CN105504354B - A kind of pressure sensitive adhesive efficient halogen-free element fire retardant combination and preparation method thereof - Google Patents
A kind of pressure sensitive adhesive efficient halogen-free element fire retardant combination and preparation method thereof Download PDFInfo
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- CN105504354B CN105504354B CN201510973909.XA CN201510973909A CN105504354B CN 105504354 B CN105504354 B CN 105504354B CN 201510973909 A CN201510973909 A CN 201510973909A CN 105504354 B CN105504354 B CN 105504354B
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- sensitive adhesive
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- melamine
- fire retardant
- free element
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- HSWZPAQXEQVNDL-UHFFFAOYSA-N O=P1(OCCCOc2ccccc2)OCCCO1 Chemical compound O=P1(OCCCOc2ccccc2)OCCCO1 HSWZPAQXEQVNDL-UHFFFAOYSA-N 0.000 description 1
- 0 OCC(C*1)(CO2)COP12=O Chemical compound OCC(C*1)(CO2)COP12=O 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
Abstract
The invention discloses a kind of pressure sensitive adhesive efficient halogen-free element fire retardant combination and preparation method thereof, the component and weight percent of efficient halogen-free element fire retardant combination of the invention include：Aluminium hydroxide 25 90%, pentaerythrite young laying ducks in cage 3 25%, hypophosphorous acid melamine salt 5 20%, melamine and its derivative 2 30%.A kind of preparation method of High-efficiency flame retardant composition of the present invention is to be sufficiently mixed aluminium hydroxide, pentaerythrite young laying ducks in cage, hypophosphorous acid melamine salt, melamine and its derivative uniformly to obtain efficient halogen-free element fire retardant combination.The High-efficiency flame retardant composition of the present invention, compounding is cooperateed with by the phosphorus compound of different valence state and melamine and its derivative, obtain unique highly effective flame-retardant, with flame retarding efficiency height, mobility and good dispersion, the features such as applicability is wide also can be used in addition to the halogen-free flame-retardant that can be used for pressure sensitive adhesive in polyester and non-woven polyolefin, fabric coating and the fire proofings such as various resins and plastics.
Description
Technical field
The present invention relates to a kind of pressure sensitive adhesive efficient halogen-free element fire retardant combinations and preparation method thereof, are especially suitable for
Polyacrylate pressure-sensitive, polyurethane, polyvinyl acetate, organic siliconresin and rubber pressure-sensitive adhesive and hot-fusible pressure-sensitive adhesive are used
Efficient halogen-free element fire retardant combination and preparation method thereof.
Background technology
Pressure sensitive adhesive is the abbreviation of pressure-sensitive adhesive, is a kind of adhesive for having and having sensibility to pressure.Pressure sensitive adhesive according to
Matrix resin ingredient is different, can be divided into acrylate pressure-sensitive adhesive, rubber pressure-sensitive adhesive and hot-fusible pressure-sensitive adhesive.Pressure sensitive adhesive is extensive
Applied to fields such as automobile, communication, electronic apparatus, aerospace equipment and buildings, specifically there are packaging, protection, insulation, police
Show, indicate, the products such as stationery.To being used to prepare the pressure sensitive adhesive of packaging and electric insulation pressure sensitive adhesive tape etc., pressure sensitive adhesive is often required that
With good flame retardant property, therefore pressure sensitive adhesive is fire-retardant to expanding its application field, it is ensured that safety in utilization has important meaning
Justice.
Invention content
The object of the present invention is to provide a kind of pressure sensitive adhesive efficient halogen-free element fire retardant combinations and preparation method thereof, are
Can be used for polyacrylic resin, polyurethane and polyvinyl acetate, organic silicon resin, rubber formulation pressure sensitive adhesive binder,
And the efficient halogen-free element fire retardant and preparation method thereof of the pressure-sensitive gum resin of hot melt adhesive.
A kind of pressure sensitive adhesive efficient halogen-free element fire retardant combination of the present invention, component and its weight percent include：
Aluminium hydroxide 25-90%；
Pentaerythrite young laying ducks in cage 3-25%；
Hypophosphorous acid melamine salt 5-20%；
Melamine and its derivative 2-30%.
As preferred technical solution：
A kind of pressure sensitive adhesive of the present invention efficient halogen-free element fire retardant combination, the pressure sensitive adhesive are polyacrylic acid
Resin, polyurethane or polyvinyl acetate, organic silicon resin, rubber formulation pressure sensitive adhesive binder and hot-fusible pressure-sensitive adhesive
Resin.
A kind of pressure sensitive adhesive of the present invention efficient halogen-free element fire retardant combination, the pentaerythrite caged phosphoric acid
Ester refers to the compound for having the following structure (I)：
Wherein, the siliceous alkoxy and its derivative of the alkoxy of R=OH, C1-12 and its derivative and C1-12.
A kind of pressure sensitive adhesive of the present invention efficient halogen-free element fire retardant combination, the hypophosphorous acid melamine salt
It refer to the compound (II) having the following structure；
The present invention also provides more than one pressure sensitive adhesives preparation methods of efficient halogen-free element fire retardant combination, by hydrogen-oxygen
Change aluminium, pentaerythrite young laying ducks in cage, hypophosphorous acid melamine salt and melamine and its derivative is sufficiently mixed uniformly to obtain the final product
To efficient halogen-free element fire retardant combination；The weight percent of each component is：
Aluminium hydroxide 25-90%；
Pentaerythrite young laying ducks in cage 3-25%；
Hypophosphorous acid melamine salt 5-20%；
Melamine and its derivative 2-30%.
A kind of preparation method of efficient halogen-free element fire retardant combination of the present invention is by aluminium hydroxide, pentaerythrite caged
Phosphate, hypophosphorous acid melamine salt and melamine and its derivative are sufficiently mixed in a mixer uniformly obtains target production
Product also can make fire retardant concentrate feed with above-mentioned composition and a certain proportion of resin and use.The product of the present invention can be used for respectively
The fire-retardant of vistanex is planted, is particularly suitable for requiring the flame retardant polyolefine material of resistance to precipitation, such as electric appliance casing, socket, ripple
Pipe and light decoration light fitting etc. use polypropylene flame redardant.
The beneficial effects of the invention are as follows：
The pressure sensitive adhesive High-efficiency flame retardant composition of the present invention, by the phosphorus compound of different valence state and melamine and its
The collaboration of derivative compounds, and obtains unique highly effective flame-retardant, has flame retarding efficiency height, mobility and good dispersion, applicability
The features such as wide, and production technology is easy, three wastes generate, it can be achieved that clean environment firendly produces.The efficient halogen-free element of the present invention is fire-retardant
Agent composition can be widely used for polyacrylate pressure-sensitive, polyurethane, polyvinyl acetate, and organic siliconresin and rubber-type are pressure-sensitive
Glue and hot-fusible pressure-sensitive adhesive, are particularly suitable for polyacrylate, polyurethane and polyester hot-melt adhesive, and flame retardant rating can reach UL94V-
0, the requirement of the materials such as non-flammable adhesive tape such as building materials, electric appliance can be met.
Specific implementation mode
The invention will be further elucidated with reference to specific embodiments.It should be understood that these embodiments are merely to illustrate this hair
It is bright rather than limit the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, art technology
Personnel can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Fixed range.
Embodiment 1
Weigh 25 kilograms of aluminium hydroxide, 20 kilograms of hypophosphorous acid melamine salt, the pentaerythrite cage with such as (III) structure
25 kilograms of shape phosphate obtains High-efficiency flame retardant composition after 30 kilograms of mixing of melamine.This composition is pressed into quality hundred
Score is that 15% ratio is added in the copolyester hot melt adhesive that melting range is 120-130 DEG C, and suitable processing aid, antioxygen is added
Agent and light stabilizer, obtain flame-proof copolyester hot melt adhesive after melting mixing, and fire-retardant rank is UL94 V-0 (1.6mm).
Embodiment 2
Weigh 90 kilograms of aluminium hydroxide, 5 kilograms of hypophosphorous acid melamine salt, the pentaerythrite caged with such as (IV) structure
3 kilograms of phosphate, 2 kilograms of melamine phosphate obtain High-efficiency flame retardant composition.By weight percent by this composition
It is added in methyl silicon resin for 25% ratio, and suitable processing aid, antioxidant and light stabilizer is added, through melting mixing
After obtain flame-proof organosilicon hot melt adhesive, fire-retardant rank is UL94 V-0 (1.6mm).
Embodiment 3
Weigh 55 kilograms of aluminium hydroxide, 10 kilograms of hypophosphorous acid melamine salt, the pentaerythrite cage with such as (V) structure
15 kilograms of shape phosphate obtains High-efficiency flame retardant composition after 20 kilograms of mixing of melamine cyanurate.By this composition
Be by weight percent 15% ratio be added to polymethyl acrylate glue (solvent is the mixed solvents such as butyl acetate, toluene, tree
Fat content 40%) in, and suitable processing aid, antioxidant and light stabilizer is added, coated machine is coated on polyester tape
(coating layer thickness 0.2mm), obtains fire retardant pressure sensitive insulating tape after dry, flame retardant property presses UL510 standard testings, self-extinguishing time
For 0 second (500w).
Embodiment 4
Weigh 30 kilograms of aluminium hydroxide, 20 kilograms of hypophosphorous acid melamine salt, the pentaerythrite cage with such as (VI) structure
20 kilograms of shape phosphate obtains High-efficiency flame retardant composition after 30 kilograms of mixing of melamine polyphosphate.By this composition
By weight percent be 25% ratio be added in SEBS (Hydrogenated SBS rubber), and be added suitable processing aid, antioxidant and
Light stabilizer, obtains fire-retardant SEBS hot melt adhesive after melting mixing, and fire-retardant rank is UL94 V-0 (1.6mm).
Embodiment 5
Weigh 70 kilograms of aluminium hydroxide, 10 kilograms of hypophosphorous acid melamine salt, the pentaerythrite cage with such as (VII) structure
15 kilograms of shape phosphate obtains High-efficiency flame retardant composition after the 5 kilograms of mixing of melamine borate salt.This composition is pressed into matter
Amount percentage is that 20% ratio is added in SEBS polyurethane elastomers, and it is steady that suitable processing aid, antioxidant and light is added
Determine agent, flame resistance polyurethane elastomer is obtained after melting mixing, fire-retardant rank is UL94 V-0 (1.6mm).
Embodiment 6
Weigh 40 kilograms of aluminium hydroxide, 20 kilograms of hypophosphorous acid melamine salt, the pentaerythrite cage with such as (VIII) structure
25 kilograms of shape phosphate obtains High-efficiency flame retardant composition after the 15 kilograms of mixing of melamine phthalate.By this group
It is that 20% ratio is added in polyvinyl acetate hot melt adhesive, and suitable processing aid is added, resists to close object by weight percent
Oxygen agent and light stabilizer, obtain fire-retardant polyvinyl acetate hot melt adhesive after melting mixing, and fire-retardant rank is UL94 V-0
(1.6mm)。
Claims (5)
1. a kind of pressure sensitive adhesive efficient halogen-free element fire retardant combination, it is characterized in that its component and its weight percent include：
Aluminium hydroxide 25-90%；
Pentaerythrite young laying ducks in cage 3-25%；
Hypophosphorous acid melamine salt 5-20%；
Components I 2-30%；
The components I is melamine phosphate, melamine polyphosphate, melamine cyanurate, melamine boron
Hydrochlorate or melamine phthalate.
2. a kind of pressure sensitive adhesive according to claim 1 efficient halogen-free element fire retardant combination, which is characterized in that described
Pressure sensitive adhesive be polyacrylic resin, polyurethane or polyvinyl acetate, organic silicon resin, rubber formulation pressure sensitive adhesive bond
Agent and melt pressure sensitive gum resin.
3. a kind of pressure sensitive adhesive according to claim 1 efficient halogen-free element fire retardant combination, which is characterized in that described
Pentaerythrite young laying ducks in cage, structure such as (I) are
Wherein, the siliceous alkoxy of the alkoxy of R=OH, C1-12 and C1-12.
4. a kind of pressure sensitive adhesive according to claim 1 efficient halogen-free element fire retardant combination, which is characterized in that described
Hypophosphorous acid melamine salt, structure such as (II) are
5. a kind of system of pressure sensitive adhesive efficient halogen-free element fire retardant combination according to any one of above claim 1-4
Preparation Method, it is characterized in that：Aluminium hydroxide, pentaerythrite young laying ducks in cage, hypophosphorous acid melamine salt and components I are sufficiently mixed
Uniformly obtain the pressure sensitive adhesive efficient halogen-free element fire retardant combination；The weight percent of each component is：
Aluminium hydroxide 25-90%；
Pentaerythrite young laying ducks in cage 3-25%；
Hypophosphorous acid melamine salt 5-20%；
Components I 2-30%.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510973909.XA CN105504354B (en) | 2015-12-22 | 2015-12-22 | A kind of pressure sensitive adhesive efficient halogen-free element fire retardant combination and preparation method thereof |
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| CN201510973909.XA CN105504354B (en) | 2015-12-22 | 2015-12-22 | A kind of pressure sensitive adhesive efficient halogen-free element fire retardant combination and preparation method thereof |
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| CN105504354A CN105504354A (en) | 2016-04-20 |
| CN105504354B true CN105504354B (en) | 2018-09-18 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108949048B (en) * | 2018-08-01 | 2021-03-30 | 深圳日高胶带新材料有限公司 | Organic silicon flame-retardant pressure-sensitive adhesive tape and preparation method thereof |
| CN111040716A (en) * | 2019-12-25 | 2020-04-21 | 江苏晟宏生态纺织科技有限公司 | Preparation method and application of phosphorus-containing flame-retardant polyurethane adhesive |
| CN113088210B (en) * | 2021-04-25 | 2022-09-06 | 东莞澳中新材料科技股份有限公司 | Flame-retardant adhesive tape for wrapping lithium ion battery and preparation method thereof |
| WO2023178660A1 (en) * | 2022-03-25 | 2023-09-28 | Rohm and Haas Electronic Materials (Shanghai) Ltd. | Two-component polyurethane adhesive |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1086390C (en) * | 1999-07-22 | 2002-06-19 | 岳阳石油化工总厂研究院 | Preparation method of pentaerythritol phosphate |
| CN1159373C (en) * | 2001-08-28 | 2004-07-28 | 中国石化集团巴陵石油化工有限责任公司 | Expanding fire retardant composition without halide for polyolefine |
| WO2005012435A1 (en) * | 2003-07-31 | 2005-02-10 | World Properties, Inc. | Electrically conductive, flame retardant fillers, method of manufacture, and use thereof |
| CN100482757C (en) * | 2005-08-15 | 2009-04-29 | 上海化工研究院 | Flame resisting agent with no halogen in series of crylic acid in use for pressure sensitive adhesive tape, and prepartion method |
| CN101570518B (en) * | 2009-06-12 | 2010-11-17 | 东华大学 | Preparation method for expansion type melamine hypophosphite fire retardant |
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Effective date of registration: 20200818 Address after: 201613, Songjiang District, China Road, No. 68, 13, 5, Shanghai Patentee after: Shanghai Li Dao new material Polytron Technologies Inc. Address before: 425300, Hunan, Daoxian County province Yongzhou Industrial Park, East Ring Road Patentee before: HUNAN MEILAIPO SCIENCE AND TECHNOLOGY Co.,Ltd. |