CN105504880A - Gamma-chloropropyl triethoxysilane auxiliary agent - Google Patents

Gamma-chloropropyl triethoxysilane auxiliary agent Download PDF

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Publication number
CN105504880A
CN105504880A CN201510861273.XA CN201510861273A CN105504880A CN 105504880 A CN105504880 A CN 105504880A CN 201510861273 A CN201510861273 A CN 201510861273A CN 105504880 A CN105504880 A CN 105504880A
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CN
China
Prior art keywords
parts
chloropropyl triethoxysilane
auxiliary agent
ethanol
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510861273.XA
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Chinese (zh)
Inventor
廖煜明
杨毅
李伟强
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Individual
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Individual
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Priority to CN201510861273.XA priority Critical patent/CN105504880A/en
Publication of CN105504880A publication Critical patent/CN105504880A/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/021—Calcium carbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds

Abstract

The invention provides a gamma-chloropropyl triethoxysilane auxiliary agent. The auxiliary agent comprises the following components: 15-28 parts of gamma-chloropropyl triethoxysilane, 5-6 parts of 3-(2-aminoethylamino)propyl-dimethoxymethylsilane, 5-8 parts of dipropylene glycol mono-n-butyl ether, 3-8 parts of pentaerythrite colophony europium resin, 25-30 parts of coconut diethanolamide, 5-8 parts of sodium carbonate, 3-5 parts of poly[(sodium acrylate)-co-(4-vinylpyridine)], 10-12 parts of di-n-octyltin oxide, 3-5 parts polyvinyl acetal resin, 3-5 parts of benzyldodecyldimethylammonium bromide, 20-30 parts of ethanol, and 350-400 parts of water. The auxiliary agent has the advantages of easily available raw materials, low cost, substantial effects, etc.

Description

γ-chloropropyl triethoxysilane auxiliary agent
Technical field
The invention belongs to a kind of functional agent producing non-metallic powder.
Background technology
At present, calcium carbonate is widely used in papermaking, plastics, plastics film, chemical fibre, rubber, tackiness agent, sealing agent, daily-use chemical industry, makeup, building materials, coating, paint, ink, putty, sealing wax, putty, carpet veneer is packed, medicine, food is (as chewing gum, chocolate), in feed, its effect has: increase small product size, reduce costs, improve processing characteristics (as adjusting viscosity, rheological property, curability), improve dimensional stability, reinforcement or half reinforcement, improve printing performance, improve physicals (as thermotolerance, extinction, wear resistance, flame retardant resistance, whiteness, glossiness) etc., for obtaining more superior performance, auxiliary agent is all adopted to carry out activation treatment.
Summary of the invention
The object of the invention is to; A kind of γ-chloropropyl triethoxysilane auxiliary agent and preparation method thereof is proposed.
γ of the present invention-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 15-28 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 350-400 part forms.
The preparation method of γ of the present invention-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 15-28 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 350-400 part forms, first with ethanol by rosin europium resin dissolves, after adding water 350-400 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
The present invention compared with prior art its beneficial effect is: have design science reasonable, and technique is simple, safe reliability, is easy to control, easy to operate, is applicable to scale operation, the advantages such as production cost is low.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited thereto.
All raw materials of the present invention can buy acquisition.
Embodiment 1, the preparation of γ of the present invention-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 15-28 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 350-400 part forms, first with ethanol by rosin europium resin dissolves, after adding water 350-400 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 2, the preparation of γ of the present invention-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 15 parts, aminoethyl third aminopropyltriethoxy methoxy silane 5 parts, Dipropylene glycol mono-n-butyl Ether 5 parts, rosin pentaerythritol ester europium resin 3 parts, cocoanut fatty acid diethanolamide 25 parts, 5 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 3 parts, di-n-octyltin oxide 10 parts, polyvinyl acetal resin 3 parts, dodecyl dimethyl benzyl ammonium bromide 3 parts, ethanol 20-30 part, water 350-400 part forms, first with ethanol by rosin europium resin dissolves, after adding water 350-400 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 3, the preparation of γ of the present invention-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 28 parts, aminoethyl third aminopropyltriethoxy methoxy silane 6 parts, Dipropylene glycol mono-n-butyl Ether 8 parts, rosin pentaerythritol ester europium resin 8 parts, cocoanut fatty acid diethanolamide 30 parts, 8 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 5 parts, di-n-octyltin oxide 12 parts, polyvinyl acetal resin 5 parts, dodecyl dimethyl benzyl ammonium bromide 5 parts, ethanol 20-30 part, water 350-400 part forms, first with ethanol by rosin europium resin dissolves, after adding water 350-400 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 4, the preparation of γ of the present invention-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 28 parts, aminoethyl third aminopropyltriethoxy methoxy silane 5 parts, Dipropylene glycol mono-n-butyl Ether 8 parts, rosin pentaerythritol ester europium resin 3 parts, cocoanut fatty acid diethanolamide 30 parts, 5 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 5 parts, di-n-octyltin oxide 10 parts, polyvinyl acetal resin 5 parts, dodecyl dimethyl benzyl ammonium bromide 3 parts, ethanol 20-30 part, water 350-400 part forms, first with ethanol by rosin europium resin dissolves, after adding water 350-400 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Product of the present invention, uses through production firm, and produce modified superfine water-ground limestone functional product, reaction effect is fine.
Part material illustrates:
1, described rosin pentaerythritol ester europium resin, the method that can be preferably ZL201410078259.8 by the Chinese patent patent No. obtains.
2, aminoethyl third aminopropyltriethoxy methoxy silane, embodiment Nanjing Xu Yang Chemical Co., Ltd. product, trade(brand)name: precoated sand highly efficient intensifying agent silicon XY-812.
3, γ-chloropropyl triethoxysilane, molecular formula: C 9h 21clO 3si.

Claims (2)

1. γ-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 15-28 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 350-400 part forms.
2. the preparation method of γ-chloropropyl triethoxysilane auxiliary agent, it is characterized in that: by weight, its formula is by γ-chloropropyl triethoxysilane 15-28 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 350-400 part forms, first with ethanol by rosin europium resin dissolves, after adding water 350-400 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
CN201510861273.XA 2015-11-26 2015-11-26 Gamma-chloropropyl triethoxysilane auxiliary agent Pending CN105504880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510861273.XA CN105504880A (en) 2015-11-26 2015-11-26 Gamma-chloropropyl triethoxysilane auxiliary agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510861273.XA CN105504880A (en) 2015-11-26 2015-11-26 Gamma-chloropropyl triethoxysilane auxiliary agent

Publications (1)

Publication Number Publication Date
CN105504880A true CN105504880A (en) 2016-04-20

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Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101883485A (en) * 2007-10-02 2010-11-10 世界矿物公司 Enhanced retention capabilities through methods comprising surface treatment of functional particulate carrier materials, and functional particulate carrier materials made therefrom
CN101987927A (en) * 2009-08-05 2011-03-23 任绍志 Method for preparing modified nano-silica from polysilane
CN102911441A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 High-temperature-resistant moisture-proof mould-proof environment-friendly cable material and preparation method thereof
CN103045106A (en) * 2012-12-12 2013-04-17 滁州市鑫彩印务有限公司 Adhesive containing modified PVC (polyvinyl chloride) resin for packaging materials
CN103059721A (en) * 2012-12-18 2013-04-24 芜湖恒坤汽车部件有限公司 Metal surface silicane treating agent containing polyethylene glycol and preparing method thereof
CN103088327A (en) * 2012-12-18 2013-05-08 芜湖恒坤汽车部件有限公司 Metal surface silane treatment agent containing water-soluble phenolic resin and preparation method thereof
CN103102724A (en) * 2012-12-18 2013-05-15 芜湖恒坤汽车部件有限公司 Metal surface silane treating agent containing acrylic acid and preparation method of metal surface silane treating agent
CN103131374A (en) * 2013-03-21 2013-06-05 黑龙江省科学院石油化学研究院 Inorganic/organic nano particle compound modification epoxy resin adhesive and preparation method thereof
CN103173140A (en) * 2013-02-26 2013-06-26 安徽明珠颜料科技有限公司 Neoprene adhesive for woodworking
CN103820032A (en) * 2014-03-05 2014-05-28 张雅静 Preparation method of pentaerythrite colophony europium resin
CN103923593A (en) * 2014-04-16 2014-07-16 杭州之江有机硅化工有限公司 One-component silane-modified polyurethane sealant and preparation method thereof
CN104371376A (en) * 2014-10-31 2015-02-25 陈显鹏 Glycidol ether superfine calcium carbonate powder assistant
CN104403367A (en) * 2014-10-31 2015-03-11 廖文成 Calcium carbonate gamma-aminopropyl triethoxy silane modifier
CN104403266A (en) * 2014-10-31 2015-03-11 廖文成 Amino resin-containing calcium carbonate powder modifier
CN104403246A (en) * 2014-10-31 2015-03-11 廖文成 Ultrafine calcium carbonate powder acetal modifier
CN104479412A (en) * 2014-11-26 2015-04-01 甘振辉 Preparation method of polydimethyl siloxane ground limestone superfine powder

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101883485A (en) * 2007-10-02 2010-11-10 世界矿物公司 Enhanced retention capabilities through methods comprising surface treatment of functional particulate carrier materials, and functional particulate carrier materials made therefrom
CN101987927A (en) * 2009-08-05 2011-03-23 任绍志 Method for preparing modified nano-silica from polysilane
CN102911441A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 High-temperature-resistant moisture-proof mould-proof environment-friendly cable material and preparation method thereof
CN103045106A (en) * 2012-12-12 2013-04-17 滁州市鑫彩印务有限公司 Adhesive containing modified PVC (polyvinyl chloride) resin for packaging materials
CN103059721A (en) * 2012-12-18 2013-04-24 芜湖恒坤汽车部件有限公司 Metal surface silicane treating agent containing polyethylene glycol and preparing method thereof
CN103088327A (en) * 2012-12-18 2013-05-08 芜湖恒坤汽车部件有限公司 Metal surface silane treatment agent containing water-soluble phenolic resin and preparation method thereof
CN103102724A (en) * 2012-12-18 2013-05-15 芜湖恒坤汽车部件有限公司 Metal surface silane treating agent containing acrylic acid and preparation method of metal surface silane treating agent
CN103173140A (en) * 2013-02-26 2013-06-26 安徽明珠颜料科技有限公司 Neoprene adhesive for woodworking
CN103131374A (en) * 2013-03-21 2013-06-05 黑龙江省科学院石油化学研究院 Inorganic/organic nano particle compound modification epoxy resin adhesive and preparation method thereof
CN103820032A (en) * 2014-03-05 2014-05-28 张雅静 Preparation method of pentaerythrite colophony europium resin
CN103923593A (en) * 2014-04-16 2014-07-16 杭州之江有机硅化工有限公司 One-component silane-modified polyurethane sealant and preparation method thereof
CN104371376A (en) * 2014-10-31 2015-02-25 陈显鹏 Glycidol ether superfine calcium carbonate powder assistant
CN104403367A (en) * 2014-10-31 2015-03-11 廖文成 Calcium carbonate gamma-aminopropyl triethoxy silane modifier
CN104403266A (en) * 2014-10-31 2015-03-11 廖文成 Amino resin-containing calcium carbonate powder modifier
CN104403246A (en) * 2014-10-31 2015-03-11 廖文成 Ultrafine calcium carbonate powder acetal modifier
CN104479412A (en) * 2014-11-26 2015-04-01 甘振辉 Preparation method of polydimethyl siloxane ground limestone superfine powder

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Application publication date: 20160420