CN107933033A - With heat-insulating and energy-saving effect fenestrated membrane and include its glassware - Google Patents
With heat-insulating and energy-saving effect fenestrated membrane and include its glassware Download PDFInfo
- Publication number
- CN107933033A CN107933033A CN201711498656.0A CN201711498656A CN107933033A CN 107933033 A CN107933033 A CN 107933033A CN 201711498656 A CN201711498656 A CN 201711498656A CN 107933033 A CN107933033 A CN 107933033A
- Authority
- CN
- China
- Prior art keywords
- layer
- energy
- fenestrated membrane
- heat
- insulating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000694 effects Effects 0.000 title claims abstract description 67
- 239000012528 membrane Substances 0.000 title claims abstract description 67
- 229910052751 metal Inorganic materials 0.000 claims abstract description 47
- 239000002184 metal Substances 0.000 claims abstract description 47
- 230000003287 optical effect Effects 0.000 claims abstract description 19
- 229910044991 metal oxide Inorganic materials 0.000 claims description 19
- 150000004706 metal oxides Chemical class 0.000 claims description 18
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 239000000853 adhesive Substances 0.000 claims description 12
- 230000001070 adhesive effect Effects 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 5
- 229910000599 Cr alloy Inorganic materials 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910003437 indium oxide Inorganic materials 0.000 claims description 4
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910021332 silicide Inorganic materials 0.000 claims description 4
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 3
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 3
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 229910001922 gold oxide Inorganic materials 0.000 claims 1
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical group O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 26
- 230000005540 biological transmission Effects 0.000 abstract description 13
- 238000005286 illumination Methods 0.000 abstract description 8
- 238000005265 energy consumption Methods 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 5
- 238000005057 refrigeration Methods 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 124
- 210000004379 membrane Anatomy 0.000 description 50
- 230000006870 function Effects 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical group CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000009418 renovation Methods 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 3
- 210000002469 basement membrane Anatomy 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004821 Contact adhesive Substances 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000005391 art glass Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- -1 nano titanium dioxide compound Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000011895 specific detection Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/041—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of fenestrated membrane with heat-insulating and energy-saving effect and include its glassware, it is related to function film technical field, above-mentioned fenestrated membrane is mainly made of anti-scratch layer, flexible base film layer, flexible controlled metal film layer, optical pressure sensitive glue-line and release film layer, and each layer stacks gradually and is complex as an entirety.The fenestrated membrane can pass through making choice property of light, possess high visible transmission than effect under, the infrared reflection ratio and ultraviolet isolating rate of fenestrated membrane can also be effectively improved, and then there is very excellent energy-saving heat preserving effect, solve the problems, such as glass door and window heat-insulating and energy-saving less effective in the prior art.The fenestrated membrane is mainly used in automobile and building glass door and window surface, can play the role of attractive, decorative, security protection, adjust illumination and heat-insulating and energy-saving, effectively reduce building and the refrigeration and heating energy consumption of automobile.
Description
Technical field
The present invention relates to function film technical field, more particularly, to a kind of fenestrated membrane with heat-insulating and energy-saving effect and comprising
Its glassware.
Background technology
With expanding economy and the change of environment, pursuit of the people for energy saving, low-carbon life style is also compeled all the more
Cut.Glass is as a kind of material for being widely used in door and window industry, and the quality of life to people brings great lifting, especially
After it is modern urbanization progress faster, the utilization rate of glass is substantially improved in skyscraper.However, the spy due to glass in itself
Property, causes amount of heat to distribute loss by glass door and window, is added significantly to the energy consumption in terms of heating and refrigeration, therefore such as
What effectively reduces the thermal losses via glass door and window, just into one of research hotspot of research staff.
One kind extension of the fenestrated membrane as glass door and window function, by the tea paper of early stage, common dyeing film, reflective membrane, is arrived again
Nano ceramics film, the performance of fenestrated membrane have been obtained for significant progress.However as people to energy saving and environmental requirement into one
Step improves, and traditional fenestrated membrane product has been difficult to meet the needs of present social development.
Therefore, it is badly in need of a kind of fenestrated membrane with heat-insulating and energy-saving effect of exploitation, which can be saturating to making choice property of light
Cross, possess high visible transmission than effect under, also with high IR line reflection ratio and high ultraviolet isolating rate, so as to room
Interior environment plays the effect of heat-insulation and heat-preservation, becomes very necessary and urgent.
In view of this, it is special to propose the present invention.
The content of the invention
The first object of the present invention is to provide a kind of fenestrated membrane with heat-insulating and energy-saving effect, and the fenestrated membrane can be to light
Making choice property of line passes through, possess high visible transmission than effect under, the infrared reflection of fenestrated membrane can also be effectively improved
Than with ultraviolet isolating rate, and then there is very excellent energy-saving effect, with existing automobile and building energy-saving renovation scheme phase
Than energy saving magnetic control fenestrated membrane of the invention, which has, implements convenient, cost-effective, effect more outstanding feature, efficiently solves existing
There is the problem of glass door and window heat-insulating and energy-saving less effective in technology.
The second object of the present invention is to provide a kind of glassware for including the above-mentioned fenestrated membrane with heat-insulating and energy-saving effect,
The glassware not only has excellent spectral selective penetrated property energy, also has very excellent energy-saving effect, can extensive use
In automobile and building glass door and window surface, play the role of attractive, decorative, security protection, adjust illumination and heat-insulating and energy-saving.
A kind of fenestrated membrane with heat-insulating and energy-saving effect provided by the invention, the fenestrated membrane is mainly by anti-scratch layer, flexible base
Film layer, flexible controlled metal film layer, optical pressure sensitive glue-line and release film layer are formed, and each layer stack gradually be complex as one it is whole
Body.
Further, the flexible base film layer and flexible controlled metal film layer are bonded by optics adhesive.
Further, the flexible controlled metal film layer is mainly made of 5~9 layer function dielectric layers；
The functional medium layer includes metal layer, metal oxide dielectric film and shielding layer；The shielding layer is arranged at
Between metal layer and metal oxide dielectric film.
Further, the metal layer is Ag sheaths.
Further, the metal oxide dielectric film for titanium oxide, tin-oxide, zinc oxide, nitrogen silicide,
Any one in bismuth oxide, indium oxide or indium tin oxide.
Further, the shielding layer is made of metal alloy or metal oxide；
Preferably, the metal alloy is the alloy of chromium, nickel element or titanium elements；The metal oxide is oxidation
Indium tin or zinc oxide.
Further, the thickness of each functional medium layer is 30~300nm in the flexible controlled metal film layer.
Further, the thickness of the flexible base film layer, flexible controlled metal film layer and release film layer is 10~100 μm.
Further, the thickness of the anti-scratch layer is 1~5 μm, and the thickness of the optical pressure sensitive glue-line is 3~15 μm.
A kind of glassware for including the above-mentioned fenestrated membrane with heat-insulating and energy-saving effect provided by the invention.
Compared with prior art, beneficial effects of the present invention are：
Fenestrated membrane provided by the invention with heat-insulating and energy-saving effect is mainly by anti-scratch layer, flexible base film layer, flexible magnetic control
Metallic diaphragm, optical pressure sensitive glue-line and release film layer are formed, and each layer stacks gradually and is complex as an entirety.Above-mentioned fenestrated membrane can
Making choice property of light is passed through, possess high visible transmission than effect under, the infrared ray of fenestrated membrane can also be effectively improved
Reflectivity and ultraviolet isolating rate, and then there is very excellent energy-saving effect, with existing automobile and building energy-saving renovation side
Case is compared, and energy saving magnetic control fenestrated membrane of the invention, which has, implements convenient, cost-effective, effect more outstanding feature, effectively solves
In the prior art the problem of glass door and window heat-insulating and energy-saving less effective.The film is mainly used in automobile and building glass door and window
Surface, can play the role of attractive, decorative, security protection, adjust illumination and heat-insulating and energy-saving, and can effectively reduce building and automobile
Refrigeration and heating energy consumption.
A kind of glassware for including the above-mentioned fenestrated membrane with heat-insulating and energy-saving effect provided by the invention, the glassware is not
But there is excellent spectral selective penetrated property energy, also there is very excellent energy-saving effect, can be widely applied to automobile and building
Glass door and window surface, plays the role of attractive, decorative, security protection, adjusts illumination and heat-insulating and energy-saving.
Brief description of the drawings
, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution of the prior art
Embodiment or attached drawing needed to be used in the description of the prior art are briefly described, it should be apparent that, in describing below
Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor
Put, other attached drawings can also be obtained according to these attached drawings.
Fig. 1 is the flow chart of optics adhesive preparation method in embodiment of the present invention；
Fig. 2 is the flow chart of the fenestrated membrane preparation method in embodiment of the present invention with heat-insulating and energy-saving effect；
Fig. 3 is the structure diagram for the flexible controlled metal film layer that the embodiment of the present invention 1 provides；
Fig. 4 is the structure diagram for the fenestrated membrane with heat-insulating and energy-saving effect that the embodiment of the present invention 2 provides.
Icon：1- anti-scratch layers；2- flexible base film layers；3- flexibility controlled metal film layers；4- optical pressure sensitive glue-lines；5- is release
Film layer；31- metal layers；32- metal oxide dielectric films；33- shielding layers.
Embodiment
Technical scheme is clearly and completely described below in conjunction with attached drawing, it is clear that described implementation
Example is part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill
Personnel's all other embodiments obtained without making creative work, belong to the scope of protection of the invention.
In the description of the present invention, it is necessary to explanation, such as occur term " " center ", " on ", " under ", "left", "right",
" vertical ", " level ", " interior ", " outer " etc., orientation or position relationship indicated by it are based on orientation shown in the drawings or position
Relation, is for only for ease of and describes the present invention and simplify description, rather than indicates or imply that signified device or element must have
There is specific orientation, with specific azimuth configuration and operation, therefore be not considered as limiting the invention.In addition, as occurred
Term " first ", " second ", " the 3rd " are only used for description purpose, and it is not intended that instruction or hint relative importance.
In the description of the present invention, it is necessary to which explanation, unless otherwise clearly defined and limited, term " peace such as occurs
Dress ", " connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integratedly
Connection；Can mechanically connect or be electrically connected；It can be directly connected, can also be indirectly connected by intermediary,
It can be the connection inside two elements.For the ordinary skill in the art, above-mentioned art can be understood with concrete condition
The concrete meaning of language in the present invention.
According to an aspect of the present invention, a kind of fenestrated membrane with heat-insulating and energy-saving effect, the fenestrated membrane is mainly by anti-scratch
Layer 1, flexible base film layer 2, flexible controlled metal film layer 3, optical pressure sensitive glue-line 4 and release film layer 5 are formed, and each layer stacks gradually
It is complex as an entirety.
The present invention have heat-insulating and energy-saving effect fenestrated membrane in above-mentioned each functional layer role be：
Anti-scratch layer 1 can prevent product from being drawn during production, storage, transportation, installation and use, scrape, rubbing wound, protect
It is apparent intact to demonstrate,prove product；
Flexible base film layer 2 has the function of certain blocking oxygen and steam, can extend product service life, in addition have
Fine definition and high visible transmission ratio, it is ensured that the good visual field and sufficient illumination；
Flexible controlled metal film layer 3 has high visible transmission ratio and infrared ray rejection rate, it can be ensured that product has excellent
Heat-insulating and energy-saving effect, in addition can adjust product colour, enrich product category；
Optical pressure sensitive glue-line 4 has a good paste performance, and it is clear it is bright, do not shift, do not remain, free from extraneous odour；
Release film layer 5 protects the production of optical pressure sensitive glue-line, storage, is not damaged in transportational process, and when ensuring to use
Can conveniently it remove.
The present invention has the fenestrated membrane of heat-insulating and energy-saving effect, and the fenestrated membrane is mainly by anti-scratch layer 1, flexible base film layer 2, flexibility
Controlled metal film layer 3, optical pressure sensitive glue-line 4 and release film layer 5 are formed, and each layer stacks gradually and is complex as an entirety.Wherein,
Flexible controlled metal film layer 3 has high visible transmission ratio and infrared ray rejection rate, it can be ensured that product has excellent heat-insulated section
Can effect.The above-mentioned fenestrated membrane with heat-insulating and energy-saving effect not only with excellent spectral selective penetrated property energy, also has very excellent
Energy-saving effect, compared with existing automobile and building energy-saving renovation scheme, energy saving magnetic control fenestrated membrane of the invention have implement just
The characteristics of sharp, cost-effective, significant effect, efficiently solve asking for glass door and window heat-insulating and energy-saving less effective in the prior art
Topic.The film is mainly used in automobile and building glass door and window surface, can play attractive, decorative, security protection, adjust illumination and
The effect of heat-insulating and energy-saving, effectively reduces building and the refrigeration and heating energy consumption of automobile.
Preferably, the anti-scratch layer 1 is mainly polyacrylate polymers, nano titanium dioxide compound composition；
The flexible base film layer 2 is mainly transparent PET basement membrane；The optics pressure sensitive adhesive is mainly polyacrylate, polyurethane or organic
Silica type pressure sensitive adhesive；The release film layer 5 is mainly PET release films.
In the preferred embodiment of the present invention, the flexible base film layer 2 and flexible controlled metal film layer 3 pass through light
Learn adhesive bonding.
As a preferred embodiment, the flexible base film layer 2 and flexible controlled metal film layer 3 pass through optics gluing
Agent is bonded, which has effects that to absorb ultraviolet.
As shown in Figure 1, it is preferred that the preparation method of above-mentioned optics adhesive is, first by adhesive and ultraviolet radiation absorption
Agent is mixed 10~20min with reactive diluent respectively and is fully diluted both respectively, and then both are mixed and are added
Enter initiator and stir 5~20min, optics adhesive is made.
It is furthermore preferred that the adhesive is the SAA1401 gluing resins of Xi'an Naviation Sanwo Chemical Co., Ltd.'s production；Institute
State the T-571 ultraviolet absorbers that ultra-violet absorber is E.I.Du Pont Company's production；The initiator irrigates chemistry for Xi'an space flight three to be had
The SAC12 initiators of limit company production；The diluent is ethyl acetate or toluene.
It is furthermore preferred that the component of each raw material is in the preparation method of above-mentioned optics adhesive：SAA1401 gluing resins 40-
60%th, SAC12 initiators 0.5-1.5%, T-571 ultraviolet absorbers 0.5-1.5%, ethyl acetate 20-40%, toluene 10-
22%.
As shown in Figure 2, it is preferred that the preparation method of fenestrated membrane of the present invention with heat-insulating and energy-saving effect is, first by optics
Adhesive is compounded and is uniformly dispersed, and is then bonded in flexible base film layer 2 and flexible controlled metal film layer 3 using optics adhesive
Together；Then optics pressure sensitive adhesive and anti-scratch agent are compounded and be uniformly dispersed, be respectively applied in flexible base film layer 2 and flexible magnetic control
On metallic diaphragm 3, finally optical pressure sensitive glue-line 4 is overlaid on release film layer 5, the present invention, which is made, has heat-insulating and energy-saving effect
Fenestrated membrane.
In the preferred embodiment of the present invention, the flexible controlled metal film layer 3 is mainly by 5~9 layer functions
Dielectric layer is formed；
The functional medium layer includes metal layer 31, metal oxide dielectric film 32 and shielding layer 33；The shielding layer
33 are arranged between metal layer 31 and metal oxide dielectric film 32.
As a preferred embodiment, the metal layer 31 has the function that to reflect infrared ray, Jin Erke
To improve reflection ratio of the fenestrated membrane of the present invention to infrared ray；The metal oxide dielectric film 32 adjusts fenestrated membrane optical property and face
The effect of color；The shielding layer 33 has the function that to prevent that metal layer 31 is aoxidized in process, while can improve metal layer
31 and the Percentage bound of metal oxide dielectric film 32.
Preferably, the metal oxide dielectric film 32 can be further divided into outer dielectric layer, function medium layer and bottom
Layer dielectric layer, wherein, the outer dielectric layer, which primarily serves, lowers visible reflectance and protection film layer effect without damage；Work(
Energy dielectric layer primarily serves the effect for adjusting fenestrated membrane optical property and color；Underlying dielectric layer, which primarily serves, improves metal and basement membrane
The adhesive force on surface, has the effect for adjusting fenestrated membrane optical property and color concurrently；
In above-mentioned preferred embodiment, the metal layer 31 is Ag sheaths；Ag ion pairs infrared ray has good
Reflex.
In above-mentioned preferred embodiment, the metal oxide dielectric film 32 is titanium oxide, the oxidation of tin-oxide, zinc
Any one in thing, nitrogen silicide, bismuth oxide, indium oxide or indium tin oxide.
In above-mentioned preferred embodiment, the shielding layer 33 is made of metal alloy or metal oxide；
Preferably, the metal alloy is the alloy of chromium, nickel element or titanium elements；The metal oxide is oxidation
Indium tin or zinc oxide.
In the preferred embodiment of the present invention, each functional medium layer in the flexible controlled metal film layer 3
Thickness is 30~300nm.
In the present invention, the thickness of each functional medium layer is typical but non-limiting in above-mentioned flexibility controlled metal film layer 3
For：30nm, 70nm, 100nm, 130nm, 170nm, 200nm, 230nm, 270nm or 300nm.
In the preferred embodiment of the present invention, the flexible base film layer 2, flexible controlled metal film layer 3 and release
The thickness of film layer 5 is 10~100 μm.
In the present invention, the thickness of above-mentioned flexible base film layer 2 is typical but non-limiting to be：10μm、20μm、40μm、60μm、
80 μm or 100 μm.In the present invention, the thickness of above-mentioned flexibility controlled metal film layer 3 is typical but non-limiting to be：10μm、20μm、
40 μm, 60 μm, 80 μm or 100 μm.In the present invention, the thickness of above-mentioned release film layer 5 is typical but non-limiting to be：10μm、20μ
M, 40 μm, 60 μm, 80 μm or 100 μm.
In the preferred embodiment of the present invention, the thickness of the anti-scratch layer 1 is 1~5 μm, the optical pressure sensitive
The thickness of glue-line 4 is 3~15 μm.
In the present invention, the thickness of above-mentioned anti-scratch layer 1 is typical but non-limiting to be：1 μm, 2 μm, 3 μm, 4 μm or 5 μm.
In the present invention, the thickness of above-mentioned optical pressure sensitive glue-line 4 is typical but non-limiting to be：3 μm, 5 μm, 8 μm, 10 μm, 12 μm or 15 μ
m。
According to an aspect of the present invention, a kind of glassware for including the above-mentioned fenestrated membrane with heat-insulating and energy-saving effect.
The glassware of fenestrated membrane of the present invention with heat-insulating and energy-saving effect is gone back not only with excellent spectral selective penetrated property energy
With very excellent energy-saving effect, automobile and building glass door and window surface are can be widely applied to, plays attractive, decorative, safety
Protection, adjust illumination and the effect of heat-insulating and energy-saving.
Embodiment 1
As shown in figure 3, a kind of flexible controlled metal film layer 3 of the fenestrated membrane with heat-insulating and energy-saving effect, the flexibility magnetic control
Metallic diaphragm 3 is made of 8 Rotating fields, respectively is：Outer dielectric layer, the first function medium layer, the first shielding layer, the first gold medal
Belong to layer, the second function medium layer, the second shielding layer, second metal layer and underlying dielectric layer composition.The underlying dielectric layer with it is soft
Property base membrane layer 2 is bonded by optics adhesive, wherein：
The outer dielectric layer is made of titanium oxide；The first function medium layer is made of zinc oxide；Described
One shielding layer is made of chromium alloy；The first metal layer is Ag sheaths；
The second function medium layer is made of nitrogen silicide；Second shielding layer is made of zinc oxide；Described second
Metal layer is Ag sheaths；
The underlying dielectric layer is made of indium oxide.
Embodiment 2
As shown in figure 4, a kind of fenestrated membrane with heat-insulating and energy-saving effect, the fenestrated membrane is mainly by anti-scratch layer 1, flexible base film
Layer 2, flexible controlled metal film layer 3, optical pressure sensitive glue-line 4 and release film layer 5 are formed, and each layer stack gradually be complex as one it is whole
Body, wherein：
The anti-scratch layer 1 is polyacrylate polymers；The flexible base film layer 2 is transparent PET basement membrane；It is described soft
The flexible controlled metal film layer 3 of 3 embodiment 1 of property controlled metal film layer；The optical pressure sensitive glue-line 4 is polyurethane contact adhesive；Institute
It is PET release films to state release film layer 5.
Embodiment 3
A kind of glassware, the glassware are motor-vehicle glass window, which is pasted with embodiment 2 and provides
Have heat-insulating and energy-saving effect fenestrated membrane.
Embodiment 4
A kind of glassware, the glassware are glass for building purposes window, which is pasted with embodiment 2
What is provided has the fenestrated membrane of heat-insulating and energy-saving effect.
Effect example 1
To show that fenestrated membrane of the present invention can pass through making choice property of light, possess high visible transmission than effect
Under, the infrared reflection ratio and ultraviolet isolating rate of fenestrated membrane can also be effectively improved, and then there is very excellent energy-saving heat preserving
Effect.Two pieces of the same batch shield glass now produced selected from Fuyao Glass Industry Group Co., Ltd, will be real
Apply example 2 preparation fenestrated membrane release film layer 5 remove after be attached on one block of glass, another block of glass is not attached as experiment contrast
Fenestrated membrane.Performance detection then is carried out to two blocks of glass, specific detection method is：
Visible light transmission：The solar film transmission measurement instrument (model produced using Lin Shang Science and Technology Ltd.s of Shenzhen
LS103), carried out with reference to ASTM D1003 standard methods；
Ultraviolet-resistant rate：Using Japanese Shimadzu UV-3600 types spectrophotometer test, with reference to standard GB/T/T2680 into
Row detection；
Infrared light rejection rate：The solar film transmission measurement instrument (model produced using Lin Shang Science and Technology Ltd.s of Shenzhen
LS103) it is detected by the test method of the instrument, the wave-length coverage of test is 850~1050nm.
The total rejection rate of solar energy, shading coefficient：Lambda 750s using the production of PerkinElmer Instrument Ltd. are purple
Outer visible spectrophotometer test, is detected with reference to standard GB/T/T 2680；
Its result is as shown in the table：
| Detection project | Glass 1 | Glass 2 |
| Visible transmission ratio (%) | 70.25 | 88.39 |
| Infrared ray rejection rate (%) | 85.7 | 16.2 |
| The total rejection rate of solar energy (%) | 63.52 | 12.9 |
| Shading coefficient | 0.476 | 1.001 |
| Ultraviolet isolating rate (%) | 99 | 11.9 |
In conclusion the fenestrated membrane provided by the invention with heat-insulating and energy-saving effect can pass through making choice property of light,
Possess high visible transmission than effect under, the infrared reflection ratio and ultraviolet isolating rate of fenestrated membrane can also be effectively improved,
And then there is very excellent energy-saving effect, compared with existing automobile and building energy-saving renovation scheme, energy saving magnetic of the invention
Control fenestrated membrane have implement convenient, cost-effective, effect more outstanding feature, efficiently solve in the prior art glass door and window every
Not the problem of hot energy-saving effect is not good enough.The film is mainly used in automobile and building glass door and window surface, can play attractive, decorative, peace
Full protection, adjust illumination and the effect of heat-insulating and energy-saving, effectively reduces building and the refrigeration and heating energy consumption of automobile.
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe is described in detail the present invention with reference to foregoing embodiments, it will be understood by those of ordinary skill in the art that：Its according to
Can so modify to the technical solution described in foregoing embodiments, either to which part or all technical characteristic into
Row equivalent substitution；And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology
The scope of scheme.
Claims (10)
1. a kind of fenestrated membrane with heat-insulating and energy-saving effect, it is characterised in that the fenestrated membrane is mainly by anti-scratch layer, flexible base film
Layer, flexible controlled metal film layer, optical pressure sensitive glue-line and release film layer are formed, and each layer stacks gradually and is complex as an entirety.
2. the fenestrated membrane according to claim 1 with heat-insulating and energy-saving effect, it is characterised in that the flexible base film layer and soft
Property controlled metal film layer is bonded by optics adhesive.
3. the fenestrated membrane according to claim 1 with heat-insulating and energy-saving effect, it is characterised in that the flexibility controlled metal film
Layer is mainly made of 5~9 layer function dielectric layers；
The functional medium layer includes metal layer, metal oxide dielectric film and shielding layer；The shielding layer is arranged at metal
Between layer and metal oxide dielectric film.
4. the fenestrated membrane according to claim 3 with heat-insulating and energy-saving effect, it is characterised in that the metal layer is Ag ions
Layer.
5. the fenestrated membrane according to claim 3 with heat-insulating and energy-saving effect, it is characterised in that the metal oxide dielectric
Layer is any in titanium oxide, tin-oxide, zinc oxide, nitrogen silicide, bismuth oxide, indium oxide or indium tin oxide
It is a kind of.
6. the fenestrated membrane according to claim 3 with heat-insulating and energy-saving effect, it is characterised in that the shielding layer is closed by metal
Gold or metal oxide composition；
Preferably, the metal alloy is the alloy of chromium, nickel element or titanium elements；The metal oxide is tin indium oxide
Or zinc oxide.
7. the fenestrated membrane according to claim 3 with heat-insulating and energy-saving effect, it is characterised in that the flexibility controlled metal film
The thickness of each functional medium layer is 30~300nm in layer.
8. the fenestrated membrane according to claim 1 with heat-insulating and energy-saving effect, it is characterised in that the flexible base film layer, soft
Property controlled metal film layer and release film layer thickness be 10~100 μm.
9. the fenestrated membrane according to claim 1 with heat-insulating and energy-saving effect, it is characterised in that the thickness of the anti-scratch layer
For 1~5 μm, the thickness of the optical pressure sensitive glue-line is 3~15 μm.
A kind of 10. glassware for the fenestrated membrane that comprising claim 1-9 any one of them there is heat-insulating and energy-saving to act on.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711498656.0A CN107933033A (en) | 2017-12-29 | 2017-12-29 | With heat-insulating and energy-saving effect fenestrated membrane and include its glassware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711498656.0A CN107933033A (en) | 2017-12-29 | 2017-12-29 | With heat-insulating and energy-saving effect fenestrated membrane and include its glassware |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107933033A true CN107933033A (en) | 2018-04-20 |
Family
ID=61938264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711498656.0A Pending CN107933033A (en) | 2017-12-29 | 2017-12-29 | With heat-insulating and energy-saving effect fenestrated membrane and include its glassware |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107933033A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977110A (en) * | 2018-08-24 | 2018-12-11 | 宁波瑞凌辐射制冷科技有限公司 | A kind of radiation refrigeration automobile window films |
| CN115093801A (en) * | 2022-06-21 | 2022-09-23 | 常州山由帝杉防护材料制造有限公司 | Energy-saving window film for hollow glass and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1871181A (en) * | 2003-08-20 | 2006-11-29 | 法国圣戈班玻璃厂 | Transparent substrate incorporating a stack of thin layers with reflective properties to infrared and/or solar radiation for glazing applications |
| CN102765224A (en) * | 2012-08-13 | 2012-11-07 | 乐凯胶片股份有限公司 | Anti-ultraviolet high-heat-insulation window film |
| CN104245303A (en) * | 2012-04-05 | 2014-12-24 | 柯尼卡美能达株式会社 | Infrared-shielding film and infrared-shielding element |
| CN204054821U (en) * | 2014-08-08 | 2014-12-31 | 常州山由帝杉防护材料制造有限公司 | Intercept ultraviolet reflection fenestrated membrane |
| CN104385713A (en) * | 2014-10-22 | 2015-03-04 | 张家港康得新光电材料有限公司 | Temperature control fenestrated membrane and making method thereof |
| CN106183148A (en) * | 2016-08-30 | 2016-12-07 | 常州山由帝杉防护材料制造有限公司 | Nano ceramics heat-insulation and heat-preservation fenestrated membrane |
| US20170059750A1 (en) * | 2015-08-26 | 2017-03-02 | Saint-Gobain Performance Plastics Corporation | Infrared reflecting film |
-
2017
- 2017-12-29 CN CN201711498656.0A patent/CN107933033A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1871181A (en) * | 2003-08-20 | 2006-11-29 | 法国圣戈班玻璃厂 | Transparent substrate incorporating a stack of thin layers with reflective properties to infrared and/or solar radiation for glazing applications |
| CN104245303A (en) * | 2012-04-05 | 2014-12-24 | 柯尼卡美能达株式会社 | Infrared-shielding film and infrared-shielding element |
| CN102765224A (en) * | 2012-08-13 | 2012-11-07 | 乐凯胶片股份有限公司 | Anti-ultraviolet high-heat-insulation window film |
| CN204054821U (en) * | 2014-08-08 | 2014-12-31 | 常州山由帝杉防护材料制造有限公司 | Intercept ultraviolet reflection fenestrated membrane |
| CN104385713A (en) * | 2014-10-22 | 2015-03-04 | 张家港康得新光电材料有限公司 | Temperature control fenestrated membrane and making method thereof |
| US20170059750A1 (en) * | 2015-08-26 | 2017-03-02 | Saint-Gobain Performance Plastics Corporation | Infrared reflecting film |
| CN106183148A (en) * | 2016-08-30 | 2016-12-07 | 常州山由帝杉防护材料制造有限公司 | Nano ceramics heat-insulation and heat-preservation fenestrated membrane |
Non-Patent Citations (2)
| Title |
|---|
| 中国建筑标准设计研究院 编: "《国家建筑标准设计图集 16J908-8 被动式低能耗建筑 严寒和寒冷地区居住建筑》", 31 July 2017, 中国计划出版社, pages: 97 * |
| 白振中 等: "《工程玻璃深加工技术手册》", 30 April 2014, 中国建材工业出版社, pages: 285 - 286 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977110A (en) * | 2018-08-24 | 2018-12-11 | 宁波瑞凌辐射制冷科技有限公司 | A kind of radiation refrigeration automobile window films |
| CN115093801A (en) * | 2022-06-21 | 2022-09-23 | 常州山由帝杉防护材料制造有限公司 | Energy-saving window film for hollow glass and preparation method and application thereof |
| WO2023245542A1 (en) * | 2022-06-21 | 2023-12-28 | 常州山由帝杉防护材料制造有限公司 | Energy-saving window film for insulating glass unit, preparation method therefor, and use thereof |
| CN115093801B (en) * | 2022-06-21 | 2024-04-19 | 江苏航天山由科技有限公司 | Energy-saving window film for hollow glass and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104736338B (en) | Be suitable to solar energy system has colour reflective and the laminated windows of high sunlight transmissivity | |
| US20210124228A1 (en) | High performance privacy glazing structures | |
| CN104960277B (en) | Thermal-insulating heat-preserving laminated safety glass and manufacturing method thereof | |
| CN102795790A (en) | Post-heat-treatable substrate with thermochromic film | |
| CN106183148A (en) | Nano ceramics heat-insulation and heat-preservation fenestrated membrane | |
| CN107933033A (en) | With heat-insulating and energy-saving effect fenestrated membrane and include its glassware | |
| CN201809285U (en) | Single-silver coated glass | |
| CN203876339U (en) | Thermal-insulation and sound-proof window film | |
| CN109720026A (en) | A kind of high transmission high reflection thermal isolation film | |
| CN206467149U (en) | A kind of novel photochromic half mirror | |
| CN106853706A (en) | A kind of high transmission high reflection thermal isolation film | |
| CN106183271B (en) | Nana intelligent thermal-insulation window film | |
| CN208101259U (en) | Fenestrated membrane with heat-insulating and energy-saving effect and the glassware comprising it | |
| CN103350534B (en) | A kind of nano-angle color-changing solar can control film and preparation method thereof | |
| CN203284327U (en) | Low-reflectivity gold remote toughened off-line LOW-E coated glass | |
| JP2017185669A (en) | Thermal barrier film and thermal barrier laminated glass | |
| CN206623483U (en) | Multifunctional glass film | |
| CN205974274U (en) | High three silver medal low -emissivity coated glass of light green color bendable steel that pass through | |
| TWM498197U (en) | Thermal-shielding glass | |
| CN205241593U (en) | Heat insulation film structure | |
| CN203093215U (en) | Temperable low-emissivity coated glass with double golden surfaces | |
| CN103213348A (en) | Three-Ag low-emissivity coated glass | |
| CN204725952U (en) | The sunshade low radiation coated glass of the ultralow reflection of two silver-colored indoor and outdoors | |
| CN208314440U (en) | Transparence display laminated glass | |
| CN106273911B (en) | Low emissivity pad pasting, low radiation coated glass and hollow glass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |