
(2) have passed through rainfall, rainwater, in contacting with the mixture mixing of ion exchange material containing the material of mineral substance, makes this mixture dissolve, and generates artificial mineral's matter solution, namely waters the liquid fertilizer spilt to animals and plants;
(3) artificial mineral's matter solution supplies the animals and plants of below to absorb along with rainwater goes downstream;
(4) liquid fertilizer is to animals and plants, waters plant absorption, comprises
1) liquid fertilizer absorbs to animals and plants, artificial mineral's matter solution is put into there is water-permeable, the container of film like accommodates, then be buried in the earth slowly-releasing and absorb for animals and plants; Container makes material available chlorine ethene, polyethylene, polyester, urethane organic chemical, or vegetable fibre natural organic; Use the soil method of burying to be plant feeding liquid fertilizer, the seepage discharge of adjustable mineral substance, thus provide lasting mineral substance supply to Soil Surrounding, go back the machine watering of using spray machine, also available pump watering, method is not limit;
2) liquid fertilizer is to waters plant absorption, by the artificial mineral's matter solution after being dissolved by rainwater containing the material of mineral substance and the mixture of ion chelating material, put into and there is water-permeable, pack bag-shaped, accommodate in the container of film like, be placed in fresh water, seawater bank, the water surface or the bottom, the seepage discharge of this container adjustable mineral substance, thus provide lasting mineral substance supply to surrounding body; The making material available chlorine ethene of this container, polyethylene, polyester, urethane organic chemical and vegetable fibre natural organic, synthetic Water permeable film, except the material that can pollute waters, the material of above-mentioned effect can be completed, the method of adjustment mineral substance stripping quantity, with having water-permeable, is packed bag-shaped, the container of film like with not there is the bag-shaped of water-permeable, film like container combination adjusts;
(5) with mass ratio be 1 ~ 50% gelating agent or tackifier, thickening material or stablizer to mix with artificial mineral's matter solution and make its gelation, material after gel reaction is with having water-permeable, pack bag-shaped, the container collecting of film like, can provide lasting mineral substance supply to vegeto-animal growing environment.
7. the use of the mineral ion inner complex artificial mineral matter solution of biological effectiveness as claimed in claim 1, it is characterized in that the method for described gelation is: use alginates, gelatin, carrageenin, the pectin vegetalitas phlegmatic temperaments such as algin acid esters, starch, Mierocrystalline cellulose, glycogen tackifier, thickening material, gum stabilizers.
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| CN201510942065.2A CN105523830A (en) | 2015-12-16 | 2015-12-16 | Preparation method of bioavailable mineral ion chelate artificial mineral solution |
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| CN201510942065.2A CN105523830A (en) | 2015-12-16 | 2015-12-16 | Preparation method of bioavailable mineral ion chelate artificial mineral solution |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112645744A (en) * | 2021-01-13 | 2021-04-13 | 陈建伟 | Chelated iron compound fertilizer and preparation method thereof and slow-release soil conditioner |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52127865A (en) * | 1976-04-19 | 1977-10-26 | Kenkichi Tsukamoto | Iron oxideealcaline fertilizer |
| CN1053419A (en) * | 1991-02-06 | 1991-07-31 | 白远存 | Fertilizer synergistic agent and production technique thereof |
| CN1371889A (en) * | 2001-02-19 | 2002-10-02 | 邵建华 | Amino-acid trace element chalted silicon fertilizer and productive method thereof |
| CN102119651A (en) * | 2010-12-22 | 2011-07-13 | 郭云征 | Small soilless culture method and device |
| WO2014189314A1 (en) * | 2013-05-23 | 2014-11-27 | Wang Youngsung | Organic fertilizer pack having environmentally friendly biodegradable function |
-
2015
- 2015-12-16 CN CN201510942065.2A patent/CN105523830A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52127865A (en) * | 1976-04-19 | 1977-10-26 | Kenkichi Tsukamoto | Iron oxideealcaline fertilizer |
| CN1053419A (en) * | 1991-02-06 | 1991-07-31 | 白远存 | Fertilizer synergistic agent and production technique thereof |
| CN1371889A (en) * | 2001-02-19 | 2002-10-02 | 邵建华 | Amino-acid trace element chalted silicon fertilizer and productive method thereof |
| CN102119651A (en) * | 2010-12-22 | 2011-07-13 | 郭云征 | Small soilless culture method and device |
| WO2014189314A1 (en) * | 2013-05-23 | 2014-11-27 | Wang Youngsung | Organic fertilizer pack having environmentally friendly biodegradable function |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112645744A (en) * | 2021-01-13 | 2021-04-13 | 陈建伟 | Chelated iron compound fertilizer and preparation method thereof and slow-release soil conditioner |
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Application publication date: 20160427 |