CN105505092A - Odorless and wear-resisting smooth UV (ultraviolet) matt finish paint coating and preparation method thereof - Google Patents
Odorless and wear-resisting smooth UV (ultraviolet) matt finish paint coating and preparation method thereof Download PDFInfo
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- CN105505092A CN105505092A CN201510988077.9A CN201510988077A CN105505092A CN 105505092 A CN105505092 A CN 105505092A CN 201510988077 A CN201510988077 A CN 201510988077A CN 105505092 A CN105505092 A CN 105505092A
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- wear
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
- C08F283/008—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00 on to unsaturated polymers
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to the field of coatings and particularly relates to an odorless and wear-resisting smooth UV (ultraviolet) matt finish paint coating and a preparation method thereof. The odorless and wear-resisting smooth UV matt finish paint coating comprises components in percentage by weight as follows: 25%-50% of hexa-functional polyurethane acrylate prepolymers, 15%-50% of trifunctional modified polyurethane acrylate prepolymers, 15%-50% of acrylate monomers, 1%-10% of a photoinitiator, 0.2%-2% of a wetting dispersant, 0.2%-1% of a leveling agent, 0.2%-0.5% of a defoaming agent and 1%-15% of a matting agent. According to the odorless and wear-resisting smooth UV matt finish paint coating, the technical problems that a pungent smell is left, wetting of the matting agent is difficult, matting is difficult, a paint film is prone to floating and the like after curing of a conventional UV matt finish paint coating are solved, and meanwhile, the defect of crispness of the paint film caused by improvement of the wear resistance of the conventional UV matt finish paint coating is overcome.
Description
Technical field
The invention belongs to paint field, be specifically related to the wear-resisting silk of a kind of clean taste sliding UV dull finishing coat coating and preparation method thereof.
Background technology
UV photo-cured coating (also known as ultraviolet-curing paint) refers under UV-irradiation can a kind of new coating of crosslinking curing in the short period of time, save the energy because it has, be beneficial to environmental protection, economy and the feature such as efficient, meet the environmental requirement of the mankind to environmental problem and VOC emission control, be world's coating industry and the accreditation of most administration, be widely used in the field that woodenware, paper, plastics, metal etc. are different.
Domestic a lot of coating producer is proposed UV photo-cured coating, some patent of invention discloses the UV-light carpentry matt varnish without remaining irritating smell after solidification, clean taste problem after solving paint solidification, but not solving UV dull finishing coat coating, to there is the wettability of matting agent poor, mobility is bad, and after coated solidified, hardness of paint film soft wear resisting property difference and paint film such as easily to grow dim at the drawback problem.Some patents of invention are also had to disclose clean taste, wear-resisting UV photo-cured coating technology, but the varnish colour of its just UV solidification related to, and do not belong to UV dull finishing coat coating category.
In existing patented invention, mention clean taste, the technology of wear-resisting UV coating has a lot, but relate to clean taste, patent that is wear-resisting, the sliding UV dull finishing coat coating aspect of silk does not also have, the clean taste that the wear-resisting silk of clean taste sliding UV dull finishing coat coating is run into and being worn no resistance, matting agent wettability is difficult, and the delustring difficult and paint film technical barrier such as easily to grow dim can not provide good solution.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of clean taste, UV dull finishing coat coating that wear-resisting, silk is sliding.This coating gloss is even, easy delustring, and paint film not easily grows dim, and feel silk is sliding.
Another object of the present invention is to provide the preparation method of the wear-resisting silk of above-mentioned clean taste sliding UV dull finishing coat coating.
Technical problem to be solved by this invention is achieved by the following technical programs:
The wear-resisting silk of a kind of clean taste sliding UV dull finishing coat coating, is made up of the component of following weight percent:
Six functionality urethane acrylate class prepolymers 25 ~ 50%;
Three-functionality-degree modified urethane acrylate class prepolymer 15 ~ 50%;
Acrylic ester monomer 15 ~ 50%;
Light trigger 1 ~ 10%;
Wetting dispersing agent 0.2 ~ 2%;
Flow agent 0.2 ~ 1%;
Defoamer 0.2 ~ 0.5%;
Matting agent 1 ~ 15%.
Six functionality urethane acrylate class prepolymers selected by the present invention can provide high speed of response, hardness, wear resisting property and materialization excellent, for paint film provides good rigidity, are preferably Changxing 6145-100, the models such as Baeyer U400.The three-functionality-degree modified urethane acrylate class prepolymer selected has that snappiness is high, sticking power good, easy delustring, the features such as the arrangement of wettability good, mute powder is good, well wetting and alignment can be played to matting agent in system, prevent paint film from growing dim, and good extinction effect can be issued in the situation of adding less matting agent, six functionality urethane acrylate class prepolymers of arranging in pairs or groups use together, good sticking power can be provided, prevent paint film really up to the mark, excessively crisp, be preferably vast and boundless brightness MP5130 model.
Further, described acrylic ester monomer is the mixture of esters of acrylic acid difunctionality monomer and esters of acrylic acid three-functionality-degree monomer.Esters of acrylic acid difunctionality monomer is tri (propylene glycol) diacrylate (TPGDA), has the features such as low viscosity, low volatilization, snappiness be good, preferred Changxing EM223-TF model.Esters of acrylic acid three-functionality-degree monomer is Viscoat 295 (TMPTA), has that wear resistance is good, hyperergy and feature, a preferred Changxing EM231-TF such as high crosslink density, high gloss and hardness is good.
Further, described light trigger is 2-hydroxy-2-methyl-1-phenyl-acetone, and 2-hydroxy-2-methyl-1-phenyl-acetone has the features such as high-level efficiency, non yellowing, low smell, color inhibition, color stability are good, preferably day chemistry JRCure1103 model for a long time.
Further, described wetting dispersing agent is at least one, the modified polyurethane superpolymer of preferred EFKA4010 and the acrylic acid copolymer soln of BYK2009 model in modified polyurethane superpolymer and acrylic acid copolymer soln.
Further, described flow agent is at least one, many acrylate-functional groups modified dimethyl polysiloxane solution of preferred BYK3576 model and the fluorine-carbon modified polyacrylic acid of EFKA3777 model in modified polyorganosiloxane copolyether and fluorine-carbon modified polyacrylic ester.
Further, described defoamer is not containing organosilyl broken bubble polymeric blends, preferred BYK1790 model.
Further, described matting agent is the silicon-dioxide of surface through special organism process, preferred GRACERAD2105, RAD2105 and Degussa OK500 model.
A preparation method for the wear-resisting silk of clean taste as above sliding UV dull finishing coat coating, comprises the following steps:
(1) join in reactor by six functionality urethane acrylate class prepolymers, three-functionality-degree modified urethane acrylate class prepolymer and acrylic ester monomer, by stirrer stirring at low speed 5 minutes, rotating speed was 500 ~ 600 revs/min;
(2), after stirring 5 minutes, add light trigger, proceed stirring at low speed, churning time 5 minutes, rotating speed is 500 ~ 600 revs/min;
(3), after stirring 5 minutes, by wetting dispersing agent, flow agent and defoamer add in reactor, carry out moderate-speed mixer, churning time 25 minutes, and rotating speed is 800 ~ 1000 revs/min;
(4) finally add matting agent while stirring, adjustment stirring velocity is 1200 ~ 1500 revs/min, stirs 30 minutes;
(5) after all formula materials added are uniformly dispersed, products obtained therefrom is the wear-resisting silk of clean taste sliding UV dull finishing coat coating, carries out being packaged to be the wear-resisting silk of the clean taste of finished product sliding UV dull finishing coat coating after detection.
The present invention has following beneficial effect:
Compared with prior art, six functionality urethane acrylate class prepolymers of the wear-resisting silk of the clean taste of the present invention sliding UV dull finishing coat coating selection and three-functionality-degree modified urethane acrylate class prepolymer, the resin that inherently clean taste is wear-resisting, acrylic ester monomer aspect is also wear-resisting clean taste monomer.The light trigger 2-hydroxy-2-methyl-1-phenyl-acetone selected also is low smell type, and the problem that after solving solidification very well, irritating smell remains, reaches clean taste effect.UV dull finishing coat coating Odor Evaluations progression scope is 0 ~ 5, product of the present invention, and it is 1 grade that oder levels evaluates progression, and evaluate progression on the low side, clean taste is effective.
The wetting dispersing agent selected, flow agent and defoamer can be well compatible with system, and effect that is wetting and dispersion can be played to the UV dull finishing coat coating system containing matting agent, the stability in use of raising system and the wettability to base material, improve coat film flatness, there is provided feel silk sliding, do not affect recoat performance; Select surface through the matting agent of special organism process simultaneously, have that oil number is little, transparency good, anti-settling performance is good, the feature of good dispersity, the common matting agent wettability solving UV dull finishing coat coating is difficult, the problem that the difficult and paint film of delustring easily grows dim.
In addition, the step that preparation method of the present invention describes compared with prior art, solve the problem of the matting agent wettability difficulty of UV dull finishing coat coating, preparation method of the present invention plays well wetting and dissemination to matting agent, has good reference to the preparation of UV dull finishing coat coating.
Embodiment
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, is not limitation of the invention.
Embodiment 1 ~ 4 is four preferred implementations of the present invention:
For embodiment 1, the preparation method of the wear-resisting silk of a kind of clean taste of product of the present invention sliding UV dull finishing coat coating is described.
Preparation process is as follows:
(1) six functionality urethane acrylate class prepolymers of formulation weight, three-functionality-degree modified urethane acrylate class prepolymer, tri (propylene glycol) diacrylate (TPGDA) and Viscoat 295 (TMPTA) are joined in reactor, by stirrer stirring at low speed 5 minutes, rotating speed was 500 ~ 600 revs/min;
(2), after stirring 5 minutes, add 2-hydroxy-2-methyl-1-phenyl-acetone (1173), proceed stirring at low speed, churning time 5 minutes, rotating speed is 500 ~ 600 revs/min;
(3), after stirring 5 minutes, by wetting dispersing agent BYK2009, flow agent BYK3576 and defoamer BYK1790 adds in reactor, carries out moderate-speed mixer, churning time 25 minutes, and rotating speed is 800 ~ 1000 revs/min;
(4) finally add matting agent GRACERAD2105 while stirring, adjustment stirring velocity is 1200 ~ 1500 revs/min, stirs 30 minutes;
(5) add after all formula materials are uniformly dispersed, products obtained therefrom is the wear-resisting silk of clean taste sliding UV dull finishing coat coating, carries out being packaged to be the wear-resisting silk of the clean taste of finished product sliding UV dull finishing coat coating after detection.
By above-described embodiment 1,2,3,4 gained model, according to UV-light (UV) woodwork coating related detecting method, carry out performance test, test record is as follows:
1, detection method:
(1) examination criteria: HG/T3655-2012;
(2) oder levels: 60 DEG C of constant temperature 30min, evaluates oder levels, and evaluating progression scope is 0 ~ 5, and numerical value is less, represents that smell is lower.
2, detected result: the Product checking of embodiment 1,2,3,4 the results are shown in following table
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Solid content | 98% | 98% | 98% | 98% |
| Fineness/um | ≤15um | ≤15um | ≤15um | ≤15um |
| Gloss (60 DEG C) | 23-24 | 20-21 | 17-19 | 17-19 |
| Snappiness | 2mm | 2mm | 2mm | 2mm |
| Sticking power (drawing hundred lattice)/level | 1 grade | 1 grade | 1 grade | 1 grade |
| Pencil hardness (scratch) | 3H | 3H | 2H-3H | 2H-3H |
| Wear resistance | 0.023 | 0.03 | 0.037 | 0.042 |
| Oder levels/level | 1 grade | 1 grade | 1 grade | 1 grade |
| Package stability ((50 ± 2) DEG C), 7d) | Without exception | Without exception | Without exception | Without exception |
| Dry heat resistance ((90 ± 2) DEG C, 15min)/level | Without exception | Without exception | Without exception | Without exception |
| Water tolerance (24h) | Without exception | Without exception | Without exception | Without exception |
| Alkali resistance (2h) | Without exception | Without exception | Without exception | Without exception |
| Alcohol resistance (8h) | Without exception | Without exception | Without exception | Without exception |
4 embodiment products of the present invention known to upper table, oder levels evaluation is 1 grade, evaluates progression on the low side, and illustrate that the wear-resisting silk of the clean taste of product of the present invention sliding UV dull finishing coat coating smell is low, clean taste is effective.Simultaneously also very excellent according to other coating correlated performances such as wear resistance, water tolerance, alkali resistance, alcohol resistance of the known product of the present invention of test result.
The above embodiment only have expressed embodiments of the present invention; it describes comparatively concrete and detailed; but therefore can not be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme adopting the form of equivalent replacement or equivalent transformation to obtain, all should drop within protection scope of the present invention.
Claims (10)
1. the wear-resisting silk of a clean taste sliding UV dull finishing coat coating, is characterized in that, be made up of the component of following weight percent:
Six functionality urethane acrylate class prepolymers 25 ~ 50%;
Three-functionality-degree modified urethane acrylate class prepolymer 15 ~ 50%;
Acrylic ester monomer 15 ~ 50%;
Light trigger 1 ~ 10%;
Wetting dispersing agent 0.2 ~ 2%;
Flow agent 0.2 ~ 1%;
Defoamer 0.2 ~ 0.5%;
Matting agent 1 ~ 15%.
2. the wear-resisting silk of clean taste according to claim 1 sliding UV dull finishing coat coating, is characterized in that: described acrylic ester monomer is the mixture of difunctionality acrylic ester monomer and three-functionality-degree acrylic ester monomer.
3. the wear-resisting silk of clean taste according to claim 2 sliding UV dull finishing coat coating, is characterized in that: described difunctionality acrylic ester monomer is tri (propylene glycol) diacrylate.
4. the wear-resisting silk of clean taste according to claim 2 sliding UV dull finishing coat coating, is characterized in that: described three-functionality-degree acrylic ester monomer is Viscoat 295.
5. the wear-resisting silk of clean taste according to claim 1 sliding UV dull finishing coat coating, is characterized in that: described light trigger is 2-hydroxy-2-methyl-1-phenyl-acetone.
6. the wear-resisting silk of clean taste according to claim 1 sliding UV dull finishing coat coating, is characterized in that: described wetting dispersing agent is at least one in modified polyurethane superpolymer and acrylic acid copolymer soln.
7. the wear-resisting silk of clean taste according to claim 1 sliding UV dull finishing coat coating, is characterized in that: described flow agent is at least one in modified polyorganosiloxane copolyether and fluorine-carbon modified polyacrylic ester.
8. the wear-resisting silk of clean taste according to claim 1 sliding UV dull finishing coat coating, is characterized in that: described defoamer is not for containing organosilyl broken bubble polymeric blends.
9. the wear-resisting silk of clean taste according to claim 1 sliding UV dull finishing coat coating, is characterized in that: described matting agent is the silicon-dioxide of surface through special organism process.
10. prepare a preparation method for the wear-resisting silk of the clean taste sliding UV dull finishing coat coating in claim 1 ~ 9 described in any one, it is characterized in that, preparation process is as follows:
(1) join in reactor by six functionality urethane acrylate class prepolymers, three-functionality-degree modified urethane acrylate class prepolymer and acrylic ester monomer, by stirrer stirring at low speed 5 minutes, rotating speed was 500 ~ 600 revs/min;
(2), after stirring 5 minutes, add light trigger, proceed stirring at low speed, churning time 5 minutes, rotating speed is 500 ~ 600 revs/min;
(3), after stirring 5 minutes, by wetting dispersing agent, flow agent and defoamer add in reactor, carry out moderate-speed mixer, churning time 25 minutes, and rotating speed is 800 ~ 1000 revs/min;
(4) finally add matting agent while stirring, adjustment stirring velocity is 1200 ~ 1500 revs/min, stirs 30 minutes;
(5) after all formula materials added are uniformly dispersed, products obtained therefrom is the wear-resisting silk of clean taste sliding UV dull finishing coat coating, carries out being packaged to be the wear-resisting silk of the clean taste of finished product sliding UV dull finishing coat coating after detection.
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| CN201510988077.9A CN105505092A (en) | 2015-12-25 | 2015-12-25 | Odorless and wear-resisting smooth UV (ultraviolet) matt finish paint coating and preparation method thereof |
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| CN201510988077.9A CN105505092A (en) | 2015-12-25 | 2015-12-25 | Odorless and wear-resisting smooth UV (ultraviolet) matt finish paint coating and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105936804A (en) * | 2016-06-03 | 2016-09-14 | 江门市国美化工有限公司 | UV wood original paint and preparation method thereof |
| CN106700798A (en) * | 2017-01-03 | 2017-05-24 | 大连佳秀百隆新材料股份有限公司 | Monocomponent semi-gloss finishing paint formula |
| CN107502177A (en) * | 2017-08-28 | 2017-12-22 | 天津汇仁恒通科技有限公司 | A kind of environment-friendly solidified coating containing ultraviolet initiator |
| CN109439047A (en) * | 2018-09-30 | 2019-03-08 | 广州申威新材料科技有限公司 | A kind of preparation method of high abrasion UV low luster coating and its preparation method of UV dumb light coating |
| CN109666396A (en) * | 2019-01-15 | 2019-04-23 | 张聪聪 | Novel water-based low-gloss ultraviolet curing coating and preparation and use methods thereof |
| CN109926291A (en) * | 2019-03-28 | 2019-06-25 | 湖南邦弗特新材料技术有限公司 | A kind of coating process of UV light solidifying matt film |
| CN110325604A (en) * | 2017-05-15 | 2019-10-11 | 迪睿合美国株式会社 | Floor paint composition and flooring material |
| CN110564287A (en) * | 2019-09-26 | 2019-12-13 | 江苏利田科技股份有限公司 | UV coating adhesive for textile fabric based on PUA with functionality of 6, and preparation method and application thereof |
| CN111484798A (en) * | 2020-04-08 | 2020-08-04 | 广州申威新材料科技有限公司 | Matte UV coating for white board film and preparation method thereof |
| CN113185646A (en) * | 2021-06-12 | 2021-07-30 | 湖南创瑾科技有限公司 | Conductive 3D printing material and preparation method thereof |
| CN113402968A (en) * | 2021-07-19 | 2021-09-17 | 江门市久冠松高分子材料有限公司 | Development method of novel UV ultraviolet curing skin-feel coating |
| CN113845835A (en) * | 2021-09-16 | 2021-12-28 | 湖南松井新材料股份有限公司 | Coating and preparation method and application thereof |
| CN114806388A (en) * | 2022-04-13 | 2022-07-29 | 佳化化学科技发展（上海）有限公司 | Ultraviolet-curing matte coating and preparation method and product thereof |
| CN116694225A (en) * | 2023-06-20 | 2023-09-05 | 恒昌涂料（惠阳）有限公司 | Excimer curing skin-dumb clear finishing paint and preparation method thereof |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105936804A (en) * | 2016-06-03 | 2016-09-14 | 江门市国美化工有限公司 | UV wood original paint and preparation method thereof |
| CN106700798A (en) * | 2017-01-03 | 2017-05-24 | 大连佳秀百隆新材料股份有限公司 | Monocomponent semi-gloss finishing paint formula |
| CN110325604B (en) * | 2017-05-15 | 2021-09-07 | 迪睿合美国株式会社 | Floor coating composition and flooring material |
| CN110325604A (en) * | 2017-05-15 | 2019-10-11 | 迪睿合美国株式会社 | Floor paint composition and flooring material |
| CN107502177A (en) * | 2017-08-28 | 2017-12-22 | 天津汇仁恒通科技有限公司 | A kind of environment-friendly solidified coating containing ultraviolet initiator |
| CN109439047A (en) * | 2018-09-30 | 2019-03-08 | 广州申威新材料科技有限公司 | A kind of preparation method of high abrasion UV low luster coating and its preparation method of UV dumb light coating |
| CN109666396A (en) * | 2019-01-15 | 2019-04-23 | 张聪聪 | Novel water-based low-gloss ultraviolet curing coating and preparation and use methods thereof |
| CN109926291A (en) * | 2019-03-28 | 2019-06-25 | 湖南邦弗特新材料技术有限公司 | A kind of coating process of UV light solidifying matt film |
| CN110564287A (en) * | 2019-09-26 | 2019-12-13 | 江苏利田科技股份有限公司 | UV coating adhesive for textile fabric based on PUA with functionality of 6, and preparation method and application thereof |
| CN110564287B (en) * | 2019-09-26 | 2022-01-14 | 江苏利田科技股份有限公司 | UV coating adhesive for textile fabric based on PUA with functionality of 6, and preparation method and application thereof |
| CN111484798A (en) * | 2020-04-08 | 2020-08-04 | 广州申威新材料科技有限公司 | Matte UV coating for white board film and preparation method thereof |
| CN111484798B (en) * | 2020-04-08 | 2022-06-03 | 广州申威新材料科技有限公司 | Matte UV coating for white board film and preparation method thereof |
| CN113185646A (en) * | 2021-06-12 | 2021-07-30 | 湖南创瑾科技有限公司 | Conductive 3D printing material and preparation method thereof |
| CN113402968A (en) * | 2021-07-19 | 2021-09-17 | 江门市久冠松高分子材料有限公司 | Development method of novel UV ultraviolet curing skin-feel coating |
| CN113845835A (en) * | 2021-09-16 | 2021-12-28 | 湖南松井新材料股份有限公司 | Coating and preparation method and application thereof |
| CN113845835B (en) * | 2021-09-16 | 2022-08-09 | 湖南松井新材料股份有限公司 | Coating and preparation method and application thereof |
| CN114806388A (en) * | 2022-04-13 | 2022-07-29 | 佳化化学科技发展（上海）有限公司 | Ultraviolet-curing matte coating and preparation method and product thereof |
| CN116694225A (en) * | 2023-06-20 | 2023-09-05 | 恒昌涂料（惠阳）有限公司 | Excimer curing skin-dumb clear finishing paint and preparation method thereof |
| CN116694225B (en) * | 2023-06-20 | 2024-05-03 | 恒昌涂料（惠阳）有限公司 | Excimer curing skin-dumb clear finishing paint and preparation method thereof |
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