CN105505490A - Oxidation reduction pressurizing agent - Google Patents

Oxidation reduction pressurizing agent Download PDF

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CN105505490A
CN105505490A CN201510894408.2A CN201510894408A CN105505490A CN 105505490 A CN105505490 A CN 105505490A CN 201510894408 A CN201510894408 A CN 201510894408A CN 105505490 A CN105505490 A CN 105505490A
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oil
percent
magnesium
oxide
peroxide
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CN105505490B (en
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谢传林
朱斌
眭晔
谢荣顺
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1208Inorganic compounds elements
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
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    • C10L1/1216Inorganic compounds metal compounds, e.g. hydrides, carbides
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
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    • C10L2200/0209Group I metals: Li, Na, K, Rb, Cs, Fr, Cu, Ag, Au
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
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    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
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    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204Metals or alloys
    • C10L2200/0245Lanthanide group metals: La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu
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    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
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    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
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    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
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    • C10L2300/00Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/40Mixture of four or more components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention provides an oxidation reduction pressurizing agent, which belongs to a material applied to internal combustion engine equipment for enhancing power, saving fuel oil and reducing three-waste emission, and can be widely applied to internal combustion engines of equipment such as automobiles, trains, boats, airplanes, tanks and agricultural machinery. The oxidation reduction pressurizing agent is characterized by being formed by proportionally grinding, screening and mixing the following ingredients in percentage by weight: 1 to 20 percent of magnesium oxide, 1 to 20 percent of magnesium peroxide, 1 to 15 percent of sodium peroxide, 1 to 15 percent of phosphorus oxide, 1 to 10 percent of rare earth, 0.1 to 1 percent of porpezite, 0.1 to 1 percent of rhodium powder and the balance of lubricating oil.

Description

Redox pressor
Technical field
What redox pressor of the present invention related to is a kind of material be applied in apparatus of the internal-combustion engine, the redox series reaction of chemical substance is produced by work, make the raising of fuel of internal combustion engine combustion value, the enhancing of fuel oil Thorough combustion, engine power, react by this materials chemistry the explosive power produced and form steam film at cylinder inner wall, the effect can also play and save fuel oil, reducing cylinder of internal combustion engine three waste discharge.The present invention can be widely used in the oil engine of automobile, train, boats and ships, aircraft, tank, agricultural machinery, and multiple science and technology field such as its practicality and effect is manufactured, the energy, thermodynamics approved.
Background technology
Carbon reduction is world's spring tide, and governments at all levels of both the central and local governments of China all attach great importance to this problem.Current China to the disposal of three wastes compare effective measures be mostly mend the fold after the sheep is lost a bit, the systems engineering of mending-leakage formula afterwards, time-consuming, effort, expensive, bothersome.How preventing trouble before it happens, reducing three waste discharge from source is the problem that emphasis of the present invention solves.As the air of oil engine working medium, the waste gas derived while being inhaled into cylinder acting is finally discharged back again in air, obviously can not meet the requirement of environmental protection.On market most of oil engine all remain carry over use air working medium, with this traditional mode of petrochemical industry high-carbon fuel, particularly diesel engine, be born so far from it, the limitation that modern manufacturing professional technique exists, determines it and cannot change and depart from this traditional mode.The power factor that traditional mode brings is low, exhaust emissions major polluting atmosphere environment, and the oil engine worked under traditional mode in addition also exists the problem that oil inflame is insufficient, power/oil consumption is wasted in a large number.
At present, home and abroad cylinder of internal combustion engine reduction of discharging, subtract carbon, energy-conservation in done a lot of research, but method is few, mainly contains following 2 points: 1. modified node method design and installation supercharging blower; Such as at exhaust passage, turbo-supercharger is installed, utilize mechanically compress air, increase the strength pressure entering cylinder, to improve quality and the density of air working medium, seem from macroscopically can effectively address this problem, but, still have that supercharging pressure is passive, delayed, asynchronous, supercharging pressure is unstable, can not meet the drawback of plateau low pressure environment.2. select the additive be applicable to, especially consider to improve combustion value.To this, home and abroad never stops the investigation and application of this respect in decades, wish that reaching the fuel oil (vapour, bavin, heavy oil) used for engine improves its combustion value, increases power, save the effect of fuel oil, result proves that efficiency is not high, expense is not low, cost performance is not obvious and hangs upside down even.Such as: domestic certain gasoline dope extensively sold in service station in recent years.The external additive component of eliminating be proved to be containing tetraethyllead and ferrocene can cause engine life to shorten.Again such as, some automobile friend is in order to obtain the raising of engine power, refitted vehicles, and the various vehicle Claims Resolution privately changing performance of dispatching from the factory is prohibited in China's various types of vehicles insurance.In external import additive; really effect that is fuel-efficient, that reduce discharging, improve power is had; but their main component remains petroleum product, after burning, in cylinder, form plasticity protective layer, easily come off after using after a while; the major oil appearance of a street on cylinder head and cylinder body easily blocks; need routine cleaning engine and element of oil filter, if filter core is crossed dirty, need to change, life-time service is cumbersome; and costly, be unfavorable for popularizing.According to comment of experts: domestic the production of saving petrol is difficult to the oil-saving effect reaching 5% technically.
Summary of the invention
The object of the invention is to provide a kind of redox pressor for above-mentioned weak point, by the thermal energy differential that the technology application oxidation and redox reaction produce, even if the larger heat energy of the fully oxidized rear generation of the hydrocarbon of fuel oil, improves mechanical efficiency greatly, reach new energy-saving and emission-reduction object.At present this technical products is through a large amount of various vehicle and tries out average energy-saving effect and can reach more than 20%, IC engine for saving oil 5-40%.And having cleaning carbon distribution function automatically, efficiency is high, expense is little, cost performance is fine.
Cylinder of internal combustion engine pressor takes following scheme to realize: with magnesium oxide, Magnesium peroxide, sodium peroxide, phosphorus oxide, rare earth, porpezite, rhodium powder, often kind of oxide compound is after extra-fine grinding, 0.01-3 micron particle is selected with oil or water sieve, after de-oiling or dewatered drying, then several oxide compound mineral oil modulation synthesis the present invention.Its various Ingredients Weight per distribution ratio is:
Magnesium oxide 1-20%
Magnesium peroxide 1-20%
Sodium peroxide 1-15%
Phosphorus oxide 1-15%
Rare earth 1-10%
Porpezite 0.1-1%
Rhodium powder 0.1-1%
Lubricating oil surplus
Lubricating oil adopts mineral oil.
Manufacturing process:
By said ratio by magnesium oxide, Magnesium peroxide, sodium peroxide, phosphorus oxide, rare earth, porpezite, rhodium powder after extra-fine grinding, 0.01-3 micron particle is filtered out with water or oily precipitated and separated, after dehydration or de-oiling are dried, mix with lubricating oil again, after filtration, fillingly make redox pressor.
Feature of the present invention:
The present invention is different from commercially available common solid-state ignition dope and liquid additive, and it is a kind of novel material: it does not contain alkane but can improve octane value; It is not leaded but have plumbous lubricating effect; Its non-soda acid, but can eliminate carbon distribution protection cylinder body; It does not form cylinder body plastic membrane, but can form the steam film being better than plastic membrane, thus really reaches energy-conservation, reduces discharging, subtracts carbon, improves the effect in cylinder of internal combustion engine work-ing life, has revolutionary significance.Its feature is, the series of theories of applied chemistry oxidation of the present invention and reduction, the oxide compound that the reaction of blindly dating after filtering out several redox is violent, and different oxide compound successively decomposes or distillation at a certain temperature, decomposites oxygen and metal or nonmetallic ion.Solid oxygen changes gaseous state into after decomposing distillation; volume expansion more than 20,000 times; be oxidized with hydrocarbons again; generation is far longer than primary oxide and decomposes; heat energy needed for distillation; produce more to produce shockingly in cylinder simultaneously and have an effect; the fuel oil of equivalent is increased at inner cylinder pressure; efficiency of combustion brings up to 99.5%; remove carbon distribution in combustion chamber and prevent it from producing again; eliminate because carbon distribution " early burning-point " is on the impact of burning, finally reach the object of saving fuel oil, emissions reduction, the combustion motor cylinder effect playing protection, lengthen the life simultaneously.
Embodiment:
Embodiment 1, making cylinder of internal combustion engine pressor 100kg
By proportioning raw materials weighing magnesium oxide 18kg (18%), Magnesium peroxide 15kg (15%), sodium peroxide 8kg (8%), phosphorus oxide 8kg (8%), rare earth 8kg (8%), porpezite 0.5kg (0.5%), rhodium powder 0.5kg (0.5%), lubricating oil 42kg (42%); Lubricating oil adopts mineral oil only;
By above-mentioned by proportioning raw materials weighing magnesium oxide, Magnesium peroxide, sodium peroxide, phosphorus oxide, rare earth, porpezite, rhodium powder pressed powder and lubricating oil, solid powder put into super grinder and grinds 4-20 hour.According to the characteristic of the hydrophilic or oleophylic of powder after grinding, put into water or oil layering screen selects 0.01-3 micron particle, and then dehydration or de-oiling, the lubricating oil adding weighing mixes, then through filtering, cannedly make redox pressor of the present invention.
Embodiment 2, making cylinder of internal combustion engine pressor 100kg
By proportioning raw materials weighing magnesium oxide 12kg (12%), Magnesium peroxide 10kg (10%), sodium peroxide 9kg (9%), phosphorus oxide 9kg (9%), rare earth 9kg (9%), porpezite 0.6kg (0.6%), rhodium powder 0.6kg (0.6%), lubricating oil 49.4kg (49.4%); Lubricating oil adopts mineral oil only;
By above-mentioned by proportioning raw materials weighing magnesium oxide, Magnesium peroxide, sodium peroxide, phosphorus oxide, rare earth, porpezite, rhodium powder pressed powder and lubricating oil, solid powder put into super grinder and grinds 4-20 hour.According to the characteristic of the hydrophilic or oleophylic of powder after grinding, put into the particle that water or oil layering screen select 0.01-3 micron, and then dehydration or de-oiling, the lubricating oil adding weighing mixes, then through filtering, cannedly make redox pressor of the present invention.
Embodiment 3, making cylinder of internal combustion engine pressor 100kg
By proportioning raw materials weighing magnesium oxide 15kg (15%), Magnesium peroxide 15kg (15%), sodium peroxide 10kg (10%), phosphorus oxide 10kg (10%), rare earth 10kg (10%), porpezite 0.8kg (0.8%), rhodium powder 0.8kg (0.8%), lubricating oil 38.4kg (38.4%); Lubricating oil adopts mineral oil only;
By above-mentioned by proportioning raw materials weighing magnesium oxide, Magnesium peroxide, sodium peroxide, phosphorus oxide, rare earth, porpezite, rhodium powder pressed powder, solid powder put into super grinder and grinds 4-20 hour.According to the characteristic of the hydrophilic or oleophylic of powder after grinding, put into the particle that water or oil layering screen select 0.01-3 micron, and then dehydration or de-oiling, the lubricating oil adding weighing mixes, then through filtering, cannedly make redox pressor of the present invention.
Using method
The present invention is used to mainly contain following two kinds of methods:
Method one, compression method.With compression gas tank, the present invention is injected in cylinder of internal combustion engine by inlet valve, then oil engine normally works, and the present invention utonomous working can tell in oil engine.
Method two, addition method.Directly add in fuel oil by the present invention, by fuel oil as carrier, directly enter cylinder of internal combustion engine, after acting, Transient transformation is decomposed into pressor, tells in oil engine.
After tested, can improve after using the present invention and make apparatus of the internal-combustion engine fuel-economizing 5-40%, motor car engine gasoline octane rating improves more than 4%, gasoline Thorough combustion, carbon monoxide, hydrocarbon polymer, the generation of oxynitrides and discharge can be reduced, blowdown reduces 75%, reduces the workload of automobile three-way catalysts, extends its work-ing life.
Redox pressor service condition illustrates:
1, redox pressor is on probation in one 2010 Volkswagen produced per year of Nanjing company, before using, this car has travelled 6.5 ten thousand kilometers, one case oil approximately wheeled 500 kilometers, after adding the present invention, one case oil approximately drives to 650 kilometers (operating mode is identical).Every case oil multirow sails the milimeter number of 30%.
2, redox pressor is on probation on Zhejiang company five domestic water chestnut minibuses bought in January, 2010, this car uses the present invention to travel 80,000 kilometers, F-Zero 80 kilometers/hour, and oil consumption is 320 kilometers/case, noise is large, over-emitting black exhaust during exhaust emissions.After adding the present invention, noise obviously reduces, and does not also have black smoke during exhaust emissions, and one case oil feasiblely in urban district sails to 395 kilometers, and oil consumption reduces by 23.44%.
3, redox pressor is on probation on Nanjing company one 2008 Guangzhou Honda car produced per year, this car uses the present invention to travel 230,000 kilometers, and oil consumption is 600 kilometers/case, after adding the present invention, every case oil wheeled 750 kilometers, operating mode be main in urban district, suburbs traveling.Every case oil multirow sails the milimeter number of 25%.

Claims (3)

1. a redox pressor, it is characterized in that being mixed by proportioning grinding, screening by magnesium oxide, Magnesium peroxide, sodium peroxide, phosphorus oxide, rare earth, porpezite, rhodium powder, lubricating oil, its various Ingredients Weight per distribution ratio is:
Magnesium oxide 1-20%
Magnesium peroxide 1-20%
Sodium peroxide 1-15%
Phosphorus oxide 1-15%
Rare earth 1-10%
Porpezite 0.1-1%
Rhodium powder 0.1-1%
Lubricating oil surplus.
2. the redox pressor according to right 1, is characterized in that lubricating oil can only adopt mineral oil.
3. the redox pressor according to right 1, its technology characteristics is magnesium oxide, Magnesium peroxide, sodium peroxide, phosphorus oxide, rare earth, porpezite, rhodium powder, often kind of oxide compound presses proportioning after extra-fine grinding, 0.01-3 micron particle is selected with oil or water sieve, after de-oiling or dehydration, oven dry, then be modulated into the present invention with mineral oil.
CN201510894408.2A 2015-12-08 2015-12-08 Oxidoreduction pressor Active CN105505490B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1737090A (en) * 2005-09-01 2006-02-22 上海纳米技术及应用国家工程研究中心有限公司 Nanometer fuel oil addition agent
CN1764711A (en) * 2003-01-23 2006-04-26 奥克松尼卡有限公司 Cerium oxide nanoparticles as fuel additives.
CN1863589A (en) * 2003-10-03 2006-11-15 罗狄亚电子与催化公司 Cerium organic colloidal dispersion and element selected from rhodium and palladium and use thereof as an additive to diesel fuel for internal combustion engines
US20130283674A1 (en) * 2012-04-25 2013-10-31 Julian Martin Gaspar Vasquez Fuel additive
CN103566927A (en) * 2013-10-15 2014-02-12 黄铂焜 Automobile fuel saving and emission reducing mineral catalyst

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1764711A (en) * 2003-01-23 2006-04-26 奥克松尼卡有限公司 Cerium oxide nanoparticles as fuel additives.
CN1863589A (en) * 2003-10-03 2006-11-15 罗狄亚电子与催化公司 Cerium organic colloidal dispersion and element selected from rhodium and palladium and use thereof as an additive to diesel fuel for internal combustion engines
CN1737090A (en) * 2005-09-01 2006-02-22 上海纳米技术及应用国家工程研究中心有限公司 Nanometer fuel oil addition agent
US20130283674A1 (en) * 2012-04-25 2013-10-31 Julian Martin Gaspar Vasquez Fuel additive
CN103566927A (en) * 2013-10-15 2014-02-12 黄铂焜 Automobile fuel saving and emission reducing mineral catalyst

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