CN105518080B - 低辐射涂敷物及包括其的窗户用建筑材料 - Google Patents
低辐射涂敷物及包括其的窗户用建筑材料 Download PDFInfo
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- CN105518080B CN105518080B CN201480048460.XA CN201480048460A CN105518080B CN 105518080 B CN105518080 B CN 105518080B CN 201480048460 A CN201480048460 A CN 201480048460A CN 105518080 B CN105518080 B CN 105518080B
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- 238000000576 coating method Methods 0.000 title claims abstract description 68
- 239000011248 coating agent Substances 0.000 title claims abstract description 66
- 239000004035 construction material Substances 0.000 title claims description 21
- 239000010410 layer Substances 0.000 claims abstract description 163
- 229910052751 metal Inorganic materials 0.000 claims abstract description 67
- 239000002184 metal Substances 0.000 claims abstract description 67
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 28
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004411 aluminium Substances 0.000 claims abstract description 23
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 23
- 239000011701 zinc Substances 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 230000005540 biological transmission Effects 0.000 claims description 14
- 150000004767 nitrides Chemical class 0.000 claims description 12
- 230000008033 biological extinction Effects 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 239000010931 gold Substances 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 150000004706 metal oxides Chemical class 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 150000001399 aluminium compounds Chemical class 0.000 claims 1
- 239000010936 titanium Substances 0.000 description 21
- 239000000463 material Substances 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 12
- 239000005344 low-emissivity glass Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 230000003287 optical effect Effects 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910052786 argon Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 238000002310 reflectometry Methods 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 229910003087 TiOx Inorganic materials 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 229910001120 nichrome Inorganic materials 0.000 description 4
- 238000010406 interfacial reaction Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910017083 AlN Inorganic materials 0.000 description 1
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 230000010748 Photoabsorption Effects 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
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- C—CHEMISTRY; METALLURGY
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3642—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating containing a metal layer
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/007—Other surface treatment of glass not in the form of fibres or filaments by thermal treatment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2551/00—Optical elements
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/257—Refractory metals
- C03C2217/26—Cr, Mo, W
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/28—Other inorganic materials
- C03C2217/281—Nitrides
Abstract
本发明提供多层结构的低辐射涂敷物，上述多层结构的低辐射涂敷物依次包括Ti类氧化物层、锌及铝的复合金属类氧化物层、低辐射保护金属层及低辐射层。
Description
技术领域
本发明涉及低辐射涂敷物及包括其的窗户用建筑材料。
背景技术
低辐射玻璃(Low-Emissivity glass)是指包含银(Ag)等在红外线范围的反射率高的金属的低辐射层以薄膜的方式蒸镀的玻璃。这种低辐射玻璃是一种功能性原材料，夏天反射太阳辐射热，冬天保存在室内取暖器中产生的红外线，从而带来建筑物节能效果。
一般，用作低辐射层的银(Ag)在露出于空气中时会氧化，因而在上述低辐射层的上部及下部蒸镀电介质层作为抗氧化膜。这种电介质层还起到增加可见光透射率的作用。
发明内容
本发明要解决的技术问题
本发明的一实例提供低辐射涂敷物，上述低辐射涂敷物在热处理后也维持耐久性，且光学性能优秀。
本发明的另一实例提供窗户用建筑材料，上述窗户用建筑材料包括上述低辐射涂敷膜。
技术方案
在本发明的一实例中，提供多层结构的低辐射涂敷物，上述多层结构的低辐射涂敷物依次包括Ti类氧化物层、锌及铝的复合金属类氧化物层、低辐射保护金属层及低辐射层。
上述锌及铝的复合金属类氧化物层可包含由ZnAlOx、0.9≤x≤1.1表示的锌及铝的复合金属类氧化物。
上述锌及铝的复合金属类氧化物层的厚度可以为约2nm至约10nm。
上述低辐射层的辐射率可以为约0.01至约0.3。
上述低辐射层可包含选自包含Ag、Au、Cu、Al、Pt、离子掺杂金属氧化物及它们的组合的组中的至少一种。
上述低辐射层的厚度可以为约5nm至约25nm。
上述低辐射保护金属层的可见光范围的消光系数可以为约1.5至约4。
上述低辐射保护金属层可包含选自包含Ni、Cr、Ni和Cr的合金、Ti及它们的组合的组中的至少一种。
在上述低辐射涂敷物的最外围一面或两面还可形成有包含Si类复合金属氮化物的最外围电介质层。
上述Si类复合金属氮化物可包含选自由Al、Ti、Co及它们的组合组成的组中的至少一种。
本发明可以为从下部起层叠第一最外围电介质层、Ti类氧化物层、锌及铝的复合金属类氧化物层、第一吸光金属层、低辐射层、第二吸光金属层及第二最外围电介质层而成的结构，上述第一最外围电介质层及上述第二最外围电介质层可以为包含Si类复合金属氮化物的层。
在本发明的另一实例中，提供窗户用功能性建筑材料，上述窗户用功能性建筑材料包括：透明基材；以及上述低辐射涂敷物，涂敷于上述透明基材而成。
上述低辐射涂敷物可向上述Ti类氧化物层比上述低辐射层更接近上述透明基材的方向层叠。
上述透明基材的可见光透射率可以为约90至约100％。
上述透明基材可以为玻璃或透明塑料。
有益效果
上述低辐射涂敷物的光学性能优秀，且热处理加工处理后的耐久性也优秀。
附图说明
图1为本发明一实例的低辐射涂敷物的简要剖视图。
图2为本发明另一实例的低辐射涂敷物的窗户用建筑材料的简要剖视图。
具体实施方式
以下，参照附图详细说明本发明的实施例，以使本发明所属技术领域的普通技术人员可容易实施。本发明不局限于在此说明的实施例，能够以多种不同的方式实现。
为了明确说明本发明，省略了与说明无关的部分，在说明书全文中，对于相同或类似的结构要素，标注相同的附图标记。
在附图中，为了明确表示各层及区域，放大示出了厚度。并且，在附图中，为了便于说明，夸张示出了一部分层及区域的厚度。
以下，在基材的“上部(或下部)”或基材的“上(或下)”形成任意结构不仅指任意结构与上述基材的上部面(或下部面)相接触来形成，而且不局限于在上述基材和形成于基材上(或下)的任意结构之间不包括其他结构。
以下，参照图1说明本发明一实例的低辐射涂敷物。
图1为本发明一实例的低辐射涂敷物100的剖视图。上述低辐射涂敷物100为依次包括Ti类氧化物层110、锌及铝的复合金属类氧化物层120、低辐射保护金属层130及低辐射层140的多层结构。
上述低辐射涂敷物100可用于制备所谓的低辐射(Low-e，low emissivity)玻璃。上述低辐射玻璃作为具有低辐射率的窗户用功能性建筑材料，通常在透明玻璃基材上形成涂敷层来实现。上述低辐射涂敷物100可用作上述涂敷层。
上述低辐射涂敷物100形成包括以如上方式特定的材料的各层及按照其层叠顺序特定的结构，可提高所适用的窗户用功能性建筑材料的耐久性。
上述低辐射涂敷物100为基于选择性地反射太阳光中的远红外线的低辐射层140的多层薄膜结构，适用上述低辐射涂敷物100的窗户用功能性建筑材料通过上述低辐射涂敷物100赋予辐射率变低的低辐射效果，并且，可赋予基于低辐射效果的绝热性能。
包括上述低辐射涂敷物100作为涂敷层的窗户用功能性建筑材料是一种功能性原材料，形成包括透明基材及由上述低辐射涂敷物100形成的涂敷层的结构，从而夏天反射太阳辐射热，冬天保存在室内取暖器中产生的红外线，从而带来建筑物节能效果。
“辐射率(Emissivity)”是指物体吸收、透射及反射具有任意特定波长的能量的比率。即，在本说明书中，辐射率表示红外线波长区域的红外线能量的吸收程度，具体地，是指当施加相当于表示强的热作用的、约5μm至约50μm的波长区域的远红外线时，相对于施加的红外线能量吸收的红外线能量的比率。
根据基尔霍夫定律，被物质吸收的红外线能量与再次辐射的能量相同，因而吸收率与辐射率相同。
并且，未被吸收的红外线能量在物质表面反射，因而红外线能量反射越高，辐射率越低。若用数值表示这一情况，则具有(辐射率＝1－红外线反射率)的关系。
如上所述的辐射率可通过本领域中众所周知的各种方法来测定，虽然没有特别限制，但例如，可按照KSL2514规格利用傅里叶变换红外光谱仪(FT-IR)等的设备来测定。
相对于这种表示强的热作用的远红外线的吸收率，即，辐射率在测定绝热性能的程度方面可具有非常重要的意义。
上述低辐射涂敷物100可用作如下的节能型功能性建筑材料，即，在玻璃等的透明基材形成如上所述的涂敷层，以使在可见光范围维持规定的透射特性，并降低辐射率，从而可提供优秀的绝热效果。
以下，对包括于上述低辐射涂敷物100的各层进行详细的说明。
上述低辐射层140作为可具有低辐射率的导电性材料，例如，由金属形成的层，即，具有低的面电阻，由此具有低辐射率。例如，上述低辐射层140的辐射率可以为约0.01至约0.3，具体地，上述低辐射层140的辐射率可以为约0.01至约0.2，更具体地，上述低辐射层140的辐射率可以为约0.01至约0.1，尤其具体地，上述低辐射层140的辐射率可以为约0.01至约0.08。在上述低辐射层140具有上述范围的辐射率的情况下，一同考虑低辐射涂敷物100的绝热效果及可见光透射率，从而可适当。具有如上所述的辐射率的上述低辐射层140的、由薄膜形成的材料的面电阻可以为约0.78Ω/sq至约6.42Ω/sq。
上述低辐射层140起到选择性地透射及反射太阳辐射线的功能。上述低辐射层140可包含选自包含Ag、Au、Cu、Al、Pt、离子掺杂金属氧化物及它们的组合的组中的至少一种，但不局限于这些。例如，上述离子掺杂金属氧化物包含氧化铟锡(ITO)、氟掺杂氧化锡(FTO)、Al掺杂氧化锌(AZO)、镓掺杂氧化锌(GZO)等。在一实例中，上述低辐射层140可以为银(Ag)，由此，上述低辐射涂敷物100可实现高电导率、可见光范围的低吸收率、优秀的耐久性等。
例如，上述低辐射层140的厚度可以为约10nm至约25nm。具有上述范围的厚度的低辐射层140适合一同实现低辐射率及高的可见光透射率。
上述低辐射保护金属层130由吸光性能突出的金属形成，从而起到调节太阳光的功能，可调节上述低辐射保护金属层130的材料、厚度等，来调节上述低辐射涂敷膜100实现的颜色。
上述低辐射保护金属层130可层叠于上述低辐射层140的一面或两面而成。
在一实例中，上述低辐射保护金属层130在可见光范围的消光系数(extinctioncoefficient)可以为约1.5至约3.5。上述消光系数为从作为原材料的物质固有的特性的光学常数中所导出的值，上述光学常数由表达式n-ik表示。此时，作为实数部分的n指折射率，作为虚数部分的k指消光系数(命名为吸收系数、吸光系数、消光系数等)。消光系数为波长(λ)的函数，在金属的情况下，一般，消光系数大于0。消光系数k与吸收系数α具有α＝(4πk)/λ的关系，当光通过的介质的厚度为d时，吸收系数α因I＝I0exp(-αd)的关系，由于通过介质吸收光，通过的光的强度(I)比入射的光的强度(I0)减少。
上述低辐射保护金属层130使用具有上述范围内的可见光范围的消光系数的金属，来吸收可见光的规定部分，从而使上述低辐射涂敷物100具有规定的颜色。
例如，上述低辐射保护金属层130可包含选自包含Ni、Cr、Ni和Cr的合金、Ti及它们的组合的组中的一种以上，但不局限于这些。
例如，上述低辐射保护金属层130的厚度可以为约1nm至约5nm。上述低辐射涂敷物100包括上述厚度范围内的低辐射保护金属层130，从而可起到低辐射保护层的作用，并以具有规定的透射率及反射率的方式进行调节。
上述Ti类氧化物层110及上述锌及铝的复合金属类氧化物层120用电介质层起到保护上述低辐射保护金属层130及上述低辐射层140的保护膜的作用，可调节材料、厚度等，来根据折射率的值以所需的目标水平实现透射率、反射率、透射及反射颜色等的光学性能。
具体地，上述Ti类氧化物层110可以为蒸镀由TiOx、1.8≤x≤2.2表示的氧化钛而成的层。上述Ti类氧化物层110容易向上述低辐射涂敷物100赋予各种光学性能(透射率、反射率、色指数)。即，适用上述Ti类氧化物层110，从而可实现除了上述Ti类氧化物层110之外的无法用低辐射涂敷物100实现的光学性能范围。
但是，在包括Ti类氧化物层的情况下，若在上部形成低辐射保护金属层，则由于Ti类氧化物层和低辐射保护金属层之间的界面反应，有可能产生热处理后耐磨耗性能等的耐久性降低的问题。
上述锌及铝的复合金属类氧化物层120介于上述低辐射保护金属层130和上述Ti类氧化物层110之间，从而在上述低辐射保护金属层130与上述Ti类氧化物层110直接相接触的情况下，可起到防止热处理后由界面反应导致的耐久性降低的作用。即，上述锌及铝的复合金属类氧化物层120提高上述低辐射保护金属层130和上述Ti类氧化物层110的粘结力，从而防止热处理后低辐射涂敷物的耐久性降低。
由此，上述低辐射涂敷物100通过上述Ti类氧化物层110实现各种光学性能，且可解决因上述锌及铝的复合金属类氧化物层120而降低耐久性的问题。
上述锌及铝的复合金属类氧化物层120作为包含由ZnAlOx、0.9≤x≤1.1表示的锌及铝的复合金属类氧化物的层，具体地，可蒸镀上述锌及铝的复合金属类氧化物而成。
上述锌及铝的复合金属类氧化物层120的厚度可以为约2nm至约10nm。
在上述低辐射涂敷物100的、上述低辐射涂敷物的最外围一面或两面还可形成有包含Si类复合金属氮化物的最外围电介质层150。
上述Si类复合金属氮化物可由包含选自由Al、Ti、Co及它们的组合组成的组中的至少一种的金属和Si的氮化物形成。具体地，上述Si类复合金属氮化物可以为蒸镀由SiAlNx、1.2≤x≤1.5表示的化合物而成的层。
上述低辐射涂敷物100除了上述的层之外，根据要实现的性能及目的用途，还可包括另外的电介质层。例如，上述另外的电介质层可包含各种金属氧化物、金属氮化物等，例如，可包含选自由氧化钛、锌锡氧化物、锌氧化物、锌铝氧化物、氧化锡、氧化铋、氮化硅、硅氮化铝及它们的组合组成的组中的至少一种，但不局限于这些。可在这种金属氧化物和/或金属氮化物中掺杂选自由铋(Bi)、硼(B)、铝(Al)、硅(Si)、镁(Mg)、锑(Sb)、铍(Be)及它们的组合组成的组中的至少一种元素。
上述低辐射涂敷物100为了实现符合使用目的的光谱，可调节构成上述低辐射涂敷物100的各层的材料、位置及厚度，从而控制根据光的波长带的透射率和反射率来达成。即，上述低辐射涂敷物100可调节各层的材料及厚度，来微细控制从外部可见的上述低辐射涂敷物100的高反射面的颜色、反射率、透射率等的光学性能。
图1所示的上述低辐射涂敷物100示出从下部起层叠第一最外围电介质层150、Ti类氧化物层110、锌及铝的复合金属类氧化物层120、第一吸光金属层130、低辐射层140、第二吸光金属层130及第一最外围电介质层150而成的结构。
上述第一最外围电介质层150及上述第二最外围电介质层150为包含Si类复合金属氮化物的层。
以上述低辐射涂敷物100的低辐射层140为基准，可向锌及铝的复合金属类氧化物层120方向附着于需要低辐射涂敷的基材。
例如，上述基材190作为透明基材，可通过形成上述低辐射涂敷物100的涂敷层来制备低辐射玻璃等的窗户用功能性建筑材料。
在本发明的另一实例中，提供窗户用功能性建筑材料200，上述窗户用功能性建筑材料200包括：透明基材290；以及上述低辐射涂敷物280，涂敷于上述透明基材290而成。
图2图示上述窗户用功能性建筑材料的截面。
上述透明基材290可以为可见光透射率高的透明基材，例如，可使用可见光透射率为约90至约100％的玻璃或透明塑料基板。例如，上述透明基材290可无限制地使用建筑用玻璃，根据使用目的，例如，厚度可以为约2mm至约12mm。
上述窗户用功能性建筑材料200适用上述低辐射涂敷物280，来确保基于低辐射效果的绝热性能，并且，如上所述，通过上述低辐射涂敷物280具有优秀的耐久性。
上述低辐射涂敷物280可根据公知的方法层叠各层来制备。例如，上述各层可通过蒸镀方法来层叠，上述蒸镀方法没有特别限制，可根据公知的方法来进行。
例如，上述低辐射涂敷物280的各层可通过蒸镀来实现，也可根据公知的方法来无限制地实现，例如，可利用磁控溅射蒸镀机来蒸镀。
以下，记载本发明的实施例及比较例。但是，以下实施例只是本发明的一实施例，本发明不局限于以下实施例。
(实施例)
实施例1
使用磁控(C-Mag)溅射蒸镀机(Selcos，Cetus-S)，来制备了涂敷具有以下表1所示的结构及厚度的多层结构的低辐射涂敷物而成的低辐射玻璃。
首先，在氮/氩(氮为60体积百分比，氩为40体积百分比)气氛下，在厚度为6mm的透明玻璃基材上蒸镀了厚度为38nm的SiAlNx层。接着，在氧/氩(氧为10体积百分比，氩为90体积百分比)气氛下，蒸镀了厚度为34nm的TiOx层，在氩为100体积百分比的气氛下，蒸镀了厚度为6nm的ZnAlOx层。在氩为100体积百分比的气氛下，依次蒸镀厚度分别为3.5nm、11nm及3.5nm的NiCr层、Ag层、NiCr层后，最后，在与上述SiAlNx层的蒸镀条件相同的条件下，以50nm的厚度蒸镀SiAlNx层，来制备了涂敷低辐射涂敷物而成的低辐射玻璃。
实施例2
除了在实施例1中层叠厚度为3nm的ZnAlOx层之外，以与实施例1相同的条件制备了低辐射玻璃。
比较例1
除了在实施例1等的多层结构的膜中去除ZnAlOx层之外，以与实施例1相同的条件制备了低辐射玻璃。
比较例2
除了在实施例1等的多层结构的膜中去除TiOx层及ZnAlOx层之外，以与实施例1相同的条件制备了低辐射玻璃。
表1
评价
实验例1
针对在实施例1至实施例5及比较例1至比较例3中制备的低辐射玻璃的样品，通过以下所述的方法热处理后，评价了光学物性。
使用实验室用箱式炉(box furnace)设备，并在将设备内部的温度维持约700℃的状态下，放入上述样品，并维持7分钟后，拿出样品。
热处理前和热处理后，分别利用透射雾影仪(haze-gardner plus)设备来测定了可见光透射率和雾度(Haze)。在下列表2中表示结果。
实验例2
针对在实施例1至实施例5及比较例1至比较例3中制备的低辐射玻璃的样品，利用小型清洗机来进行了热处理前后的耐磨耗性测试。放入样品，并在刷子位置停留57秒钟，而经过3秒钟。此时，充分供水。将清洗等级分为1～6等级，将清洗后未发生划痕的情况评价为1等级，并记载在下列表3中。
表2
表3
在比较例2的情况下，热处理前后的可见光透射率及雾度变化量小于实施例1、实施例2及比较例1，但由于除了金属层之外，只使用一种物质(SiAlNx)，因而在添加TiOx层的情况下，与实施例1、实施例2及比较例1相比，可实现的光学性能范围受限。
实施例1、实施例2及比较例1虽然与比较例2相比添加TiOx层来增大光学性能，但是，比较例1在热处理后，产生TiOx层和NiCr层的界面粘结力问题，从而可从上述表2及表3的结果确认耐磨耗性能降低。
相反，在实施例1及实施例2中，热处理后的耐磨耗性能也优秀，从而可确认解除了TiOx层和NiCr层的界面粘结力问题。从表3可知，在实施例1及实施例2中，热处理后，在清洗测试中，也未发生低辐射涂敷物的损伤。
在表2中，形成更厚的ZnAlOx层的实施例1与实施例2相比，热处理后几乎未发生雾度，且基于蒸镀膜之间的界面反应的可见光透射率变化更小。
附图标记的说明
100、280：低辐射涂敷物
110、210：Ti类氧化物层
120、220：锌及铝的复合金属类氧化物层
130、230：低辐射保护金属层
140、240：低辐射层
150、250：最外围电介质层
190、290：玻璃基材
200：窗户用建筑材料
Claims (11)
1.一种低辐射涂敷物，具有多层结构，所述低辐射涂敷物的特征在于，依次包括Ti类氧化物层、锌及铝的复合金属类氧化物层、低辐射保护金属层及低辐射层；
所述锌及铝的复合金属类氧化物层包含由ZnAlOx、0.9≤x≤1.1表示的锌及铝的复合金属类氧化物；
所述低辐射保护金属层包含选自包含Ni、Cr、Ni和Cr的合金、Ti及它们的组合的组中的至少一种；
在所述低辐射涂敷物的最外围一面或两面还形成有包含Si类复合金属氮化物的最外围电介质层；
所述Si类复合金属氮化物包含Ti。
2.根据权利要求1所述的低辐射涂敷物，其特征在于，所述锌及铝的复合金属类氧化物层的厚度为2nm至10nm。
3.根据权利要求1所述的低辐射涂敷物，其特征在于，所述低辐射层的辐射率为0.01至0.3。
4.根据权利要求1所述的低辐射涂敷物，其特征在于，所述低辐射层包含选自包含Ag、Au、Cu、Al、Pt、离子掺杂金属氧化物及它们的组合的组中的至少一种。
5.根据权利要求1所述的低辐射涂敷物，其特征在于，所述低辐射层的厚度为5nm至25nm。
6.根据权利要求1所述的低辐射涂敷物，其特征在于，所述低辐射保护金属层的可见光范围的消光系数为1.5至4。
7.根据权利要求1所述的低辐射涂敷物，其特征在于，
所述低辐射涂敷物为从下部起层叠第一最外围电介质层、Ti类氧化物层、锌及铝的复合金属类氧化物层、第一吸光金属层、低辐射层、第二吸光金属层及第二最外围电介质层而成的结构，
所述第一最外围电介质层及所述第二最外围电介质层为包含Si类复合金属氮化物的层。
8.一种窗户用功能性建筑材料，其特征在于，包括：
透明基材；以及
权利要求1至7中任一项所述的低辐射涂敷物，涂敷于所述透明基材。
9.根据权利要求8所述的窗户用功能性建筑材料，其特征在于，所述低辐射涂敷物向所述Ti类氧化物层比所述低辐射层更接近所述透明基材的方向层叠。
10.根据权利要求8所述的窗户用功能性建筑材料，其特征在于，所述透明基材的可见光透射率为90至100％。
11.根据权利要求8所述的窗户用功能性建筑材料，其特征在于，所述透明基材为玻璃或透明塑料基板。
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| KR20160015513A (ko) * | 2014-07-30 | 2016-02-15 | (주)엘지하우시스 | 저방사 코팅, 및 저방사 코팅을 포함하는 창호용 기능성 건축 자재 |
| JP6423198B2 (ja) * | 2014-08-05 | 2018-11-14 | 日東電工株式会社 | 赤外線反射フィルム |
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| JP6972317B2 (ja) * | 2017-09-08 | 2021-11-24 | エルエックス・ハウシス・リミテッドLx Hausys, Ltd. | 窓戸用機能性建材 |
| CN108252623B (zh) * | 2017-12-26 | 2019-11-01 | 东莞奔迅汽车玻璃有限公司 | 中空发光玻璃 |
| KR102433169B1 (ko) * | 2018-09-12 | 2022-08-16 | (주)엘엑스하우시스 | 창호용 기능성 건축 자재 및 복층 유리 |
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