CN105504780A - Low-gloss high-impact automobile imitation leather interior material - Google Patents
Low-gloss high-impact automobile imitation leather interior material Download PDFInfo
- Publication number
- CN105504780A CN105504780A CN201610055306.6A CN201610055306A CN105504780A CN 105504780 A CN105504780 A CN 105504780A CN 201610055306 A CN201610055306 A CN 201610055306A CN 105504780 A CN105504780 A CN 105504780A
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- parts
- deionized water
- aqueous polyurethane
- wool fiber
- chitosan
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- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 31
- 239000010985 leather Substances 0.000 title claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004814 polyurethane Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 21
- 229920002635 polyurethane Polymers 0.000 claims abstract description 21
- 210000002268 wool Anatomy 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 229920001661 Chitosan Polymers 0.000 claims abstract description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 11
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 11
- 239000004927 clay Substances 0.000 claims abstract description 10
- -1 alkyl dimethyl ammonium bromide Chemical compound 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 229910052582 BN Inorganic materials 0.000 claims abstract description 5
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 3
- 238000005238 degreasing Methods 0.000 claims description 3
- 230000001877 deodorizing effect Effects 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000003760 magnetic stirring Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 238000011161 development Methods 0.000 abstract description 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a low-gloss high-impact automobile imitation leather interior material which is prepared from, by weight, 25-30 parts of wool fibers, 4-5 parts of chitosan, 2-3 parts of titanium dioxide, 0.6-1 part of polyethylene glycol, 100-110 parts of waterborne polyurethane, 0.2-0.4 part of 12-12 alkyl dimethyl ammonium bromide, 5-6 parts of clay, 7-9 parts of carbon nano tubes, 4-5 parts of SEBS4, 5-6 parts of boron nitride and a proper amount of deionized water. The prepared material is excellent in anti-aging performance, rigidity, flexibility, impact resistance and the like, simple in preparation process and has good development prospect when used for automobile interior.
Description
Technical field
The present invention relates to technical field of polymer materials, particularly relate to the automobile imitation leather interior material of a kind of low gloss, HI high impact.
Background technology
Along with the develop rapidly of automobile industry, human consumer not only just values the attractive in appearance of automobile external moulding when purchasing car, attractive in appearance to automotive interior material of increasing human consumer, functional, low emission is had higher requirement, and automotive interior material has become the important factor affecting vehicle complete vehicle quality and class.Current automotive trim material has PVC imitation leather, PU leatheroid etc.For the material of automotive trim, good property indices should be had, such as, resistance to illumination, low-temperature resistant flexile are fire-retardant good, low fogging, requirement simultaneously need meet the requirement to raw-material composition of laws and regulations, and requires that the recyclable ratio proposing inside gadget is more and more higher.But now conventional automotive interior material exists problem more or less, can not meet the requirement of consuming public to interior material, along with the proposition of energy-saving, emission-reducing, environment friendly slogan, therefore, the automotive interior material researching and developing novel environment friendly recoverable is necessary.
Polyurethane material is applied to many fields because of the structure of its uniqueness and excellent performance, it is the focus of research always, and water-base polyurethane material has low cost because of it, pollution-free, the advantage such as flexible, have broad application prospects, the synthetic leather processed with urethane and leatheroid have good advantage, as intensity is high, wear resistance is good, flexible resistance is good, lower temperature resistance and oil resistant, chemical resistance is good, but shortcoming is that the water tolerance of aqueous polyurethane and thermotolerance are not high, water vapour permeability is poor, have a strong impact on work-ing life and the human comfort of material, reduce the performance of automobile, the present invention focuses on the improvement of this respect, to reaching the requirement of people to material for car interior trim parts.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides the automobile imitation leather interior material of a kind of low gloss, HI high impact.
The present invention is achieved by the following technical solutions:
An automobile imitation leather interior material for low gloss, HI high impact, is made up of the raw material of following weight part: wool fiber 25-30, chitosan 4-5, titanium dioxide 2-3, polyoxyethylene glycol 0.6-1, aqueous polyurethane 100-110, didodecyldimethylammbromide bromide 0.2-0.4, clay 5-6, carbon nanotube 7-9, SEBS4-5, boron nitride 5-6, deionized water are appropriate;
The automobile imitation leather interior material of described a kind of low gloss, HI high impact, be made up of following concrete preparation method:
(1) wool fiber is carried out degreasing deodorizing process, again mechanical disintegration is carried out to it, obtain median size lower than the wool fiber of 10 μm, again chitosan is dissolved the chitosan solution obtaining 8-10% with 5% acetum, then by titanium dioxide and polyoxyethylene glycol mixing 4-5 times amount deionized water ultrasonic disperse even, add above-mentioned chitosan solution and continue dispersion 5-10min, finally wool fiber is impregnated in mixed solution, dipping 10-20min;
(2) wool fiber is transferred in high-temperature high-pressure reaction kettle together with mixed solution, constant temperature process 0.5-1h under 100-120 ° of C, clarify to solution with deionized water wash after modified wool is taken out, finally naturally dry for subsequent use;
(3) by ultrasonic for carbon nanotube methyl alcohol 20-30min, dry to neutral with deionized water wash afterwards, carbon nanotube is added to rapid stirring 1-2h in aqueous polyurethane again, by the dissolve with ethanol of didodecyldimethylammbromide bromide by 3-4 times amount, clay is added to ultrasonic disperse 10-20min in didodecyldimethylammbromide bromide solution again, filtration deionized water wash is to neutral post-drying;
(4) clay and modified aqueous polyurethane emulsion are added in magnetic stirring apparatus, heating evaporation 1-2h in water bath with thermostatic control, then by modified aqueous polyurethane emulsion casting film-forming, drying for standby at the temperature of 60-90 ° of C;
(5) modified aqueous polyurethane step (4) obtained and other surplus materialss are added in twin screw extruder, spout adds modified woolen fiber prepared by step (2), at the temperature of 100-110 ° of C, screw speed is extruding pelletization under the condition of 150 revs/min, obtains material of the present invention.
Advantage of the present invention is: the present invention adopts water-base polyurethane material as automotive interior material, asepsis environment-protecting, be harmful to human health, and adopt the hardness of carbon nanotube enhancing modified aqueous polyurethane, intensity and anti-impact force, extend its work-ing life, and by chitosan and titanium dichloride load on wool fiber, strengthen it antibacterial, uvioresistant, automatically cleaning and shrinkproof effect, the wool fiber of modification is added in urethane when not affecting its mechanical property and thermostability and enhances water vapour permeability, improve human comfort and easily clean, the SEBS added and boron nitride can improve the wear resistance of material, resistance to acids and bases, the performance of the aspects such as shock resistance, material ageing resistance prepared by the present invention, rigidity, snappiness, the excellent performances such as shock resistance, preparation technology is simple, for automotive trim, there is good development prospect.
Embodiment
An automobile imitation leather interior material for low gloss, HI high impact, is made up of the raw material of following weight part (kilogram): wool fiber 25, chitosan 4, titanium dioxide 2, polyoxyethylene glycol 0.6, aqueous polyurethane 100, didodecyldimethylammbromide bromide 0.2, clay 5, carbon nanotube 7, SEBS4, boron nitride 5, deionized water are appropriate;
The automobile imitation leather interior material of described a kind of low gloss, HI high impact, be made up of following concrete preparation method:
(1) wool fiber is carried out degreasing deodorizing process, again mechanical disintegration is carried out to it, obtain median size lower than the wool fiber of 10 μm, again chitosan is dissolved the chitosan solution obtaining 8% with 5% acetum, then titanium dioxide and polyoxyethylene glycol are mixed even with 4 times amount deionized water ultrasonic disperse, add above-mentioned chitosan solution and continue dispersion 5min, finally wool fiber is impregnated in mixed solution, dipping 10min;
(2) wool fiber is transferred in high-temperature high-pressure reaction kettle together with mixed solution, constant temperature process 0.5h under 100 ° of C, clarify to solution with deionized water wash after modified wool is taken out, finally naturally dry for subsequent use;
(3) by ultrasonic for carbon nanotube methyl alcohol 20min, dry to neutral with deionized water wash afterwards, carbon nanotube is added to rapid stirring 1h in aqueous polyurethane again, by the dissolve with ethanol of didodecyldimethylammbromide bromide by 3 times amount, clay is added to ultrasonic disperse 10min in didodecyldimethylammbromide bromide solution again, filtration deionized water wash is to neutral post-drying;
(4) clay and modified aqueous polyurethane emulsion are added in magnetic stirring apparatus, heating evaporation 1h in water bath with thermostatic control, then by modified aqueous polyurethane emulsion casting film-forming, drying for standby at the temperature of 60 ° of C;
(5) modified aqueous polyurethane step (4) obtained and other surplus materialss are added in twin screw extruder, spout adds modified woolen fiber prepared by step (2), at the temperature of 100 ° of C, screw speed is extruding pelletization under the condition of 150 revs/min, obtains material of the present invention.
Performance test:
Test its material according to embodiment preparation, result is as follows: water vapour permeability: 3586g/ (m2 ﹡ 24h), water-intake rate: 4.9%, tension set: 584%, tensile strength: 149Mpa, ageing resistance: 4 grades, light fastness aging: 4 grades, rolling processing: good.
Claims (2)
1. the automobile imitation leather interior material of a low gloss, HI high impact, it is characterized in that, be made up of the raw material of following weight part: wool fiber 25-30, chitosan 4-5, titanium dioxide 2-3, polyoxyethylene glycol 0.6-1, aqueous polyurethane 100-110, didodecyldimethylammbromide bromide 0.2-0.4, clay 5-6, carbon nanotube 7-9, SEBS4-5, boron nitride 5-6, deionized water are appropriate.
2. the automobile imitation leather interior material of a kind of low gloss, HI high impact according to claim 1, is characterized in that, be made up of following concrete preparation method:
(1) wool fiber is carried out degreasing deodorizing process, again mechanical disintegration is carried out to it, obtain median size lower than the wool fiber of 10 μm, again chitosan is dissolved the chitosan solution obtaining 8-10% with 5% acetum, then by titanium dioxide and polyoxyethylene glycol mixing 4-5 times amount deionized water ultrasonic disperse even, add above-mentioned chitosan solution and continue dispersion 5-10min, finally wool fiber is impregnated in mixed solution, dipping 10-20min;
(2) wool fiber is transferred in high-temperature high-pressure reaction kettle together with mixed solution, constant temperature process 0.5-1h under 100-120 ° of C, clarify to solution with deionized water wash after modified wool is taken out, finally naturally dry for subsequent use;
(3) by ultrasonic for carbon nanotube methyl alcohol 20-30min, dry to neutral with deionized water wash afterwards, carbon nanotube is added to rapid stirring 1-2h in aqueous polyurethane again, by the dissolve with ethanol of didodecyldimethylammbromide bromide by 3-4 times amount, clay is added to ultrasonic disperse 10-20min in didodecyldimethylammbromide bromide solution again, filtration deionized water wash is to neutral post-drying;
(4) clay and modified aqueous polyurethane emulsion are added in magnetic stirring apparatus, heating evaporation 1-2h in water bath with thermostatic control, then by modified aqueous polyurethane emulsion casting film-forming, drying for standby at the temperature of 60-90 ° of C;
(5) modified aqueous polyurethane step (4) obtained and other surplus materialss are added in twin screw extruder, spout adds modified woolen fiber prepared by step (2), at the temperature of 100-110 ° of C, screw speed is extruding pelletization under the condition of 150 revs/min, obtains material of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610055306.6A CN105504780A (en) | 2016-01-26 | 2016-01-26 | Low-gloss high-impact automobile imitation leather interior material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610055306.6A CN105504780A (en) | 2016-01-26 | 2016-01-26 | Low-gloss high-impact automobile imitation leather interior material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105504780A true CN105504780A (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610055306.6A Pending CN105504780A (en) | 2016-01-26 | 2016-01-26 | Low-gloss high-impact automobile imitation leather interior material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746563A (en) * | 2019-10-24 | 2020-02-04 | 江苏理工学院 | PEG ball-milling intercalation h-BN modified polyurethane heat-conducting composite material and preparation method thereof |
Citations (4)
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| CN105176023A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Sound-absorbing and heat-preserving composite environment-friendly material for automotive upholstery and preparing method of sound-absorbing and heat-preserving composite environment-friendly material |
| CN105176028A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Ultraviolet and aging resisting composite material for automotive upholstery and a preparing method composite material |
| CN105176027A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Low-VOC environmentally-friendly high-quality automobile interior trim part material and preparation method thereof |
| CN105219042A (en) * | 2015-09-23 | 2016-01-06 | 芜湖环瑞汽车内饰件有限公司 | A kind of enhancement type composite automobile inner decoratire part material adding bamboo powder and preparation method thereof |
-
2016
- 2016-01-26 CN CN201610055306.6A patent/CN105504780A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176023A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Sound-absorbing and heat-preserving composite environment-friendly material for automotive upholstery and preparing method of sound-absorbing and heat-preserving composite environment-friendly material |
| CN105176028A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Ultraviolet and aging resisting composite material for automotive upholstery and a preparing method composite material |
| CN105176027A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Low-VOC environmentally-friendly high-quality automobile interior trim part material and preparation method thereof |
| CN105219042A (en) * | 2015-09-23 | 2016-01-06 | 芜湖环瑞汽车内饰件有限公司 | A kind of enhancement type composite automobile inner decoratire part material adding bamboo powder and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746563A (en) * | 2019-10-24 | 2020-02-04 | 江苏理工学院 | PEG ball-milling intercalation h-BN modified polyurethane heat-conducting composite material and preparation method thereof |
| CN110746563B (en) * | 2019-10-24 | 2021-06-29 | 江苏理工学院 | PEG ball-milling intercalation h-BN modified polyurethane heat-conducting composite material and preparation method thereof |
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