CN1055072C - Colour sandwiched glass and production method thereof - Google Patents
Colour sandwiched glass and production method thereof Download PDFInfo
- Publication number
- CN1055072C CN1055072C CN96114644A CN96114644A CN1055072C CN 1055072 C CN1055072 C CN 1055072C CN 96114644 A CN96114644 A CN 96114644A CN 96114644 A CN96114644 A CN 96114644A CN 1055072 C CN1055072 C CN 1055072C
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- China
- Prior art keywords
- glass
- production method
- organic dye
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- rising
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- Expired - Fee Related
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- 239000011521 glass Substances 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 239000003086 colorant Substances 0.000 claims abstract description 11
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 9
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 10
- 239000005357 flat glass Substances 0.000 claims description 6
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical class COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 230000000630 rising effect Effects 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 3
- 238000005502 peroxidation Methods 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 239000005315 stained glass Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 15
- -1 methylpropene methyl ester Chemical class 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 abstract description 2
- 239000005340 laminated glass Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 238000005034 decoration Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 2
- 229960001826 dimethylphthalate Drugs 0.000 description 2
- 238000007688 edging Methods 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- 241000227425 Pieris rapae crucivora Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 239000012945 sealing adhesive Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Joining Of Glass To Other Materials (AREA)
Abstract
The present invention relates to chromatic sandwich glass and a production method thereof. The chromatic sandwich glass is characterized in that the elastic transparent middle layer of the sandwich glass is chromatic and is prepared from 48 to 60% of methylpropene methyl ester, 0.05 to 0.1% of primary-color organic dye, etc. The production method is characterized in that all the primary-color organic dyes are proportionally mixed and dissolved in a butanol solution with the concentration of 2 to 5% before slurry is made. The chromatic sandwich glass of the present invention can ensure bright colors and high durability; the production method has the advantages of low cost, and simple and easy realization.
Description
The present invention relates to a kind of transparent laminate.
As everyone knows, laminated glass is a kind of transparent glass-middle layer-glass laminates that two sheet glass good bond is formed with transparent elastic film.This published in " Shanghai science tech publishing house " in June, 1985, had done many descriptions in " aeronautical material " chapter 12 of being write by Beijing Inst. of Aeronautical Materials.Its physical strength height, transparent, heat-resisting, wear-resisting.During destruction,, can prevent the danger that fragment wounds, thereby be called as " shatter proof glass " because glass is clung by the middle layer and do not fragmentate.Laminated glass is as a kind of safe finishing material, being accepted by increasing people at present, mainly is that it is applied on the glass curtain wall, skylight, ceiling, partition, safe antitheft door and window, commodity display kitchen window of commercial building, hotel, restaurant's contour level building.But, when people need colour sandwich glass, then often still adopt colored glass to do former, realize it with the transparent elastic film is bonding.Like this, certainly will be the glass what color is arranged, could make the laminated glass of what color.And because stained glass is exposed outdoor, wind and weather life-time service, the defective that has color to come off unavoidably.At present, the stained glass cost of domestic glass manufacturer production is high and have only indigo plant, tea, green etc. several, far can not satisfy the needs in market.Chinese patent 87103395 discloses a kind of photopolymerisable laminated safety glass, and disclose its interlayer and can manifest certain color, but its details and unexposed.In sum, these reasons have limited the production and the use of colour sandwich glass greatly.
The object of the present invention is to provide the method for a kind of colour sandwich glass and production thereof.Simple, with low cost when producing this colour sandwich glass, when using this colour sandwich glass, it can guarantee bright-colored brilliant, durable prolonged and do not come off.
Technical solution of the present invention is as follows: adopt two can be that the white transparent glass of all size, various thin and thicks is done former, the transparent film of configuration elasticity fills does the middle layer, and two sheet glass good bond are formed.Be characterized in that it is that elastic film is chromatic that this middle layer is colour, and comprise account for raw material weight 48-60% methyl methacrylate as body material, the primary colours organic dye that accounts for 0.05-0.1% is as center material.Because dyestuff is organic substance, when mixing, exist certain resistance gather power with organosilane ester, therefore must organic dye be dissolved first butanols, and then be filled in other solvent and go with 2-5%.The present invention selects for use the first machine vinylformic acid of 1-5% to do toughener, so that the middle layer has certain rigidity.Selecting Diisopropyl azodicarboxylate and the peroxidation formyl of 0.5-4% for use is initiator, to weaken intermolecular forces, make its preferably with the dyestuff phased soln.The vinyltriethoxysilane of selecting 1-3% for use is a coupling agent, to promote film bonding.Other then for increasing the prestige agent, can select dimethyl phthalate and dibutyl phthalate for use.
Technical process of the present invention is as follows:
Wait for grouting behind glass chip select → cutting → edging → washing → drying → the close sheet.
Organic materials batching → slurrying → close sheet grouting → thermopolymerization → cleaning → check → packing to dispatch from the factory.
The invention has the advantages that: the colored restriction that is not subjected to original sheet glass, can configure various depth distinct colors according to user's needs, and colored film puts between the sub-white glass, use durable can not fading and come off.Because pyritous influence when dyestuff is not subject to processing glass during the configuration color, the fluorescent performance of organic dye has no to destroy, so its color and luster remains bright-coloured, lucid and lively.In addition, a large amount of what use is general common white glass by sub-film glass up and down, thereby greatly reduces the production cost of colour sandwich glass of the present invention, approximately reaches about 30 percent.Decorate in that the large glass curtain is strong, if adopt the colored sheet glass of selling in the market to make laminated glass, dull coloring not only then, and also volume is big, Heavy Weight, price are also high.Compare with a large amount of 5 mm thick colored sheet glasses that use on the market, if the present invention selects for use the common of 3 mm thick to do former from glass, the laminated glass weight of producing so will alleviate 25-40%, and this is very favourable to the design of large glass curtain wall undoubtedly, can quicken applying of glass curtain wall.The national already glass quality supervision and inspection of the colour sandwich glass center that the present invention produces is detected, and conclusion is for " its anti-width of cloth all reaches the requirement of GB 9962-88 standard techniques according to property, thermotolerance, shock resistance, and it is qualified to judge.”
The embodiment of the invention 1, this embodiment is applicable to the decoration of indoor partition, roof, door and window.Be limited to indoor environment, require to have certain intensity and reach fluorescent transparency preferably, so following prescription is selected in the middle layer for use:
Methyl methacrylate 48-60%
Primary colours organic dye 0.05-0.1%
Butanols 2-5%
Methacrylic acid 1-5%
Diisopropyl azodicarboxylate 0.5-4%
Vinyltriethoxysilane 1-3%
Dibutyl phthalate all the other
At first glass cutting being become desired size, obturages, is in the milk with waiting for after the clamp with the edge sealing adhesive tape in edging, clean, dry back.Secondly, Organic Chemicals is prepared in proportion be dissolved in the container.In the present embodiment, used primary colours organic dye is red and blue, and they are dissolved in butanols by 37 to 63, refilter in the above-mentioned container, heat 80-85 ℃, 10-15 minute vacuumized 30-40 minute after reducing to room temperature then, in slurries till the no bubble.Then by the area of required glass, in calculate required grouting amount with layer thickness, the polymerization of being in the milk, obturaging, heating.Concrete operations are since 40 ℃, keep 6 hours when rising 5 ℃ to 60 ℃ per half an hour, rise 5 ℃ to 85 ℃ per again half an hour and keep 4 hours, rise 5 ℃ to 100 ℃ per again half an hour and keep 2 hours.Stop heating back and be cooled to 40 ℃ under the polymerization furnace situation not opening, open fire door then and take out glass.This glass is purple laminated glass required in the present embodiment.Its cleaning is cleaned, test, can pack after qualified and dispatch from the factory by GB.
The embodiment of the invention 2, this embodiment is applicable to outer decoration, the decoration of buildings.Outer decoration need have oxygen and the action of ultraviolet ray in Chinese People's Anti-Japanese Military and Political College's gas, need certain low temperature flexibility and shock resistance, thereby following prescription is selected in its middle layer for use:
Methyl methacrylate 50-60%
Primary colours organic dye 0.05-0.1%
Butanols 2-5%
Methacrylic acid 1-5%
Peroxidation formyl 0.5-4%
Dimethyl phthalate 20-16%
Dibutyl phthalate all the other
The production technique of this prescription is identical with embodiment 1.But the primary colours organic dye in the present embodiment is selected yellow and blueness for use, and they are dissolved in butanols by 70 to 30, refilters in the container.It is final like this that what obtain is the required green laminated glass of this example.Certainly, the organic dye total amount is less than normal, and the color that obtains is then shallow partially; The organic dye total amount is bigger than normal, and the color that obtains is then dark partially.In a word, when we with the organic dye of red, yellow, blue three kinds of primary colours by different total amounts, when different ratios is prepared, just can obtain the colour sandwich glass of the different variety of colors of the depth.
Claims (2)
1, a kind of colour sandwich glass, the elasticity transparent intermediate layer between two sheet glass constitutes by two white glass and good bond, it is characterized in that this middle layer be colored and by
The 48-60% methyl methacrylate
0.05-0.1% primary colours organic dye
The 2-5% butanols
The 1-5% methacrylic acid
Fine or the peroxidation formyl of 0.5-4% azo two isobutyls
The 1-3% vinyltriethoxysilane
All the other phthalic acid dimethyl esters or dibutyl phthalate (DBP) are formed
2, state the production method of stained glass, by chip select, close sheet, batching, slurrying, close sheet grouting, thermopolymerization is formed, it is characterized in that: used primary colours organic dye is prepared in proportion before the slurrying and be dissolved among the butanols of 2-5%, and then be filled in other solvent, the thermopolymerization heating method is: since 40 ℃, kept 6 hours when rising 5 ℃ to 60 ℃ per half an hour, rising 5 ℃ to 85 ℃ per again half an hour kept 4 hours, rising 5 ℃ to 100 ℃ per again half an hour kept 2 hours, stop heating back and be cooled to 40 ℃ under the polymerization furnace situation not opening, open fire door then and take out glass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96114644A CN1055072C (en) | 1996-12-19 | 1996-12-19 | Colour sandwiched glass and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96114644A CN1055072C (en) | 1996-12-19 | 1996-12-19 | Colour sandwiched glass and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1185421A CN1185421A (en) | 1998-06-24 |
| CN1055072C true CN1055072C (en) | 2000-08-02 |
Family
ID=5122219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96114644A Expired - Fee Related CN1055072C (en) | 1996-12-19 | 1996-12-19 | Colour sandwiched glass and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1055072C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101306922B (en) * | 2008-07-02 | 2010-12-29 | 福耀玻璃工业集团股份有限公司 | Process for production of noise insulation laminated glass for vehicle |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103802588B (en) * | 2013-12-31 | 2016-05-11 | 都匀开发区福田化工有限责任公司 | A kind of manufacture method of interlayer safe and colour glass mirror |
| CN107353622A (en) * | 2017-07-12 | 2017-11-17 | 苏州珀力玛高分子材料有限公司 | Temperature becomes light control material, becomes temperature control sunshade photo chromic glass of light control material and preparation method thereof containing temperature |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103395A (en) * | 1987-05-08 | 1988-11-16 | 河北化工学院 | High-strength laminated safety glass and its production method |
| CN1038441A (en) * | 1988-06-11 | 1990-01-03 | 河北轻化工学院 | A kind of manufacture method of laminated safety glass |
| CN2217016Y (en) * | 1995-03-07 | 1996-01-10 | 郑州市有机玻璃厂汜水分厂 | Color sandwich glass for automobiles |
-
1996
- 1996-12-19 CN CN96114644A patent/CN1055072C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103395A (en) * | 1987-05-08 | 1988-11-16 | 河北化工学院 | High-strength laminated safety glass and its production method |
| CN1038441A (en) * | 1988-06-11 | 1990-01-03 | 河北轻化工学院 | A kind of manufacture method of laminated safety glass |
| CN2217016Y (en) * | 1995-03-07 | 1996-01-10 | 郑州市有机玻璃厂汜水分厂 | Color sandwich glass for automobiles |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101306922B (en) * | 2008-07-02 | 2010-12-29 | 福耀玻璃工业集团股份有限公司 | Process for production of noise insulation laminated glass for vehicle |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1185421A (en) | 1998-06-24 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |