CN105602419B - 一种斑纹效果的美术型粉末涂料及其制备方法 - Google Patents

一种斑纹效果的美术型粉末涂料及其制备方法 Download PDF

Info

Publication number
CN105602419B
CN105602419B CN201610094744.3A CN201610094744A CN105602419B CN 105602419 B CN105602419 B CN 105602419B CN 201610094744 A CN201610094744 A CN 201610094744A CN 105602419 B CN105602419 B CN 105602419B
Authority
CN
China
Prior art keywords
powder
polyester resin
raw material
preparation
mixed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610094744.3A
Other languages
English (en)
Other versions
CN105602419A (zh
Inventor
苏捷
林琳艺
黄文�
黄溪福
陈家兴
陈冠军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Wanan Industrial Group Co. Ltd.
Original Assignee
FUJIAN WANAN INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUJIAN WANAN INDUSTRY Co Ltd filed Critical FUJIAN WANAN INDUSTRY Co Ltd
Priority to CN201610094744.3A priority Critical patent/CN105602419B/zh
Publication of CN105602419A publication Critical patent/CN105602419A/zh
Application granted granted Critical
Publication of CN105602419B publication Critical patent/CN105602419B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03—Powdery paints
    • C09D5/032—Powdery paints characterised by a special effect of the produced film, e.g. wrinkle, pearlescence, matt finish
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06—Artists' paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明属于粉末涂料的制备领域，具体涉及一种斑纹效果的美术型粉末涂料及其制备方法。该涂料由A粉、B粉和珠光粉按重量比90:5:5混合制得；所述的A粉由以下原料组成：环氧树脂40wt%，端羧基聚酯树脂40wt%，沉淀硫酸钡5wt%，醋酸丁酸纤维素0.2wt%，钛白粉14wt%，炭黑0.8 wt%；所述的B粉由以下原料组成：端羟基聚酯树脂90wt%，颜料5wt%，聚醚聚合物5wt%。所制得的涂料耐候性好，附着力明显提高，明显降低了涂层擦拭时的颜料颗粒脱落现象，产品质量品质得到全面提升。

Description

一种斑纹效果的美术型粉末涂料及其制备方法
技术领域
本发明属于粉末涂料的制备领域，具体涉及一种斑纹效果的美术型粉末涂料及其制备方法。
背景技术
美术型粉末涂料是粉末涂料的重要品种之一，目前美术型粉末涂料主要有砂皱、橘纹、锤纹、浮花、闪光、金属色等种类，其中斑纹粉末涂料则以优选的外观视感、突出的凹凸触感、优异的物理机械性能以及良好的遮盖效果不断获得人们的青睐。
然而在斑纹粉末涂料的应用中发现，斑纹涂膜还存在明显的抹擦掉色现象，这是由于纹理颜料与基料树脂润湿先天不足造成的，即使是采用热混工艺生产的产品也无法消除。
发明内容
本发明的目的在于针对现有技术的不足，提供一种斑纹效果的美术型粉末涂料及其制备方法。该粉末涂料由以环氧树脂/端羧基聚酯树脂为主要原料的A组分以及以端羟基聚酯树脂为主要原料的B组分通过热粘合工艺制成，对原料之间的配比进行了优选，提高了原料之间的分散性，耐候性好，附着力明显提高，明显降低了涂层擦拭时的颜料颗粒脱落现象，产品质量品质得到全面提升。
为实现上述目的，本发明采用如下技术方案：
一种斑纹效果的美术型粉末涂料，由A粉、B粉和珠光粉按重量比90:5:5混合制得；
所述的A粉由以下原料组成：环氧树脂40wt%，端羧基聚酯树脂40wt%，沉淀硫酸钡5wt%，醋酸丁酸纤维素0.2wt%，钛白粉14wt%，炭黑0.8 wt%；
所述的B粉由以下原料组成：端羟基聚酯树脂90wt%，颜料5wt%，聚醚聚合物5wt%。
所述聚醚聚合物为聚氧化丙烯二醇或聚氧乙烯中的一种。
一种制备如上所述的斑纹效果的美术型粉末涂料的方法，包括以下步骤：
1）将环氧树脂、端羧基聚酯树脂、沉淀硫酸钡、醋酸丁酸纤维素、钛白粉和炭黑经混合、挤出、压片破碎、磨粉筛分，制得A粉；
2）将端羟基聚酯树脂、颜料和聚醚聚合物经混合、挤出、压片破碎、磨粉筛分，制得B粉；
3）将A粉、B粉和珠光粉按重量比加入混合机中，进行干混、热粘合（55℃）处理，当粘结过程完成时，经高速混合均匀后立即出料、筛分。
本发明的有益效果在于：
1）该粉末涂料由以环氧树脂/端羧基聚酯树脂为主要原料的A组分以及以端羟基聚酯树脂为主要原料的B组分通过热粘合工艺制成，提高了原料之间的分散性，耐候性好，附着力明显提高，明显降低了涂层擦拭时的颜料颗粒脱落现象，产品质量品质得到全面提升；
2）本发明对该粉末涂料原料的配方进行了反复研究，最终确定了最佳配比，在该配比上，粉末涂料在应用时，凹凸触感突出，耐候性好，附着力明显比其他配比时高，经擦拭测试时完全没有抹擦掉色现象；而当改变配比时，均有一定程度的少量抹擦掉色现象。
具体实施方式
本发明用下列实施例来进一步说明本发明，但本发明的保护范围并不限于下列实施例。
实施例1
一种斑纹效果的美术型粉末涂料，由A粉、B粉和珠光粉按重量比90:5:5混合制得；
所述的A粉由以下原料组成：环氧树脂40wt%，端羧基聚酯树脂40wt%，沉淀硫酸钡5wt%，醋酸丁酸纤维素0.2wt%，钛白粉14wt%，炭黑0.8 wt%；
所述的B粉由以下原料组成：端羟基聚酯树脂90wt%，颜料5wt%，聚醚聚合物5wt%。
所述聚醚聚合物为聚氧化丙烯二醇。
一种制备如上所述的斑纹效果的美术型粉末涂料的方法，包括以下步骤：
1）将环氧树脂、端羧基聚酯树脂、沉淀硫酸钡、醋酸丁酸纤维素、钛白粉和炭黑经混合、挤出、压片破碎、磨粉筛分，制得A粉；
2）将端羟基聚酯树脂、颜料和聚醚聚合物经混合、挤出、压片破碎、磨粉筛分，制得B粉；
3）将A粉、B粉和珠光粉按重量比加入混合机中，进行干混、热粘合（温度55℃）处理，当粘结过程完成时，经高速混合均匀后立即出料、筛分。
以上所述仅为本发明的较佳实施例，凡依本发明申请专利范围所做的均等变化与修饰，皆应属本发明的涵盖范围。

Claims (1)

1.一种斑纹效果的美术型粉末涂料的制备方法，其特征在于：所述的粉末涂料由A粉、B粉和珠光粉按重量比90:5:5混合制得；
所述的A粉由以下原料组成：环氧树脂40wt%，端羧基聚酯树脂40wt%，沉淀硫酸钡5wt%，醋酸丁酸纤维素0.2wt%，钛白粉14wt%，炭黑0.8 wt%；
所述的B粉由以下原料组成：端羟基聚酯树脂90wt%，颜料5wt%，聚醚聚合物5wt%；所述聚醚聚合物为聚氧化丙烯二醇或聚氧乙烯中的一种；
制备方法包括以下步骤：
1）将环氧树脂、端羧基聚酯树脂、沉淀硫酸钡、醋酸丁酸纤维素、钛白粉和炭黑经混合、挤出、压片破碎、磨粉筛分，制得A粉；
2）将端羟基聚酯树脂、颜料和聚醚聚合物经混合、挤出、压片破碎、磨粉筛分，制得B粉；
3）将A粉、B粉和珠光粉按重量比加入混合机中，进行干混、在55℃热粘合处理，当粘结过程完成时，经高速混合均匀后立即出料、筛分。
CN201610094744.3A 2016-02-22 2016-02-22 一种斑纹效果的美术型粉末涂料及其制备方法 Active CN105602419B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610094744.3A CN105602419B (zh) 2016-02-22 2016-02-22 一种斑纹效果的美术型粉末涂料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610094744.3A CN105602419B (zh) 2016-02-22 2016-02-22 一种斑纹效果的美术型粉末涂料及其制备方法

Publications (2)

Publication Number Publication Date
CN105602419A CN105602419A (zh) 2016-05-25
CN105602419B true CN105602419B (zh) 2017-11-17

Family

ID=55982791

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610094744.3A Active CN105602419B (zh) 2016-02-22 2016-02-22 一种斑纹效果的美术型粉末涂料及其制备方法

Country Status (1)

Country Link
CN (1) CN105602419B (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497320A (zh) * 2016-10-18 2017-03-15 浙江捷宇新材料科技股份有限公司 一种点花扩散型粉末涂料及其制备方法
CN106833293A (zh) * 2017-03-16 2017-06-13 苏州新富捷自动化科技有限公司 一种耐磨涂料及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1311036C (zh) * 2004-07-02 2007-04-18 徐州正菱涂装有限公司 斑纹效果的美术型粉末涂料
EP1978064A1 (en) * 2007-04-04 2008-10-08 DuPont Powder Coatings Ibérica, S.L. Powder coating composition
CN102533064A (zh) * 2010-12-24 2012-07-04 管静 一种粉末涂料
CN103642290A (zh) * 2013-11-29 2014-03-19 六安市捷通达化工有限责任公司 一种金属效果粉末涂料的制备方法
CN104194577A (zh) * 2014-09-05 2014-12-10 晁兵 斑纹粉末涂料及其制备方法

Also Published As

Publication number Publication date
CN105602419A (zh) 2016-05-25

Similar Documents

Publication Publication Date Title
CN102746768B (zh) 水性彩色玻璃涂料及其制备方法与应用
CN105602419B (zh) 一种斑纹效果的美术型粉末涂料及其制备方法
CN105238115A (zh) 水粉颜料及其制备方法
CN104987776A (zh) 一种环保涂料及其制备方法
CN103709918B (zh) 抗刮耐候的聚氨酯pu亮光黑面漆
CN106189620B (zh) 一种改性二氧化钛及其在户外pvc木塑制品喷涂中的应用
CN104151961B (zh) 一种纳米改性聚醋酸乙烯-丙烯酸建筑外墙乳胶漆
CN105714996A (zh) 超耐候性建筑外墙漆膜壁布及其制作工艺
CN105238185A (zh) 一种抗剥离木器涂料及其制备方法
JP2011213764A (ja) フライアッシュバルーンの白色度向上方法、並びに被覆フライアッシュバルーン及びその製造方法
CN104073119A (zh) 用于路面标识的标注涂料和制备方法
CN105440904A (zh) 一种高吸附性聚酯粉末涂料及其制作方法
CN106349761A (zh) 一种耐磨性复合碳酸钙及其制备方法
CN105368093A (zh) 异丙基三(二辛基磷酸酰氧基)钛酸酯非金属粉体活化剂
CN108641518A (zh) 一种外墙乳胶漆
CN105368074A (zh) 双乙撑钛酸酯粉体改性剂
CN104446205B (zh) 一种常温可固化工艺粘土及其制备方法
CN105367962A (zh) 双-(γ-三乙氧基硅基丙基)四硫化物粉体改性剂
CN107033782A (zh) 一种木制品表面做旧后耐腐透明涂层及其制备方法
CN106243780A (zh) 一种耐老化性复合碳酸钙及其制备方法
CN106349759A (zh) 一种耐高温复合碳酸钙及其制备方法
CN105482329A (zh) 二硬脂酰氧异丙氧基铝酸酯助剂
CN106380894A (zh) 非金属粉体助剂
CN105367963A (zh) 三异硬酯酸钛酸异丙酯非金属粉体活化剂
CN105440910A (zh) 一种环保型防腐聚酯粉末涂料及其制作方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 363000 Fujian city of Zhangzhou Province Shi Ting Industrial Zone, Nanshan Scenic Area

Patentee after: Fujian Wanan Industrial Group Co. Ltd.

Address before: 363000 Fujian city of Zhangzhou Province Shi Ting Industrial Zone, Nanshan Scenic Area

Patentee before: Fujian Wanan Industry Co., Ltd.