CN105481474A - Preparation method for glaze applicable to both high-expansion and low-expansion ceramic materials - Google Patents

Preparation method for glaze applicable to both high-expansion and low-expansion ceramic materials Download PDF

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Publication number
CN105481474A
CN105481474A CN201510807257.2A CN201510807257A CN105481474A CN 105481474 A CN105481474 A CN 105481474A CN 201510807257 A CN201510807257 A CN 201510807257A CN 105481474 A CN105481474 A CN 105481474A
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CN
China
Prior art keywords
expansion
glaze
low
ceramic body
expansion ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510807257.2A
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Chinese (zh)
Inventor
李晓婷
袁家俭
施小罗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUNAN JIASHENG ELECTRIC CERAMIC NEW MATERIALS CO Ltd
Original Assignee
HUNAN JIASHENG ELECTRIC CERAMIC NEW MATERIALS CO Ltd
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Publication date
Application filed by HUNAN JIASHENG ELECTRIC CERAMIC NEW MATERIALS CO Ltd filed Critical HUNAN JIASHENG ELECTRIC CERAMIC NEW MATERIALS CO Ltd
Priority to CN201510807257.2A priority Critical patent/CN105481474A/en
Publication of CN105481474A publication Critical patent/CN105481474A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5037Clay, Kaolin
    • C04B41/504Engobes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2205/00Compositions applicable for the manufacture of vitreous enamels or glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a self-adaptive glaze applicable to both high-expansion and low-expansion ceramic materials. The glaze is characterized by its ultra-high adaptability; i.e., the glaze presents itself as a low-expansion matt glaze with a matching expansion coefficient when applied to an ultra-low-expansion ceramic body and as a high-expansion shining glaze with a matching expansion coefficient when applied to a high-expansion ceramic body like a domestic ceramic. A preparation method for the glaze comprises the following steps: subjecting the glaze to wet-process ball milling and sieving with a 400-mesh screen; adjusting the specific gravity of glaze slip to a range of 1.5 to 1.6 g/cm3; then impregnating the ultra-low-expansion ceramic body or high-expansion domestic ceramic body with the glaze slip; and carrying out sintering at 1260 to 1280 in an oxidation atmosphere. The self-adaptive glaze applicable to both high-expansion and low-expansion ceramic materials prepared by using the method has the characteristics of a unique style, adaptability to two ceramics with substantially different expansion coefficients, easily controllable process and a wide sintering range.

Description

A kind of high and all spendable glaze preparation method for material of expansion ceramic material
technical field:
The present invention relates to the technology for producing field of super-low expansion pottery and domestic ceramics and glaze that both are suitable for, be specifically related to a kind of high with all spendable glaze preparation method for material of expansion ceramic material.
background technology:
Be used in current industry super-low expansion ceramic body presents be the coefficient of expansion coupling low bulk dumb light microcrystalline glaze, and be used in be similar to domestic ceramics relatively high expansion ceramic base substrate on present be the coefficient of expansion coupling height expansion light glaze, two kinds of glaze are diverse systems, the height light glaze that expands to be executed and on super-low expansion ceramic body, to be there will be the coefficient of expansion do not mate and glaze occurs and split phenomenon with existing technology, in household ceramic blank, also there will be the coefficient of expansion do not mate if low bulk dumb light microcrystalline glaze is executed and base glaze peeling occurs.
Heat-stable ceramic meal needs the lid surface last layer glaze at crockery, has serious in coloured glaze, strictly, noble, graceful, the style of light, and lid is also without the need to heat-resisting available common household china material.If have a kind of glaze energy simultaneous adaptation in production without the need to the heat-resisting lid of common household china material and the pot body of super-low expansion material, so just can simplify production distribution, enamel frit makeing system shares set of system, from outward appearance, production and cost, all bring very large benefit.Glaze prepared by method of the present invention is a kind of high and all spendable self-adaptation glaze of expansion ceramic material.
summary of the invention:
A kind of high and all spendable glaze preparation method for material of expansion ceramic material, the coefficient of expansion of described high expansion ceramic material is 40-60 × 10 -7/ DEG C, the coefficient of expansion of described expansion ceramic material is 5-20 × 10 -7/ DEG C, comprise
(1) preparation of glaze slip
Glaze component is weighed according to following ratio: petalite 70 ~ 75%, triphane 3 ~ 6%, quartz 3 ~ 8%, talcum 5 ~ 10%, kaolin 3 ~ 7%, barium carbonate 2 ~ 4%, Strontium carbonate powder 0 ~ 1%.
(2) ball milling enamel frit makeing
Wet ball grinding: material: ball: water=1:2:0.5.
Granularity: D97 controls to cross 400 mesh sieves at 17 ~ 20 μ.
Slurry proportion: 1.5 ~ 1.6g/cm 3.
(3) glazing
Be immersed in respectively by glaze slip on the household china ceramic body of super-low expansion ceramic body or relatively high expansion, gauge control is at 0.3mm ~ 0.6mm.
(4) burn till
Form sintering under the atmosphere of the 1260 DEG C ~ 1280 DEG C of temperature range oxydizing flame in roller kiln of the sample after glazing.
Height prepared by method provided by the invention and all spendable self-adaptation glaze of expansion ceramic material have unique style, and differ great two kinds of coefficients of expansion pottery all energy self-adaptations, technique easily controls, the feature that sintering range is wide.
embodiment:
Below in conjunction with specific embodiment, specifically set forth the present invention, these examples only for illustration of the present invention, and are not used in restriction use range of the present invention.
Embodiment 1
(1) preparation of glaze slip
Glaze component is weighed according to following ratio: petalite 73%, triphane 5%, quartz 4%, talcum 7%, kaolin 6%, barium carbonate 4%, Strontium carbonate powder 1%
(2) ball milling enamel frit makeing
Wet ball grinding: material: ball: water=1:2:0.5.
Granularity: D97 crosses 400 mesh sieves at 17 ~ 20 μ.
Slurry proportion: 1.5 ~ 1.6g/cm 3.
(3) glazing
Be immersed in by glaze slip on the household china ceramic body of super-low expansion ceramic body or relatively high expansion respectively, the coefficient of expansion of described high expansion ceramic material is 40-60 × 10 -7/ DEG C, the coefficient of expansion of described expansion ceramic material is 5-20 × 10 -7/ DEG C, gauge control is at 0.3mm ~ 0.6mm.
(4) burn till
Form sintering under the atmosphere of the 1260 DEG C ~ 1280 DEG C of temperature range oxydizing flame in roller kiln of the sample after glazing.

Claims (2)

1. a high glaze preparation method for material all spendable with expansion ceramic material, the coefficient of expansion of described high expansion ceramic material is 40-60 × 10 -7/ DEG C, the coefficient of expansion of described expansion ceramic material is 5-20 × 10 -7/ DEG C, it is characterized in that, comprise glaze wet ball grinding, cross 400 eye mesh screens, regulate glaze slip proportion at 1.5 ~ 1.6g/cm 3scope in, then glaze slip is immersed on low expansion ceramic body or the high household china ceramic body expanded, under the scope internal oxidition atmosphere of 1260 ~ 1280 DEG C, is fired into sample.
2. a kind of high and all spendable glaze preparation method for material of expansion ceramic material according to claim 1, it is characterized in that, described glaze compositions in weight percentage comprises as follows: petalite 70 ~ 75%, triphane 3 ~ 6%, quartz 3 ~ 8%, talcum 5 ~ 10%, kaolin 3 ~ 7%, barium carbonate 2 ~ 4%, Strontium carbonate powder 0 ~ 1%.
CN201510807257.2A 2015-11-22 2015-11-22 Preparation method for glaze applicable to both high-expansion and low-expansion ceramic materials Pending CN105481474A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510807257.2A CN105481474A (en) 2015-11-22 2015-11-22 Preparation method for glaze applicable to both high-expansion and low-expansion ceramic materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510807257.2A CN105481474A (en) 2015-11-22 2015-11-22 Preparation method for glaze applicable to both high-expansion and low-expansion ceramic materials

Publications (1)

Publication Number Publication Date
CN105481474A true CN105481474A (en) 2016-04-13

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107382069A (en) * 2017-07-20 2017-11-24 景德镇陶瓷大学 A kind of inexpensive low expansion ceramic is without zirconia enamel and preparation method thereof
WO2017206413A1 (en) * 2016-06-01 2017-12-07 李勇德 Low expansion ceramic barbecue mesh and manufacturing method thereof
CN108585499A (en) * 2018-08-02 2018-09-28 张家港市六福新材料科技有限公司 A kind of preparation method of low expansion ceramic glaze
CN108726878A (en) * 2017-04-24 2018-11-02 佛山市顺德区美的电热电器制造有限公司 A kind of high cold-resistant thermal shock ceramic glaze, ceramic body and preparation method thereof
CN109354405A (en) * 2018-09-30 2019-02-19 湖南益嘉瓷业有限公司 Dumb light streak glaze and preparation method thereof
CN109796132A (en) * 2017-11-16 2019-05-24 佛山市顺德区美的电热电器制造有限公司 Fine and close glaze coating and fine and close glaze layer and compound glaze layer and composite guide magnetosphere and ceramic cooker and culinary art equipment
CN110028243A (en) * 2019-04-22 2019-07-19 江西嘉顺瓷业有限公司 A kind of parian glaze heat resisting porcelain formula and preparation method thereof
CN110386758A (en) * 2018-04-18 2019-10-29 佛山市顺德区美的电热电器制造有限公司 IH ceramic pan and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017206413A1 (en) * 2016-06-01 2017-12-07 李勇德 Low expansion ceramic barbecue mesh and manufacturing method thereof
CN108726878A (en) * 2017-04-24 2018-11-02 佛山市顺德区美的电热电器制造有限公司 A kind of high cold-resistant thermal shock ceramic glaze, ceramic body and preparation method thereof
CN108726878B (en) * 2017-04-24 2021-09-21 佛山市顺德区美的电热电器制造有限公司 High-thermal-shock-resistant ceramic glaze, ceramic body and preparation method thereof
CN107382069A (en) * 2017-07-20 2017-11-24 景德镇陶瓷大学 A kind of inexpensive low expansion ceramic is without zirconia enamel and preparation method thereof
CN107382069B (en) * 2017-07-20 2019-11-05 景德镇陶瓷大学 It is a kind of low cost low expansion ceramic without zirconia enamel and preparation method thereof
CN109796132A (en) * 2017-11-16 2019-05-24 佛山市顺德区美的电热电器制造有限公司 Fine and close glaze coating and fine and close glaze layer and compound glaze layer and composite guide magnetosphere and ceramic cooker and culinary art equipment
CN110386758A (en) * 2018-04-18 2019-10-29 佛山市顺德区美的电热电器制造有限公司 IH ceramic pan and preparation method thereof
CN108585499A (en) * 2018-08-02 2018-09-28 张家港市六福新材料科技有限公司 A kind of preparation method of low expansion ceramic glaze
CN109354405A (en) * 2018-09-30 2019-02-19 湖南益嘉瓷业有限公司 Dumb light streak glaze and preparation method thereof
CN110028243A (en) * 2019-04-22 2019-07-19 江西嘉顺瓷业有限公司 A kind of parian glaze heat resisting porcelain formula and preparation method thereof

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Application publication date: 20160413

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