CN105495686A - Moisture-proof and embrittling treatment method of cigarette capsules and product obtained by treatment method - Google Patents
Moisture-proof and embrittling treatment method of cigarette capsules and product obtained by treatment method Download PDFInfo
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- CN105495686A CN105495686A CN201610054655.6A CN201610054655A CN105495686A CN 105495686 A CN105495686 A CN 105495686A CN 201610054655 A CN201610054655 A CN 201610054655A CN 105495686 A CN105495686 A CN 105495686A
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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Abstract
The invention relates to a moisture-proof and embrittling treatment method of cigarette capsules and a moisture-proof embrittling cigarette capsule. The treatment method comprises steps: preparing cigarette capsules, post-treating cigarette capsules, preparing a coating liquid and a coating and the like. The moisture-proof and embrittling treatment method of the cigarette capsules enables improved brittleness for cigarette capsules, an improvement of 25.0-37.9 % in moisture-proof effect, an improvement in capsule surface gloss and thereby improvements in cigarette capsule appearance and quality of use.
Description
[technical field]
The invention belongs to technical field of cigarette processing.More specifically, the present invention relates to the protection against the tide of a kind of cigarette capsule and increase crisp processing method, also relate to the cigarette capsule that the crisp processing method of described protection against the tide increasing obtains.
[background technology]
Cigarette capsule refers to a certain amount of flavouring essence for tobacco, is sealed in spherical soft capsule by pressing or dropping preparation method.Cigarette capsule being added in filter stick for cigarettes, enabling cigarette burn and suck under state or people discharges fragrance component for pinching brokenly, play flavouring and improve the effect of inhaling taste.Cigarette capsule is mainly made with wall material raw materials such as gelatin, natural plant gum, plant polyose, polyethylene glycol, because these raw materials are hydroaropic substance, so cigarette capsule places a period of time in open environment, constantly can absorb the moisture in air, there is the phenomenon such as softening of making moist, reduce cigarette capsule appearance quality and using character.
Existing moisture-proof coating technology, sugar-coat technology are replaced by film-coated technique gradually because of auxiliary material security and poor stability problem.Film coating is evenly sprayed on thing wicking surface with spray pattern by macromolecular compound under suitable solvent and certain processing conditions, forms the macromolecule material film layer of number micron thickness.It is short that film-coated technique not only has Coating times, and film forming is even, and increase weight little, security is high, also has certain moisture effect.CN104799432A discloses and uses pulullan polysaccharide to carry out film coating to cigarette capsule, make cigarette capsule surface smooth glossy, the film formed has certain gas barrier property and oil resistivity, but its defect is with pure pulullan polysaccharide dressing, cost is high, and film hardness is excessive and cause not easily broken, affects cigarette capsule result of use.CN102895926A reacts by polyvalent metal ion in glue and shitosan to form water-fast chitin metal salt chelate, can reach effective moisture resistance, but the film generated is thin and soft, not anti-extrusion.Current coating material is mainly divided into water-soluble and fat-soluble two kinds of coating materials.Water-soluble material mainly comprises hydroxypropyl methylcellulose (HPMC), polyacrylic resin class, polyethylene glycol (PEG) and PVP (PVP) etc.; Fat soluble materials mainly comprises ethyl cellulose (EC), CAP (CAP) and polyethylene rope acetaldehyde diethylamine acetate (AEA) etc.
Add in cigarette filter rod and carry cigarette capsule, not only will considering that cigarette capsule easily absorbs water in open environment and make moist, also will considering part smoker custom at suction cigarette through just being pinched brokenly by the capsule in filter stick after a period of time simultaneously.The main flume that cigarette produces when suction fuel is also mingled with the moisture of certain content, and capsule impacts lower ruckbildung through the main flume that high temperature contains moisture can be more serious, very needs so the humidity resistance finding a kind of processing method raising filter stick capsule seems.
Hydroxypropyl methylcellulose (HPMC) is the pharmaceutical polymers with premium properties, obtains by reacting with propylene oxide at high temperature under high pressure after methylcellulose naoh treatment.Finished product is white to milky, tasteless, and odorless dissolves and forms the transparent or sticking colloidal solution of milky tool in water.According to the difference of methoxyl group and hydroxypropyl content, HPMC can be divided into different grades, and wherein E type is usually used in dressing filmogen, is characterized in smooth appearance, good film-forming property.HPMC both can be dissolved in ethanol also can be water-soluble.Polyethylene glycol (PEG-4000) is good coating material, can be used as plasticizer and hydrophilic polishing agent, and the polyvinyl alcohol (PVA) of low polymerization degree has stronger caking property, gas barrier performance and certain water proofing property.
[summary of the invention]
[technical problem that will solve]
The object of this invention is to provide the protection against the tide of a kind of cigarette capsule and increase crisp processing method.
Another object of the present invention is to provide the cigarette capsule that the crisp process of a kind of protection against the tide increasing obtains.
[technical scheme]
The present invention is achieved through the following technical solutions.
The present invention relates to the protection against the tide of a kind of cigarette capsule and increase crisp processing method.
The step of this processing method is as follows:
A, prepare cigarette capsule
By 1 ~ 1.5 weight portion film forming agent, 0.1 ~ 0.5 parts by weight of plasticizer, 0.1 ~ 0.5 weight portion polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The cigarette capsule allowing steps A obtain soaks 2 ~ 5 minutes in saturated aqueous metal salt, then takes out described capsule, then to be put in rotating cage at room temperature forced air drying 3.5 ~ 4.5 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
By 10 ~ 15 weight portion film forming agents, 1 ~ 5 parts by weight of plasticizer, 1 ~ 5 weight portion stabilizing agent and be supplemented to 100 weight parts waters or ethanol water mixes, obtain a kind of coating solution;
D, dressing
At temperature 20 ~ 30 DEG C, air quantity 150 ~ 350m in high-efficiency coating pot
3/ hr, hot blast temperature 20 ~ 40 DEG C are with under the condition of rotating speed 20 ~ 40rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.2 ~ 0.3, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 25 ~ 35min at temperature 30 ~ 40 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 35 ~ 45% dehumidifying between in, leave standstill 3 ~ 5h, carry out increasing crisp process, so obtain described cigarette capsule product.
A preferred embodiment of the invention, in step, described film forming agent is that one or more are selected from the film forming agent of carragheen, Arabic gum or malt extract; Described plasticizer is that one or more are selected from the plasticizer of glycerine, polyethylene glycol or sorbierite; Described polysaccharide copolymer is that one or more are selected from the polysaccharide copolymer of algal polysaccharides, starch or pectin.
According to another kind of preferred embodiment of the present invention, in stepb, described slaine is that one or more are selected from the slaine of sylvite, magnesium salts or calcium salt.
According to another kind of preferred embodiment of the present invention, described slaine is sulfate, nitrate, phosphate, carbonate or chloride.
Another kind of preferred embodiment according to the present invention is in step C, and described film forming agent is that one or more are selected from the film forming agent of hydroxypropyl methylcellulose, hydroxypropyl cellulose, ethyl cellulose or cellulose acetate; Described plasticizer is that one or more are selected from the plasticizer of polyethylene glycol, glycerine or propane diols; Described stabilizing agent is that one or more are selected from the stabilizing agent of polyethylene glycol, polyvinyl alcohol or PVP.
According to another kind of preferred embodiment of the present invention, in step C, the concentration of described ethanol water is by volume 50 ~ 70%.
The invention still further relates to the protection against the tide adopting the crisp disposal methods of described protection against the tide increasing to obtain and increase crisp cigarette capsule.
According to another kind of preferred embodiment of the present invention, described protection against the tide increases crisp cigarette capsule and has following characteristic:
At the water absorption rate 0.35 ~ 0.40% of 30min; Water absorption rate 0.41 ~ 0.52% at 60min: the water absorption rate 0.63 ~ 0.73% at 120min:
At the withstand voltage 1.41 ~ 1.51Kg of 30min; At the withstand voltage 1.49 ~ 1.59Kg of 60min; At the withstand voltage 1.52 ~ 1.67Kg of 120min.
In more detail the present invention will be described below.
The present invention relates to the protection against the tide of a kind of cigarette capsule and increase crisp processing method.
The step of this processing method is as follows:
A, prepare cigarette capsule
By 1 ~ 1.5 weight portion film forming agent, 0.1 ~ 0.5 parts by weight of plasticizer, 0.1 ~ 0.5 weight portion polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
According to the present invention; described film forming agent should be appreciated that it is that some can form continuous film, to cigarette quality and the healthy polymer without any negative interaction of smoker; every material with this performance may be used to the present invention, and they are also all within protection scope of the present invention.
The film forming agent that the present invention uses is preferably carragheen, Arabic gum or malt extract.Carragheen is the hydrophilic colloid extract from the red algae sea grass such as Eucheuma, calcium, potassium, sodium, the ammonium salt of the polysaccharide sulfuric ester that its chemical constitution is made up of galactolipin and Anhydrogalactose.Arabic gum derives from the trunk exudate of Acacia Pterostyrax, and its main component is high molecular polysaccharide and calcium, magnesium and sylvite.Malt extract carries out deep processing with fructus hordei germinatus, its barley elite of extracting and the one made is thick, the product of the peculiar fragrance of tool Fructus Hordei Germinatus.They are all product solds in the market, such as, the carragheen sold with trade name carragheen by Qingdao De Hui marine organisms Science and Technology Ltd., the Arabic gum sold with trade name gum arabic by Dongli District, Tianjin Li Chang Chemical Co., Ltd., believe by Chengdu ten thousand malt extract that Chemical Co., Ltd. sells with trade name malt extract.
According to the present invention; described plasticizer should be appreciated that it is a kind of industrial macromolecular material auxiliary agent be widely used; its pliability can be made to strengthen when adding this material; easy processing; every material with this performance may be used to the present invention, and they are also all within protection scope of the present invention.
The plasticizer that the present invention uses is the plasticizer of glycerine, polyethylene glycol or sorbierite, they are all product solds in the market, the sorbierite that the glycerine such as sold with trade name glycerine by Chemical Reagent Co., Ltd., Sinopharm Group, the polyethylene glycol sold with trade name PEG-4000 by Chemical Reagent Co., Ltd., Sinopharm Group, effluent Bei Huaxu medicine company Co., Ltd sell with trade name Neosorb.
The polysaccharide copolymer that the present invention uses is algal polysaccharides, starch or pectin.Algal polysaccharides is mainly from marine algas such as sea-tangle, bulk kelp, yellow tangs, and algal polysaccharides mainly comprises algin, fucoidin and laminaran.Be stored in the storage polysaccharide in cell with form of starch grains during starch is plant growth.Its content in the organs such as seed, stem tuber and block root is abundant especially.Pectin is one group of polygalacturonic acid, and its solution can form gel and partly methoxylation occur under appropriate conditions.
In the present invention, the Main Function of described polysaccharide copolymer is the toughness increasing capsule wall material.
The polysaccharide copolymer that the present invention uses is all product sold in the market, algal polysaccharides, the starch sold with trade name modified starch by Chemical Reagent Co., Ltd., Sinopharm Group or the pectin sold with trade name pectin by Chemical Reagent Co., Ltd., Sinopharm Group that such as effluent Nan great Yuan food additives Co., Ltd sells with trade name algin.
In the present invention, if when the amount of polysaccharide copolymer and plasticizer is in described scope, if the amount of film forming agent is less than 1.0 weight portions, then affect capsule shaping process; If the amount of film forming agent is greater than 1.5 weight portions, then glue thickness is unfavorable for prepared by capsule; Therefore the amount of film forming agent is 1.0 ~ 1.5 weight portions is rational, preferably 1.1 ~ 1.4 weight portions, more preferably 1.2 ~ 1.3 weight portions.
If when the amount of polysaccharide copolymer and film forming agent is in described scope, if the amount of plasticizer is less than 0.1 weight portion, then reduce the toughness of capsule wall material; If the amount of plasticizer is greater than 0.5 weight portion, then affect capsule dryness finalization process; Therefore the amount of plasticizer is 0.1 ~ 0.5 weight portion is rational, preferably 0.2 ~ 0.4 weight portion, more preferably 0.3 weight portion.
If when the amount of film forming agent and plasticizer is in described scope, if the amount of polysaccharide copolymer is less than 0.1 weight portion, then reduce the toughness of capsule wall material; If the amount of polysaccharide copolymer is greater than 0.5 weight portion, then glue thickness is unfavorable for prepared by capsule; Therefore the amount of polysaccharide copolymer is 0.1 ~ 0.5 weight portion is rational, preferably 0.2 ~ 0.4 weight portion, more preferably 0.3 weight portion.
The capsule post processing of B, cigarette
The cigarette capsule allowing steps A obtain soaks 2 ~ 5 minutes in saturated aqueous metal salt, then takes out described capsule, then to be put in rotating cage at room temperature forced air drying 3.5 ~ 4.5 hours, obtains semi-finished product cigarette capsule;
In the present invention, the effect that described cigarette capsule soaks in saturated aqueous metal salt is mainly that the polysaccharide material on rubber surface and ionizable metal salt react and improve capsule toughness.
According to the present invention, described slaine is sylvite, magnesium salts or calcium salt.Preferably, described slaine is sulfate, nitrate, phosphate, carbonate or chloride.More preferably, described slaine is sulfate, phosphate or chloride.
Cigarette capsule of the present invention is after with rotating cage forced air drying, and its water content should be less than 2% of semi-finished product cigarette capsules weight.If its water content is higher than this scope, then can make capsule deliquescing.
C, prepare coating solution
By 10 ~ 15 weight portion film forming agents, 1 ~ 5 parts by weight of plasticizer, 1 ~ 5 weight portion stabilizing agent and be supplemented to 100 weight parts waters or ethanol water mixes, obtain a kind of coating solution;
The chemical sense of the film forming agent used in this step and plasticizer and previously described identical, does not repeat them here.
In the present invention, the Main Function of described film forming agent is to have film forming.The film forming agent that the present invention uses is hydroxypropyl methylcellulose, hydroxypropyl cellulose, ethyl cellulose or cellulose acetate.The film forming agent that the present invention uses is product sold in the market, hydroxypropyl methylcellulose, hydroxypropyl cellulose, ethyl cellulose or cellulose acetate that such as Chemical Reagent Co., Ltd., Sinopharm Group sells.
In the present invention, the Main Function of described plasticizer is, for coatings provides toughness, to prevent coating film from occurring crackle, affect outward appearance.
The plasticizer that the present invention uses is polyethylene glycol, glycerine or propane diols, polyethylene glycol, glycerine, propane diols that such as Chemical Reagent Co., Ltd., Sinopharm Group sells.
The present invention uses the Main Function of stabilizing agent to be stable coating solution viscous systems, and that improves coating film draws high intensity.
The stabilizing agent that the present invention uses is polyethylene glycol, polyvinyl alcohol or PVP, polyethylene glycol, polyvinyl alcohol, PVP that such as Chemical Reagent Co., Ltd., Sinopharm Group sells.
In the present invention, if when the amount of stabilizing agent and plasticizer is in described scope, if the amount of film forming agent is less than 10 weight portions, then dressing rate of film build declines; If the amount of film forming agent is greater than 15 weight portions, then dressing film forming is uneven; Therefore the amount of film forming agent is 10 ~ 15 weight portions is rational, preferably 11 ~ 14 weight portions, more preferably 12 ~ 13 weight portions.
If when the amount of stabilizing agent film forming agent is in described scope, if the amount of plasticizer is less than 1 weight portion, then coating film easily comes off; If the amount of plasticizer is greater than 5 weight portions, then reduce film forming; Therefore the amount of plasticizer is 1 ~ 5 weight portion is rational, preferably 2 ~ 4 weight portions, more preferably 3 weight portions.
If when the amount of film forming agent and plasticizer is in described scope, if the amount of stabilizing agent is less than 1 weight portion, be then unfavorable for that film adsorbs in capsule surface; If the amount of stabilizing agent is greater than 5 weight portions, then make that film forming is uneven affects capsule appearance; Therefore the amount of stabilizing agent is 1 ~ 5 weight portion is rational, preferably 2 ~ 4 weight portions, more preferably 3 weight portions.
In the present invention, the concentration of ethanol water is used to be by volume 50 ~ 70%.
D, dressing
At temperature 20 ~ 30 DEG C, air quantity 150 ~ 350m in high-efficiency coating pot
3/ hr, hot blast temperature 20 ~ 40 DEG C are with under the condition of rotating speed 20 ~ 40rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.2 ~ 0.3, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 25 ~ 35min at temperature 30 ~ 40 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 35 ~ 45% dehumidifying between in, leave standstill 3 ~ 5h, carry out increasing crisp process, so obtain described cigarette capsule product.
The high-efficiency coating pot that this step uses is a kind of product of spray structure with controlled normal temperature hot-air system, automatic liquid supply air feed, and it is one product sold in the market, such as, by Guangzhou Chen Diao plant equipment Co., Ltd product sold.
Semi-finished product cigarette capsule in high-efficiency coating pot the drying coated by coating solution reaches water content below 5%, its object is to reduce film surface moisture.
Dry cigarette capsule be placed on relative humidity be 35 ~ 45% dehumidifying between in the effect of process be that the moisture stabilization in capsule surface coating film is scattered and disappeared.
The invention still further relates to the protection against the tide adopting the crisp disposal methods of described protection against the tide increasing to obtain and increase crisp cigarette capsule.The present invention's protection against the tide increases the concrete structure of crisp cigarette capsule see accompanying drawing 1.
At temperature 25 DEG C with the condition of relative humidity 80%, increase crisp cigarette capsule to described protection against the tide measure, its result is as follows:
At the water absorption rate 0.35 ~ 0.40% of 30min; Water absorption rate 0.41 ~ 0.52% at 60min: the water absorption rate 0.63 ~ 0.73% at 120min:
At the withstand voltage 1.41 ~ 1.51Kg of 30min; At the withstand voltage 1.49 ~ 1.59Kg of 60min; At the withstand voltage 1.52 ~ 1.67Kg of 120min.
Cigarette capsule (the cigarette capsule that the steps A prepares) measurement result increasing crisp process without protection against the tide is as follows:
At the water absorption rate 0.42 ~ 0.51% of 30min; Water absorption rate 0.53 ~ 0.66% at 60min: the water absorption rate 0.72 ~ 0.84% at 120min:
At the withstand voltage 1.53 ~ 1.67Kg of 30min; At the withstand voltage 1.72 ~ 1.83Kg of 60min; At the withstand voltage 1.79 ~ 1.96Kg of 120min.
The above results shows, the protection against the tide increasing fragility that protection against the tide of the present invention increases crisp cigarette capsule can significantly improve.
[beneficial effect]
The invention has the beneficial effects as follows: the present invention, by adding a small amount of polysaccharide copolymer in the glue preparing cigarette capsule, adopts saturated metal salt solution to soak, to improve the fragility of cigarette capsule before the drying.Phase is by art for coating after treatment, forms the polymeric membrane of one deck densification in cigarette capsule surface, blocks extraneous moisture and directly contacts with cigarette capsule wall material, effectively reach moisture effect.After dressing completes, carry out drying, polishing, the crisp process of increasing, glossiness and the fragility of capsule surface can be improved, reach the outward appearance and using character that improve cigarette capsule.
[accompanying drawing explanation]
Fig. 1 is that the present invention's protection against the tide increases crisp cigarette capsule structure schematic diagram.
[detailed description of the invention]
The present invention can be understood better by following embodiment.
Embodiment 1: the protection against the tide of cigarette capsule increases crisp process
The implementation step of this embodiment is as follows:
A, prepare cigarette capsule
By 1.1 weight portion carragheen film forming agents, 0.3 parts by weight of glycerin plasticizer, 0.2 weight portion algal polysaccharides copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The first tobacco curing capsule allowing steps A obtain soaks 3 minutes in saturated potassium sulfate solution, then takes out described cigarette capsule, then to be put in rotating cage at room temperature forced air drying 3.5 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
By 12 weight portion hydroxypropyl methylcellulose film forming agents, 2 weight portion polyethylene glycol plasticizer, 3 weight account polyethylene alcohol stabilizing agents and be supplemented to 100 weight parts waters and mix, obtain a kind of coating solution;
D, dressing
At temperature 20 DEG C, air quantity 180m in the high-efficiency coating pot sold by Guangzhou Chen Diao plant equipment Co., Ltd
3/ hr, hot blast temperature 30 DEG C are with under the condition of rotating speed 30rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.2, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 25min at temperature 40 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 45% dehumidifying between in, leave standstill 4.0h, carry out drying and increase crisp process, so obtain described cigarette capsule product.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.36% of 30min; Water absorption rate 0.52% at 60min: the water absorption rate 0.63% at 120min:
At the withstand voltage 1.50Kg of 30min; At the withstand voltage 1.56Kg of 60min; At the withstand voltage 1.52Kg of 120min.
Embodiment 2: the protection against the tide of cigarette capsule increases crisp process
The implementation step of this embodiment is as follows:
A, prepare cigarette capsule
By 1.4 weight portion Arabic gum film forming agents, 0.1 weight portion polyethylene glycol plasticizer, 0.4 weight portion wheaten starch polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The first tobacco curing capsule allowing steps A obtain soaks 5 minutes in unsaturated carbonate magnesium salt solution, then takes out described cigarette capsule, then to be put in rotating cage at room temperature forced air drying 3.8 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
By 13 weight portion hydroxypropyl cellulose film forming agents, 4 parts by weight of glycerin plasticizer, polyethylene glycol stabilized dose of 3 weight portions and be supplemented to 100 weight parts waters and mix, obtain a kind of coating solution;
D, dressing
At temperature 24 DEG C, air quantity 230m in the high-efficiency coating pot sold by Guangzhou Chen Diao plant equipment Co., Ltd
3/ hr, hot blast temperature 25 DEG C are with under the condition of rotating speed 25rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.3, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 26min at temperature 30 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 40% dehumidifying between in, leave standstill 3.0h, carry out drying and increase crisp process, so obtain described cigarette capsule product.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.35% of 30min; Water absorption rate 0.41% at 60min: the water absorption rate 0.65% at 120min:
At the withstand voltage 1.46Kg of 30min; At the withstand voltage 1.58Kg of 60min; At the withstand voltage 1.65Kg of 120min.
Embodiment 3: the protection against the tide of cigarette capsule increases crisp process
The implementation step of this embodiment is as follows:
A, prepare cigarette capsule
By 1 weight portion malt extract film forming agent, 0.5 weight portion sorbierite plasticizer, 0.1 weight portion pectin polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The first tobacco curing capsule allowing steps A obtain soaks 2 minutes in the saturated calcium chloride salt aqueous solution, then takes out described cigarette capsule, then to be put in rotating cage at room temperature forced air drying 4.2 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
By 10 weight portion ethyl cellulose film forming agents, 1 parts by weight of propylene glycol plasticizer, 1 weight portion PVP stabilizing agent and be supplemented to 100 weight parts waters and mix, obtain a kind of coating solution;
D, dressing
At temperature 30 DEG C, air quantity 150m in the high-efficiency coating pot sold by Guangzhou Chen Diao plant equipment Co., Ltd
3/ hr, hot blast temperature 20 DEG C are with under the condition of rotating speed 20rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.2, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then be put into by Guangzhou Chen Diao plant equipment Co., Ltd sell high-efficiency coating pot at temperature 32 DEG C dry 30min, transfer to again relative humidity be 38% dehumidifying between in, leave standstill 5.0h, carry out drying and increase crisp process, so obtain described cigarette capsule product.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.40% of 30min; Water absorption rate 0.48% at 60min: the water absorption rate 0.73% at 120min:
At the withstand voltage 1.41Kg of 30min; At the withstand voltage 1.49Kg of 60min; At the withstand voltage 1.62Kg of 120min.
Embodiment 4: the protection against the tide of cigarette capsule increases crisp process
The implementation step of this embodiment is as follows:
A, prepare cigarette capsule
By 1.5 weight portion carragheens and Arabic gum mixture (weight ratio 1:1) film forming agent, 0.5 parts by weight of glycerin and polyethylene glycol mixture (weight ratio 1:2) plasticizer, 0.3 weight portion algal polysaccharides and starch mixture (weight ratio 2:1) polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The first tobacco curing capsule allowing steps A obtain soaks 3 minutes in saturated potassium phosphate,monobasic saline solution, then takes out described cigarette capsule, then to be put in rotating cage at room temperature forced air drying 4.5 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
By 15 parts by weight acetic acid cellulose film forming agent, 5 weight portion polyethylene glycol and glycerol mixture (weight ratio 1:1) plasticizer, 5 weight account polyethylene alcohol and povidone mixture (weight ratio 3:1) stabilizing agent and be supplemented to 100 weight portion concentration and mix for 50% ethanol water by volume, obtain a kind of coating solution;
D, dressing
At temperature 26 DEG C, air quantity 280m in the high-efficiency coating pot sold by Guangzhou Chen Diao plant equipment Co., Ltd
3/ hr, hot blast temperature 35 DEG C are with under the condition of rotating speed 35rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.3, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 35min at temperature 36 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 35% dehumidifying between in, leave standstill 3.6h, carry out drying and increase crisp process, so obtain described cigarette capsule product.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.38% of 30min; Water absorption rate 0.50% at 60min: the water absorption rate 0.70% at 120min:
At the withstand voltage 1.51Kg of 30min; At the withstand voltage 1.50Kg of 60min; At the withstand voltage 1.67Kg of 120min.
Embodiment 5: the protection against the tide of cigarette capsule increases crisp process
The implementation step of this embodiment is as follows:
A, prepare cigarette capsule
By 1.2 weight portion Arabic gums and malt extract mixture (weight ratio 4:1) film forming agent, 0.2 weight portion polyethylene glycol and sorbitol mixture (weight ratio 1:3) plasticizer, 0.5 parts by weight Corn starch and pectin mixture (weight ratio 1:3) polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The first tobacco curing capsule allowing steps A obtain soaks 5 minutes in saturated magnesium nitrate saline solution, then takes out described cigarette capsule, then to be put in rotating cage at room temperature forced air drying 4.0 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
11 weight portion hydroxypropyl methylcelluloses and ethyl cellulose mixture (weight ratio 1:2) film forming agent, 3 parts by weight of glycerin and propylene glycol mixture (weight ratio 2:1) plasticizer, 2 weight account polyethylene alcohol and povidone mixture (weight ratio 1:1) stabilizing agent and the concentration that is supplemented to 100 weight portions are mixed for 60% ethanol water by volume, obtains a kind of coating solution;
D, dressing
At temperature 24 DEG C, air quantity 350m in the high-efficiency coating pot sold by Guangzhou Chen Diao plant equipment Co., Ltd
3/ hr, hot blast temperature 40 DEG C are with under the condition of rotating speed 40rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.2, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 32min at temperature 35 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 42% dehumidifying between in, leave standstill 4.5h, carry out drying and increase crisp process, so obtain described cigarette capsule product.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.38% of 30min; Water absorption rate 0.46% at 60min: the water absorption rate 0.68% at 120min:
At the withstand voltage 1.48Kg of 30min; At the withstand voltage 1.59Kg of 60min; At the withstand voltage 1.56Kg of 120min.
Embodiment 6: the protection against the tide of cigarette capsule increases crisp process
The implementation step of this embodiment is as follows:
A, prepare cigarette capsule
By 1.3 weight portion carragheens and malt extract mixture (weight ratio 2:1) film forming agent, 0.4 weight portion polyethylene glycol and sorbitol mixture (weight ratio 3:1) plasticizer, 0.3 weight portion algal polysaccharides and pectin mixture (weight ratio 1:1) polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The first tobacco curing capsule allowing steps A obtain soaks 2 minutes in saturated calcium nitrate saline solution, then takes out described cigarette capsule, then to be put in rotating cage at room temperature forced air drying 3.6 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
By 14 weight portion hydroxypropyl celluloses and cellulose acetate mixture (weight ratio 2:3) film forming agent, 3 weight portion polyethylene glycol and propylene glycol mixture (weight ratio 3:2) plasticizer, 4 weight portion polyethylene glycol and povidone mixture (weight ratio 1:1) stabilizing agent and be supplemented to 100 weight portion concentration by volume 70% ethanol water mix, obtain a kind of coating solution;
D, dressing
At temperature 30 DEG C, air quantity 310m in the high-efficiency coating pot sold by Guangzhou Chen Diao plant equipment Co., Ltd
3/ hr, hot blast temperature 25 DEG C are with under the condition of rotating speed 25rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.3, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 28min at temperature 32 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 44% dehumidifying between in, leave standstill 3.2h, carry out drying and increase crisp process, so obtain described cigarette capsule product.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.35% of 30min; Water absorption rate 0.44% at 60min: the water absorption rate 0.70% at 120min:
At the withstand voltage 1.43Kg of 30min; At the withstand voltage 1.53Kg of 60min; At the withstand voltage 1.58Kg of 120min.
Comparative example 1: the not moistureproof cigarette capsule increasing crisp process
Prepare just tobacco curing capsule according to the mode identical with embodiment 1 and to be put in the rotating cage sold by Guangzhou Chen Diao plant equipment Co., Ltd at room temperature forced air drying 4.2 hours, the cigarette capsule of the crisp process of moistureproof increasing described in obtaining.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.48% of 30min; Water absorption rate 0.58% at 60min: the water absorption rate 0.78% at 120min:
At the withstand voltage 1.66Kg of 30min; At the withstand voltage 1.79Kg of 60min; At the withstand voltage 1.85Kg of 120min.
Comparative example 2: the not moistureproof cigarette capsule increasing crisp process
Prepare just tobacco curing capsule according to the mode identical with embodiment 3 and to be put in the rotating cage sold by Guangzhou Chen Diao plant equipment Co., Ltd at room temperature forced air drying 4.5 hours, the cigarette capsule of the crisp process of moistureproof increasing described in obtaining.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.42% of 30min; Water absorption rate 0.53% at 60min: the water absorption rate 0.72% at 120min:
At the withstand voltage 1.53Kg of 30min; At the withstand voltage 1.72Kg of 60min; At the withstand voltage 1.79Kg of 120min.
Comparative example 3: the not moistureproof cigarette capsule increasing crisp process
Prepare just tobacco curing capsule according to the mode identical with embodiment 5 and to be put in the rotating cage sold by Guangzhou Chen Diao plant equipment Co., Ltd at room temperature forced air drying 4.5 hours, the cigarette capsule of the crisp process of moistureproof increasing described in obtaining.
The method described according to this description increases crisp cigarette capsule to the protection against the tide that the present embodiment obtains, and to measure its result as follows:
At the water absorption rate 0.51% of 30min; Water absorption rate 0.66% at 60min: the water absorption rate 0.84% at 120min:
At the withstand voltage 1.67Kg of 30min; At the withstand voltage 1.83Kg of 60min; At the withstand voltage 1.96Kg of 120min.
Contrasted by the result of implementation of above-described embodiment result of implementation and comparative example and know that cigarette capsule of the present invention protection against the tide increases fragility that crisp processing method can improve cigarette capsule and improves moisture effect.
Claims (8)
1. the protection against the tide of cigarette capsule increases a crisp processing method, it is characterized in that the step of the method is as follows:
A, prepare cigarette capsule
By 1 ~ 1.5 weight portion film forming agent, 0.1 ~ 0.5 parts by weight of plasticizer, 0.1 ~ 0.5 weight portion polysaccharide copolymer and be supplemented to 100 weight parts waters and mix, obtain without precipitation mixed liquor, take conventional dropping preparation method to prepare just tobacco curing capsule;
The capsule post processing of B, cigarette
The cigarette capsule allowing steps A obtain soaks 2 ~ 5 minutes in saturated aqueous metal salt, then takes out described capsule, then to be put in rotating cage at room temperature forced air drying 3.5 ~ 4.5 hours, obtains semi-finished product cigarette capsule;
C, prepare coating solution
By 10 ~ 15 weight portion film forming agents, 1 ~ 5 parts by weight of plasticizer, 1 ~ 5 weight portion stabilizing agent and be supplemented to 100 weight parts waters or ethanol water mixes, obtain a kind of coating solution;
D, dressing
At temperature 20 ~ 30 DEG C, air quantity 150 ~ 350m in high-efficiency coating pot
3/ hr, hot blast temperature 20 ~ 40 DEG C are with under the condition of rotating speed 20 ~ 40rpm, according to semi-finished product cigarette capsule and coating solution weight ratio 1:0.2 ~ 0.3, the coating solution obtained by step C is coated on the semi-finished product cigarette capsule that step B obtains, then dry 25 ~ 35min at temperature 30 ~ 40 DEG C is put in high-efficiency coating pot, transfer to again relative humidity be 35 ~ 45% dehumidifying between in, leave standstill 3 ~ 5h, carry out increasing crisp process, so obtain described cigarette capsule product.
2. protection against the tide according to claim 1 increases crisp processing method, and it is characterized in that in step, described film forming agent is that one or more are selected from the film forming agent of carragheen, Arabic gum or malt extract; Described plasticizer is that one or more are selected from the plasticizer of glycerine, polyethylene glycol or sorbierite; Described polysaccharide copolymer is that one or more are selected from the polysaccharide copolymer of algal polysaccharides, starch or pectin.
3. protection against the tide according to claim 1 increases crisp processing method, and it is characterized in that in stepb, described slaine is that one or more are selected from the slaine of sylvite, magnesium salts or calcium salt.
4. protection against the tide according to claim 3 increases crisp processing method, it is characterized in that described slaine is sulfate, nitrate, phosphate, carbonate or chloride.
5. protection against the tide according to claim 1 increases crisp processing method, and it is characterized in that in step C, described film forming agent is that one or more are selected from the film forming agent of hydroxypropyl methylcellulose, hydroxypropyl cellulose, ethyl cellulose or cellulose acetate; Described plasticizer is that one or more are selected from the plasticizer of polyethylene glycol, glycerine or propane diols; Described stabilizing agent is that one or more are selected from the stabilizing agent of polyethylene glycol, polyvinyl alcohol or PVP.
6. protection against the tide according to claim 1 increases crisp processing method, it is characterized in that in step C, and the concentration of described ethanol water is by volume 50 ~ 70%.
7. the protection against the tide that described in claim, the crisp processing method of moistureproof increasing obtains any one of claim 1-6 increases crisp cigarette capsule.
8. the protection against the tide according to claim 1-6 increases crisp cigarette capsule, it is characterized in that it has following characteristic:
At the water absorption rate 0.35 ~ 0.40% of 30min; Water absorption rate 0.41 ~ 0.52% at 60min: the water absorption rate 0.63 ~ 0.73% at 120min:
At the withstand voltage 1.41 ~ 1.51Kg of 30min; At the withstand voltage 1.49 ~ 1.59Kg of 60min; At the withstand voltage 1.52 ~ 1.67Kg of 120min.
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| CN106666822A (en) * | 2016-11-29 | 2017-05-17 | 将军烟草集团有限公司 | Cigarette blast bead and preparation method thereof |
| CN107616546A (en) * | 2017-08-30 | 2018-01-23 | 武汉黄鹤楼香精香料有限公司 | The preparation method of the quick-fried pearl lapping of cigarette |
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| CN112599422A (en) * | 2020-12-14 | 2021-04-02 | 电子科技大学 | High heat-resistant structure for heat dissipation of photoelectronic device and preparation method thereof |
| CN113583519A (en) * | 2021-08-13 | 2021-11-02 | 新火智造(深圳)有限公司 | Coating liquid for heating non-burning smoke cartridge and preparation method thereof |
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