CN105507550B - The material of built-in heating layer electric heating solid wooden compound floor - Google Patents
The material of built-in heating layer electric heating solid wooden compound floor Download PDFInfo
- Publication number
- CN105507550B CN105507550B CN201610036120.6A CN201610036120A CN105507550B CN 105507550 B CN105507550 B CN 105507550B CN 201610036120 A CN201610036120 A CN 201610036120A CN 105507550 B CN105507550 B CN 105507550B
- Authority
- CN
- China
- Prior art keywords
- parts
- stirring
- reaction
- adds
- polyamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/04—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members
- E04F15/041—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members with a top layer of wood in combination with a lower layer of other material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/40—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/32—Modified amine-aldehyde condensates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D13/00—Electric heating systems
- F24D13/02—Electric heating systems solely using resistance heating, e.g. underfloor heating
- F24D13/022—Electric heating systems solely using resistance heating, e.g. underfloor heating resistances incorporated in construction elements
- F24D13/024—Electric heating systems solely using resistance heating, e.g. underfloor heating resistances incorporated in construction elements in walls, floors, ceilings
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Civil Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Structural Engineering (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Floor Finish (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of material of built-in heating layer electric heating solid wooden compound floor, the new material includes the cyanurotriamide modified urea resin glue for being bonded with carbon fiber paper, and the preparation method of the cyanurotriamide modified urea resin glue comprises the following steps；(1) preparation of polyamide；30 40 parts of diethylenetriamine is added into suitable quantity of water stirring, 40 50 parts of adipic acid is added while stirring, it is interior when 15 is small after stirring 30min to be uniformly heating to 150 170 DEG C and keep the temperature 15min, 80 120 DEG C are cooled to again, add appropriate water cooling, 80 120 DEG C are again heated to, polyamide is obtained after stirring evenly；(2) 40 60 parts of formalins are adjusted to pH as 9.5, add 15 30 parts of urea, it is heated to 85 95 DEG C of 40 60min of reaction, pH is adjusted to again as 5, fully 10 20 parts of polyamide and 20 30 parts of melamines are added after reaction, 5 10 parts of epoxychloropropane are added dropwise to again, are reacted while stirring, wait reaction to terminate to obtain cyanurotriamide modified urea resin glue.
Description
Technical field
The present invention relates to a kind of material of solid wooden compound floor, especially a kind of built-in heating layer electric heating solid wooden compound floor
Material, belong to electric heating floor technical field.
Background technology
It is well known that floor is gradually used as family wear due to having the function of damp proof insulation, resistance to cool, comfortable etc. very useful
The necessity repaiied, into most of family.With the continuous improvement of people's living standards, the use function on floor
It is continuously improved.In order to solve winter warming problem, the electric heating floor that family's use increasingly can generate heat carries out heating.So
And since floor particularly solid wooden compound floor is to be formed by multi-disc plank by adhesive fitting, under long-term fever state,
The reduction of adhesive bond power is be easy to cause, the problem of plank degumming tilting occurs.On the other hand, due to existing adhesive and anti-
The performance of aqua is bad so that and the waterproof effect of existing electric heating floor is not satisfactory, and for electric heating floor
Water resistance is very important index, once electric heating floor water inlet extremely be easy to cause security incident.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of material of built-in heating layer electric heating solid wooden compound floor.
The present invention not only has superior mechanical strength, but also the present invention has superior water resistance.
In order to solve the above technical problems, technical scheme：A kind of built-in heating layer electric heating solid wooden compound floor
Material, the built-in heating layer electric heating solid wooden compound floor include composite base material layer, carbon are bonded with above composite base material layer
Fibrous paper, the both sides of carbon fiber paper are equipped with copper plate electrode, and the top of carbon fiber paper is equipped with decoration dash board；The composite base material layer
Lower section be equipped with backboard, it is characterised in that：The new material includes being bonded with the melamine modified urea-formaldehyde tree of carbon fiber paper
Fat glue, the preparation method of the cyanurotriamide modified urea resin glue comprise the following steps；
(1) preparation of polyamide；30-40 parts of diethylenetriamine is added into suitable quantity of water stirring, adds 40-50 while stirring
Part adipic acid, stir it is interior when 1-5 is small after 30min be uniformly heating to 150-170 DEG C and keep the temperature 15min, then be cooled to 80-
120 DEG C, appropriate water cooling is added, is again heated to 80-120 DEG C, polyamide is obtained after stirring evenly；
(2) it is 9.5 20-60 parts of formalins to be adjusted to pH, adds 15-30 parts of urea, is heated to 85-95 DEG C of reaction
40-60min, then it is 5 to be adjusted to pH, fully adds 10-20 parts of polyamide and 20-30 parts of melamines after reaction, then be added dropwise to 5-
10 parts of epoxychloropropane, react while stirring, wait reaction to terminate to obtain cyanurotriamide modified urea resin glue.
In the material of above-mentioned built-in heating layer electric heating solid wooden compound floor, in step (2), the molar ratio of formaldehyde and urea
For 0.98.
In the material of foregoing built-in heating layer electric heating solid wooden compound floor, the cyanurotriamide modified urea resin glue
Preparation method comprise the following steps；
(1) preparation of polyamide；35 parts of diethylenetriamine is added into suitable quantity of water stirring, adds 45 parts oneself while stirring
Diacid, stir it is interior when 2-4 is small after 30min be uniformly heating to 160 DEG C and keep the temperature 15min, then be cooled to 110 DEG C, add appropriate
Water cooling, is again heated to 110 DEG C, and polyamide is obtained after stirring evenly；
(2) it is 9.5 40 parts of formalins of part to be adjusted to pH, adds 20 parts of urea, is heated to 90 DEG C of reaction 40-60min,
It is 5 that solution is adjusted to pH again, fully adds 15 parts of polyamide and 25 parts of melamines after reaction, then be added dropwise to 6 parts of epoxy chloropropionates
Alkane, reacts while stirring, obtains cyanurotriamide modified urea resin glue.
In the material of foregoing built-in heating layer electric heating solid wooden compound floor, the new material further includes waterproofing agent, institute
The new material stated further includes the waterproofing agent coated in decoration four side of dash board surface and composite base plate, the preparation method of the waterproofing agent
Comprise the following steps；
(1) 70-100 parts of octamethylcy-clotetrasiloxane, N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxy silane 2-10 are taken
1-2 parts of part and tetramethyl-ring tetrasiloxane are mixed evenly, and are warming up to 80-90 DEG C and add tetramethylammonium hydroxide 0.1-
0.5 part, be warming up to 100-125 DEG C of reaction 1-3 it is small when, then remove low-boiling-point substance and obtain first product；
(2) 2-5 in mass ratio：1 ratio adds first product and melamine, even heats side and stirs to 70-80 DEG C, reacts
1.5h, obtains finished product.
In the material of foregoing built-in heating layer electric heating solid wooden compound floor, the preparation method of the waterproofing agent include with
Lower step；
(1) 85 parts of octamethylcy-clotetrasiloxane, N- β-aminoethyl-γ -5.5 parts of aminopropyltriethoxy dimethoxy silane and four are taken
1.6 parts of methyl cyclotetrasiloxane is mixed evenly, and is warming up to 80-90 DEG C and adds 0.3 part of tetramethylammonium hydroxide, is warming up to
When 100-125 DEG C of reaction 2.5 is small, then removes low-boiling-point substance and obtain first product；
(2) in mass ratio 4：1 ratio adds first product and melamine, even heats side and stirs to 70-80 DEG C, reacts
1.5h, obtains finished product.
Compared with prior art, the invention has the advantages that：
(1) present invention improves the preparation process of cyanurotriamide modified urea resin glue, improved melamine
Modified urea-formaldehyde resin glue is greatly improved in viscosity, solid content, working life and storage period, and result of the test is as follows：
From upper table improved cyanurotriamide modified urea resin glue can be learnt in viscosity, solid content, working life and storage
Depositing the phase greatly improves, by cyanurotriamide modified urea resin it is gluing together in the present invention when, greatly increase the bonding of product
Performance, avoids because heating the problem of bond properties brought declines for a long time.Through experiment, after lasting heating January, this hair
Bright composite base material and the intensity of carbon fiber paper gluing have reached 3.5MPa, dipping and stripping 0mm, same with the intensity of decorative panel
3.1MPa, dipping and stripping 0mm are reached, performance is significantly larger than other electric heating floors.
(2) further, the present invention also floor surface apply waterproofing agent, for waterproofing agent preparation process made into
One step is innovated, and the particle diameter of improved waterproofing agent is as shown in Figure 1, the particle diameter of waterproofing agent is substantially in 10-15nm as can be seen from Figure 1
Between, illustrate that particle diameter is highly uniform, while the Potential distribution of improved waterproofing agent is as shown in Figure 2, can be seen that from attached drawing 2
The Potential distribution of the waterproofing agent of the present invention is very narrow, illustrates between each particle there are stronger repulsive force, the group between preventing agent grain
Coagulation drops, and improves the stability of product, will not lose waterproof because of the reduction of stability under long-term fever state
Effect.
Brief description of the drawings
Fig. 1 is the grain-size graph of waterproofing agent；
Fig. 2 is the potential image of waterproofing agent；
Fig. 3 is the sectional view of built-in heating layer electric heating solid wooden compound floor；
Fig. 4 is the structure chart of carbon fiber paper；
Fig. 5 is the structure diagram of composite base plate.
The present invention is further illustrated with reference to the accompanying drawings and detailed description.
Embodiment
Embodiment 1：A kind of built-in heating layer electric heating solid wooden compound floor, as shown in figures 3-5, including composite base material layer 1,
The top of composite base material layer 1 is bonded with carbon fiber paper 2, and the both sides of carbon fiber paper 2 are equipped with copper plate electrode 3, the top of carbon fiber paper 2
Equipped with fancy veneer 4；The lower section of the composite base material layer 1 is equipped with backboard 5.The composite base material 1 is formed including 8 layers of fitting
Eucalyptus veneer 6, and the grain of wood direction of described 8 layers of Eucalyptus veneer vertically overlays, namely the adjacent wood by veneer
Material grain direction is perpendicular.The Eucalyptus veneer is 1.5mm, and the beech veneer is 0.8mm.The Eucalyptus veneer is
1.5mm, the beech veneer are 0.8mm.
The preparation process of above-mentioned built-in heating layer electric heating solid wooden compound floor, comprises the following steps successively；
A, cyanurotriamide modified urea resin glue is coated on composite base material, is pasted after standing 5min on composite base material surface
Carbon fiber paper and the copper electrode for installing copper sheet and fastener composition；
B, above carbon fiber paper coat cyanurotriamide modified urea resin glue, stand 10min after in carbon fiber paper overlying
Incrustation veneer；
C, 10min is cold-pressed with the pressure of 0.6MPa, again with hot pressing 8min under the pressure of 1.2MPa after cold pressing；
D, 5-7 days are stood, after sizing and fluting, blanket is made, in blanket termination and side coating waterproofing agent, surface warp
Paint finishing, obtains finished product.
The preparation method of above-mentioned cyanurotriamide modified urea resin glue comprises the following steps；
(1) preparation of polyamide；35 parts of diethylenetriamine is added into suitable quantity of water stirring, adds 45 parts oneself while stirring
Diacid, stir it is interior when 2-4 is small after 30min be uniformly heating to 160 DEG C and keep the temperature 15min, then be cooled to 110 DEG C, add appropriate
Water cooling, is again heated to 110 DEG C, and polyamide is obtained after stirring evenly；
(2) it is 9.5 40 parts of formalins of part to be adjusted to pH, adds 20 parts of urea, is heated to 90 DEG C of reaction 40-60min,
It is 5 that solution is adjusted to pH again, fully adds 15 parts of polyamide and 25 parts of melamines after reaction, then be added dropwise to 6 parts of epoxy chloropropionates
Alkane, reacts while stirring, obtains cyanurotriamide modified urea resin glue.
The preparation method of above-mentioned waterproofing agent comprises the following steps；
(1) 85 parts of octamethylcy-clotetrasiloxane, N- β-aminoethyl-γ -5.5 parts of aminopropyltriethoxy dimethoxy silane and four are taken
1.6 parts of methyl cyclotetrasiloxane is mixed evenly, and is warming up to 80-90 DEG C and adds 0.3 part of tetramethylammonium hydroxide, is warming up to
When 100-125 DEG C of reaction 2.5 is small, then removes low-boiling-point substance and obtain first product；
(2) in mass ratio 4：1 ratio adds first product and melamine, even heats side and stirs to 70-80 DEG C, reacts
1.5h, obtains finished product.
Embodiment 2：The preparation method of cyanurotriamide modified urea resin glue comprises the following steps；
(1) preparation of polyamide；30 parts of diethylenetriamine is added into suitable quantity of water stirring, adds 50 parts oneself while stirring
Diacid, stir it is interior when 3 is small after 30min be uniformly heating to 160 DEG C and keep the temperature 15min, then be cooled to 110 DEG C, add suitable quantity of water
Cooling, is again heated to 100 DEG C, polyamide is obtained after stirring evenly；
(2) it is 9.5 45 parts of formalins to be adjusted to pH, adds 15 parts of urea, is heated to 95 DEG C of reaction 60min, then will
It is 5 that solution, which is adjusted to pH, fully adds 10 parts of polyamide and 30 parts of melamines after reaction, then be added dropwise to 5 parts of epoxychloropropane, side
Side reaction is stirred, waits reaction to terminate to obtain cyanurotriamide modified urea resin glue.
Embodiment 3：The preparation method of waterproofing agent comprises the following steps；
(1) 80 parts of octamethylcy-clotetrasiloxane, N- β-aminoethyl-γ -3 parts of aminopropyltriethoxy dimethoxy silane and tetramethyl are taken
2 parts of basic ring tetrasiloxane is mixed evenly, and is warming up to 80 DEG C and adds 0.2 part of tetramethylammonium hydroxide, is warming up to 125 DEG C instead
Answer 3 it is small when, then remove low-boiling-point substance and obtain first product；
(2) in mass ratio 2:1 ratio adds first product and melamine, even heats side and stirs to 70-80 DEG C, reacts
1.5h, obtains finished product.
Embodiments of the present invention are not limited to above-described embodiment, and that is made on the premise of present inventive concept is not departed from is various
Change is belonged within protection scope of the present invention.
Claims (4)
1. the material of built-in heating layer electric heating solid wooden compound floor, the built-in heating layer electric heating solid wooden compound floor includes multiple
Substrate layer is closed, is bonded with carbon fiber paper above composite base material layer, the both sides of carbon fiber paper are equipped with copper plate electrode, carbon fiber paper
Top is equipped with decoration dash board；The lower section of the composite base material layer is equipped with backboard, it is characterised in that：The material includes bonding
Have the cyanurotriamide modified urea resin glue of carbon fiber paper, the preparation method of the cyanurotriamide modified urea resin glue include with
Lower step；
(1) preparation of polyamide；30-40 parts of diethylenetriamine is added into suitable quantity of water stirring, adds 40-50 parts while stirring
Adipic acid, stir it is interior when 1-5 is small after 30min be uniformly heating to 150-170 DEG C and keep the temperature 15min, then be cooled to 80-120 DEG C,
Appropriate water cooling is added, is again heated to 80-120 DEG C, polyamide is obtained after stirring evenly；
(2) it is 9.5 20-60 parts of formalins to be adjusted to pH, adds 15-30 parts of urea, is heated to 85-95 DEG C of reaction 40-
60min, then it is 5 to be adjusted to pH, fully adds 10-20 parts of polyamide and 20-30 parts of melamines after reaction, then be added dropwise to 5-10 parts
Epoxychloropropane, reacts while stirring, waits reaction to terminate to obtain cyanurotriamide modified urea resin glue；
The material further includes the waterproofing agent coated in decoration four side of dash board surface and composite base plate, the preparation of the waterproofing agent
Method comprises the following steps；
(1) take 70-100 parts of octamethylcy-clotetrasiloxane, N- β-aminoethyl-γ -2-10 parts of aminopropyltriethoxy dimethoxy silane and
1-2 parts of tetramethyl-ring tetrasiloxane is mixed evenly, and is warming up to 80-90 DEG C and adds 0.1-0.5 parts of tetramethylammonium hydroxide,
Be warming up to 100-125 DEG C of reaction 1-3 it is small when, then remove low-boiling-point substance and obtain first product；
(2) 2-5 in mass ratio：1 ratio adds first product and melamine, even heats side and stirs to 70-80 DEG C, reacts 1.5h,
Obtain finished product.
2. the material of built-in heating layer electric heating solid wooden compound floor according to claim 1, it is characterised in that：Step (2)
In, the molar ratio of formaldehyde and urea is 0.98.
3. the material of built-in heating layer electric heating solid wooden compound floor according to claim 1, it is characterised in that：Described three
The preparation method of poly cyanamid modified urea-formaldehyde resin glue comprises the following steps；
(1) preparation of polyamide；35 parts of diethylenetriamine is added into suitable quantity of water stirring, add while stirring 45 parts oneself two
Acid, stir it is interior when 2-4 is small after 30min be uniformly heating to 160 DEG C and keep the temperature 15min, then be cooled to 110 DEG C, add suitable quantity of water
Cooling, is again heated to 110 DEG C, polyamide is obtained after stirring evenly；
(2) it is 9.5 40 parts of formalins of part to be adjusted to pH, adds 20 parts of urea, is heated to 90 DEG C of reaction 40-60min, then will
It is 5 that solution, which is adjusted to pH, fully adds 15 parts of polyamide and 25 parts of melamines after reaction, then be added dropwise to 6 parts of epoxychloropropane, side
Side reaction is stirred, obtains cyanurotriamide modified urea resin glue.
4. the material of built-in heating layer electric heating solid wooden compound floor according to claim 1, it is characterised in that：Described is anti-
The preparation method of aqua comprises the following steps；
(1) 85 parts of octamethylcy-clotetrasiloxane, N- β-aminoethyl-γ -5.5 parts of aminopropyltriethoxy dimethoxy silane and tetramethyl are taken
1.6 parts of cyclotetrasiloxane is mixed evenly, and is warming up to 80-90 DEG C and adds 0.3 part of tetramethylammonium hydroxide, is warming up to 100-
When 125 DEG C of reactions 2.5 are small, then remove low-boiling-point substance and obtain first product；
(2) in mass ratio 4：1 ratio adds first product and melamine, even heats side and stirs to 70-80 DEG C, reacts 1.5h, obtain
To finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610036120.6A CN105507550B (en) | 2016-01-20 | 2016-01-20 | The material of built-in heating layer electric heating solid wooden compound floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610036120.6A CN105507550B (en) | 2016-01-20 | 2016-01-20 | The material of built-in heating layer electric heating solid wooden compound floor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105507550A CN105507550A (en) | 2016-04-20 |
| CN105507550B true CN105507550B (en) | 2018-04-20 |
Family
ID=55715822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610036120.6A Active CN105507550B (en) | 2016-01-20 | 2016-01-20 | The material of built-in heating layer electric heating solid wooden compound floor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105507550B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318297A (en) * | 2016-08-22 | 2017-01-11 | 安徽大松树脂有限公司 | High toughness waterproof acid-alkali resistant adhesive for shoes |
| CN106476089B (en) * | 2016-12-09 | 2019-01-29 | 久盛地板有限公司 | The manufacturing process and its timber floor of built-in carbon fiber electrothermal layer wood bamboo composite floor |
| CN108914663A (en) * | 2018-07-10 | 2018-11-30 | 临沂市鲁源浸渍纸业有限公司 | A method of yield of guaranteeing the quality reduces paper-making industry melamine-impregnated liquid aldehyde |
| CN111892890A (en) * | 2020-08-13 | 2020-11-06 | 马鞍山富华装饰材料有限公司 | Environment-friendly composite glue for PVC paper and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01315554A (en) * | 1988-06-14 | 1989-12-20 | Mitsui Constr Co Ltd | Floor structure |
| JPH0732518A (en) * | 1993-07-16 | 1995-02-03 | Dairin Shoji:Kk | Composite building material |
| CN102312545A (en) * | 2011-07-05 | 2012-01-11 | 上海热丽电热材料有限公司 | Low-temperature heating solid wood composite floor and preparation method thereof |
| CN102383571A (en) * | 2011-08-15 | 2012-03-21 | 上海热丽电热材料有限公司 | Low-temperature plane waterproof heating floor module and manufacturing method thereof |
| CN102391619A (en) * | 2011-08-24 | 2012-03-28 | 广西大学 | Preparation method of permeation resistant addition agent with functions of reinforcing stiffness and wet-strength |
| CN102679438A (en) * | 2011-03-14 | 2012-09-19 | 滁州索菲斯电器制造有限公司 | Carbon-fiber electric-heating core-warming floor and preparation technology thereof |
| CN103628362A (en) * | 2013-12-02 | 2014-03-12 | 大亚人造板集团有限公司 | Process for manufacturing damp-proof low-water-swelling floor base material and method for manufacturing adhesive |
| CN204804260U (en) * | 2014-05-15 | 2015-11-25 | 张正国 | Multilayer wood heating floor |
-
2016
- 2016-01-20 CN CN201610036120.6A patent/CN105507550B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01315554A (en) * | 1988-06-14 | 1989-12-20 | Mitsui Constr Co Ltd | Floor structure |
| JPH0732518A (en) * | 1993-07-16 | 1995-02-03 | Dairin Shoji:Kk | Composite building material |
| CN102679438A (en) * | 2011-03-14 | 2012-09-19 | 滁州索菲斯电器制造有限公司 | Carbon-fiber electric-heating core-warming floor and preparation technology thereof |
| CN102312545A (en) * | 2011-07-05 | 2012-01-11 | 上海热丽电热材料有限公司 | Low-temperature heating solid wood composite floor and preparation method thereof |
| CN102383571A (en) * | 2011-08-15 | 2012-03-21 | 上海热丽电热材料有限公司 | Low-temperature plane waterproof heating floor module and manufacturing method thereof |
| CN102391619A (en) * | 2011-08-24 | 2012-03-28 | 广西大学 | Preparation method of permeation resistant addition agent with functions of reinforcing stiffness and wet-strength |
| CN103628362A (en) * | 2013-12-02 | 2014-03-12 | 大亚人造板集团有限公司 | Process for manufacturing damp-proof low-water-swelling floor base material and method for manufacturing adhesive |
| CN204804260U (en) * | 2014-05-15 | 2015-11-25 | 张正国 | Multilayer wood heating floor |
Non-Patent Citations (1)
| Title |
|---|
| 三聚氰胺-尿素-甲醛共聚树脂的胶接性能;郑云武;《东北林业大学学报》;20100228;第83、84页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105507550A (en) | 2016-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105507550B (en) | The material of built-in heating layer electric heating solid wooden compound floor | |
| CN103147346B (en) | High-brightness wear-resistant decorative sticky membrane paper and preparation method thereof | |
| US3723223A (en) | Heat curing adhesive | |
| CN105729597B (en) | A kind of color and luster sootiness treatment process of timber modification face layer | |
| CN108656250A (en) | A kind of flame-retardant impregnating glued membrane paper face artificial board and its manufacturing method | |
| CN105672611B (en) | Preparation technology of built-in heating layer electric heating solid wooden compound floor and products thereof | |
| JP2021094842A (en) | Ligneous material composite plate and manufacturing method thereof | |
| CN108705621A (en) | A kind of the paint-free ecological plate and its manufacture craft of cracking resistance | |
| CN108587057A (en) | A kind of daylighting weather-resistant composite, plane skylight and preparation method thereof | |
| CN110405896A (en) | Without aldehyde is fire-retardant can facing particieboard and its preparation process and application | |
| CN109263187A (en) | A kind of preparation method of wooden composite door | |
| CN109666450A (en) | A kind of no aldehyde flame retardant type soybean adhesive and its preparation method and application | |
| CN205296722U (en) | Built -in real wood composite floor of layer electric heat that generates heat | |
| CN105295740A (en) | Aldehyde-free liquid glue and artificial board processing method | |
| CN110172329A (en) | Rubber made from soybean cake with great friction coefficient and preparation method thereof and the application in making sheet | |
| CN105949416A (en) | Quaternary copolymerized melamine-impregnated resin adhesive and preparation method thereof | |
| CN115781831A (en) | Isocyanate-containing formaldehyde-free shaving board and preparation method thereof | |
| CN114143920B (en) | Low-voltage electric heating veneer and preparation method thereof | |
| CN112457053B (en) | Modified calcium silicate board and surface treatment method and application thereof | |
| CN109722941A (en) | A kind of production technology of the short melamine impregnated paper of pressing cycle | |
| JP2000135758A (en) | Decorative material and its production | |
| CN115008558A (en) | Plate bending process with bending structure and manufactured composite plate | |
| CN101607403A (en) | The preparation method of solid-wood composite strengthened plates | |
| CN110527449A (en) | A kind of even heat-insulation composite material and preparation method thereof | |
| CN107099011B (en) | Graphene amine aldehyde resin for impregnation and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Material of electric heating solid wood composite floor with built-in heating layer Effective date of registration: 20211216 Granted publication date: 20180420 Pledgee: Zhejiang Nanxun Rural Commercial Bank Co.,Ltd. Hengjie sub branch Pledgor: JIUSHENG WOOD Co.,Ltd. Registration number: Y2021330002541 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |