CN103696285B - A kind of random grain gas mold materials pigment liquid and application thereof - Google Patents
A kind of random grain gas mold materials pigment liquid and application thereof Download PDFInfo
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- CN103696285B CN103696285B CN201310663726.9A CN201310663726A CN103696285B CN 103696285 B CN103696285 B CN 103696285B CN 201310663726 A CN201310663726 A CN 201310663726A CN 103696285 B CN103696285 B CN 103696285B
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Abstract
The present invention discloses a kind of random grain gas mold materials pigment liquid, and it is made up of the component of following parts by weight: PVC paste resin 100 parts; 50 ~ 60 parts, plasticizer; Powdered whiting 10 ~ 20 parts; Fumed silica 1 ~ 5 part; Liquid barium zinc stabilizer 2 ~ 3 parts; Titanium dioxide slurry 10 ~ 30 parts; Mill base 5 ~ 20 parts; 0.5 ~ 3 part, adhesive.Random grain gas mold materials pigment liquid of the present invention, good dispersion, without vitta, weather-proof, not fugitive color, variable color; Meanwhile, after the content of pigment liquid is adjusted, not only can pigment liquid as a setting, as lines pigment liquid, can also can be used as gas mold materials pigment liquid simultaneously.Background pigment liquid of the present invention and lines pigment liquid with the use of, the gas mold materials surface color and polish contrast of preparation is high, lines are naturally clear, product surface bubble-free.
Description
Technical field
The present invention relates to a kind of pigment liquid of gas mold materials, particularly relate to a kind of random grain gas mold materials pigment liquid and application thereof.
Background technology
Gas mold materials is generally in preparation technology: with polyester fiber screen cloth for base material, polyester fiber screen cloth first floods PVC paste agent, and then at polyester fiber screen cloth surface coating background pigment liquid, synchronous coating lines pigment liquid, obtains surface for colored gas mold materials finally by drying simultaneously.
But the lines pigment liquid used at present is very easily miscible in background pigment liquid, and cause the gas mold materials surface pattern of production unintelligible, color contrast is not obvious, poor visual effect.
Summary of the invention
In order to overcome the deficiencies in the prior art, the object of the present invention is to provide that a kind of gas mold materials color contrast prepared is high, lines are naturally clear, the bubble-free random grain gas mold materials pigment liquid in surface, the invention still further relates to the application of this random grain gas mold materials pigment liquid.
Technical scheme of the present invention is: a kind of random grain gas mold materials pigment liquid, and it is made up of the component of following parts by weight:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 1 ~ 5 part;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 30 parts;
Mill base 5 ~ 20 parts;
0.5 ~ 3 part, adhesive.
Further, pigment liquid of the present invention is background pigment liquid, and described background pigment liquid is made up of the component of following parts by weight:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 1 ~ 3 part;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 30 parts;
Mill base 5 ~ 20 parts;
1 ~ 3 part, adhesive.
Further, pigment liquid of the present invention is lines pigment liquid, and described lines pigment liquid comprises following component:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 3 ~ 5 parts;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 20 parts;
Mill base 10 ~ 20 parts;
0.5 ~ 1 part, adhesive.
The present invention adopts above technical scheme, and lines pigment liquid adds aerosil in component, and increase the thixotropy of pigment paste system, pigment liquid is applied to after on gas mold materials, the interfaces transition nature of the lines color on gas mold materials surface.
Flood PVC paste agent on the surface at polyester fiber screen cloth, and then at polyester fiber screen cloth surface coating background pigment liquid, the color after polyester fiber screen cloth is stuck with paste can well be hidden, the lines pigment liquid finally applied on polyester fiber screen cloth.By the proportion design of background pigment liquid and lines pigment liquid look solubility, in background pigment liquid, titanium dioxide slurry can play good covering effect, the color contrast of background pigment liquid and lines pigment liquid is obvious, make that overall color effect is better, lines are naturally clear, the gas mold materials surface bubble-free of preparation.
Random grain gas mold materials pigment liquid of the present invention, wherein titanium dioxide slurry comprises the component of following parts by weight:
Titanium dioxide 100 parts;
Epoxidized soybean oil 0.5 ~ 1.5 part;
40 ~ 45 parts, plasticizer;
Dispersant 2 ~ 4 parts.
Titanium dioxide slurry in the present invention adopts above formula, and the dispersive property of titanium dioxide slurry is good, without white vitta, and then makes the covering efficiency of pigment liquid high.
The preparation method of described titanium dioxide slurry comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, after stirring, then add titanium dioxide, after stirring into pasty state, soak 24h ~ 48h, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm.
Random grain gas mold materials pigment liquid of the present invention, wherein, described mill base comprises the component of following parts by weight:
Toner 100 parts;
Epoxidized soybean oil 0.5 ~ 1.5 part;
90 ~ 140 parts, plasticizer;
Dispersant 1 ~ 2 part;
Ultra-violet absorber 1 ~ 3 part.
Mill base of the present invention adopts above formula, and the dispersive property of mill base is good, and the pigment liquid be made into by this mill base is coated to after on gas mold materials, makes gas mold materials weather-proof, not easy to change, fades.
Further, the preparation method of described mill base comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, ultra-violet absorber, after stirring, add toner again, after stirring into pasty state, soak more than 3 days, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm.
The adhesive that the present invention is above-mentioned mentioned is commercially available prod, buys in the meticulous coating of Si Taer (Suzhou) Co., Ltd.
The plasticizer that the present invention is above-mentioned mentioned is commercially available prod, buys in Ao Ruila Chemical Co., Ltd. of Yichuan County.
The dispersant that the present invention is above-mentioned mentioned is commercially available prod, is anion surfactant, buys in Shanghai Yong Yan Chemical Industry Science Co., Ltd.
Ultra-violet absorber of the present invention is commercially available prod, buys in Huizhou fluorescent plastic pigment Co., Ltd.
Random grain gas mold materials pigment liquid of the present invention can be used as the application of background pigment liquid.
Random grain gas mold materials pigment liquid of the present invention also can be used as the application of lines pigment liquid.Concrete is applied as: on the polyester fiber screen cloth flooding PVC paste agent, coating background pigment liquid, and adds lines pigment liquid at random during the course, after scraper is coated with and scrapes, finally sends into that oven for drying is shaping obtains the gas mold materials that surface has random grain.
Random grain gas mold materials pigment liquid of the present invention, good dispersion, without vitta, weather-proof, not fugitive color, variable color; Meanwhile, after the content of pigment liquid is adjusted, not only can pigment liquid as a setting, as lines pigment liquid, can also can be used as gas mold materials pigment liquid simultaneously.Background pigment liquid of the present invention and lines pigment liquid with the use of, the gas mold materials surface color and polish contrast of preparation is high, lines are naturally clear, product surface bubble-free.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further detailed explanation.
A kind of random grain gas of the present invention mold materials pigment liquid, it is made up of the component of following parts by weight:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 1 ~ 5 part;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 30 parts;
Mill base 5 ~ 20 parts;
0.5 ~ 3 part, adhesive.
Further, pigment liquid of the present invention is background pigment liquid, and described background pigment liquid is made up of the component of following parts by weight:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 1 ~ 3 part;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 30 parts;
Mill base 5 ~ 20 parts;
1 ~ 3 part, adhesive.
Further, pigment liquid of the present invention is lines pigment liquid, and described lines pigment liquid comprises following component:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 3 ~ 5 parts;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 20 parts;
Mill base 10 ~ 20 parts;
0.5 ~ 1 part, adhesive.
Random grain gas mold materials pigment liquid of the present invention, wherein titanium dioxide slurry comprises the component of following parts by weight:
Titanium dioxide 100 parts;
Epoxidized soybean oil 0.5 ~ 1.5 part;
40 ~ 45 parts, plasticizer;
Dispersant 2 ~ 4 parts.
The preparation method of described titanium dioxide slurry comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, after stirring, then add titanium dioxide, after stirring into pasty state, soak 24h ~ 48h, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm.
Random grain gas mold materials pigment liquid of the present invention, wherein, described mill base comprises the component of following parts by weight:
Toner 100 parts;
Epoxidized soybean oil 0.5 ~ 1.5 part;
90 ~ 140 parts, plasticizer;
Dispersant 1 ~ 2 part;
Ultra-violet absorber 1 ~ 3 part.
Further, the preparation method of described mill base comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, ultra-violet absorber, after stirring, add toner again, after stirring into pasty state, soak more than 3 days, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm.
Random grain gas mold materials pigment liquid of the present invention can be used as the application of background pigment liquid.
Random grain gas mold materials pigment liquid of the present invention also can be used as the application of lines pigment liquid.Concrete is applied as: on the polyester fiber screen cloth flooding PVC paste agent, coating background pigment liquid, and adds lines pigment liquid at random during the course, after scraper is coated with and scrapes, finally sends into that oven for drying is shaping obtains the gas mold materials that surface has random grain.
Embodiment 1
1, the raw material preparing titanium dioxide slurry is taken by following formula:
Titanium dioxide 100 parts;
Epoxidized soybean oil 0.5 part;
45 parts, plasticizer;
Dispersant 2 parts.
The preparation method of described titanium dioxide slurry comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, after stirring, then add titanium dioxide, after stirring into pasty state, soak 24h ~ 48h, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm, then for subsequent use.
2, the raw material preparing mill base is taken by following formula:
Toner 100 parts;
Epoxidized soybean oil 1.5 parts;
90 parts, plasticizer;
Dispersant 2 parts;
Ultra-violet absorber 1 part.
The preparation method of described mill base comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, ultra-violet absorber, after stirring, add toner again, after stirring into pasty state, soak more than 3 days, grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm, then for subsequent use again.
3, take the raw material of preparation background pigment liquid by following formula and be mixed to get background pigment liquid:
PVC paste resin 100 parts;
60 parts, plasticizer;
Powdered whiting 10 parts;
Fumed silica 3 parts;
Liquid barium zinc stabilizer 2 parts;
Titanium dioxide slurry 30 parts;
Mill base 5 parts;
3 parts, adhesive.
4, take by following formula the raw material of preparing lines pigment liquid and be mixed to get lines pigment liquid:
PVC paste resin 100 parts;
50 parts, plasticizer;
Powdered whiting 20 parts;
Fumed silica 3 parts;
Liquid barium zinc stabilizer 3 parts;
Titanium dioxide slurry 10 parts;
Mill base 20 parts;
0.5 part, adhesive.
5, background pigment liquid step 3 and step 4 prepared and lines pigment liquid are applied to the random grain preparing gas mold materials surface, be specially: on the polyester fiber screen cloth flooding PVC paste agent, coating background pigment liquid, and add lines pigment liquid at random during the course, after scraper is coated with and scrapes, finally send into that oven for drying is shaping obtains the gas mold materials that surface has random grain.
Embodiment 2
1, the raw material preparing titanium dioxide slurry is taken by following formula:
Titanium dioxide 100 parts;
Epoxidized soybean oil 1.5 parts;
40 parts, plasticizer;
Dispersant 4 parts.
The preparation method of described titanium dioxide slurry comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, after stirring, then add titanium dioxide, after stirring into pasty state, soak 24h ~ 48h, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm, then for subsequent use.
2, the raw material preparing mill base is taken by following formula:
Toner 100 parts;
Epoxidized soybean oil 0.5 part;
140 parts, plasticizer;
Dispersant 1 part;
Ultra-violet absorber 3 parts.
The preparation method of described mill base comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, ultra-violet absorber, after stirring, add toner again, after stirring into pasty state, soak more than 3 days, grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm, then for subsequent use again.
3, take the raw material of preparation background pigment liquid by following formula and be mixed to get background pigment liquid:
PVC paste resin 100 parts;
50 parts, plasticizer;
Powdered whiting 20 parts;
Fumed silica 1 part;
Liquid barium zinc stabilizer 3 parts;
Titanium dioxide slurry 10 parts;
Mill base 20 parts;
1 part, adhesive.
4, take by following formula the raw material of preparing lines pigment liquid and be mixed to get lines pigment liquid:
PVC paste resin 100 parts;
60 parts, plasticizer;
Powdered whiting 10 parts;
Fumed silica 5 parts;
Liquid barium zinc stabilizer 2 parts;
Titanium dioxide slurry 20 parts;
Mill base 10 parts;
1 part, adhesive.
5, background pigment liquid step 3 and step 4 prepared and lines pigment liquid are applied to the random grain preparing gas mold materials surface, be specially: on the polyester fiber screen cloth flooding PVC paste agent, coating background pigment liquid, and add lines pigment liquid at random during the course, after scraper is coated with and scrapes, finally send into that oven for drying is shaping obtains the gas mold materials that surface has random grain.
Embodiment 3
1, the raw material preparing titanium dioxide slurry is taken by following formula:
Titanium dioxide 100 parts;
Epoxidized soybean oil 1.0 parts;
42 parts, plasticizer;
Dispersant 3 parts.
The preparation method of described titanium dioxide slurry comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, after stirring, then add titanium dioxide, after stirring into pasty state, soak 24h ~ 48h, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm, then for subsequent use.
2, the raw material preparing mill base is taken by following formula:
Toner 100 parts;
Epoxidized soybean oil 1.0 parts;
120 parts, plasticizer;
Dispersant 2 parts;
Ultra-violet absorber 2 parts.
The preparation method of described mill base comprises the following steps: first add in plasticizer by dispersant, epoxidized soybean oil, ultra-violet absorber, after stirring, add toner again, after stirring into pasty state, soak more than 3 days, grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm, then for subsequent use again.
3, take the raw material of preparation background pigment liquid by following formula and be mixed to get background pigment liquid:
PVC paste resin 100 parts;
55 parts, plasticizer;
Powdered whiting 15 parts;
Fumed silica 2 parts;
Liquid barium zinc stabilizer 3 parts;
Titanium dioxide slurry 20 parts;
Mill base 10 parts;
2 parts, adhesive.
4, take by following formula the raw material of preparing lines pigment liquid and be mixed to get lines pigment liquid:
PVC paste resin 100 parts;
50 parts, plasticizer;
Powdered whiting 15 parts;
Fumed silica 4 parts;
Liquid barium zinc stabilizer 3 parts;
Titanium dioxide slurry 15 parts;
Mill base 15 parts;
0.7 part, adhesive.
5, background pigment liquid step 3 and step 4 prepared and lines pigment liquid are applied to the random grain preparing gas mold materials surface, be specially: on the polyester fiber screen cloth flooding PVC paste agent, coating background pigment liquid, and add lines pigment liquid at random during the course, after scraper is coated with and scrapes, finally send into that oven for drying is shaping obtains the gas mold materials that surface has random grain.
Claims (7)
1. a random grain gas mold materials pigment liquid, is characterized in that: it is made up of the component of following parts by weight:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 1 ~ 5 part;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 30 parts;
Mill base 5 ~ 20 parts;
0.5 ~ 3 part, adhesive;
Described titanium dioxide slurry comprises the component of following parts by weight: titanium dioxide 100 parts, epoxidized soybean oil 0.5 ~ 1.5 part, 40 ~ 45 parts, plasticizer, dispersant 2 ~ 4 parts; Described mill base comprises the component of following parts by weight: toner 100 parts, epoxidized soybean oil 0.5 ~ 1.5 part, 90 ~ 140 parts, plasticizer, dispersant 1 ~ 2 part, ultra-violet absorber 1 ~ 3 part.
2. random grain gas mold materials pigment liquid according to claim 1, it is characterized in that: described pigment liquid is background pigment liquid, described background pigment liquid is made up of the component of following parts by weight:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 1 ~ 3 part;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 30 parts;
Mill base 5 ~ 20 parts;
1 ~ 3 part, adhesive;
Described titanium dioxide slurry comprises the component of following parts by weight: titanium dioxide 100 parts, epoxidized soybean oil 0.5 ~ 1.5 part, 40 ~ 45 parts, plasticizer, dispersant 2 ~ 4 parts; Described mill base comprises the component of following parts by weight: toner 100 parts, epoxidized soybean oil 0.5 ~ 1.5 part, 90 ~ 140 parts, plasticizer, dispersant 1 ~ 2 part, ultra-violet absorber 1 ~ 3 part.
3. random grain gas mold materials pigment liquid according to claim 1, it is characterized in that: described pigment liquid is lines pigment liquid, described lines pigment liquid is made up of the component of following parts by weight:
PVC paste resin 100 parts;
50 ~ 60 parts, plasticizer;
Powdered whiting 10 ~ 20 parts;
Fumed silica 3 ~ 5 parts;
Liquid barium zinc stabilizer 2 ~ 3 parts;
Titanium dioxide slurry 10 ~ 20 parts;
Mill base 10 ~ 20 parts;
0.5 ~ 1 part, adhesive;
Described titanium dioxide slurry comprises the component of following parts by weight: titanium dioxide 100 parts, epoxidized soybean oil 0.5 ~ 1.5 part, 40 ~ 45 parts, plasticizer, dispersant 2 ~ 4 parts; Described mill base comprises the component of following parts by weight: toner 100 parts, epoxidized soybean oil 0.5 ~ 1.5 part, 90 ~ 140 parts, plasticizer, dispersant 1 ~ 2 part, ultra-violet absorber 1 ~ 3 part.
4. according to the random grain gas mold materials pigment liquid one of claim 1-3 Suo Shu, it is characterized in that: the preparation method of described titanium dioxide slurry comprises the following steps: first dispersant, epoxidized soybean oil are added in plasticizer, after stirring, add titanium dioxide again, after stirring into pasty state, soak 24h ~ 48h, then grind on three-roll grinder, fineness of grind is 20 ~ 25 μm.
5. according to the random grain gas mold materials pigment liquid one of claim 1-3 Suo Shu, it is characterized in that: the preparation method of described mill base comprises the following steps: first dispersant, epoxidized soybean oil, ultra-violet absorber are added in plasticizer, after stirring, add toner again, after stirring into pasty state, soak more than 3 days, then grind on three-roll grinder, fineness of grind is at 20 ~ 25 μm.
6. the application of a random grain gas mold materials pigment liquid as claimed in claim 2 pigment liquid as a setting.
7. a random grain gas mold materials pigment liquid as claimed in claim 3 is as the application of lines pigment liquid.
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| CN104449001B (en) * | 2014-12-18 | 2016-01-20 | 南阳理工学院 | Chinese painting color liquid |
| CN108034162A (en) * | 2017-11-27 | 2018-05-15 | 广德粤华塑业制品有限公司 | A kind of PVC environmental protection organic color |
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| CN101509203A (en) * | 2008-12-30 | 2009-08-19 | 福建思嘉环保材料科技有限公司 | Production process for high-strength dacron laminated film construction material |
| CN102632671A (en) * | 2012-05-09 | 2012-08-15 | 福建思嘉环保材料科技有限公司 | Novel waterproof membrane material with patterns and preparation method thereof |
| CN102926199A (en) * | 2012-11-28 | 2013-02-13 | 福建思嘉环保材料科技有限公司 | PVC (polyvinyl chloride) coated fabric paste and preparation method thereof |
| CN103240939A (en) * | 2013-04-25 | 2013-08-14 | 福建思嘉环保材料科技有限公司 | Anti-sticking gas mould material and preparation method thereof |
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| JP5461098B2 (en) * | 2009-08-05 | 2014-04-02 | 本多産業株式会社 | Multi-layer sheet, endless belt and method for producing the same |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101509203A (en) * | 2008-12-30 | 2009-08-19 | 福建思嘉环保材料科技有限公司 | Production process for high-strength dacron laminated film construction material |
| CN102632671A (en) * | 2012-05-09 | 2012-08-15 | 福建思嘉环保材料科技有限公司 | Novel waterproof membrane material with patterns and preparation method thereof |
| CN102926199A (en) * | 2012-11-28 | 2013-02-13 | 福建思嘉环保材料科技有限公司 | PVC (polyvinyl chloride) coated fabric paste and preparation method thereof |
| CN103240939A (en) * | 2013-04-25 | 2013-08-14 | 福建思嘉环保材料科技有限公司 | Anti-sticking gas mould material and preparation method thereof |
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