CN105482505A - 苯胺甲基三乙氧基硅烷助剂 - Google Patents

苯胺甲基三乙氧基硅烷助剂 Download PDF

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CN105482505A
CN105482505A CN201510866147.3A CN201510866147A CN105482505A CN 105482505 A CN105482505 A CN 105482505A CN 201510866147 A CN201510866147 A CN 201510866147A CN 105482505 A CN105482505 A CN 105482505A
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ethanol
resin
anilinomethyl triethoxysilane
water
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黄景诚
李�杰
李安平
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    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/021—Calcium carbonates
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    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/021—Calcium carbonates
    • C09C1/022—Treatment with inorganic compounds
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
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    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06—Treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds

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Abstract

本发明的苯胺甲基三乙氧基硅烷助剂，由苯胺甲基三乙氧基硅烷15-28份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水350-400份组成；适合大规模生产，生产成本低等优点。

Description

苯胺甲基三乙氧基硅烷助剂
技术领域
本发明属于一种生产非金属粉体用的功能助剂。
背景技术
目前，碳酸钙已广泛应用于造纸、塑料、塑料薄膜、化纤、橡胶、胶粘剂、密封剂、日用化工、化妆品、建材、涂料、油漆、油墨、油灰、封蜡、腻子、毡层包装、医药、食品(如口香糖、巧克力)、饲料中，其作用有：增加产品体积、降低成本，改善加工性能(如调节粘度、流变性能、硫化性能)，提高尺寸稳定性，补强或半补强，提高印刷性能，提高物理性能(如耐热性、消光性、耐磨性、阻燃性、白度、光泽度)等；为获得更优越的性能，均采用助剂进行活化处理。
发明内容
本发明的目的在于；提出一种苯胺甲基三乙氧基硅烷助剂及其制备方法。
本发明的苯胺甲基三乙氧基硅烷助剂，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷15-28份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水350-400份组成。
本发明的苯胺甲基三乙氧基硅烷助剂的制备方法，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷15-28份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水350-400份组成；先用乙醇将松香铕树脂溶解，加入水350-400份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
本发明与现有技术相比其有益效果是：具有设计科学合理，工艺简单，安全可靠性，易于控制，操作方便，适合大规模生产，生产成本低等优点。
具体实施方式
下面结合实施例对本发明作进一步说明，但本发明的实施方式不限于此。
本发明的所有原料可购买获得。
实施例1，本发明的苯胺甲基三乙氧基硅烷助剂的制备，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷15-28份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水350-400份组成；先用乙醇将松香铕树脂溶解，加入水350-400份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
实施例2，本发明的苯胺甲基三乙氧基硅烷助剂的制备，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷15份，氨乙基丙氨丙基甲基甲氧基硅烷5份，二丙二醇单丁醚5份，季戊四醇松香铕树脂3份，椰子油脂肪酸二乙醇酰胺25份，碳酸钠5份，丙烯酸钠-4-乙烯基吡啶共聚物3份，氧化二辛基锡10份，聚乙烯醇缩醛树脂3份，十二烷基二甲基苄基溴化铵3份，乙醇20-30份，水350-400份组成；先用乙醇将松香铕树脂溶解，加入水350-400份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
实施例3，本发明的苯胺甲基三乙氧基硅烷助剂的制备，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷28份，氨乙基丙氨丙基甲基甲氧基硅烷6份，二丙二醇单丁醚8份，季戊四醇松香铕树脂8份，椰子油脂肪酸二乙醇酰胺30份，碳酸钠8份，丙烯酸钠-4-乙烯基吡啶共聚物5份，氧化二辛基锡12份，聚乙烯醇缩醛树脂5份，十二烷基二甲基苄基溴化铵5份，乙醇20-30份，水350-400份组成；先用乙醇将松香铕树脂溶解，加入水350-400份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
实施例4，本发明的苯胺甲基三乙氧基硅烷助剂的制备，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷28份，氨乙基丙氨丙基甲基甲氧基硅烷5份，二丙二醇单丁醚8份，季戊四醇松香铕树脂3份，椰子油脂肪酸二乙醇酰胺30份，碳酸钠5份，丙烯酸钠-4-乙烯基吡啶共聚物5份，氧化二辛基锡10份，聚乙烯醇缩醛树脂5份，十二烷基二甲基苄基溴化铵3份，乙醇20-30份，水350-400份组成；先用乙醇将松香铕树脂溶解，加入水350-400份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
本发明的产品，经生产厂商使用，生产改性超细重质碳酸钙功能产品，反应效果很好。
部分原料说明：
1、所述季戊四醇松香铕树脂，可优选按中国专利专利号为ZL201410078259.8的方法制得。
2、氨乙基丙氨丙基甲基甲氧基硅烷，实施例用南京旭杨化工有限公司产品，商品名：覆膜砂高效增强剂硅XY-812。
3、苯胺甲基三乙氧基硅烷，分子式：C6H5NHCH2Si(OC2H5)3。

Claims (2)

1.一种苯胺甲基三乙氧基硅烷助剂，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷15-28份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水350-400份组成。
2.一种苯胺甲基三乙氧基硅烷助剂的制备方法，其特征在于：以重量计，其配方由苯胺甲基三乙氧基硅烷15-28份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水350-400份组成；先用乙醇将松香铕树脂溶解，加入水350-400份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
CN201510866147.3A 2015-11-29 2015-11-29 苯胺甲基三乙氧基硅烷助剂 Pending CN105482505A (zh)

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Application publication date: 20160413