CN105368093A - Isopropyl tri(dioctyl acyloxy phosphate) titanate non-metal powder activator - Google Patents
Isopropyl tri(dioctyl acyloxy phosphate) titanate non-metal powder activator Download PDFInfo
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- CN105368093A CN105368093A CN201510860642.3A CN201510860642A CN105368093A CN 105368093 A CN105368093 A CN 105368093A CN 201510860642 A CN201510860642 A CN 201510860642A CN 105368093 A CN105368093 A CN 105368093A
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Abstract
The invention relates to an isopropyl tri(dioctyl acyloxy phosphate) titanate non-metal powder activator which is composed of 5-8 parts of isopropyl tri(dioctyl acyloxy phosphate) titanate, 5-6 parts of aminoethyl propyl aminopropyl methyl methoxyl saline, 5-8 parts of dipropylene glycol monobutyl ether, 3-8 parts of pentaerythritol rosin europium resin, 25-30 parts of cocoanut fatty acid diethanolamide, 5-8 parts of sodium carbonate, 3-5 parts of a sodium acrylate-4-vinyl pyridine copolymer, 5-6 parts of glycerol triacetate, 10-12 parts of di-n-octyltin oxide, 3-5 parts of polyvinyl acetal resin, 25-30 parts of gamma-glycidoxypropyltrimethoxysilane, 3-5 parts of dodecyl dimethyl benzyl ammonium bromide, 20-30 parts of ethanol and 550-600 parts of water. The activator has the advantages of being scientific and reasonable in design, simple in process, safe, reliable, easy to control, convenient to operate, suitable for production on a large scale, low in production cost and the like.
Description
Technical field
The invention belongs to a kind of functional agent producing non-metallic powder.
Background technology
At present, calcium carbonate is widely used in papermaking, plastics, plastics film, chemical fibre, rubber, tackiness agent, sealing agent, daily-use chemical industry, makeup, building materials, coating, paint, ink, putty, sealing wax, putty, carpet veneer is packed, medicine, food is (as chewing gum, chocolate), in feed, its effect has: increase small product size, reduce costs, improve processing characteristics (as adjusting viscosity, rheological property, curability), improve dimensional stability, reinforcement or half reinforcement, improve printing performance, improve physicals (as thermotolerance, extinction, wear resistance, flame retardant resistance, whiteness, glossiness) etc., for obtaining more superior performance, auxiliary agent is all adopted to carry out activation treatment.
Summary of the invention
The object of the invention is to; A kind of sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator its preparation method is proposed.
Sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator of the present invention, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms.
The preparation method of sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator of the present invention, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
The present invention compared with prior art its beneficial effect is: have design science reasonable, and technique is simple, safe reliability, is easy to control, easy to operate, is applicable to scale operation, the advantages such as production cost is low.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited thereto.
All raw materials of the present invention can buy acquisition.
Embodiment 1, the preparation of sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator of the present invention, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 2, the preparation of sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator of the present invention, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3 parts, cocoanut fatty acid diethanolamide 25 parts, 5 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 3 parts, Vanay 5 parts, dioctyl tin 10 parts, polyvinyl acetal resin 3 parts, glycidyl ether oxygen propyl trimethoxy silicane 25 parts, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 3, the preparation of sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator of the present invention, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 8 parts, cocoanut fatty acid diethanolamide 30 parts, 8 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 5 parts, Vanay 6 parts, dioctyl tin 12 parts, polyvinyl acetal resin 5 parts, glycidyl ether oxygen propyl trimethoxy silicane 30 parts, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 4, the preparation of sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator of the present invention, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3 parts, cocoanut fatty acid diethanolamide 30 parts, 5 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 5 parts, Vanay 5 parts, dioctyl tin 12 parts, polyvinyl acetal resin 3 parts, glycidyl ether oxygen propyl trimethoxy silicane 25 parts, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Product of the present invention, uses through production firm, and produce modified superfine water-ground limestone functional product, reaction effect is fine.
Part material illustrates:
1, described rosin pentaerythritol ester europium resin, the method that can be preferably ZL201410078259.8 by the Chinese patent patent No. obtains.
2, aminoethyl third aminopropyltriethoxy methoxy silane, embodiment Nanjing Xu Yang Chemical Co., Ltd. product, trade(brand)name: precoated sand highly efficient intensifying agent silicon XY-812.
3, γ-glycidyl ether oxygen propyl trimethoxy silicane molecular formula: C
9h
2oO
5si
4, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, molecular formula: C
51h
109o
13p
3ti.
Claims (2)
1. sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms.
2. the preparation method of sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester non-metallic powder activator, it is characterized in that: by weight, its formula is by sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester 5-8 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10-12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510860642.3A CN105368093A (en) | 2015-11-26 | 2015-11-26 | Isopropyl tri(dioctyl acyloxy phosphate) titanate non-metal powder activator |
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| CN201510860642.3A CN105368093A (en) | 2015-11-26 | 2015-11-26 | Isopropyl tri(dioctyl acyloxy phosphate) titanate non-metal powder activator |
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| CN201510860642.3A Pending CN105368093A (en) | 2015-11-26 | 2015-11-26 | Isopropyl tri(dioctyl acyloxy phosphate) titanate non-metal powder activator |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108457091A (en) * | 2018-05-21 | 2018-08-28 | 泗阳申久家纺面料有限公司 | A kind of TNC clothes that wear-resisting water proofing property is excellent |
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| CN101134852A (en) * | 2007-10-15 | 2008-03-05 | 江苏河海纳米科技股份有限公司 | Inorganic powder organic surface modifying method |
| CN101921446A (en) * | 2010-08-30 | 2010-12-22 | 佛山安亿纳米材料有限公司 | Master batch and preparation method thereof |
| CN103820032A (en) * | 2014-03-05 | 2014-05-28 | 张雅静 | Preparation method of pentaerythrite colophony europium resin |
| CN104371376A (en) * | 2014-10-31 | 2015-02-25 | 陈显鹏 | Glycidol ether superfine calcium carbonate powder assistant |
| CN104403367A (en) * | 2014-10-31 | 2015-03-11 | 廖文成 | Calcium carbonate gamma-aminopropyl triethoxy silane modifier |
| CN104403266A (en) * | 2014-10-31 | 2015-03-11 | 廖文成 | Amino resin-containing calcium carbonate powder modifier |
| CN104403246A (en) * | 2014-10-31 | 2015-03-11 | 廖文成 | Ultrafine calcium carbonate powder acetal modifier |
| CN104479412A (en) * | 2014-11-26 | 2015-04-01 | 甘振辉 | Preparation method of polydimethyl siloxane ground limestone superfine powder |
-
2015
- 2015-11-26 CN CN201510860642.3A patent/CN105368093A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134852A (en) * | 2007-10-15 | 2008-03-05 | 江苏河海纳米科技股份有限公司 | Inorganic powder organic surface modifying method |
| CN101921446A (en) * | 2010-08-30 | 2010-12-22 | 佛山安亿纳米材料有限公司 | Master batch and preparation method thereof |
| CN103820032A (en) * | 2014-03-05 | 2014-05-28 | 张雅静 | Preparation method of pentaerythrite colophony europium resin |
| CN104371376A (en) * | 2014-10-31 | 2015-02-25 | 陈显鹏 | Glycidol ether superfine calcium carbonate powder assistant |
| CN104403367A (en) * | 2014-10-31 | 2015-03-11 | 廖文成 | Calcium carbonate gamma-aminopropyl triethoxy silane modifier |
| CN104403266A (en) * | 2014-10-31 | 2015-03-11 | 廖文成 | Amino resin-containing calcium carbonate powder modifier |
| CN104403246A (en) * | 2014-10-31 | 2015-03-11 | 廖文成 | Ultrafine calcium carbonate powder acetal modifier |
| CN104479412A (en) * | 2014-11-26 | 2015-04-01 | 甘振辉 | Preparation method of polydimethyl siloxane ground limestone superfine powder |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108457091A (en) * | 2018-05-21 | 2018-08-28 | 泗阳申久家纺面料有限公司 | A kind of TNC clothes that wear-resisting water proofing property is excellent |
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Application publication date: 20160302 |