CN105502687A - Organic industrial sewage purifying agent and using method thereof - Google Patents
Organic industrial sewage purifying agent and using method thereof Download PDFInfo
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- CN105502687A CN105502687A CN201610019475.4A CN201610019475A CN105502687A CN 105502687 A CN105502687 A CN 105502687A CN 201610019475 A CN201610019475 A CN 201610019475A CN 105502687 A CN105502687 A CN 105502687A
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Abstract
The invention discloses an organic industrial sewage purifying agent and a using method thereof. Kieselguhr, medical stones, a graphene nanolayer-MnO2 compound, a chitosan-graphene composite, aluminum sulfate, ferric oxide, ferric chloride and polyacrylamide are adopted as carriers, a compound microorganism bacterium agent and an enzymic preparation are added, the materials jointly act on wastewater, therefore, secondary pollution generated through chemical treatment is avoided, the sewage discharge amount is decreased, and the water quality of the wastewater is improved; in addition, the adopted compound microorganism strain can improve the impact load resistance of a system to cope with the circumstance that the organic matter load is too high. According to the using method, the CODcr discharge amount can meet the state-specified standard.
Description
Technical field
The invention belongs to technical field of sewage, be specifically related to a kind of method of organic industry effluent purifier and process organic industry sewage.
Background technology
Because COD in organic industry sewage, nitrogen, phosphorus concentration are higher, cost for wastewater treatment is high, and the standard water discharge after process is unstable, has potential threat to ecotope, but processing waste water belongs to again the waste water type of recoverable simultaneously.Refer to glue-preparing exhausted water in part document to be directly used in irrigation and can to block soil pores, make soil compaction, cannot cultivate.The not a small amount of thing content such as removing residual glue or protein, the water solubles, acetone of waste water is higher, and polymer substance not easily spreads when too high levels, can result in blockage in the hole of soil agreegate, makes infiltration difficulty.If illustrate and be directly applied in soil by high concentrations of rubber waste water, the various physical and chemical index of soil can be made to reduce, the significantly raising being simultaneously greater than 0.25mm waterstable aggregate body burden also reflects soil pores blocking from the side, has the trend hardened.Therefore, if organic industry sewage is without process or only just factory effluent is entered water drain through simple process, very easily load impacted to sewage work and can not be effectively handled, meeting contaminated soil after entered environment, may through long-term biological accumulation effect, destroy the growth of plant, jeopardize the life of animal and human, form buterfly effect.Adopt Coagulation Method to be a kind of conventional water treatment method, having economical and efficient, the advantage such as applied widely, is extraordinary wastewater treatment or pretreatment process.But adopt the method for flocculating polymer cannot process rubber production producer waste water thoroughly.Adopt chemical coagulation process process organic industry sewage, be characterized in, for grease, jelly and the suspended solid removed in chemical engineering sewage, treatment effect is up to standard and technical scheme is more suitable, is the important step in the middle of chemical engineering sewage pre-treatment.But it is not satisfactory to water treatment effect and to the strict problem of water treatment conditional request to adopt chemical process equally also to exist, such as water wets and has obvious impact to the effect of coagulation, the hydrolysis of the coagulating agent of inorganic salts is thermo-negative reaction, when water temperature is low, hydrolysis difficulty, particularly Tai-Ace S 150, when water temperature is lower than 5 degree, hydrolysis rate slowly, Rubber Industrial Wastewater is hot wastewater when entering homogeneous pond, homogeneous pond stir stop after carry out coagulation time temperature decrease, but water temperature will far away higher than 5 degree, and select coagulating agent to be high-molecular coagulant adopting, in the process of one-level Rubber Industrial Wastewater, the impact of this factor of temperature on coagulation effect is little, the influence degree of pH value in water to coagulation is the kind of coagulating agent and different.Need to process for above-mentioned organic industry sewage, and its effect of single physical sedimentation is unsatisfactory, chemical treatment method easily brings new pollution, produces other chemical substance.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of organic industry effluent purifier, additionally provide the method adopting above-mentioned water purification agent process height nitrogen height chlorine height benzene organic industry sewage, the method is without the need to adding a large amount of chemical reagent, environmentally friendly, and its purifying water effect is good.
The present invention is realized by following technical scheme:
A kind of organic industry effluent purifier, is made up of the raw material of following weight part: diatomite 10-20, medical stone 10-30, graphene nano layer/MnO2 mixture 10-20, chitosan-graphene composite material 10-20, Tai-Ace S 150 15-20, ferric oxide 5-10, iron(ic) chloride 10-20, polyacrylamide 10-20, Chryseobacterium sp bacterium powder 0.5-1.5, pseudomonas putida bacterium powder 0.5-2.0, Pseudomonas fluorescens bacterium powder 0.5-2.0, polyP bacteria bacterium powder 0.5-1.5, Methionin genus bacillus bacterium powder 0.2-1.0, whiterot fungi bacterium powder 0.5-1.5, Rhodococcus ruber bacterium powder 0.2-1.0, Bacillus licheniformis powder 0.5-2.0, bacillus megaterium bacterium powder 0.2-1.0, Geotrichum bacterium powder 0.5-2.0, nitrated coccus bacterium powder 0.5-1.5, rhizopus bacterium powder 0.2-1.0, streptomycete bacterium powder 0.5-1.5, Staphylococcus pasteuri bacterium powder 0.5-2.0, water sprout grows bacillus bacterium powder 0.5-1.5, Shewanella decolorationis bacterium powder 0.2-1.0, bite ammonia secondary coccus bacterium powder 0.5-1.5, polygalacturonase 0.04-0.15, Enone reductase 0.03-0.2, nitroreductase 0.02-0.1, lignans hydroxylase 0.02-0.1, laccase 0.04-0.15, streptomyces proteinase 0.02-0.1, thioesterase 0.05-0.1, phytase 0.02-0.1, zytase 0.03-0.2, Nitrile hydratase 0.02-0.1, streptomyces proteinase 0.04-0.15, aldehyde dehydrogenase 0.05-0.1, M-Zyme 0.02-0.1, unslaked lime 200-500.
Preferably, a kind of organic industry effluent purifier, is characterized in that, is made up of the raw material of following weight part: diatomite 15, medical stone 20, graphene nano layer/MnO2 mixture 15, chitosan-graphene composite material 15, Tai-Ace S 150 17, ferric oxide 8, iron(ic) chloride 15, polyacrylamide 15, Chryseobacterium sp bacterium powder 1.0, pseudomonas putida bacterium powder 1.0, Pseudomonas fluorescens bacterium powder 1.0, polyP bacteria bacterium powder 1.0, Methionin genus bacillus bacterium powder 0.6, whiterot fungi bacterium powder 0.8, Rhodococcus ruber bacterium powder 0.6, Bacillus licheniformis powder 0.8, bacillus megaterium bacterium powder 0.6, Geotrichum bacterium powder 0.8, nitrated coccus bacterium powder 0.7, rhizopus bacterium powder 0.6, streptomycete bacterium powder 0.8, Staphylococcus pasteuri bacterium powder 0.9, water sprout grows bacillus bacterium powder 0.8, Shewanella decolorationis bacterium powder 0.6, bite ammonia secondary coccus bacterium powder 0.8, polygalacturonase 0.1, Enone reductase 0.1, nitroreductase 0.06, lignans hydroxylase 0.06, laccase 0.1, streptomyces proteinase 0.06, thioesterase 0.07, phytase 0.05, zytase 0.1, Nitrile hydratase 0.05, streptomyces proteinase 0.1, aldehyde dehydrogenase 0.07, M-Zyme 0.05, unslaked lime 400.
Preferably, cross-linked rectorite 6-12 weight part is also comprised.
Preferably, also comprise and draw together wilkinite 6-12 weight part.
The using method of above-mentioned a kind of organic industry effluent purifier, comprises following step:
Step 1: by dry under the condition of 90 DEG C after diatomite, medical stone, Tai-Ace S 150, ferric oxide and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder;
Step 2: mix powder step 1 obtained at room temperature mixes with polyacrylamide, obtains mixture;
Step 3: add the mixture that step 2 obtains in organic industry sewage, carries out Air Exposure 30min to mixed solution, stirs 1h after aeration, quiescent setting 2-4h after stirring, and releases upper strata clear water, removes lower sediment thing;
Step 4: add Chryseobacterium sp bacterium powder in the clear water of step 3 gained upper strata, pseudomonas putida bacterium powder, Pseudomonas fluorescens bacterium powder, polyP bacteria bacterium powder, Methionin genus bacillus bacterium powder, whiterot fungi bacterium powder, Rhodococcus ruber bacterium powder, Bacillus licheniformis powder, bacillus megaterium bacterium powder, Geotrichum bacterium powder, nitrated coccus bacterium powder, rhizopus bacterium powder, streptomycete bacterium powder, Staphylococcus pasteuri bacterium powder, water sprout grows bacillus bacterium powder, Shewanella decolorationis bacterium powder and bite ammonia secondary coccus bacterium powder, stir and Air Exposure with the rotating speed of 10-20rpm at water temperature 35-40 DEG C, after stirring Air Exposure 1h, leave standstill 2-3h,
Step 5: the sewage of step 4 is regulated pH to 4.5-6.0, the temperature continuing to keep water is 35-40 DEG C, add polygalacturonase, Enone reductase, nitroreductase, lignans hydroxylase, laccase, streptomyces proteinase, thioesterase, phytase, zytase, Nitrile hydratase, streptomyces proteinase, aldehyde dehydrogenase and M-Zyme, stir with the rotating speed of 10-20rpm, after stirring 1h, leave standstill 3-5h;
Step 6: add unslaked lime in the waste water that step 5 processed, stir with the rotating speed of 10-20rpm, leaves standstill 3-5h after stirring 30min, namely obtains the organic industry sewage processed after removing throw out.
Preferably, above-mentioned steps 1 is specially: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide, cross-linked rectorite and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder.
Preferably, above-mentioned steps 1 is specially: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide, wilkinite and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder.
The heavy metal ion of graphene nano layer (GNS)/MnO2 mixture (GNS/MnO2) in removal sewage is effective, remove tri-effects of heavy metal species ion of Ni2+, Pb2+ and Cu2+ in waste water better, GNS is as carrier, increase the specific surface area of sorbent material, MnO2 plays main adsorption, after reusing for 5 times, the adsorptive power of GNS/MnO2 can also return to 91%, has good regenerative power.
Chitosan-graphene composite material has larger specific surface area and unique meso-hole structure, and the double spirane structure of chitosan-graphene composite material, electrostatic interaction, hydrogen bond action and Van der Waals force between chitosan and Graphene all enhance the removal ability to metal ion.
Cross-linked rectorite is the cation exchange property utilizing Rectorite, select linking agent as polymerization hydroxy metal positively charged ion or oxide compound etc., make the inflatable interbed of Rectorite be crosslinked pillared the opening of agent and obtain larger interlamellar spacing, improve the performance of natural accumulation supporting stone.Cross-linked rectorite Stability Analysis of Structures, do not expand, have larger specific surface area, loading capacity and micropore size and have the features such as Heat stability is good, surface acidity are strong, adsorptive power increases more than 70%, having larger layer thickness, is a kind of catalyzer and sorbent material of excellent performance.
Wilkinite (bentonite) is the clay mineral that one is main component with montmorillonite (montmorillonite).Its chemical composition is aluminosilicate, and chemical formula is Al2O34SiO23H2O.The unit cell of microtexture is made up of two Si2O tetrahedron wafers and the octahedra wafer of Al2O or Al2OH that clips between them, and wilkinite has stronger adsorptivity and ion exchangeable.
Beneficial effect of the present invention is, adopt water purification agent of the present invention and adopt above-mentioned water purification agent to process organic industry sewage, adopt solid water purifier and complex micro organism fungicide, zymin acting in conjunction in waste water, avoid the secondary pollution that chemical treatment produces, decrease the quantity discharged of sewage, improve the water quality of waste water; And complex microorganism bacterial classification of the present invention can improve the ability of system anti-shock loading, to deal with the too high situation of organic substance load; Method of the present invention makes the quantity discharged of CODcr reach state specified standards.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Following examples industrial sewage takes from certain rubber production producer, and this waste water is specially the waste water that above-mentioned producer produces when producing epichlorohydrin rubber, and the water body of waste water has peculiar smell, has a large amount of suspended substance in water body.
Embodiment 1:
A kind of organic industry effluent purifier, is made up of the raw material of following weight part: diatomite 10, medical stone 10, graphene nano layer/MnO2 mixture 10, chitosan-graphene composite material 10, Tai-Ace S 150 15, ferric oxide 5, iron(ic) chloride 10, polyacrylamide 10, Chryseobacterium sp bacterium powder 0.5, pseudomonas putida bacterium powder 0.5, Pseudomonas fluorescens bacterium powder 0.5, polyP bacteria bacterium powder 0.5, Methionin genus bacillus bacterium powder 0.2, whiterot fungi bacterium powder 0.5, Rhodococcus ruber bacterium powder 0.2, Bacillus licheniformis powder 0.5, bacillus megaterium bacterium powder 0.2, Geotrichum bacterium powder 0.5, nitrated coccus bacterium powder 0.5, rhizopus bacterium powder 0.2, streptomycete bacterium powder 0.5, Staphylococcus pasteuri bacterium powder 0.5, water sprout grows bacillus bacterium powder 0.5, Shewanella decolorationis bacterium powder 0.2, bite ammonia secondary coccus bacterium powder 0.5, polygalacturonase 0.04, Enone reductase 0.03, nitroreductase 0.02, lignans hydroxylase 0.02, laccase 0.04, streptomyces proteinase 0.02, thioesterase 0.05, phytase 0.02, zytase 0.03, Nitrile hydratase 0.02, streptomyces proteinase 0.04, aldehyde dehydrogenase 0.05, M-Zyme 0.02, unslaked lime 200.
A using method for organic industry effluent purifier, comprises following step:
Step 1: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder;
Step 2: mix powder step 1 obtained at room temperature mixes with polyacrylamide, obtains mixture;
Step 3: add the mixture that step 2 obtains in organic industry sewage, carries out Air Exposure 30min to mixed solution, stirs 1h after aeration, quiescent setting 2h after stirring, and releases upper strata clear water, removes lower sediment thing;
Step 4: add Chryseobacterium sp bacterium powder in the clear water of step 3 gained upper strata, pseudomonas putida bacterium powder, Pseudomonas fluorescens bacterium powder, polyP bacteria bacterium powder, Methionin genus bacillus bacterium powder, whiterot fungi bacterium powder, Rhodococcus ruber bacterium powder, Bacillus licheniformis powder, bacillus megaterium bacterium powder, Geotrichum bacterium powder, nitrated coccus bacterium powder, rhizopus bacterium powder, streptomycete bacterium powder, Staphylococcus pasteuri bacterium powder, water sprout grows bacillus bacterium powder, Shewanella decolorationis bacterium powder and bite ammonia secondary coccus bacterium powder, stir and Air Exposure with the rotating speed of 10rpm at water temperature 35-40 DEG C, after stirring Air Exposure 1h, leave standstill 2h,
Step 5: the sewage of step 4 is regulated pH to 4.5-6.0, the temperature continuing to keep water is 35-40 DEG C, add polygalacturonase, Enone reductase, nitroreductase, lignans hydroxylase, laccase, streptomyces proteinase, thioesterase, phytase, zytase, Nitrile hydratase, streptomyces proteinase, aldehyde dehydrogenase and M-Zyme, stir with the rotating speed of 10rpm, after stirring 1h, leave standstill 3h;
Step 6: add unslaked lime in the waste water that step 5 processed, stir with the rotating speed of 10rpm, leaves standstill 3h after stirring 30min, namely obtains the organic industry sewage processed after removing throw out.
Embodiment 2:
A kind of organic industry effluent purifier, is made up of the raw material of following weight part: diatomite 20, medical stone 30, graphene nano layer/MnO2 mixture 20, chitosan-graphene composite material 20, Tai-Ace S 150 20, ferric oxide 10, iron(ic) chloride 20, polyacrylamide 20, Chryseobacterium sp bacterium powder 1.5, pseudomonas putida bacterium powder 2.0, Pseudomonas fluorescens bacterium powder 2.0, polyP bacteria bacterium powder 1.5, Methionin genus bacillus bacterium powder 1.0, whiterot fungi bacterium powder 1.5, Rhodococcus ruber bacterium powder 1.0, Bacillus licheniformis powder 2.0, bacillus megaterium bacterium powder 1.0, Geotrichum bacterium powder 2.0, nitrated coccus bacterium powder 1.5, rhizopus bacterium powder 1.0, streptomycete bacterium powder 1.5, Staphylococcus pasteuri bacterium powder 2.0, water sprout grows bacillus bacterium powder 1.5, Shewanella decolorationis bacterium powder 1.0, bite ammonia secondary coccus bacterium powder 1.5, polygalacturonase 0.15, Enone reductase 0.2, nitroreductase 0.1, lignans hydroxylase 0.1, laccase 0.15, streptomyces proteinase 0.1, thioesterase 0.1, phytase 0.1, zytase 0.2, Nitrile hydratase 0.1, streptomyces proteinase 0.15, aldehyde dehydrogenase 0.1, M-Zyme 0.1, unslaked lime 500.
A using method for organic industry effluent purifier, comprises following step:
Step 1: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder;
Step 2: mix powder step 1 obtained at room temperature mixes with polyacrylamide, obtains mixture;
Step 3: add the mixture that step 2 obtains in organic industry sewage, carries out Air Exposure 30min to mixed solution, stirs 1h after aeration, quiescent setting 4h after stirring, and releases upper strata clear water, removes lower sediment thing;
Step 4: add Chryseobacterium sp bacterium powder in the clear water of step 3 gained upper strata, pseudomonas putida bacterium powder, Pseudomonas fluorescens bacterium powder, polyP bacteria bacterium powder, Methionin genus bacillus bacterium powder, whiterot fungi bacterium powder, Rhodococcus ruber bacterium powder, Bacillus licheniformis powder, bacillus megaterium bacterium powder, Geotrichum bacterium powder, nitrated coccus bacterium powder, rhizopus bacterium powder, streptomycete bacterium powder, Staphylococcus pasteuri bacterium powder, water sprout grows bacillus bacterium powder, Shewanella decolorationis bacterium powder and bite ammonia secondary coccus bacterium powder, stir and Air Exposure with the rotating speed of 20rpm at water temperature 35-40 DEG C, after stirring Air Exposure 1h, leave standstill 3h,
Step 5: the sewage of step 4 is regulated pH to 4.5-6.0, the temperature continuing to keep water is 35-40 DEG C, add polygalacturonase, Enone reductase, nitroreductase, lignans hydroxylase, laccase, streptomyces proteinase, thioesterase, phytase, zytase, Nitrile hydratase, streptomyces proteinase, aldehyde dehydrogenase and M-Zyme, stir with the rotating speed of 20rpm, after stirring 1h, leave standstill 5h;
Step 6: add unslaked lime in the waste water that step 5 processed, stir with the rotating speed of 20rpm, leaves standstill 5h after stirring 30min, namely obtains the organic industry sewage processed after removing throw out.
Embodiment 3:
A kind of organic industry effluent purifier, is made up of the raw material of following weight part: diatomite 15, medical stone 20, graphene nano layer/MnO2 mixture 15, chitosan-graphene composite material 15, Tai-Ace S 150 17, ferric oxide 8, iron(ic) chloride 15, polyacrylamide 15, Chryseobacterium sp bacterium powder 1.0, pseudomonas putida bacterium powder 1.0, Pseudomonas fluorescens bacterium powder 1.0, polyP bacteria bacterium powder 1.0, Methionin genus bacillus bacterium powder 0.6, whiterot fungi bacterium powder 0.8, Rhodococcus ruber bacterium powder 0.6, Bacillus licheniformis powder 0.8, bacillus megaterium bacterium powder 0.6, Geotrichum bacterium powder 0.8, nitrated coccus bacterium powder 0.7, rhizopus bacterium powder 0.6, streptomycete bacterium powder 0.8, Staphylococcus pasteuri bacterium powder 0.9, water sprout grows bacillus bacterium powder 0.8, Shewanella decolorationis bacterium powder 0.6, bite ammonia secondary coccus bacterium powder 0.8, polygalacturonase 0.1, Enone reductase 0.1, nitroreductase 0.06, lignans hydroxylase 0.06, laccase 0.1, streptomyces proteinase 0.06, thioesterase 0.07, phytase 0.05, zytase 0.1, Nitrile hydratase 0.05, streptomyces proteinase 0.1, aldehyde dehydrogenase 0.07, M-Zyme 0.05, unslaked lime 400.
A using method for organic industry effluent purifier, comprises following step:
Step 1: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder;
Step 2: mix powder step 1 obtained at room temperature mixes with polyacrylamide, obtains mixture;
Step 3: add the mixture that step 2 obtains in organic industry sewage, carries out Air Exposure 30min to mixed solution, stirs 1h after aeration, quiescent setting 3h after stirring, and releases upper strata clear water, removes lower sediment thing;
Step 4: add Chryseobacterium sp bacterium powder in the clear water of step 3 gained upper strata, pseudomonas putida bacterium powder, Pseudomonas fluorescens bacterium powder, polyP bacteria bacterium powder, Methionin genus bacillus bacterium powder, whiterot fungi bacterium powder, Rhodococcus ruber bacterium powder, Bacillus licheniformis powder, bacillus megaterium bacterium powder, Geotrichum bacterium powder, nitrated coccus bacterium powder, rhizopus bacterium powder, streptomycete bacterium powder, Staphylococcus pasteuri bacterium powder, water sprout grows bacillus bacterium powder, Shewanella decolorationis bacterium powder and bite ammonia secondary coccus bacterium powder, stir and Air Exposure with the rotating speed of 15rpm at water temperature 35-40 DEG C, after stirring Air Exposure 1h, leave standstill 3h,
Step 5: the sewage of step 4 is regulated pH to 4.5-6.0, the temperature continuing to keep water is 35-40 DEG C, add polygalacturonase, Enone reductase, nitroreductase, lignans hydroxylase, laccase, streptomyces proteinase, thioesterase, phytase, zytase, Nitrile hydratase, streptomyces proteinase, aldehyde dehydrogenase and M-Zyme, stir with the rotating speed of 15rpm, after stirring 1h, leave standstill 4h;
Step 6: add unslaked lime in the waste water that step 5 processed, stir with the rotating speed of 15rpm, leaves standstill 4h after stirring 30min, namely obtains the organic industry sewage processed after removing throw out.
Embodiment 4:
A kind of organic industry effluent purifier, is made up of the raw material of following weight part: diatomite 15, medical stone 20, graphene nano layer/MnO2 mixture 15, chitosan-graphene composite material 15, Tai-Ace S 150 17, ferric oxide 8, cross-linked rectorite 9, iron(ic) chloride 15, polyacrylamide 15, Chryseobacterium sp bacterium powder 1.0, pseudomonas putida bacterium powder 1.0, Pseudomonas fluorescens bacterium powder 1.0, polyP bacteria bacterium powder 1.0, Methionin genus bacillus bacterium powder 0.6, whiterot fungi bacterium powder 0.8, Rhodococcus ruber bacterium powder 0.6, Bacillus licheniformis powder 0.8, bacillus megaterium bacterium powder 0.6, Geotrichum bacterium powder 0.8, nitrated coccus bacterium powder 0.7, rhizopus bacterium powder 0.6, streptomycete bacterium powder 0.8, Staphylococcus pasteuri bacterium powder 0.9, water sprout grows bacillus bacterium powder 0.8, Shewanella decolorationis bacterium powder 0.6, bite ammonia secondary coccus bacterium powder 0.8, polygalacturonase 0.1, Enone reductase 0.1, nitroreductase 0.06, lignans hydroxylase 0.06, laccase 0.1, streptomyces proteinase 0.06, thioesterase 0.07, phytase 0.05, zytase 0.1, Nitrile hydratase 0.05, streptomyces proteinase 0.1, aldehyde dehydrogenase 0.07, M-Zyme 0.05, unslaked lime 400.
A using method for organic industry effluent purifier, comprises following step:
Step 1: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide, cross-linked rectorite and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder;
Step 2: mix powder step 1 obtained at room temperature mixes with polyacrylamide, obtains mixture;
Step 3: add the mixture that step 2 obtains in organic industry sewage, carries out Air Exposure 30min to mixed solution, stirs 1h after aeration, quiescent setting 3h after stirring, and releases upper strata clear water, removes lower sediment thing;
Step 4: add Chryseobacterium sp bacterium powder in the clear water of step 3 gained upper strata, pseudomonas putida bacterium powder, Pseudomonas fluorescens bacterium powder, polyP bacteria bacterium powder, Methionin genus bacillus bacterium powder, whiterot fungi bacterium powder, Rhodococcus ruber bacterium powder, Bacillus licheniformis powder, bacillus megaterium bacterium powder, Geotrichum bacterium powder, nitrated coccus bacterium powder, rhizopus bacterium powder, streptomycete bacterium powder, Staphylococcus pasteuri bacterium powder, water sprout grows bacillus bacterium powder, Shewanella decolorationis bacterium powder and bite ammonia secondary coccus bacterium powder, stir and Air Exposure with the rotating speed of 15rpm at water temperature 35-40 DEG C, after stirring Air Exposure 1h, leave standstill 3h,
Step 5: the sewage of step 4 is regulated pH to 4.5-6.0, the temperature continuing to keep water is 35-40 DEG C, add polygalacturonase, Enone reductase, nitroreductase, lignans hydroxylase, laccase, streptomyces proteinase, thioesterase, phytase, zytase, Nitrile hydratase, streptomyces proteinase, aldehyde dehydrogenase and M-Zyme, stir with the rotating speed of 15rpm, after stirring 1h, leave standstill 4h;
Step 6: add unslaked lime in the waste water that step 5 processed, stir with the rotating speed of 15rpm, leaves standstill 4h after stirring 30min, namely obtains the organic industry sewage processed after removing throw out.
Embodiment 5:
A kind of organic industry effluent purifier, is made up of the raw material of following weight part: diatomite 15, medical stone 20, graphene nano layer/MnO2 mixture 15, chitosan-graphene composite material 15, Tai-Ace S 150 17, ferric oxide 8, wilkinite 9, iron(ic) chloride 15, polyacrylamide 15, Chryseobacterium sp bacterium powder 1.0, pseudomonas putida bacterium powder 1.0, Pseudomonas fluorescens bacterium powder 1.0, polyP bacteria bacterium powder 1.0, Methionin genus bacillus bacterium powder 0.6, whiterot fungi bacterium powder 0.8, Rhodococcus ruber bacterium powder 0.6, Bacillus licheniformis powder 0.8, bacillus megaterium bacterium powder 0.6, Geotrichum bacterium powder 0.8, nitrated coccus bacterium powder 0.7, rhizopus bacterium powder 0.6, streptomycete bacterium powder 0.8, Staphylococcus pasteuri bacterium powder 0.9, water sprout grows bacillus bacterium powder 0.8, Shewanella decolorationis bacterium powder 0.6, bite ammonia secondary coccus bacterium powder 0.8, polygalacturonase 0.1, Enone reductase 0.1, nitroreductase 0.06, lignans hydroxylase 0.06, laccase 0.1, streptomyces proteinase 0.06, thioesterase 0.07, phytase 0.05, zytase 0.1, Nitrile hydratase 0.05, streptomyces proteinase 0.1, aldehyde dehydrogenase 0.07, M-Zyme 0.05, unslaked lime 400.
A using method for organic industry effluent purifier, comprises following step:
Step 1: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide, wilkinite and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder;
Step 2: mix powder step 1 obtained at room temperature mixes with polyacrylamide, obtains mixture;
Step 3: add the mixture that step 2 obtains in organic industry sewage, carries out Air Exposure 30min to mixed solution, stirs 1h after aeration, quiescent setting 3h after stirring, and releases upper strata clear water, removes lower sediment thing;
Step 4: add Chryseobacterium sp bacterium powder in the clear water of step 3 gained upper strata, pseudomonas putida bacterium powder, Pseudomonas fluorescens bacterium powder, polyP bacteria bacterium powder, Methionin genus bacillus bacterium powder, whiterot fungi bacterium powder, Rhodococcus ruber bacterium powder, Bacillus licheniformis powder, bacillus megaterium bacterium powder, Geotrichum bacterium powder, nitrated coccus bacterium powder, rhizopus bacterium powder, streptomycete bacterium powder, Staphylococcus pasteuri bacterium powder, water sprout grows bacillus bacterium powder, Shewanella decolorationis bacterium powder and bite ammonia secondary coccus bacterium powder, stir and Air Exposure with the rotating speed of 15rpm at water temperature 35-40 DEG C, after stirring Air Exposure 1h, leave standstill 3h,
Step 5: the sewage of step 4 is regulated pH to 4.5-6.0, the temperature continuing to keep water is 35-40 DEG C, add polygalacturonase, Enone reductase, nitroreductase, lignans hydroxylase, laccase, streptomyces proteinase, thioesterase, phytase, zytase, Nitrile hydratase, streptomyces proteinase, aldehyde dehydrogenase and M-Zyme, stir with the rotating speed of 15rpm, after stirring 1h, leave standstill 4h;
Step 6: add unslaked lime in the waste water that step 5 processed, stir with the rotating speed of 15rpm, leaves standstill 4h after stirring 30min, namely obtains the organic industry sewage processed after removing throw out.
Waste water after embodiment 1-5 process, detects its each index as shown in table 1:
| CODcr（mg/L） | Nitrogen removal rate (%) | Ammonia nitrogen removal frank (%) | Benzene clearance (%) | |
| Embodiment 1 | 27.2 | 97 | 95.2 | 94.5 |
| Embodiment 2 | 26.5 | 97.3 | 95.7 | 94.7 |
| Embodiment 3 | 24.1 | 98 | 96.3 | 95.2 |
| Embodiment 4 | 23.9 | 98.2 | 96.5 | 96.6 |
| Embodiment 5 | 23.8 | 98.1 | 97.1 | 95.8 |
Table 1
Can see that the present invention has excellent treatment effect to the high nitrogen height chlorine height benzene organic industry sewage of process by table 1.
The above is only the preferred embodiment of the present invention, protection scope of the present invention be not only confined to above-described embodiment, and all technical schemes belonged under thinking of the present invention all belong to protection scope of the present invention.It should be pointed out that for those skilled in the art, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (7)
1. an organic industry effluent purifier, is characterized in that, is made up of the raw material of following weight part: diatomite 10-20, medical stone 10-30, graphene nano layer/MnO2 mixture 10-20, chitosan-graphene composite material 10-20, Tai-Ace S 150 15-20, ferric oxide 5-10, iron(ic) chloride 10-20, polyacrylamide 10-20, Chryseobacterium sp bacterium powder 0.5-1.5, pseudomonas putida bacterium powder 0.5-2.0, Pseudomonas fluorescens bacterium powder 0.5-2.0, polyP bacteria bacterium powder 0.5-1.5, Methionin genus bacillus bacterium powder 0.2-1.0, whiterot fungi bacterium powder 0.5-1.5, Rhodococcus ruber bacterium powder 0.2-1.0, Bacillus licheniformis powder 0.5-2.0, bacillus megaterium bacterium powder 0.2-1.0, Geotrichum bacterium powder 0.5-2.0, nitrated coccus bacterium powder 0.5-1.5, rhizopus bacterium powder 0.2-1.0, streptomycete bacterium powder 0.5-1.5, Staphylococcus pasteuri bacterium powder 0.5-2.0, water sprout grows bacillus bacterium powder 0.5-1.5, Shewanella decolorationis bacterium powder 0.2-1.0, bite ammonia secondary coccus bacterium powder 0.5-1.5, polygalacturonase 0.04-0.15, Enone reductase 0.03-0.2, nitroreductase 0.02-0.1, lignans hydroxylase 0.02-0.1, laccase 0.04-0.15, streptomyces proteinase 0.02-0.1, thioesterase 0.05-0.1, phytase 0.02-0.1, zytase 0.03-0.2, Nitrile hydratase 0.02-0.1, streptomyces proteinase 0.04-0.15, aldehyde dehydrogenase 0.05-0.1, M-Zyme 0.02-0.1, unslaked lime 200-500.
2. an a kind of organic industry effluent purifier as claimed in claim 1, is characterized in that, be made up of the raw material of following weight part: diatomite 15, medical stone 20, graphene nano layer/MnO2 mixture 15, chitosan-graphene composite material 15, Tai-Ace S 150 17, ferric oxide 8, iron(ic) chloride 15, polyacrylamide 15, Chryseobacterium sp bacterium powder 1.0, pseudomonas putida bacterium powder 1.0, Pseudomonas fluorescens bacterium powder 1.0, polyP bacteria bacterium powder 1.0, Methionin genus bacillus bacterium powder 0.6, whiterot fungi bacterium powder 0.8, Rhodococcus ruber bacterium powder 0.6, Bacillus licheniformis powder 0.8, bacillus megaterium bacterium powder 0.6, Geotrichum bacterium powder 0.8, nitrated coccus bacterium powder 0.7, rhizopus bacterium powder 0.6, streptomycete bacterium powder 0.8, Staphylococcus pasteuri bacterium powder 0.9, water sprout grows bacillus bacterium powder 0.8, Shewanella decolorationis bacterium powder 0.6, bite ammonia secondary coccus bacterium powder 0.8, polygalacturonase 0.1, Enone reductase 0.1, nitroreductase 0.06, lignans hydroxylase 0.06, laccase 0.1, streptomyces proteinase 0.06, thioesterase 0.07, phytase 0.05, zytase 0.1, Nitrile hydratase 0.05, streptomyces proteinase 0.1, aldehyde dehydrogenase 0.07, M-Zyme 0.05, unslaked lime 400.
3. an a kind of organic industry effluent purifier as claimed in claim 1, is characterized in that: also comprise cross-linked rectorite 6-12 weight part.
4. an a kind of organic industry effluent purifier as claimed in claim 1, is characterized in that: also comprise and draw together wilkinite 6-12 weight part.
5. the using method of a kind of organic industry effluent purifier as claimed in claim 1 or 2, comprises following step:
Step 1: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder;
Step 2: mix powder step 1 obtained at room temperature mixes with polyacrylamide, obtains mixture;
Step 3: add the mixture that step 2 obtains in organic industry sewage, carries out Air Exposure 30min to mixed solution, stirs 1h after aeration, quiescent setting 2-4h after stirring, and releases upper strata clear water, removes lower sediment thing;
Step 4: add Chryseobacterium sp bacterium powder in the clear water of step 3 gained upper strata, pseudomonas putida bacterium powder, Pseudomonas fluorescens bacterium powder, polyP bacteria bacterium powder, Methionin genus bacillus bacterium powder, whiterot fungi bacterium powder, Rhodococcus ruber bacterium powder, Bacillus licheniformis powder, bacillus megaterium bacterium powder, Geotrichum bacterium powder, nitrated coccus bacterium powder, rhizopus bacterium powder, streptomycete bacterium powder, Staphylococcus pasteuri bacterium powder, water sprout grows bacillus bacterium powder, Shewanella decolorationis bacterium powder and bite ammonia secondary coccus bacterium powder, stir and Air Exposure with the rotating speed of 10-20rpm at water temperature 35-40 DEG C, after stirring Air Exposure 1h, leave standstill 2-3h,
Step 5: the sewage of step 4 is regulated pH to 4.5-6.0, the temperature continuing to keep water is 35-40 DEG C, add polygalacturonase, Enone reductase, nitroreductase, lignans hydroxylase, laccase, streptomyces proteinase, thioesterase, phytase, zytase, Nitrile hydratase, streptomyces proteinase, aldehyde dehydrogenase and M-Zyme, stir with the rotating speed of 10-20rpm, after stirring 1h, leave standstill 3-5h;
Step 6: add unslaked lime in the waste water that step 5 processed, stir with the rotating speed of 10-20rpm, leaves standstill 3-5h after stirring 30min, namely obtains the organic industry sewage processed after removing throw out.
6. the using method of an a kind of organic industry effluent purifier as claimed in claim 5, it is characterized in that: described step 1 is specially: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide, cross-linked rectorite and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder.
7. the using method of an a kind of organic industry effluent purifier as claimed in claim 5, it is characterized in that: described step 1 is specially: by dry under the condition of 90 DEG C after diatomite, medical stone, graphene nano layer/MnO2 mixture, chitosan-graphene composite material, Tai-Ace S 150, ferric oxide, wilkinite and iron(ic) chloride Homogeneous phase mixing, be crushed to 300 orders after being down to room temperature, obtain mix powder.
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