CN105906071A - Microbial water treatment agent for heavy metal containing organic waste water - Google Patents
Microbial water treatment agent for heavy metal containing organic waste water Download PDFInfo
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- CN105906071A CN105906071A CN201610441075.2A CN201610441075A CN105906071A CN 105906071 A CN105906071 A CN 105906071A CN 201610441075 A CN201610441075 A CN 201610441075A CN 105906071 A CN105906071 A CN 105906071A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/342—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/347—Use of yeasts or fungi
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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Abstract
The invention belongs to the technical field of environment-friendly waste water treatment, and particularly relates to a microbial water treatment agent for heavy metal containing organic waste water. The microbial water treatment agent for the heavy metal containing organic waste water is prepared from dolomite powder, medical stone powder, anabaena azollae powder, water hyacinth powder, cladosporium sphaerospermum, Indian mustard powder, citrobacter amalonaticus, penicillium digitatum, hydroxyapatite powder, zeolite powder, citric acid, succinic acid, dicranopteris linearis powder, rhus lacquer powder, horse radish peroxidase, suillus bovines, laccaria amethystea, phanerochaete chrysosporium, bacillus subtilis, trichoderma koningii, trichoderma viride, bacillus mojavensis and klebsiella variicola. The microbial water treatment agent is high in treatment efficiency, low in running cost, wide in pH and temperature condition range, high in adsorbent reproducibility and free of secondary pollution.
Description
Technical field
The invention belongs to the technical field of waste water environmental protection treatment, be specifically related to a kind of for the microorganism water treatment agent containing heavy metal organic wastewater.
Background technology
Metallurgical, plating in recent years, process hides and catalyst such as prepare at a large amount of organic wastewaters containing high concentration heavy metal produced by industry, the most all by the water system being disposed to nature.These waste water are the most unprocessed will cause serious infringement to human health and life, and therefore the new method processing such waste water of development effective, harmless is extremely the most urgent.
The organic wastewater containing heavy metal is industrial wastewater most common, topmost, containing the organic pollution being difficult to degrade possibly together with dyestuff, aniline, phenol etc. while a large amount of high concentration heavy metals in this kind of waste water, the most this wastewater toxicity is big, difficult degradation, brings serious threat to the healthy of people and ecological environment.
Endanger extremely serious difficult degradation organic wastewater Han heavy metal for current, use following methods at present: oxidation-reduction method, electrolysis, evaporation concentration method and ion-exchange-resin process etc..In recent years, the method removing heavy metal in waste water mainly has 3 kinds: one to be by occurring chemical reaction to remove heavy metal ions in wastewater；Two is to adsorb it under conditions of the chemical form not changing heavy metal in waste water, concentrate, separate.Wherein absorption method is one of the more commonly used method.The main active charcoal of adsorbing material, ion exchange resin etc..Though activated carbon function admirable, China's activated carbon yield is few, and price is high, limits them and uses in some economically less developed regions and some industries.And utilizing exchanger resin to process electroplating wastewater is one of primary abatement method currently carrying out closed cycle, high treating effect, but regeneration liquid waste have Na+, Fe3+, the foreign ion such as Cl-, it is impossible to direct reuse is in coating bath, and enters environment and can pollute.
Summary of the invention
Present invention aims to process at present containing heavy metal organic wastewater cost height, the problem of secondary pollution can be produced and provide a kind of for the microorganism water treatment agent containing heavy metal organic wastewater, this microorganism water treatment agent treatment effeciency is high, operating cost is little, pH and temperature conditions wide ranges, adsorbent reactivation are strong, and will not produce secondary pollution.
The technical scheme is that a kind of for the microorganism water treatment agent containing heavy metal organic wastewater, including following raw material: dolomite dust, medical stone powder, Anabaena Azollae Based powder, phoenix eyes Nelumbo nucifera Gaertn. Powder, ball spore branch spore, Indian mustard powder, citric acid bacillus, penicillium digitatum, hydroxylapatite powder, zeolite powder, citric acid, succinic acid, ferrum Dicranopteris dichotoma powder, Rhus verniciferalaccase, horseradish peroxidase, Suillus bovines, amethyst wax mushroom, Phanerochaete chrysosporium, bacillus subtilis, koning trichoderma, Trichoderma viride, Mo Haiwei bacillus cereus and klebsiella.
nullDescribed for the microorganism water treatment agent containing heavy metal organic wastewater，It is made up of the raw material of following weight portion: dolomite dust 10-25 part、Medical stone powder 8-15 part、Anabaena Azollae Based powder 13-26 part、Phoenix eyes Nelumbo nucifera Gaertn. Powder 7-13 part、Ball spore branch spore 2-5 part、Indian mustard powder 11-19 part、Citric acid bacillus 0.7-1.4 part、Penicillium digitatum 1.2-2.0 part、Hydroxylapatite powder 8-16 part、Zeolite powder 11-22 part、Citric acid 3-7 part、Succinic acid 2-6 part、Ferrum Dicranopteris dichotoma powder 4-8 part、Rhus verniciferalaccase 1.1-2.1 part、Horseradish peroxidase 0.3-0.8 part、Suillus bovines 0.05-0.11 part、Amethyst wax mushroom 0.05-0.08 part、Phanerochaete chrysosporium 1.0-1.5 part、Bacillus subtilis 0.07-0.14 part、Koning trichoderma 1.5-2.0 part、Trichoderma viride 1.0-1.5 part、Mo Haiwei bacillus cereus 2-7 part and klebsiella 0.5-1.5 part.
nullDescribed for the microorganism water treatment agent containing heavy metal organic wastewater，It is made up of the raw material of following weight portion: dolomite dust 15-20 part、Medical stone powder 10-14 part、Anabaena Azollae Based powder 15-24 part、Phoenix eyes Nelumbo nucifera Gaertn. Powder 9-12 part、Ball spore branch spore 3-4 part、Indian mustard powder 15-18 part、Citric acid bacillus 1.0-1.3 part、Penicillium digitatum 1.5-1.8 part、Hydroxylapatite powder 10-14 part、Zeolite powder 15-20 part、Citric acid 4-6 part、Succinic acid 3-5 part、Ferrum Dicranopteris dichotoma powder 5-7 part、Rhus verniciferalaccase 1.5-2.0 part、Horseradish peroxidase 0.5-0.7 part、Suillus bovines 0.08-0.10 part、Amethyst wax mushroom 0.06-0.07 part、Phanerochaete chrysosporium 1.1-1.4 part、Bacillus subtilis 0.10-0.13 part、Koning trichoderma 1.7-1.9 part、Trichoderma viride 1.1-1.4 part、Mo Haiwei bacillus cereus 4-6 part and klebsiella 0.9-1.3 part.
Described for the microorganism water treatment agent containing heavy metal organic wastewater, it is made up of the raw material of following weight portion: dolomite dust 14 parts, medical stone powder 10 parts, 15 parts of Anabaena Azollae Based powder, phoenix eyes Nelumbo nucifera Gaertn. Powder 8 parts, ball spore branch spore 3 parts, 14 parts of Indian mustard powder, citric acid bacillus 0.9 part, penicillium digitatum 1.5 parts, hydroxylapatite powder 10 parts, zeolite powder 15 parts, citric acid 4.5 parts, succinic acid 3.5 parts, 5.5 parts of ferrum Dicranopteris dichotoma powder, Rhus verniciferalaccase 1.5 parts, horseradish peroxidase 0.45 part, Suillus bovines 0.08 part, 0.06 part of amethyst wax mushroom, Phanerochaete chrysosporium 1.1 parts, bacillus subtilis 0.09 part, koning trichoderma 1.7 parts, Trichoderma viride 1.2 parts, Mo Haiwei bacillus cereus 4 parts and klebsiella 0.8 part.
Described for the microorganism water treatment agent containing heavy metal organic wastewater, it is made up of the raw material of following weight portion: dolomite dust 22 parts, medical stone powder 14 parts, 23 parts of Anabaena Azollae Based powder, phoenix eyes Nelumbo nucifera Gaertn. Powder 12 parts, ball spore branch spore 4.5 parts, 18 parts of Indian mustard powder, citric acid bacillus 1.2 parts, penicillium digitatum 1.9 parts, hydroxylapatite powder 14 parts, zeolite powder 20 parts, citric acid 6 parts, succinic acid 5 parts, 6.5 parts of ferrum Dicranopteris dichotoma powder, Rhus verniciferalaccase 2.0 parts, horseradish peroxidase 0.65 part, Suillus bovines 0.06 part, 0.07 part of amethyst wax mushroom, Phanerochaete chrysosporium 1.3 parts, bacillus subtilis 0.12 part, koning trichoderma 1.9 parts, Trichoderma viride 1.4 parts, Mo Haiwei bacillus cereus 6 parts and klebsiella 1.2 parts.
Described dolomite dust is 40-60 mesh；Medical stone powder is 20-30 mesh.
Described hydroxylapatite powder is 30-50 mesh；Zeolite powder is 30-70 mesh.
Described Anabaena Azollae Based powder and Herba Eichhorniae are 80-100 mesh.
Described Indian mustard powder is 70-90 mesh, and described ferrum Dicranopteris dichotoma powder is 100-120 mesh.
The invention have the benefit that of the present invention for the microorganism water treatment agent containing heavy metal organic wastewater, including following raw material: dolomite dust, medical stone powder, Anabaena Azollae Based powder, phoenix eyes Nelumbo nucifera Gaertn. Powder, ball spore branch spore, Indian mustard powder, citric acid bacillus, penicillium digitatum, hydroxylapatite powder, zeolite powder, citric acid, succinic acid, ferrum Dicranopteris dichotoma powder, Rhus verniciferalaccase, horseradish peroxidase, Suillus bovines, amethyst wax mushroom, Phanerochaete chrysosporium, bacillus subtilis, koning trichoderma, Trichoderma viride, Mo Haiwei bacillus cereus and klebsiella.
First by combined to dolomite dust and medical stone powder collaborative, the metals such as the aluminum in waste water being produced adsorption, dolomite dust and medical stone powder are collaborative mutually to be made the adsorption rate of aluminum etc. is reached 91.3%-96.7%.
Phoenix eyes Nelumbo nucifera Gaertn. Powder, Indian mustard powder with ferrum Dicranopteris dichotoma powder, are carried out collocation and work in coordination with, heavy metal uranium, radium and thorium etc. can produce plants enriched adsorption, more existing plants enriched high 3～5 orders of magnitude of concentration coefficient BF of this kind of plant compound mode simultaneously.
Hydroxylapatite powder can produce good passivation effect to cadmium and arsenic with zeolite powder collocation simultaneously, reduces by two heavy metal species bio-toxicities.
By Mo Haiwei bacillus cereus and klebsiella phase matched combined, so that this water treatment agent has Biodegradable and safety, meet novel, efficient, nontoxic and without secondary pollution demand.Adding citric acid in this microorganism water treatment agent simultaneously and succinic acid is possible not only to form complex with the heavy metal such as lead, cadmium, citric acid can also provide favourable carbon source for the synthesis of microbial flocculant simultaneously.
Collaborative carry out the organic pollution in waste water of Rhus verniciferalaccase, horseradish peroxidase, Suillus bovines, amethyst wax mushroom, Phanerochaete chrysosporium being arranged in pairs or groups mutually with bacillus subtilis is the most directly degraded, and degradation rate organic in waste water is reached 94.87%-97.15%.
This microbiological garbage treatment agent has been also added with koning trichoderma and Trichoderma viride simultaneously, and the mutual coordinated of both Trichoderma spp. strengthens the adsorption effect of heavy metal.
With ball spore branch spore, Anabaena Azollae Based powder, citric acid bacillus, penicillium digitatum being collocated with each other combination, can adsorb uranium further, adsorption capacity reaches 170.31-185.20mg/g.
In sum, of the present invention can process the heavy metal in waste water and organic pollution for the microorganism water treatment agent containing heavy metal organic wastewater, wherein heavy metal clearance reaches 96.78%-98.72% simultaneously；The degradation rate of organic contamination is reached 96.23%-99.16% simultaneously.This water treatment agent carries out multi-faceted process to waste water, enumerate plants enriched, adsorb, be passivated, network, flocculate and multiple effect means of degrading.
Detailed description of the invention
Below by embodiment, the present invention will be described in detail.
Embodiment 1
Described for the microorganism water treatment agent containing heavy metal organic wastewater, it is made up of the raw material of following weight g: dolomite dust 10g, medical stone powder 8g, Anabaena Azollae Based powder 13g, phoenix eyes Nelumbo nucifera Gaertn. Powder 7g, ball spore branch spore 2g, Indian mustard powder 11g, citric acid bacillus 0.7g, penicillium digitatum 1.2g, hydroxylapatite powder 8g, zeolite powder 11g, citric acid 3g, succinic acid 2g, ferrum Dicranopteris dichotoma powder 4g, Rhus verniciferalaccase 1.1g, horseradish peroxidase 0.3g, Suillus bovines 0.05g, amethyst wax mushroom 0.05g, Phanerochaete chrysosporium 1.0g, bacillus subtilis 0.07g, koning trichoderma 1.5g, Trichoderma viride 1.0g, Mo Haiwei bacillus cereus 2g and klebsiella 0.5g.
Described dolomite dust is 40 mesh；Medical stone powder is 20 mesh.
Described hydroxylapatite powder is 30 mesh；Zeolite powder is 30 mesh.
Described Anabaena Azollae Based powder and Herba Eichhorniae are 80 mesh.
Described Indian mustard powder is 70 mesh, and described ferrum Dicranopteris dichotoma powder is 100 mesh.
The microorganism water treatment agent heavy metal clearance using the present embodiment reaches 96.98%；The degradation rate of organic contamination is reached 96.73% simultaneously.
Embodiment 2
Described for the microorganism water treatment agent containing heavy metal organic wastewater, it is made up of the raw material of following weight g: dolomite dust 25g, medical stone powder 15g, Anabaena Azollae Based powder 26g, phoenix eyes Nelumbo nucifera Gaertn. Powder 13g, ball spore branch spore 5g, Indian mustard powder 19g, citric acid bacillus 1.4g, penicillium digitatum 2.0g, hydroxylapatite powder 16g, zeolite powder 22g, citric acid 7g, succinic acid 6g, ferrum Dicranopteris dichotoma powder 8g, Rhus verniciferalaccase 2.1g, horseradish peroxidase 0.8g, Suillus bovines 0.11g, amethyst wax mushroom 0.08g, Phanerochaete chrysosporium 1.5g, bacillus subtilis 0.14g, koning trichoderma 2.0g, Trichoderma viride 1.5g, Mo Haiwei bacillus cereus 7g and klebsiella 1.5g.
Described dolomite dust is 60 mesh；Medical stone powder is 30 mesh.
Described hydroxylapatite powder is 50 mesh；Zeolite powder is 70 mesh.
Described Anabaena Azollae Based powder and Herba Eichhorniae are 100 mesh.
Described Indian mustard powder is 90 mesh, and described ferrum Dicranopteris dichotoma powder is 120 mesh.
The microorganism water treatment agent heavy metal clearance using the present embodiment reaches 98.32%；The degradation rate of organic contamination is reached 99.01% simultaneously.
Embodiment 3
Described for the microorganism water treatment agent containing heavy metal organic wastewater, it is made up of the raw material of following weight g: dolomite dust 15g, medical stone powder 10g, Anabaena Azollae Based powder 15g, phoenix eyes Nelumbo nucifera Gaertn. Powder 9g, ball spore branch spore 3g, Indian mustard powder 15g, citric acid bacillus 1.0g, penicillium digitatum 1.5g, hydroxylapatite powder 10g, zeolite powder 15g, citric acid 4g, succinic acid 3g, ferrum Dicranopteris dichotoma powder 5g, Rhus verniciferalaccase 1.5g, horseradish peroxidase 0.5g, Suillus bovines 0.08g, amethyst wax mushroom 0.06g, Phanerochaete chrysosporium 1.1g, bacillus subtilis 0.10g, koning trichoderma 1.7g, Trichoderma viride 1.1g, Mo Haiwei bacillus cereus 4g and klebsiella 0.9g.
Described dolomite dust is 45 mesh；Medical stone powder is 25 mesh.
Described hydroxylapatite powder is 40 mesh；Zeolite powder is 50 mesh.
Described Anabaena Azollae Based powder and Herba Eichhorniae are 90 mesh.
Described Indian mustard powder is 75 mesh, and described ferrum Dicranopteris dichotoma powder is 110 mesh.
The microorganism water treatment agent heavy metal clearance using the present embodiment reaches 97.58%；The degradation rate of organic contamination is reached 97.36% simultaneously.
Embodiment 4
Described for the microorganism water treatment agent containing heavy metal organic wastewater, it is made up of the raw material of following weight g: dolomite dust 14g, medical stone powder 10g, Anabaena Azollae Based powder 15g, phoenix eyes Nelumbo nucifera Gaertn. Powder 8g, ball spore branch spore 3g, Indian mustard powder 14g, citric acid bacillus 0.9g, penicillium digitatum 1.5g, hydroxylapatite powder 10g, zeolite powder 15g, citric acid 4.5g, succinic acid 3.5g, ferrum Dicranopteris dichotoma powder 5.5g, Rhus verniciferalaccase 1.5g, horseradish peroxidase 0.45g, Suillus bovines 0.08g, amethyst wax mushroom 0.06g, Phanerochaete chrysosporium 1.1g, bacillus subtilis 0.09g, koning trichoderma 1.7g, Trichoderma viride 1.2g, Mo Haiwei bacillus cereus 4g and klebsiella 0.8g.
Described dolomite dust is 55 mesh；Medical stone powder is 25 mesh.
Described hydroxylapatite powder is 45 mesh；Zeolite powder is 65 mesh.
Described Anabaena Azollae Based powder and Herba Eichhorniae are 95 mesh.
Described Indian mustard powder is 85 mesh, and described ferrum Dicranopteris dichotoma powder is 110 mesh.
The microorganism water treatment agent heavy metal clearance using the present embodiment reaches 98.42%；The degradation rate of organic contamination is reached 98.46% simultaneously.
Embodiment 5
Described for the microorganism water treatment agent containing heavy metal organic wastewater, it is made up of the raw material of following weight g: dolomite dust 22g, medical stone powder 14g, Anabaena Azollae Based powder 23g, phoenix eyes Nelumbo nucifera Gaertn. Powder 12g, ball spore branch spore 4.5g, Indian mustard powder 18g, citric acid bacillus 1.2g, penicillium digitatum 1.9g, hydroxylapatite powder 14g, zeolite powder 20g, citric acid 6g, succinic acid 5g, ferrum Dicranopteris dichotoma powder 6.5g, Rhus verniciferalaccase 2.0g, horseradish peroxidase 0.65g, Suillus bovines 0.06g, amethyst wax mushroom 0.07g, Phanerochaete chrysosporium 1.3g, bacillus subtilis 0.12g, koning trichoderma 1.9g, Trichoderma viride 1.4g, Mo Haiwei bacillus cereus 6g and klebsiella 1.2g.
Described dolomite dust is 50 mesh；Medical stone powder is 25 mesh.
Described hydroxylapatite powder is 45 mesh；Zeolite powder is 60 mesh.
Described Anabaena Azollae Based powder and Herba Eichhorniae are 90 mesh.
Described Indian mustard powder is 80 mesh, and described ferrum Dicranopteris dichotoma powder is 120 mesh.
The microorganism water treatment agent heavy metal clearance using the present embodiment reaches 98.72%；The degradation rate of organic contamination is reached 99.16% simultaneously.
Claims (9)
1. the microorganism water treatment agent being used for containing heavy metal organic wastewater, it is characterized in that, including following raw material: dolomite dust, medical stone powder, Anabaena Azollae Based powder, phoenix eyes Nelumbo nucifera Gaertn. Powder, ball spore branch spore, Indian mustard powder, citric acid bacillus, penicillium digitatum, hydroxylapatite powder, zeolite powder, citric acid, succinic acid, ferrum Dicranopteris dichotoma powder, Rhus verniciferalaccase, horseradish peroxidase, Suillus bovines, amethyst wax mushroom, Phanerochaete chrysosporium, bacillus subtilis, koning trichoderma, Trichoderma viride, Mo Haiwei bacillus cereus and klebsiella.
nullThe most according to claim 1 for the microorganism water treatment agent containing heavy metal organic wastewater，It is characterized in that，It is made up of the raw material of following weight portion: dolomite dust 10-25 part、Medical stone powder 8-15 part、Anabaena Azollae Based powder 13-26 part、Phoenix eyes Nelumbo nucifera Gaertn. Powder 7-13 part、Ball spore branch spore 2-5 part、Indian mustard powder 11-19 part、Citric acid bacillus 0.7-1.4 part、Penicillium digitatum 1.2-2.0 part、Hydroxylapatite powder 8-16 part、Zeolite powder 11-22 part、Citric acid 3-7 part、Succinic acid 2-6 part、Ferrum Dicranopteris dichotoma powder 4-8 part、Rhus verniciferalaccase 1.1-2.1 part、Horseradish peroxidase 0.3-0.8 part、Suillus bovines 0.05-0.11 part、Amethyst wax mushroom 0.05-0.08 part、Phanerochaete chrysosporium 1.0-1.5 part、Bacillus subtilis 0.07-0.14 part、Koning trichoderma 1.5-2.0 part、Trichoderma viride 1.0-1.5 part、Mo Haiwei bacillus cereus 2-7 part and klebsiella 0.5-1.5 part.
nullThe most according to claim 2 for the microorganism water treatment agent containing heavy metal organic wastewater，It is characterized in that，It is made up of the raw material of following weight portion: dolomite dust 15-20 part、Medical stone powder 10-14 part、Anabaena Azollae Based powder 15-24 part、Phoenix eyes Nelumbo nucifera Gaertn. Powder 9-12 part、Ball spore branch spore 3-4 part、Indian mustard powder 15-18 part、Citric acid bacillus 1.0-1.3 part、Penicillium digitatum 1.5-1.8 part、Hydroxylapatite powder 10-14 part、Zeolite powder 15-20 part、Citric acid 4-6 part、Succinic acid 3-5 part、Ferrum Dicranopteris dichotoma powder 5-7 part、Rhus verniciferalaccase 1.5-2.0 part、Horseradish peroxidase 0.5-0.7 part、Suillus bovines 0.08-0.10 part、Amethyst wax mushroom 0.06-0.07 part、Phanerochaete chrysosporium 1.1-1.4 part、Bacillus subtilis 0.10-0.13 part、Koning trichoderma 1.7-1.9 part、Trichoderma viride 1.1-1.4 part、Mo Haiwei bacillus cereus 4-6 part and klebsiella 0.9-1.3 part.
nullThe most according to claim 2 for the microorganism water treatment agent containing heavy metal organic wastewater，It is characterized in that，It is made up of the raw material of following weight portion: dolomite dust 14 parts、Medical stone powder 10 parts、15 parts of Anabaena Azollae Based powder、Phoenix eyes Nelumbo nucifera Gaertn. Powder 8 parts、Ball spore branch spore 3 parts、14 parts of Indian mustard powder、Citric acid bacillus 0.9 part、Penicillium digitatum 1.5 parts、Hydroxylapatite powder 10 parts、Zeolite powder 15 parts、Citric acid 4.5 parts、Succinic acid 3.5 parts、5.5 parts of ferrum Dicranopteris dichotoma powder、Rhus verniciferalaccase 1.5 parts、Horseradish peroxidase 0.45 part、Suillus bovines 0.08 part、0.06 part of amethyst wax mushroom、Phanerochaete chrysosporium 1.1 parts、Bacillus subtilis 0.09 part、Koning trichoderma 1.7 parts、Trichoderma viride 1.2 parts、Mo Haiwei bacillus cereus 4 parts and klebsiella 0.8 part.
nullThe most according to claim 2 for the microorganism water treatment agent containing heavy metal organic wastewater，It is characterized in that，It is made up of the raw material of following weight portion: dolomite dust 22 parts、Medical stone powder 14 parts、23 parts of Anabaena Azollae Based powder、Phoenix eyes Nelumbo nucifera Gaertn. Powder 12 parts、Ball spore branch spore 4.5 parts、18 parts of Indian mustard powder、Citric acid bacillus 1.2 parts、Penicillium digitatum 1.9 parts、Hydroxylapatite powder 14 parts、Zeolite powder 20 parts、Citric acid 6 parts、Succinic acid 5 parts、6.5 parts of ferrum Dicranopteris dichotoma powder、Rhus verniciferalaccase 2.0 parts、Horseradish peroxidase 0.65 part、Suillus bovines 0.06 part、0.07 part of amethyst wax mushroom、Phanerochaete chrysosporium 1.3 parts、Bacillus subtilis 0.12 part、Koning trichoderma 1.9 parts、Trichoderma viride 1.4 parts、Mo Haiwei bacillus cereus 6 parts and klebsiella 1.2 parts.
6. according to the microorganism water treatment agent being used for according to any one of claim 1-5 containing heavy metal organic wastewater, it is characterised in that described dolomite dust is 40-60 mesh；Medical stone powder is 20-30 mesh.
The most according to claim 6 for the microorganism water treatment agent containing heavy metal organic wastewater, it is characterised in that described hydroxylapatite powder is 30-50 mesh；Zeolite powder is 30-70 mesh.
8. according to the microorganism water treatment agent being used for according to any one of claim 1-5 containing heavy metal organic wastewater, it is characterised in that described Anabaena Azollae Based powder and Herba Eichhorniae are 80-100 mesh.
The most according to claim 8 for the microorganism water treatment agent containing heavy metal organic wastewater, it is characterised in that described Indian mustard powder is 70-90 mesh, and described ferrum Dicranopteris dichotoma powder is 100-120 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610441075.2A CN105906071A (en) | 2016-06-20 | 2016-06-20 | Microbial water treatment agent for heavy metal containing organic waste water |
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| CN201610441075.2A CN105906071A (en) | 2016-06-20 | 2016-06-20 | Microbial water treatment agent for heavy metal containing organic waste water |
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| CN106987535A (en) * | 2017-03-01 | 2017-07-28 | 沃邦环保有限公司 | It is a kind of for complex micro organism fungicide of river regulation and preparation method thereof, river sewage processing method |
| CN106987536A (en) * | 2017-03-01 | 2017-07-28 | 沃邦环保有限公司 | Complex micro organism fungicide for river regulation and its preparation method and application |
| CN107043718A (en) * | 2017-03-01 | 2017-08-15 | 沃邦环保有限公司 | It is a kind of for complex micro organism fungicide of river regulation and its preparation method and application |
| CN107469783A (en) * | 2017-08-30 | 2017-12-15 | 常州市天宁区鑫发织造有限公司 | A kind of preparation method of biomass metal absorbent |
| CN108865154A (en) * | 2018-06-11 | 2018-11-23 | 佛山皖阳生物科技有限公司 | A kind of cadmium soil remediation biological agent |
| CN113332960A (en) * | 2021-03-23 | 2021-09-03 | 中南大学 | Supported apatite composite adsorption material and preparation method and application thereof |
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| CN106987535A (en) * | 2017-03-01 | 2017-07-28 | 沃邦环保有限公司 | It is a kind of for complex micro organism fungicide of river regulation and preparation method thereof, river sewage processing method |
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| CN107043718A (en) * | 2017-03-01 | 2017-08-15 | 沃邦环保有限公司 | It is a kind of for complex micro organism fungicide of river regulation and its preparation method and application |
| CN107469783A (en) * | 2017-08-30 | 2017-12-15 | 常州市天宁区鑫发织造有限公司 | A kind of preparation method of biomass metal absorbent |
| CN107469783B (en) * | 2017-08-30 | 2020-08-14 | 胜利油田新邦石油科技有限责任公司 | Preparation method of biomass metal adsorbent |
| CN108865154A (en) * | 2018-06-11 | 2018-11-23 | 佛山皖阳生物科技有限公司 | A kind of cadmium soil remediation biological agent |
| CN113332960A (en) * | 2021-03-23 | 2021-09-03 | 中南大学 | Supported apatite composite adsorption material and preparation method and application thereof |
| CN113651512A (en) * | 2021-08-16 | 2021-11-16 | 中南大学 | Method for passivating heavy metal lead in bottom mud by coupling white-rot fungi with insoluble apatite |
| CN116948896A (en) * | 2023-07-20 | 2023-10-27 | 西南大学 | Klebsiella variabilis, sodium alginate microcapsule and application thereof in cadmium polluted soil treatment |
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